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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Hydrogen Uptake Kinetics of 1,4-Bis(phenylethynyl)benzene Rubberized O-Rings: Measurements, Modeling, and Comparison with Additional Forms of Organic Getters

A class of molecules called “hydrogen getters” can react with, or scavenge, H 2 in applications where the hydrogen presence and/or buildup are not desirable. One such “getter”, 1,4-bis(phenylethynyl)benzene or DEB, can be incorporated into a silicone matrix in the form of an O-ring for added flexibility, environmental resiliency, and convenient use as a gasket in sealed applications. However, the performance and kinetics of this DEB-loaded rubberized O-ring have not yet been characterized. Here in this work, the hydrogen uptake kinetics of the rubberized DEB O-ring were extracted by the isoconversional analysis from isothermal isobaric data under conditions of 13,332 Pa H 2 and 305–325 K. The isoconversional and cylindrical diffusion approximations were then used to predict and model the hydrogen uptake of rubberized DEB O-rings under any arbitrary condition, as illustrated in this work for the simple case of a constant rate of hydrogen generation/input. In comparison with other Pd/carbon-based/organic getter systems, these rubberized DEB O-rings provide a type of hydrogen getter material with enhanced flexibility and catalyst protection in applications where an O-ring seal is needed.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Role of ring-enlargement reactions in the formation of aromatic hydrocarbons

Ring-enlargement reactions can provide a fast route towards the formation of six-membered single-ring or polycyclic aromatic hydrocarbons (PAHs). To investigate the participation of the cyclopentadienyl (C 5 H 5 ) radical in ring-enlargement reactions in high-temperature environments, a mass-spectrometric study was conducted. Experimental access to the C 5 H 5 high-temperature chemistry was provided by two counterflow diffusion flames. Cyclopentene was chosen as a primary fuel given the large amount of resonantly stabilized cyclopentadienyl radicals produced by its decomposition and its high tendency to form PAHs. In a second experiment, methane was added to the fuel stream to promote methyl addition pathways and to assess the importance of ring-enlargement reactions for PAH growth. The experimental dataset includes mole fraction profiles of small intermediate hydrocarbons and of several larger species featuring up to four condensed aromatic rings. Results show that, while the addition of methane enhances the production of methylcyclopentadiene and benzene, the concentration of larger polycyclic hydrocarbons is reduced. The increase of benzene is probably attributable to the interaction between the methyl and the cyclopentadienyl radicals. However, the formation of larger aromatics seems to be dominated only by the cyclopentadienyl driven molecular-growth routes which are hampered by the addition of methane. Furthermore, in addition to the experimental work, two chemical mechanisms were tested and newly calculated reaction rates for cyclopentadiene reactions were included. In an attempt to assess the impact of cyclopentadienyl ring-enlargement chemistry on the mechanisms’ predictivity, pathways to form benzene, toluene, and ethylbenzene were investigated. Results show that the updated mechanism provides an improved agreement between the computed and measured aromatics concentrations. Nevertheless, a detailed study of the single reaction steps leading to toluene, styrene, and ethylbenzene would be certainly beneficial.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Coherent ring-current migration of Mg-phthalocyanine probed by time-resolved X-ray circular dichroism

The coherent ring current of Mg-phthalocyanine created by a broad band UV-visible pump pulse shows variation with time, where the ring currents at the corner benzene rings, around the Mg cation and on the outer ring oscillate with different time periods and the current density migrates among these regions. The 7 pairs of E u degenerate excited states populated upon photoexcitation, generate 21 distinct coherent ring currents. We further calculate the time-resolved X-ray circular dichroism (TRXCD) spectrum of the coherences contributing to the ring current obtained by an attosecond X-ray probe pulse resonant with the nitrogen K-edge. A frequency domain TRXCD signal obtained by a Fourier transform of the signal with respect to the pump-probe delay time clearly separates the currents induced by different state pairs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Conformation and dynamics of ring polymers under symmetric thin film confinement

