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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Substituted Quaternary Ammonium Salts Improve Low-Temperature Performance of Double-Layer Capacitors

Double-layer capacitors are unique energy storage devices, capable of supporting large current pulses as well as a very high number of charging and discharging cycles. The performance of doublelayer capacitors is highly dependent on the nature of the electrolyte system used. Many applications, including for electric and fuel cell vehicles, back-up diesel generators, wind generator pitch control back-up power systems, environmental and structural distributed sensors, and spacecraft avionics, can potentially benefit from the use of double-layer capacitors with lower equivalent series resistances (ESRs) over wider temperature limits. Higher ESRs result in decreased power output, which is a particular problem at lower temperatures. Commercially available cells are typically rated for operation down to only 40 C. Previous briefs [for example, Low Temperature Supercapacitors (NPO-44386), NASA Tech Briefs, Vol. 32, No. 7 (July 2008), p. 32, and Supercapacitor Electrolyte Solvents With Liquid Range Below 80 C (NPO-44855), NASA Tech Briefs, Vol. 34, No. 1 (January 2010), p. 44] discussed the use of electrolytes that employed low-melting-point co-solvents to depress the freezing point of traditional acetonitrile-based electrolytes. Using these modified electrolyte formulations can extend the low-temperature operational limit of double-layer capacitors beyond that of commercially available cells. This previous work has shown that although the measured capacitance is relatively insensitive to temperature, the ESR can rise rapidly at low temperatures, due to decreased electrolyte conductance within the pores of the high surface- area carbon electrodes. Most of these advanced electrolyte systems featured tetraethylammonium tetrafluoroborate (TEATFB) as the salt. More recent work at JPL indicates the use of the asymmetric quaternary ammonium salt triethylmethylammonium tetrafluoroborate (TEMATFB) or spiro-(l,l')-bipyrrolidium tetrafluoroborate (SBPBF4) in a 1:1 by volume solvent mixture of acetonitrile (AN) and methyl formate (MF) enables double-layer capacitor cells to operate well below -40 C with a relatively low ESR. Typically, a less than twofold increase in ESR is observed at -65 C relative to room-temperature values, when these modified electrolyte blends are used in prototype cells. Double-layer capacitor coin cells filled with these electrolytes have displayed the lowest measured ESR for an organic electrolyte to date at low temperature (based on a wide range of electrolyte screening studies at JPL). The cells featured high-surface-area (approximately equal to 2,500 m/g) carbon electrodes that were 0.50 mm thick and 1.6 cm in diameter, and coated with a thin layer of platinum to reduce cell resistance. A polyethylene separator was used to electrically isolate the electrodes.

Brandon, Erik J.↗
NASA NTRS2014

Low Temperature Double-Layer Capacitors Using Asymmetric and Spiro-Type Quaternary Ammonium Salts

Double-layer capacitors capable of operating at extremely low temperatures (e.g., as low as -80.degree. C.) are disclosed. Electrolyte solutions combining a base solvent (e.g., acetonitrile) and a cosolvent are employed to lower the melting point of the base electrolyte. Example cosolvents include methyl formate, ethyl acetate, methyl acetate, propionitrile, butyronitrile, and 1,3-dioxolane. A quaternary ammonium salt including at least one of triethylmethylammonium tetrafluoroborate (TEMATFB) and spiro-(1,1')-bipyrrolidium tetrafluoroborate (SBPBF.sub.4), is used in an optimized concentration (e.g., 0.10 M to 0.75 M), dissolved into the electrolyte solution. Conventional device form factors and structural elements (e.g., porous carbon electrodes and a polyethylene separator) may be employed.

Brandon, Erik J.↗
NASA NTRS1972

Origin of quaternary basalts from the Black Rock Desert Region, Utah.

An evaluation has been made of the relative roles of fractional crystallization and crustal contamination in the genesis of basaltic magmas from the Black Rock Desert region in Utah. As a result, geochemical variations of these basalts have been defined as a function of their ages of eruption.

Condie, K. C.↗
NASA NTRS1972

A study of Quaternary landforms and materials in the Midwest and Great Plains

The author has identified the following significant results. Measurements made from prints of ERTS-1, MSS 5 images, show practical limits of detectability for this imagery in the Midwest. The smallest high contrast object detectable has an approximate measured diameter of 150 feet. The smallest clearly identifiable cultural feature is roughly 300 feet for high contrast, and 400 to 500 feet for low contrast objects. Rural roadways, with an average width of 75 feet, are clearly defined due to high reflectivity, linearity, and the instantaneous field of view of the scanner. On the infrared a farm pond slightly greater than one acre is detectable. Crop and natural foliage cover in the Midwest during summar months obscures geologic and soils information and hinders detailed mapping. In the western Great Plains large-scale mapping of this kind may be possible, even at this time of year. In southwestern Iowa, topographic and drainage system anomalies, revealed by the imagery, are related to the slope of and depth to the buried bedrock surface. In eastern Iowa land use classification can be done from ERTS-1 imagery.

