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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Direct Synthesis of Highly Siliceous ZnO-FAU Zeolite with Enhanced Performance in Hydrocarbon Cracking Reactions

The hydrothermal stability and catalytic activity of zeolite Y (faujasite, FAU) is highly dependent on its composition. High silicon content is often desirable for catalytic applications; however, direct synthesis of faujasite with high silicon content (Si/Al > 2.5) is nontrivial. Here, we present an organic-free synthesis of FAU-type zeolite with Si/Al = 3.4 using zinc oxide as a modifier. A combination of spectroscopy and microscopy confirm that ZnO is well-distributed within zeolite pores as extra-framework species, and the nature of these species differs from bulk ZnO and framework zinc in Zn-FAU crystals. We demonstrate that the increased Si/Al ratio leads to improved hydrothermal stability, while catalytic cracking of 1-hexene and cumene show that ZnO-FAU exhibits significantly longer lifetime compared to in-house and commercial zeolite Y. Collectively, this study presents a facile and efficient method to prepare more siliceous FAU with enhanced catalytic performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Performance Enhancements Under Dual-task Conditions

Research on dual-task performance has been concerned with delineating the antecedent conditions which lead to dual-task decrements. Capacity models of attention, which propose that a hypothetical resource structure underlies performance, have been employed as predictive devices. These models predict that tasks which require different processing resources can be more successfully time shared than tasks which require common resources. The conditions under which such dual-task integrality can be fostered were assessed in a study in which three factors likely to influence the integrality between tasks were manipulated: inter-task redundancy, the physical proximity of tasks and the task relevant objects. Twelve subjects participated in three experimental sessions in which they performed both single and dual-tasks. The primary task was a pursuit step tracking task. The secondary tasks required the discrimination between different intensities or different spatial positions of a stimulus. The results are discussed in terms of a model of dual-task integrality.

Kramer, A. F.↗
NASA NTRS1995

Dual Wall Angles Would Enhance Performance Of A Solar Pond

Proposed dual-angle design for Sun-facing wall of solar pond enhances solar-energy-storage performance of pond; increase in performance over that of similar pond with conventional (single-angle) wall estimated to be 25 percent. Design compromises between maximizing heating and minimizing convection. Top part of Sun-facing wall optimized for top colder layer of water, less tendency toward convective mixing. Bottom part of wall optimized for bottom, warmer layer of water, greater tendency towards convection. Optimization involves consideration of both anticipated temperature-vs.-depth profile (affects tendency toward convection) and latitude (affects angle of incidence of solar radiation and rate of heating).

Noever, David A.↗
DOE OSTI2020

Geomancy: Automated Performance Enhancement through Data Layout Optimization

Large distributed storage systems such as high- performance computing (HPC) systems used by national or international laboratories require sufficient performance and scale for demanding scientific workloads and must handle shifting workloads with ease. Ideally, data is placed in locations to optimize performance, but the size and complexity of large storage systems inhibit rapid effective restructuring of data layouts to maintain performance as workloads shift. To address these issues, we have developed Geomancy, a tool that models the placement of data within a distributed storage system and reacts to drops in performance. Using a combination of machine learning techniques suitable for temporal modeling, Geomancy determines when and where a bottleneck may happen due to changing workloads and suggests changes in the layout that mitigate or prevent them. Our approach to optimizing throughput offers benefits for storage systems such as avoiding potential bottlenecks and increasing overall I/O throughput from 11% to 30%.

