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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Composite Bear Canister

To many national park campers and mountain climbers saving their foods in a safe and unbreakable storage container without worrying being attacked by a bear is a challenging task. In some parks, the park rangers have mandated that park visitors rent a bear canister for their food storage. Commercially available bear canisters are made of ABS plastic, weigh 2.8 pounds, and have a 180 cubic inch capacity for food storage. A new design with similar capacity was conducted in this study to reduce its weight and make it a stiffer and stronger canister. Two prototypes incorporating carbon prepreg with and without honeycomb constructions were manufactured using hand lay-up and vacuum bag forming techniques. A 6061-T6-aluminum ring was machined to dimensions in order to reinforce the opening area of the canister. Physical properties (weight and volume) along with mechanical properties (flexural strength and specific allowable moment) of the newly fabricated canisters are compared against the commercial ones. The composite canister weighs only 56% of the ABS one can withstand 9 times of the force greater. The advantages and limitations of using composite bear canisters will be discussed in the presentation.

Chung, W. Richard↗
DOE OSTI2023

Evaluation of Desiccation Behavior in Basalt Microfiber–Reinforced Bentonite Clay for Geological Repositories of Nuclear Spent Fuel Using Digital Image Correlation

ABSTRACT Secure storage of nuclear spent fuel (NSF) is of great concern for protecting public health and safety. The preferred long-term solution is underground containment in geological repositories, where one or more engineered barrier materials (EBM) encapsulate the NSF and separate it from the natural rock. Bentonite clay is commonly used as an EBM due to its many advantageous properties including low hydraulic conductivity, which ensures limitation of water infiltration to the system and the subsequent risk of corrosion in NSF canisters. However, bentonite clay subjected to heating from nuclear decay may form desiccation cracking. This study conducted disk-shaped free shrinkage tests and ring-shaped restrained shrinkage tests of bentonite clay samples reinforced with basalt microfibers. Digital image correlation was used as a noncontact full-field displacement measurement to track the time-evolving shrinkage and desiccation cracking phenomena and make quantified comparisons between plain bentonite and bentonite with varying contents of basalt microfibers (i.e., 0.0, 0.5, 1.0, and 1.5 % wt.). Results indicate that plain bentonite and basalt microfiber-reinforced samples showed similar free shrinkage behavior, while desiccation cracking behavior was significantly altered by adding basalt microfibers. Microfiber reinforcement effectively reduced major cracks through a “crack-bridging” effect while causing minor cracks to initiate earlier and at higher moisture contents than plain bentonite. Results infer that reinforcing plain bentonite with inorganic microfibers can potentially control desiccation cracking, leading to safer and improved nuclear waste management.

Materials Science↗
NASA NTRS1991

Tribological characteristics of silicon carbide whisker-reinforced alumina at elevated temperatures

The enhanced fracture toughness of whisker reinforced ceramics makes them attractive candidates for sliding components of advanced hear engines. Examples include piston rings and valve stems for Stirling engines and other low heat rejection devices. However, the tribological behavior of whisker reinforced ceramics is largely unknown. This is especially true for the applications described where use temperatures can vary from below ambient to well over 1000 C. An experimental research program to identify the dominant wear mechanism(s) for a silicon carbide whisker reinforced alumina composite, SiCw-Al2O3 is described. In addition, a wear mechanism model is developed to explain and corroborate the experimental results and to provide insight for material improvement.