Understanding the structure and dynamics of polymers under confinement has been of widespread interest, and one class of polymers that have received comparatively little attention under confinement is that of ring polymers. The properties of non-concatenated ring polymers can also be important in biological fields because ring polymers have been proven to be a good model to study DNA organization in the cell nucleus. From our previous study, linear polymers in a cylindrically confined polymer melt were found to segregate from each other as a result of the strong correlation hole effect that is enhanced by the confining surfaces. By comparison, our subsequent study of linear polymers in confined thin films at similar levels of confinements found only the onset of segregation. Here, we use molecular dynamics simulation to investigate the chain conformations and dynamics of ring polymers under planar (1D) confinement as a function of film thickness. Our results show that conformations of ring polymers are similar to the linear polymers under planar confinement, except that ring polymers are less compressed in the direction normal to the walls. While we find that the correlation hole effect is enhanced under confinement, it is not as pronounced as the linear polymers under 2D confinement. Finally, we show that chain dynamics far above Tg are primarily affected by the friction from walls based on the monomeric friction coefficient we get from the Rouse mode analysis.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Generation of nanosecond THz pulses using a high gain ring resonator with a semiconductor switch

A 250 GHz quasi-optical ring resonator consisting of an input coupler and three mirrors has been designed and tested. A low-loss silicon wafer in the ring provides output coupling of the stored power when irradiated by a pulse from a 532 nm laser. The ring created 5.8 ns, 268 mW output power pulses when excited by a 17 mW, 250 GHz continuously operating input source, achieving a power gain of 16. In a fully tuned ring, higher gain is achievable. If the ring was used with a pulsed input source having a pulse length of several times the fill time, the ring could be used as an efficient pulse compressor with similar high gain. The resonator has a wide range of applications, including, at low power, spectroscopy and, at high power, testing of accelerator structures and materials.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Frequency combs in optically injected terahertz ring quantum cascade lasers

Quantum cascade lasers (QCLs) have emerged as promising candidates for generating chip-scale frequency combs in mid-infrared and terahertz wavelengths. In this work, we demonstrate frequency comb formation in ring terahertz QCLs using the injection of light from a distributed feedback (DFB) laser. The DFB design frequency is chosen to match the modes of the ring cavity (near 3.3 THz), and light from the DFB is injected into the ring QCL via a bus waveguide. By controlling the power and frequency of the optical injection, we show that combs can be selectively formed and controlled in the ring cavity. Numerical modeling suggests that this comb is primarily frequency-modulated in character, with the injection serving to trigger comb formation. We also show that the ring can be used as a filter to control the output of the DFB QCL, potentially being of interest in terahertz photonic integrated circuits. Our work demonstrates that waveguide couplers are a compelling approach for injecting and extracting radiation from ring terahertz combs and offer exciting possibilities for the generation of new comb states in terahertz, such as frequency-modulated waves, solitons, and more.

47 OTHER INSTRUMENTATION↗
DOE OSTI2024

Proton rings from late-forming ballistic sheath fields

Many laser-driven ion experiments have seen ring-like patterns in the proton angular distribution across a wide array of laser and target parameters. These rings can impede measurement due to the small acceptance angle of detectors and often inhibit potential applications. A myriad of explanations for their formation have been proposed, yet most studies attribute them to some aspect of the laser–plasma interaction. Using 3D particle-in-cell simulations, we show that late-forming strong radial electric fields can arise due to charge separation while the beam is in flight, long after the laser–plasma interaction. These fields can accelerate ions to significant divergences (≈ 10°) as they propagate away from the target. We compare our results to a recent experiment where a high intensity, short pulse laser (I 0 ≈ 10 21 W/cm 2 , τ ≈ 30 fs) was incident upon thin (≈ 1 μm) liquid crystal targets. Our simulations capture all the main features of the experimental results—namely, robust ring formation and larger rings for higher energy protons. In addition, we show that rings do not form for sufficiently short preplasma scale lengths. Finally, we develop a phenomenological model to describe the spatiotemporal structure of the radial electric field and use this to explain the proton rings' energy and preplasma dependencies.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

The luminosity function of ringed galaxies

ABSTRACT We perform an analysis of the luminosity functions (LFs) of two types of ringed galaxies – polar-ring galaxies and collisional ring galaxies – using data from the Sloan Digital Sky Survey (SDSS). Both classes of galaxies were formed as a result of interaction with their environment and they are very rare objects. We constructed LFs of galaxies by different methods and found their approximations by the Schechter function. The luminosity functions of both types of galaxies show a systematic fall-off at low luminosities. The polar structures around bright (Mr ≤ −20m) and red (g − r > +0.8) galaxies are about twice as common as around blue ones. The LF of collisional rings is shifted towards brighter luminosities compared to polar-ring galaxies. We analysed the published data on the ringed galaxies in several deep fields and confirmed the increase in their volume density with redshift: up to z ∼ 1 their density grows as (1 + z)m, where m ≳ 5.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Hydrodynamic Interactions in Topologically Linked Ring Polymers.