Bel, Oceane M.↗
NASA NTRS2022

Low-Speed Performance Enhancement Using Localized Active Flow Control: Localized Active Flow Control Simulations on a Reference Aircraft (2/4)

A study of the potential implementations of localized active flow control (AFC) technology onto future airplanes is presented. This collaborative investigation addresses key objectives of the NASA Advanced Air Transport Technology (AATT) Project, in terms of reduction in fuel consumption and lower emission. It specifically targets the goals set forth in a roadmap developed by the NASA/Boeing team. The roadmap is a result of a series of meetings held between the two parties over the years and it represents a shared vision for practical implementations, leading up to flight demonstrations of localized flow control. If successful, localized flow control may lead to important ramifications for next generation airplanes from both the economic and environmental perspectives. Under this contract localized AFC has been used to improve aerodynamic performance during high-lift operations using Computational Fluid Dynamics (CFD). Specifically, AFC has been applied at the aileron and at various location in the wing leading edge (LE) regions. The applications target reduced drag and enhanced lift over the range of practical angles of attack, including stall. These benefits translate to airplane performance improvements, such as longer range or larger payload. The CFD results are used to quantify potential aerodynamic benefits, as well as the input required for actuation. This helps identify the most promising candidates, which potentially provide material net airplane level enhancements using onboard fluidic sources. The airplane configuration selected for the CFD study is a representative of a future short/medium-range twin-engine airplane dubbed the Reference Aircraft. A slew of AFC applications has been explored and their aerodynamic performance enhancements were benchmarked against the baseline Reference Aircraft. Promising AFC candidates have been deemed practical and potentially suitable for both the aileron and the wing LE implementations. The findings on the Reference Aircraft are used to guide the development of the AFC-enhanced aileron for the CRM-HL. The wind-tunnel model of the CRM-HL will be used by NASA to validate the AFC concepts, complementing the CFD-based analysis and the integration study (final report document #3).

CFD↗
NASA NTRS2013

Performance Enhancement of a Vertical Tail Model with Sweeping Jet Actuators

Active Flow Control (AFC) experiments performed at the Caltech Lucas Adaptive Wall Wind Tunnel on a 12%-thick, generic vertical tail model indicated that sweeping jets emanating from the trailing edge (TE) of the vertical stabilizer significantly increased the side force coefficient for a wide range of rudder deflection angles and yaw angles at free-stream velocities approaching takeoff rotation speed. The results indicated that 2% blowing momentum coefficient (C(sub mu) increased the side force in excess of 50% at the maximum conventional rudder deflection angle in the absence of yaw. Even C(sub mu) = 0.5% increased the side force in excess of 20% under these conditions. This effort was sponsored by the NASA Environmentally Responsible Aviation (ERA) project and the successful demonstration of this flow-control application could have far reaching implications. It could lead to effective applications of AFC technologies on key aircraft control surfaces and lift enhancing devices (flaps) that would aid in reduction of fuel consumption through a decrease in size and weight of wings and control surfaces or a reduction of the noise footprint due to steeper climb and descent.

Seele, Roman↗
DOE OSTI2022

Facile Dual-Protection Layer and Advanced Electrolyte Enhancing Performances of Cobalt-free/Nickel-rich Cathodes in Lithium-Ion Batteries

Despite cobalt (Co)-free/nickel (Ni)-rich layered oxides being considered as one of the promising cathode materials due to their high specific capacity, their highly reactive surface is one of the shortcomings that still hinder their practical usages in high-energy-density batteries. Herein, a polyimide/polyvinylpyrrolidone (PI/PVP, denoted as PP) coating layer is demonstrated as dual-protection for LiNi 0.96 Mg 0.02 Ti 0.02 O 2 (NMT) cathode material to suppress surface contamination against moisty air and to prevent unwanted side reactions between cathode and electrolyte during electrochemical cycling. The optimal PP-coated NMT (PP@NMT) preserves a clean surface without generation of lithium (Li) residues, structural degradation, and gas evolution after exposure to air with ~30% humidity for 2 weeks. Contrarily, the exposed bare NMT shows severe contamination, structural shrinkage due to Li loss, and increased gas release during charging. In addition, the exposed PP@NMT significantly enhances the electrochemical performance of graphite (Gr)||NMT cells by decreasing byproducts and maintaining structural stability. Moreover, the exposed PP@NMT achieves a high capacity retention of 86.7% after 500 cycles in Gr||NMT cells using an advanced localized high-concentration electrolyte. Furthermore, this work demonstrates a promising facile approach to the protection of Co-free/Ni-rich layered cathodes for their practical applications even after exposure to moisty air.