Dellacorte, Christopher↗
NASA NTRS1946

Stresses in and General Instability of Monocoque Cylinders with Cutouts I : Experimental Investigation of Cylinders with a Symmetric Cutout Subjected to Pure Bending

Ten 24S-T alclad cylinders of 20-inch diameter, 45- or 58-inch length, and 0.012-inch wall thickness, reinforced with 24S-T aluminum alloy stringers and rings were tested in pure bending. In the middle of the compression side of the cylinders there was a cutout extending over 19 inches in the longitudinal direction, and over an angle of 45 degrees, 90 degrees, or 135 degrees in the circumferential direction. The strain in the stringers and in the sheet covering was measured with metal electric strain gages. The stress distribution in the cylinders deviate considerably from the linear law valid for cylinders without a cutout. The maximum strain measured was about four-thirds of the value calculated from the Mc/I formula when I was taken as the moment of inertia of the cross section of the portion of the cylinder where the cutout was situated. A diagram is presented containing the strain factors defined as the ratios of measured strain to strain calculated with the Mc/I formula. All the 10 cylinders tested failed in general instability. Two symmetric and one antisymmetric pattern of buckling were observed and the buckling load appeared to be independent of the method of manufacture and the length of the cylinder. The buckling load of the cylinders having cutouts extending over 45 degrees, 90 degrees, and 135 degrees was 66, 47, and 31 percent, respectively, of the buckling load of the cylinder without a cutout.

CYLINDERS, MONOCOQUE-BUCKLING↗
NASA NTRS1971

High performance filament wound composites for pressure vessel applications.

A new high modulus fiber was evaluated as a reinforcement for filament wound pressure vessels. Based on preliminary data it offers significant specific strength and modulus improvements over an S-glass reinforcement. Winding parameters and design data were established for the fiber with two different epoxy resin systems. NOL composite rings were evaluated for tensile strength, modulus and interlaminar shear strength at +70 F, -320 F and -423 F. Results showed that the fiber reinforced composite exhibited a specific strength of 4,100,000 inches and a specific modulus of 290,000,000 inches compared to 3,260,000 inches and 110,000,000 inches respectively for S-glass. Utilizing this data to design small filament wound pressure vessels, a performance factor of 806,000 inches was obtained experimentally with PRD 49-1 fiber compared to values of 632,000 inches and 501,000 inches for S-glass and high modulus graphite vessels, respectively.

Hoggatt, J. T.↗
NASA NTRS2002

Impact Testing and Analysis of Composites for Aircraft Engine Fan Cases

The fan case in a jet engine is a heavy structure because of its size and because of the requirement that it contain a blade released during engine operation. Composite materials offer the potential for reducing the weight of the case. Efficient design, test, and analysis methods are needed to efficiently evaluate the large number of potential composite materials and design concepts. The type of damage expected in a composite case under blade-out conditions was evaluated using a subscale test in which a glass/epoxy composite half-ring target was impacted with a wedge-shaped titanium projectile. Fiber shearing occurred near points of contact between the projectile and target. Delamination and tearing occurred on a larger scale. These damage modes were reproduced in a simpler test in which flat glass/epoxy composites were impacted with a blunt cylindrical projectile. A surface layer of ceramic eliminated fiber shear fracture but did not reduce delamination. Tests on 3D woven carbon/epoxy composites indicated that transverse reinforcement is effective in reducing delamination. A 91 cm (36 in.) diameter full-ring sub-component was proposed for larger scale testing of these and other composite concepts. Explicit, transient, finite element analyses indicated that a full-ring test is needed to simulate complete impact dynamics, but simpler tests using smaller ring sections are adequate when evaluation of initial impact damage is the primary concern.

Roberts, Gary D.↗
NASA NTRS1948

The Inward Bulge Type Buckling of Monocoque Cylinders IV : Experimental Investigation of Cylinders Subjected to Pure Bending

Eighteen 24S-T alclad cylinders of 20-inch diameter, with skin thickness varying between 0.012 inch and 0.025 inch and length varying between 40.5 inches and 64 inches, were tested in pure bending. They were reinforced with either 16 or 28 stringers and either 5 or 6 rings. One of the purposes of the investigation was to establish the critical value above which failure would occur by general instability and below which panel instability would take place. This value was found to be between 20 and 40 for cylinders with 16 stringers and between 16 and 74 for cylinders with 28 stringers.