Despite decades of interdisciplinary research on topologically linked ring polymers, their dynamics remain largely unstudied. These systems represent a major scientific challenge as they are often subject to both topological and hydrodynamic interactions (HI), which render dynamical solutions either mathematically intractable or computationally prohibitive. Here we circumvent these limitations by preaveraging the HI of linked rings. We show that the symmetry of ring polymers leads to a hydrodynamic decoupling of ring dynamics. This decoupling is valid even for nonideal polymers and nonequilibrium conditions. Physically, our findings suggest that the effects of topology and HI are nearly independent and do not act cooperatively to influence polymer dynamics. We use this result to develop highly efficient Brownian dynamics algorithms that offer enormous performance improvements over conventional methods and apply these algorithms to simulate catenated ring polymers at equilibrium, confirming the independence of topological effects and HI. The methods developed here can be used to study and simulate large systems of linked rings with HI, including kinetoplast DNA, Olympic gels, and poly[n]catenanes.

Rauscher, Phillip M.↗
DOE OSTI2024

2D material platform for overcoming the amplitude–phase tradeoff in ring resonators

Compact and high-speed electro-optic phase modulators play a vital role in various large-scale applications including optical computing, quantum and neural networks, and optical communication links. Conventional electro-refractive phase modulators such as silicon (Si), III-V and graphene on Si suffer from a fundamental tradeoff between device length and optical loss that limits their scaling capabilities. High-finesse ring resonators have been traditionally used as compact intensity modulators, but their use for phase modulation has been limited due to the high insertion loss associated with the phase shift. Here, we show that high-finesse resonators can achieve a strong phase shift with low insertion loss by simultaneous modulation of the real and imaginary parts of the refractive index, to the same extent, i.e., Δ n Δ k ∼1. To implement this strategy, we demonstrate an active hybrid platform that combines a low-loss SiN ring resonator with 2D materials such as graphene and transition metal dichalcogenide [tungsten disulphide (WSe 2 )], which induces a strong change in the imaginary and real parts of the index. Our platform consisting of a 25 µm long Gr-Al 2 O 3 -WSe 2 capacitor embedded on a SiN ring of 50 µm radius (∼8% ring coverage) achieves a continuous phase shift of (0.46±0.05) π radians with an insertion loss (IL) of 3.18±0.20 dB and a transmission modulation (Δ T Ring ) of 1.72±0.15dB at a probe wavelength ( λ p ) of 1646.18 nm. We find that our Gr-Al 2 O 3 -WSe 2 capacitor exhibits a phase modulation efficiency ( V π 2 ⋅ L ) of 0.530±0.016V⋅cm and can support an electro-optic bandwidth of 14.9±0.1GHz. We further show that our platform can achieve a phase shift of π radians with an IL of 5 dB and a minimum Δ T of 0.046 dB. We demonstrate the broadband nature of the binary phase response, by measuring a phase shift of (1.00±0.10) π radians, with an IL of 5.20±0.31dB and a minimal Δ T Ring of 0.015±0.006dB for resonances spanning from 1564 to 1650 nm. This SiN–2D hybrid platform provides the design for compact and high-speed reconfigurable circuits with graphene and transition metal dichalcogenide (TMD) monolayers that can enable large-scale photonic systems.

Datta, Ipshita (ORCID:0000000318842882)↗
DOE OSTI2021

Beam Dynamics Study in a Dual Energy Storage Ring for Ion Beam Cooling

A dual energy storage ring designed for beam cooling consists of two closed rings with significantly different energies: the cooling and damping rings. These two rings are connected by an energy recovering superconducting RF structure that provides the necessary energy difference. In our design, the RF acceleration has a main linac and harmonic cavities both running at crest that at first accelerates the beam from low energy E_{L} to high energy E_{H} and then decelerates the beam from E_{H} to E_{L} in the next pass. The purpose of the harmonic cavities is to extend the bunch length in a dual energy storage ring as such a longer bunch length may be very useful in a cooling application. Besides these cavities, a bunching cavity running on zero-crossing phase is used outside of the common beamline to provide the necessary longitudinal focusing for the system. In this paper, we present a preliminary lattice design along with the fundamental beam dynamics study in such a dual energy storage ring.