25 ENERGY STORAGE↗
DOE OSTI2021

Tuning the electronic structure of Ag-Pd alloys to enhance performance for alkaline oxygen reduction

Alloying is a powerful tool that can improve the electrocatalytic performance and viability of diverse electrochemical renewable energy technologies. Herein, we enhance the activity of Pd-based electrocatalysts via Ag-Pd alloying while simultaneously lowering precious metal content in a broad-range compositional study focusing on highly comparable Ag-Pd thin films synthesized systematically via electron-beam physical vapor co-deposition. Cyclic voltammetry in 0.1 M KOH shows enhancements across a wide range of alloys; even slight alloying with Ag (e.g. Ag 0.1 Pd 0.9 ) leads to intrinsic activity enhancements up to 5-fold at 0.9 V vs. RHE compared to pure Pd. Based on density functional theory and x-ray absorption, we hypothesize that these enhancements arise mainly from ligand effects that optimize adsorbate–metal binding energies with enhanced Ag-Pd hybridization. This work shows the versatility of coupled experimental-theoretical methods in designing materials with specific and tunable properties and aids the development of highly active electrocatalysts with decreased precious-metal content.

25 ENERGY STORAGE↗
NASA NTRS2011

High-Temperature Smart Structures for Engine Noise Reduction and Performance Enhancement

One of key NASA goals is to develop and integrate noise reduction technology to enable unrestricted air transportation service to all communities. One of the technical priorities of this activity has been to account for and reduce noise via propulsion/airframe interactions, identifying advanced concepts to be integrated with the airframe to mitigate these noise-producing mechanisms. An adaptive geometry chevron using embedded smart structures technology offers the possibility of maximizing engine performance while retaining and possibly enhancing the favorable noise characteristics of current designs. New high-temperature shape memory alloy (HTSMA) materials technology enables the devices to operate in both low-temperature (fan) and high-temperature (core) exhaust flows. Chevron-equipped engines have demonstrated reduced noise in testing and operational use. It is desirable to have the noise benefits of chevrons in takeoff/landing conditions, but have them deployed into a minimum drag position for cruise flight. The central feature of the innovation was building on rapidly maturing HTSMA technology to implement a next-generation aircraft noise mitigation system centered on adaptive chevron flow control surfaces. In general, SMA-actuated devices have the potential to enhance the demonstrated noise reduction effectiveness of chevron systems while eliminating the associated performance penalty. The use of structurally integrated smart devices will minimize the mechanical and subsystem complexity of this implementation. The central innovations of the effort entail the modification of prior chevron designs to include a small cut that relaxes structural stiffness without compromising the desired flow characteristics over the surface; the reorientation of SMA actuation devices to apply forces to deflect the chevron tip, exploiting this relaxed stiffness; and the use of high-temperature SMA (HTSMA) materials to enable operation in the demanding core chevron environment. The overall conclusion of these design studies was that the cut chevron concept is a critical enabling step in bringing the variable geometry core chevron within reach. The presence of the cut may be aerodynamically undesirable in some respects, but it is present only when the chevron is not immersed in the core jet exhaust. When deployed, the gap closes as the chevron tip enters the high-speed, high-temperature core stream. Aeroacoustic testing and flow visualization support the contention that this cut is inconsequential to chevron performance.