LOADS - CYLINDERS, MONOCOQUE↗
NASA NTRSDate not supplied

TPSAS-NF1676L-32708-DND

Proposed Effort under Advanced Air Transport Technology (AATT): - Select advanced Al alloy with formability and additive manufacturability, high combined strength and toughness - Fabricate single-piece Integrally Stiffened Cylinders (~10 ft. dia. x 10 ft. long) with longitudinal stiffeners - Demonstrate joining technology for assembly of two cylinders into 20-ft. long fuselage structure - Optimize structural design incorporating tailored, selective reinforcement for durability and damage tolerance - Build-up window, door and circumferential ring frames with large-scale additive manufacturing - Structural test to validate manufacturing demonstration, structural models and analysis

Taminger, Karen M↗
NASA NTRS1996

Spherical Joint Piston and Connecting Rod Developed

Under an interagency agreement with the Department of Energy, the NASA Lewis Research Center manages a Heavy-Duty Diesel Engine Technology (HDET) research program. The overall program objectives are to reduce fuel consumption through increased engine efficiency, reduce engine exhaust emissions, and provide options for the use of alternative fuels. The program is administered with a balance of research contracts, university research grants, and focused in-house research. The Cummins Engine Company participates in the HDET program under a cost-sharing research contract. Cummins is researching and developing in-cylinder component technologies for heavy-duty diesel engines. An objective of the Cummins research is to develop technologies for a low-emissions, 55-percent thermal efficiency (LE-55) engine. The best current-production engines in this class achieve about 46-percent thermal efficiency. Federal emissions regulations are driving this technology. Regulations for heavy duty diesel engines were tightened in 1994, more demanding emissions regulations are scheduled for 1998, and another step is planned for 2002. The LE-55 engine emissions goal is set at half of the 1998 regulation level and is consistent with plans for 2002 emissions regulations. LE-55 engine design requirements to meet the efficiency target dictate a need to operate at higher peak cylinder pressures. A key technology being developed and evaluated under the Cummins Engine Company LE-55 engine concept is the spherical joint piston and connecting rod. Unlike conventional piston and connecting rod arrangements which are joined by a pin forming a hinged joint, the spherical joint piston and connecting rod use a ball-and-socket joint. The ball-and-socket arrangement enables the piston to have an axisymmetric design allowing rotation within the cylinder. The potential benefits of piston symmetry and rotation are reduced scuffing, improved piston ring sealing, improved lubrication, mechanical and thermal load symmetry, reduced bearing stresses, reduced running clearances, and reduced oil consumption. The spherical joint piston is a monolithic, squeeze-cast, fiber-reinforced aluminum piston. The connecting rod has a ball end that seats on a spherical saddle within the piston and is retained by a pair of aluminum bronze holder rings. The holder rings are secured by a threaded ring that mates with the piston. As part of the ongoing research and development activity, the Cummins Engine Company successfully completed a 100-hr test of the spherical joint piston and connecting rod at LE- 55 peak steady-state engine conditions. In addition, a 100-hr transient cycle test that varied engine conditions between LE-55 no-load and LE-55 full-load was successfully completed.

Source record↗
DOE OSTI2022

Crystal engineering of heterocyclic arylene(ethynylene) oligomers through programmed aromatic stacking

Conjugated oligomers and polymers consisting of aromatic heterocycles are examples of next-generation organic electronic materials. However, control and optimization of the self-assembly of these materials in the solid-state, which is a crucial parameter for high efficiency performance, remains an unsolved challenge in materials development. In this work, we provide valuable insight into aromatic stacking interactions between fluorinated arene rings (ArF) and heterocycles with different electronic character (Het), and elaborate on the prospect of using these interactions to control the solid-state configurations of three-ring phenyleneethynylene oligomers (PEs). Oligomers possessing heterocycles typically thought of as electron-rich (ER) show blue-shifted optical spectra in the solid-state, while those incorporating heterocycles typically thought of us electron deficient (ED) show red-shifted solid-state optical spectra. Crystal structures show ArF-Het stacking interactions between the fluorinated side-chains and ER units, which twist the backbone out of planarity and prevent chromophore aggregation. Further, the interactions are absent in ED oligomers, highlighting cofacial incompatibility between ArF rings and ED units. A combination of TD-DFT computations and novel heterocycle descriptors reinforce our assignment of the oligomers as ED or ER, while exhaustive conformer analysis shows ArF-Het stacking interactions are a significant contributor to compound stability. Overall, this work describes the importance of heterocycle electronics in conformational control in the solid state, understanding of which can be a valuable asset in the development of novel optoelectronic materials.