Dhital, B.↗
DOE OSTI2026

Methods for Assessing Opportunities for Ring Dam Pumped Storage Hydropower

There is growing interest in new pumped storage hydropower (PSH) deployment to provide a range of grid flexibility, reliability, and resiliency services under an evolving and uncertain future power sector. The National Laboratory of the Rockies develops open PSH resource assessment and cost modeling tools to help evaluate PSH deployment opportunities, and this report describes expansions to those tools to consider an additional PSH system configuration - ring-dam reservoirs built on flat topographical features that are constructed from roller-compacted concrete material. This reservoir type is common among current PSH proposals and requires new methods to identify sites with this reservoir geometry throughout the United States and characterize the associated dam cost. Cost characterization for ring dam reservoirs required collecting historical dam cost data for earthen, rockfill, and roller-compacted concrete dams and regressing equations that relate costs between alternative materials. The ring dam site identification algorithm follows a 5-step procedure to identify circular geometry reservoirs. Once ring dam reservoirs are identified, they are then paired with potential dry-gully reservoirs, and the full set of potential paired reservoirs is cost-optimized to produce a least-cost set of potential PSH sites with no overlapping reservoirs. The resulting analysis found 1,663 ring-dam to dry-gully systems in the contiguous United States that are lower cost than any overlapping dry-gully to dry-gully systems, 29 in Alaska, and none in Hawaii or Puerto Rico. These systems constitute 1.5 TW of capacity in the contiguous United States and nearly 29 GW in Alaska, demonstrating that under suitable topography and head, ring-dam systems can provide cost-effective PSH opportunities. The greatest density of these opportunities are found in the intermountain west where there are mesas and flat land at bases of mountain ranges, but continued work could incorporate additional site characteristics or consider more complex reservoir shapes to find additional PSH deployment opportunities.

13 HYDRO ENERGY↗
DOE OSTI2020

Exploring Whether Super-puffs can be Explained as Ringed Exoplanets

An intriguing, growing class of planets are the “super-puffs,” objects with exceptionally large radii for their masses and thus correspondingly low densities (≲0.3 g cm{sup −3}). Here we consider whether they could have large inferred radii because they are in fact ringed. This would naturally explain why super-puffs have thus far only shown featureless transit spectra. We find that this hypothesis can work in some cases but not all. The close proximity of the super-puffs to their parent stars necessitates rings with a rocky rather than icy composition. This limits the radius of the rings, and makes it challenging to explain the large size of Kepler 51b, 51c, 51d, and 79d unless the rings are composed of porous material. Furthermore, the short tidal locking timescales for Kepler 18d, 223d, and 223e mean that these planets may be spinning too slowly, resulting in a small oblateness and rings that are warped by their parent star. Kepler 87c and 177c have the best chance of being explained by rings. Using transit simulations, we show that testing this hypothesis requires photometry with a precision of somewhere between ∼10 ppm and ∼50 ppm, which roughly scales with the ratio of the planet and star’s radii. We conclude with a note about the recently discovered super-puff HIP 41378f.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Ring Formation in Protoplanetary Disks Driven by an Eccentric Instability

We find that, under certain conditions, protoplanetary disks may spontaneously generate multiple, concentric gas rings without an embedded planet through an eccentric cooling instability. Using both linear theory and nonlinear hydrodynamics simulations, we show that a variety of background states may trap a slowly processing, one-armed spiral mode that becomes unstable when a gravitationally stable disk rapidly cools. The angular momentum required to excite this spiral comes at the expense of nonuniform mass transport that generically results in multiple rings. For example, one long-term hydrodynamics simulation exhibits four long-lived, axisymmetric gas rings. We verify the instability evolution and ring-formation mechanism from first principles with our linear theory, which shows remarkable agreement with the simulation results. Dust trapped in these rings may produce observable features consistent with observed disks. Additionally, direct detection of the eccentric gas motions may be possible when the instability saturates, and any residual eccentricity left over in the rings at later times may also provide direct observational evidence of this mechanism.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Advanced storage ring lattice options based on hybrid six-bend achromat for Stanford Synchrotron Radiation Lightsource upgrade