Quackenbush, Todd R.↗
DOE OSTI2021

Advanced Nanocarbons for Enhanced Performance and Durability of Platinum Catalysts in Proton Exchange Membrane Fuel Cells

Insufficient stability of current carbon supported Pt and Pt alloy catalysts is a significant barrier for proton-exchange membrane fuel cells (PEMFCs). As a primary degradation cause to trigger Pt nanoparticle migration, dissolution, and aggregation, carbon corrosion remains a significant challenge. Compared with enhancing Pt and PtM alloy particle stability, improving support stability is rather challenging due to carbon's thermodynamic instability under fuel cell operation. In recent years, significant efforts have been made to develop highly durable carbon-based supports concerning innovative nanostructure design and synthesis along with mechanistic understanding. Here, this review critically discusses recent progress in developing carbon-based materials for Pt catalysts and provides synthesis–structure–performance correlations to elucidate underlying stability enhancement mechanisms. The mechanisms and impacts of carbon support degradation on Pt catalyst performance are first discussed. The general strategies are summarized to tailor the carbon structures and strengthen the metal–support interactions, followed by discussions on how these designs lead to enhanced support stability. Based on current experimental and theoretical studies, the critical features of carbon supports are analyzed concerning their impacts on the performance and durability of Pt catalysts in fuel cells. Finally, the perspectives are shared on future directions to develop advanced carbon materials with favorable morphologies and nanostructures to increase Pt utilization, strengthen metal-support interactions, facilitate mass/charge transfer, and enhance corrosion resistance.

25 ENERGY STORAGE↗
DOE OSTI2020

Enhanced Performance of Dual Inverter with a Floating Capacitor for Motor Drive Applications

This paper studies a dual inverter supplied by a DC-link and a floating capacitor (FC), emerged as a promising inverter topology for motor drive applications. For this type of inverter, the voltage ratio between the DC-link and the FC can be actively controlled. This ratio design is crucial as it essentially defines both the DC-link voltage utilization and the inverter output quality. Several voltage ratios have previously been discussed to enhance the dual inverter performance, but only one aspect, either the voltage utilization or the output quality, is investigated. As a result, although one performance aspect can be improved, the other aspect has been adversely affected. In this work, a comparative study considering both aspects is carried out for all the possible voltage ratios. Based on this analysis, the optimal ratios for different inverter modulation indices are identified. This is followed by proposing a ratio selection strategy to double the voltage utilization without degrading the output quality. Furthermore, this strategy enables an electric drive to work at a higher maximum speed without flux weakening for a given DC-link voltage. The claimed advantages have been proved by experimental tests on an open-end windings induction motor drive.

42 ENGINEERING↗
DOE OSTI2021

Band Edge Control of Quasi–2D Metal Halide Perovskites for Blue Light–Emitting Diodes with Enhanced Performance

Perovskite light–emitting diodes (PeLEDs) have received great attention for their potential as next–generation display technology. While remarkable progress has been achieved in green, red, and near–infrared PeLEDs with external quantum efficiencies (EQEs) exceeding 20%, obtaining high performance blue PeLEDs remains a challenge. Poor charge balance due to large charge injection barriers in blue PeLEDs has been identified as one of the major roadblocks to achieve high efficiency. Here band edge control of perovskite emitting layers for blue PeLEDs with enhanced charge balance and device performance is reported. By using organic spacer cations with different dipole moments, that is, phenethyl ammonium (PEA), methoxy phenethyl ammonium (MePEA), and 4–fluoro phenethyl ammonium (4FPEA), the band edges of quasi–2D perovskites are tuned without affecting their band gaps. Furthermore, detailed characterization and computational studies have confirmed the effect of dipole moment modification to be mostly electrostatic, resulting in changes in the ionization energies of ≈0.45 eV for MePEA and ≈ –0.65 eV for 4FPEA based thin films relative to PEA–based thin films. With improved charge balance, blue PeLEDs based on MePEA quasi–2D perovskites show twofold increase of the EQE as compared to the control PEA based devices.

36 MATERIALS SCIENCE↗
NASA NTRS1974

Future applications of associative processor systems to operational KSC systems for optimizing cost and enhancing performance characteristics

The application of associative memory processor equipment to conventional host processors type systems is discussed. Efforts were made to demonstrate how such application relieves the task burden of conventional systems, and enhance system speed and efficiency. Data cover comparative theoretical performance analysis, demonstration of expanded growth capabilities, and demonstrations of actual hardware in simulated environment.