Morrison, R. B.↗
NASA NTRS1973

Evaluation of ERTS-1 imagery for mapping Quaternary deposits and landforms in the Great Plains and Midwest

The author has identified the following significant results. Maps of 1:1 million scale exemplifying the first phase of investigation were prepared for ten study areas (mostly 1 deg x 2 deg in area): 2 in Kansas, 1 in Missouri-Kansas, 2 in Nebraska, 1 in South Dakota, 3 in Illinois, and 1 in Iowa-Illinois (a total of 13 such maps, covering about 97,000 sq. mi., since the start of the project). Collection of all pertinent published geologic-terrain data also has been completed for all the study areas for which these first-phase maps have been made. The ground truth data are being used in combination with additional interpretation of the repetitive ERTS-1 images of most of these study areas to prepare enhanced information maps at 1:500,000. For areas that have not been mapped at 1:500,000 or larger scales, the maps will provide the first moderately detailed information on landform features and surficial materials. Much of the information mapped is significant for exploration and development of ground water (and locally petroleum) and for applications in engineering and environmental geology, and land use patterns as indicated by tone and texture on the images. Numerous moraines have been identified; also, the trends of parts of ancient filled valleys have been identified. Valley alinement appears controlled by faults or other structural lineaments.

Morrison, R. B.↗
NASA NTRS1973

Evaluation of ERTS-1 imagery for mapping Quaternary deposits and landforms in the Great Plains and Midwest

The author has identified the following significant results. Maps at 1:1 million scale exemplifying the first phase of the investigation (which consists of the identification and mapping of landform and land use characteristics and surficial geologic materials directly from the ERTS-1 images without use of additional data) were prepared. For areas that have not been mapped at 1:500,000 or larger scales, maps will provide the first moderately detailed information on landform features and surficial materials. Much of the information mapped is significant for exploration and development of ground (and, locally, petroleum) and for applications in engineering and environmental geology, including land use planning. Analysis of drainage patterns, stream-divide relations and land use patterns has revealed several possible moraine-controlled divices of middle and early Pleistocene age. One is an extension of the Cedar Bluffs moraine of southeastern Nebraska. Another of these divides may correspond to the terminus of Nebraska drift in the Kansas City study area. The trends of parts of various ancient filled valleys also have been identified by analysis of charges in width of the present stream valleys. The alinements of certain segments of stream valleys in Kansas and Missouri appear to be controlled by regional faults or other structural features.

Morrison, R. B.↗
NASA NTRS1975

Recent and late quaternary changes in water level

Water level changes of both the Great Lakes and the sea are described along with methods of analyzing water level data. The influence of elastic deformation of the earth and viscosity is discussed. Causes of water level changes reviewed include: earth movements, geoid changes, storm surges or meteorological phenomena, and melting ice in Antarctica, Greenland, and the mountain glaciers.

R. I. Walcott↗
NASA NTRS1982

Studies of single-mode injection lasers and of quaternary materials. Volume 1: Single-mode constricted double-heterojunction AlGaAs diode lasers

Constricted double-heterojunction (CDH) lasers are presented as the class of single-mode nonplanar-substrate devices for which the lasing cavity is on the least resistive electrical path between the contact and the substrate. Various types of CDH structures are considered under three general topics: liquid-phase epitaxy over channeled substrates, lateral mode control, and current control in nonplanar-substrate devices. Ridge-guide CDH lasers have positive-index lateral-mode confinement and provide: single-mode CW operation to 7 mW/facet at room temperature and to 3 mW/facet at 150 C; light-current characteristics with second-harmonic distortion as low as -57 dB below the fundamental level; threshold-current temperature coefficients, as high as 375 C (pulsed) and 310 C (CW); constant external differential quantum efficiency to 100 C; and lasing operation to 170 C CW and 280 C pulsed. Semileakyguide CDH lasers have an asymmetric leaky cavity for lateral-mode confinement and provide single-mode operation to 15 to 20 mW/facet CW and to 50 mW/facet at 50% duty cycle. Modulation characteristics and preliminary reliability data are discussed.

Botez, D.↗
NASA NTRS1983

Biocidal quaternary ammonium resin

Activated carbon (charcoal) and polymeric resin sorbents are widely used in the filtration and treatment of drinking water, mainly to remove dissolved organic and inorganic impurities and to improve the taste. Earlier hopes that activated carbon might "disinfect' water proved to be unfounded. The feasibility of protecting against microbial infestation in charcoal and resin beds such as those to be incorporated into total water reuse systems in spacecraft was investigated. The biocidal effect of IPCD (insoluable polymeric contact disinfectants) in combination with a representative charcoal was assessed. The ion exchange resins (IPCD) were shown to adequately protect charcoal and ion exchange beds.