36 MATERIALS SCIENCE↗
NASA NTRS1972

Improved elastomer for use with oxygen difluoride

Method improves resistance of CIS-1,4-poly(butadiene) elastomers to attack by oxygen difluoride at low temperatures by replacing silica reinforcement with less reactive substances. Improved elastomeric compound is utilized in bladders, diaphragms, valves, O-rings and seals.

Martin, J. W.↗
NASA NTRS1983

Space Shuttle solid rocket booster initial water impact loads and dynamics - Analysis, tests, and flight experience

A series of scale model tests, finite element dynamic response analyses and full scale segment tests have been performed for purposes of developing design criteria for the initial water impact loading conditions applied to the internal stiffener rings located in the aft skirt portion of the Space Shuttle Solid Rocket Booster (SRB). In addition, flight experience has yielded information relative to structural reinforcement requirements. This paper discusses the test and analysis methods and summarizes significant results. It is noted that, although scale model test data are valuable for identifying trends, they have shortcomings concerning definition of full scale design loads criteria. Also, the frequently used static equivalent loads definition approach is not applicable for this type impact loading condition applied to an aft skirt type structure. Various types of ring structural fixes, including the addition of selected types of foam, are presented as well as associated full scale segment test results. Depending on the type and contour shape of the foam, reductions on applied pressures and peak measured strains over 50 percent are noted.

Kross, D. A.↗
NASA NTRS2011

Polymerization initated at sidewalls of carbon nanotubes

The present invention is directed to aryl halide (such as aryl bromide) functionalized carbon nanotubes that can be utilized in anionic polymerization processes to form polymer-carbon nanotube materials with improved dispersion ability in polymer matrices. In this process the aryl halide is reacted with an alkyllithium species or is reacted with a metal to replace the aryl-bromine bond with an aryl-lithium or aryl-metal bond, respectively. It has further been discovered that other functionalized carbon nanotubes, after deprotonation with a deprotonation agent, can similarly be utilized in anionic polymerization processes to form polymer-carbon nanotube materials. Additionally or alternatively, a ring opening polymerization process can be performed. The resultant materials can be used by themselves due to their enhanced strength and reinforcement ability when compared to their unbound polymer analogs. Additionally, these materials can also be blended with pre-formed polymers to establish compatibility and enhanced dispersion of nanotubes in otherwise hard to disperse matrices resulting in significantly improved material properties. The resultant polymer-carbon nanotube materials can also be used in drug delivery processes due to their improved dispersion ability and biodegradability, and can also be used for scaffolding to promote cellular growth of tissue.

Tour, James M.↗
NASA NTRS1994

Thermoplastic copolyimides and composites therefrom

Copolyimide compositions and methods for their preparation which are melt-processible at relative low pressures, i.e. less than 1000 psi, and are suited for laminating and molding, are described. The invention additionally encompasses copolyimide precursors, reinforced polyimide composites and laminates made from said polyimides where the composite is reinforced by fibrous materials. This is achieved by reacting at least one aromatic dianhydride where each anhydride group is located on an aromatic ring with the carbonyl units in an ortho orientation relative to one another, with at least one diamine which is capable of a transmidization reaction upon incorporation into the polyimide backbone, and with at least one other diamine which is not capable of undergoing such reaction, the diamine which is capable of undergoing the transimidization reaction being present in an amount of from about 1-50 mole percent in relation to the diamine that is not susceptable to transimidization.

Harris, Frank↗