Perkinson, J. A.↗
DOE OSTI2025

Enhanced Performance of Silicon Anodes through Hybrid Surface Engineering

Silicon (Si) is a promising anode material for nextgeneration lithium-ion batteries (LIBs) due to its high theoretical capacity. However, Si-containing anodes typically suffer from unacceptably short lives because of the unrestricted growth of the solid electrolyte interphase (SEI). Here, in this study, hybrid surface coatings are developed to stabilize the SEI in high loading pure Si anodes using atomic and molecular layer deposition. The coatings, consisting of LiF paired with lithicone, create an ionically conductive surface that enhances the capacity retention, rate performance, and longevity. Careful binder selection helps demonstrate the full utility of the coatings by enabling high loading electrodes to cycle continuously at current densities of 1200 mA/g Si . Uncoated controls, in comparison, fail within just 10 cycles at lower loadings. X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy are used to provide supporting evidence of the coating composition and efficacy. The data indicate that our lithicone coating is converted to Li 2 CO 3 upon cycling contributing to favorable LiF/Li 2 CO 3 interfaces that enhance the space-charge effect at the active material’s surface. When applied to electrodes made with thermally stable binders and increasingly higher loadings (approaching 5 mAh/cm 2 ), ion transport through the bulk electrode, rather than SEI growth, is shown to be the limiting factor. Furthermore, data suggests a favorable interaction between lithicone precursors and poly(acrylic acid) binders mitigates thermal decomposition at higher temperatures. The work presented here represents the successful realization of composite coatings containing LiF/Li 2 CO 3 components to stabilize high-loading Si anodes. This work helps inform advanced surface engineering strategies to achieve highly reversible, high-capacity Si anodes capable of fast charging for high-performance LIBs.

atomic layer deposition↗
NASA NTRS1988

Shuttle performance enhancement using an uprated OMS engine

The NASA Space Shuttle's Orbital Maneuvering Engine (OME) has been investigated as the basis for an enhancement of Shuttle operational flexibility. The Johnson Space Center has given attention to an upgrading of the OME through the use of a gas generator-driven turbopump to raise engine specific impulse. Hardware tests have demonstrated the projected performance gains, which will yield an enhanced, intact ascent-abort capability, as well an an improved on-orbit payload and altitude capability. Attention is given to the application of these capabilities to the Hubble Space Telescope's deployment.

Mallini, Charles J.↗
DOE OSTI2021

Surface enhanced performance of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ cathodes by infiltration Pr-Ni-Mn-O progress

Herein the present study reports the enhancement of electrochemical oxygen reduction activity of porous La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3–δ (LSCF) cathodes by coating a thin film of Pr-Ni-Mn oxide (PNM5) using a multi-step infiltration process. XRD examination reveals that PNM5 mainly contains a multiphase mixture of Pr 6 O 11 , PrNiO 3 , MnO and NiO. SEM morphology shows a thin PNM5 film and small particles are formed on the surface of LSCF backbone particles. Impedance spectrum analysis indicates that PNM5 infiltrated LSCF exhibits dramatically reduced polarization resistance (R p ), reaching R p of 0.244 Ω cm 2 at 973 K, which is one-half of the baseline LSCF cathode. The activation energy of LSCF cathodes infiltrated with PNM5 is 1.45 eV, slightly lower than the baseline LSCF cathode (1.77 eV). Distribution of relaxation time (DRT) function analysis shows PNM5 infiltration layer significantly promotes the oxygen reduction reaction (ORR) of cathode surface. With the increase in firing temperature, the total resistance increases and R p changes from ion transport to oxygen reduction reaction. Degradation rate of the PNM5-infiltrated LSCF is also lower, 0.02168% vs 0.07093% for the baseline LSCF over a 200-h period. A single cell testing indicated that the peak power density of the PNM5-infiltrated cell was increased by 140.66%. Overall, PNM5 could be a potential catalyst for boosting the performance of a commercial LSCF cathode for solid oxide fuel cells (SOFC).

36 MATERIALS SCIENCE↗