Janauer, G. E.↗
NASA NTRS1991

Marine record of late quaternary glacial-interglacial fluctuations in the Ross Sea and evidence for rapid, episodic sea level change due to marine ice sheet collapse

Some of the questions to be addressed by SeaRISE include: (1) what was the configuration of the West Antarctic ice sheet during the last glacial maximum; (2) What is its configuration during a glacial minimum; and (3) has it, or any marine ice sheet, undergone episodic rapid mass wasting. These questions are addressed in terms of what is known about the history of the marine ice sheet, specifically in Ross Sea, and what further studies are required to resolve these problems. A second question concerns the extent to which disintegration of marine ice sheets may result in rises in sea level that are episodic in nature and extremely rapid, as suggested by several glaciologists. Evidence that rapid, episodic sea level changes have occurred during the Holocene is also reviewed.

Anderson, John B.↗
NASA NTRS1992

Electronic and total energy properties of ternary and quaternary semiconductor compounds, alloys, and superlattices: Theoretical study of Cu/graphite bonding

The goals of the research were to provide a fundamental science basis for why the bonding of Cu to graphite is weak, to critically evaluate the previous analysis of the wetting studies with particular regard to the values used for the surface energies of Cu and graphite, and to make recommendations for future experiments or other studies which could advance the understanding and solution of this technological problem. First principles electronic structure calculations were used to study the problem. These are based on density functional theory in the local density approximation and the use of the linear muffin-tin orbital band structure method. Calculations were performed for graphite monolayers, single crystal graphite with the hexagonal AB stacking, bulk Cu, Cu(111) surface, and Cu/graphite superlattices. The study is limited to the basal plane of graphite because this is the graphite plane exposed to Cu and graphite surface energies and combined with the measured contact angles to evaluate the experimental adhesion energy.

Lambrecht, Walter R. L.↗
NASA NTRS1992

Late quaternary time series of Arabian Sea productivity: Global and regional signals

Modern annual floral and faunal production in the northwest Arabian Sea derives primarily from upwelling induced by strong southwest winds during June, July, and August. Indian Ocean summer monsoon winds are, in turn, driven by differential heating between the Asian continent and the Indian ocean to the south. This differential heating produces a strong pressure gradient resulting in southwest monsoon winds and both coastal and divergent upwelling off the Arabian Peninsula. Over geologic time scales (10(exp 4) to 10(exp 6) years), monsoon wind strength is sensitive to changes in boundary conditions which influence this pressure gradient. Important boundary conditions include the seasonal distribution of solar radiation, global ice volume, Indian Ocean sea surface temperature, and the elevation and albedo of the Asian continent. To the extent that these factors influence monsoon wind strength, they also influence upwelling and productivity. In addition, however, productivity associated with upwelling can be decoupled from the strength of the summer monsoon winds via ocean mechanisms which serve to inhibit or enhance the nutrient supply in the intermediate waters of the Indian Ocean, the source for upwelled waters in the Arabian Sea. To differentiate productivity associated with wind-induced upwelling from that associated with other components of the system such as nutrient sequestering in glacial-age deep waters, we employ a strategy which monitors independent components of the oceanic and atmospheric subsystems. Using sediment records from the Owen Ridge, northwest Arabian Sea, we monitor the strength of upwelling and productivity using two independent indicators, percent G. bulloides and opal accumulation. We monitor the strength of southwest monsoon winds by measuring the grain-size of lithogenic dust particles blown into the Arabian Sea from the surrounding deserts of the Somali and Arabian Peninsulas. Our current hypothesis is that the variability associated with the 41 kyr power in the G. bulloides and opal accumulation records derive from nutrient availability in the intermediate waters which are upwelled via monsoon winds. This hypothesis is testable by comparison with Cd records of intermediate and deep waters of the Atlantic and Indian Ocean.

Clemens, Steven C.↗
NASA NTRS1992

The mass balance of soil evolution on late Quaternary marine terraces, northern California

Mass-balance interpretation of a soil chronosequence provides a means of quantifying elemental addition, removal, and transformation that occur in soils from a flight of marine terraces in northern California. Six soil profiles that range in age from several to 240,000 yr are developed in unconsolidated, sandy-marine, and eolian parent material deposited on bedrock marine platforms. Soil evolution is dominated by (1) open-system depletion of Si, Ca, Mg, K, and Na; (2) open-system enrichment of P in surface soil horizons; (3) relative immobility of Fe and Al; and (4) transformation of Fe, Si, and Al in the parent material to secondary clay minerals and sesquioxides. Net mass losses of bases and Si are generally uniform with depth and substantial, in some cases approaching 100 percent; however, the rate of loss of each element differs markedly, causing the ranking of each by relative abundance to shift with time. Loss of Si from the sand fraction by dissolution and particle-size diminution, from about 100 percent to less than 35 percent over 240 ky, mirrors a similar gain in the silt and clay size fractions. The Fe originally present in the sand fraction decreases from greater than 80 percent to less than 10 percent, whereas the amount of Fe present in the clay and crystalline oxyhydroxide fractions increases to 25 percent and 70 percent, respectively.

Merritts, Dorothy J.↗