Three storage ring lattices have been designed as options for a future upgrade of the Stanford synchrotron radiation lightsource (SSRL). The three options differ in circumference and targeted future site, with one to be built in the tunnel of the present SPEAR3 ring, one as a green field ring on the SLAC campus, and the third in the tunnel of the decommissioned PEP-II ring. The lattices are based on the newly proposed hybrid 6-bend achromat (H6BA) lattice cells, which is ideal for pushing the photon beam brightness while achieving excellent nonlinear dynamics performance. The transparent matching conditions are enforced to minimize the negative impact of the loss of periodicity due to insertion of various long straight sections. Numerical optimization is performed to further improve the nonlinear dynamics. Finally, in addition to reaching very low emittances, the lattices can accommodate traditional off-axis injection and achieve beam lifetimes similar to or exceeding that of typical third generation rings.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Ring currents modulate optoelectronic properties of aromatic chromophores at 25 T

The properties of organic molecules can be influenced by magnetic fields, and these magnetic field effects are diverse. They range from inducing nuclear Zeeman splitting for structural determination in NMR spectroscopy to polaron Zeeman splitting organic spintronics and organic magnetoresistance. A pervasive magnetic field effect on an aromatic molecule is the aromatic ring current, which can be thought of as an induction of a circular current of π-electrons upon the application of a magnetic field perpendicular to the π-system of the molecule. While in NMR spectroscopy the effects of ring currents on the chemical shifts of nearby protons are relatively well understood, and even predictable, the consequences of these modified electronic states on the spectroscopy of molecules has remained unknown. In this work, we find that photophysical properties of model phthalocyanine compounds and their aggregates display clear magnetic field dependences up to 25 T, with the aggregates showing more drastic magnetic field sensitivities depending on the intermolecular interactions with the amplification of ring currents in stacked aggregates. These observations are consistent with ring currents measured in NMR spectroscopy and simulated in time-dependent density functional theory calculations of magnetic field-dependent phthalocyanine monomer and dimer absorption spectra. Here, we propose that ring currents in organic semiconductors, which commonly comprise aromatic moieties, may present new opportunities for the understanding and exploitation of combined optical, electronic, and magnetic properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Effects of polarization-reversed EMIC waves on the ring current dynamics

Electromagnetic ion cyclotron (EMIC) waves are widely believed to play an important role in influencing the radiation belt and ring current dynamics. Most studies have investigated the effects or characteristics of EMIC waves by assuming their left-handed polarization. However, recent studies have found that the reversal of polarization, which occurs at higher latitudes along the wave propagation path, can change the wave-induced pitch angle diffusion coefficients. Whether such a polarization reversal can influence the global ring current dynamics remains unknown. In this study, we investigate the ring current dynamics and proton precipitation loss in association with polarization-reversed EMIC waves by using the ring current–atmosphere interactions model (RAM). The results indicate that the polarization reversal of H-band EMIC waves can truly decrease the scattering rates of protons of 10 to 50 keV or >100 keV in comparison with the scenario in which the EMIC waves are considered purely left-handed polarized. Additionally, the global ring current intensity and proton precipitation may be slightly affected by the polarization reversal, especially during prestorm time and the recovery phase, but the effects are not large during the main phase. This is probably because the H-band EMIC waves contribute to the proton scattering loss primarily at E < 10 keV, an energy range that is not strongly affected by the polarization reversal.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Multifrequency Models of Black Hole Photon Rings from Low-luminosity Accretion Disks

Images of black holes encode both astrophysical and gravitational properties. Detecting highly lensed features in images can differentiate between these two effects. We present an accretion disk emission model coupled to the Adaptive Analytical Ray Tracing (AART) code that allows a fast parameter space exploration of black hole photon ring images produced from synchrotron emission from 10 to 670 GHz. As an application, we systematically study several disk models and compute their total flux density, average radii, and optical depth. The model parameters are chosen around fiducial values calibrated to general relativistic magnetohydrodynamic (GRMHD) simulations and observations of M87*. For the parameter space studied, we characterize the transition between optically thin and thick regimes and the frequency at which the first photon ring is observable. Our results highlight the need for careful definitions of photon ring radius in the image domain, as in certain models the highly lensed photon ring is dimmer than the direct emission at certain angles. We find that at low frequencies the ring radii are set by the electron temperature, while at higher frequencies the magnetic field strength plays a more significant role, demonstrating how multifrequency analysis can also be used to infer plasma parameters. Lastly, we show how our implementation can qualitatively reproduce multifrequency black hole images from GRMHD simulations when adding time variability to our disk model through Gaussian random fields. This approach provides a new method for simulating observations from the Event Horizon Telescope and the proposed Black Hole Explorer space mission.

79 ASTRONOMY AND ASTROPHYSICS↗