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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Session on modeling of radiative transfer processes

The session on modeling of radiative transfer processes is reviewed. Six critical issues surfaced in the discussion concerning scale-interactive radiative processes relevent to the mesoscale convective systems (MCS's). These issues are the need to expand basic knowledge of how MCS's influence climate through extensive cloud shields and increased humidity in the upper troposphere; to improve radiation parameterizations used in mesoscale and General Circulation Model (GCM) models; to improve our basic understanding of the influence of radiation on MCS dynamics due to diabatic heating, production of condensate, and vertical and horizontal heat fluxes; to quantify our understanding of radiative impacts of MCS's on the surface and free atmosphere energy budgets; to quantify and identify radiative and microphysical processes important in the evolution of MCS's; and to improve the capability to remotely sense MCS radiative properties from space and ground-based systems.

Flatau, Piotr↗

Integrated atomic force microscopy and x-ray irradiation for in situ characterization of radiation-induced processes

Understanding radiation-induced chemical and physical transformations at material interfaces is important across diverse fields, but experimental approaches are often limited to either ex situ observations or in situ electron microscopy or synchrotron-based methods in which cases the radiation type and dose are inextricably tied to the imaging basis itself. In this work we overcome this limitation by demonstrating integration of an X-ray source with an atomic force microscope to directly monitor radiolytically-driven interfacial chemistry at the nanoscale. We illustrate the value of in situ observations by examining effects of radiolysis on material adhesion forces in aqueous solution, as well as examining the production of alkali nitrates at the interface between an alkali halide crystal surface and air. For the examined salt-air interface, direct visualization under flexible experimental conditions greatly extends prior observations by enabling the transformation process to be followed comprehensively from source-to-sink with mass balance quantitation. Overall, our novel rad-AFM opens doors into understanding the dynamics of radiolytically-driven mass transfer and surface alteration at the nanoscale in real-time.

47 OTHER INSTRUMENTATION↗

Advanced electrode processing for lithium-ion battery manufacturing

Lithium-ion batteries (LIBs) need to be manufactured at speed and scale for their use in electric vehicles and devices. However, LIB electrode manufacturing via conventional wet slurry processing is energy-intensive and costly, challenging the goal to achieve sustainable, affordable and facile manufacturing of high-performance LIBs. Here, in this Review, we discuss advanced electrode processing routes (dry processing, radiation curing processing, advanced wet processing and 3D-printing processing) that could reduce energy usage and material waste. Maxwell-type dry processing is a scalable alternative to conventional processing and has relatively low manufacturing cost and energy consumption. Radiation curing processing could enable high-throughput manufacturing, but binder selection is limited to certain radiation curable chemistries. 3D-printing processing can produce electrodes with diverse architectures and improved rate performance, but scalability is yet to be demonstrated. 3D-printing processing is good for special applications where throughput and cost can be compromised for performance.

25 ENERGY STORAGE↗

Space Plasma Ion Processing of Ilmenite in the Lunar Soil: Insights from In-Situ TEM Ion Irradiation Experiments

Space weathering on the moon and asteroids results largely from the alteration of the outer surfaces of regolith grains by the combined effects of solar ion irradiation and other processes that include deposition of impact or sputter-derived vapors. Although no longer considered the sole driver of space weathering, solar ion irradiation remains a key part of the space weathering puzzle, and quantitative data on its effects on regolith minerals are still in short supply. For the lunar regolith, previous transmission electron microscope (TEM) studies performed by ourselves and others have uncovered altered rims on ilmenite (FeTiO3) grains that point to this phase as a unique "witness plate" for unraveling nanoscale space weathering processes. Most notably, the radiation processed portions of these ilmenite rims consistently have a crystalline structure, in contrast to radiation damaged rims on regolith silicates that are characteristically amorphous. While this has tended to support informal designation of ilmenite as a "radiation resistant" regolith mineral, there are to date no experimental data that directly and quantitatively compare ilmenite s response to ion radiation relative to lunar silicates. Such data are needed because the radiation processed rims on ilmenite grains, although crystalline, are microstructurally and chemically complex, and exhibit changes linked to the formation of nanophase Fe metal, a key space weathering process. We report here the first ion radiation processing study of ilmenite performed by in-situ means using the Intermediate Voltage Electron Microscope- Tandem Irradiation facility (IVEM-Tandem) at Argonne National Laboratory. The capability of this facility for performing real time TEM observations of samples concurrent with ion irradiation makes it uniquely suited for studying the dose-dependence of amorphization and other changes in irradiated samples.

Christoffersen, R.↗

Apparatus for processing electromagnetic radiation and method

Measuring apparatus including a ruled member having alternate transparent and opaque zones. An optical coupler connecting the ruled member with electromagnetic radiation-conversion apparatus. The conversion apparatus may include a photomultiplier and a discriminator. Radiation impinging on the ruled member will, in part, be converted to electrical pulses which correspond to the intensity of the radiation. A method of processing electromagnetic radiation includes providing a member having alternating dark and light zones, establishing movement of the member through the beam of electromagnetic radiation with the dark zones interrupting passage of radiation through the rule, providing an optical coupler to connect a portion of the radiation with a conversion station where the radiation portion is converted into an electrical pulse which is related to the intensity of the radiation received at the conversion station. The electrical pulses may be counted and the digitized signals stored or permanently recorded to produce positional information.

Gatewood, George D.↗

Process and Radiation Induced Defects in Electronic Materials and Devices

Process and radiation induced defects are characterized by a variety of electrical techniques, including capacitance-voltage measurements and charge pumping. Separation of defect type into stacking faults, displacement damage, oxide traps, interface states, etc. and their related causes are discussed. The defects are then related to effects on device parameters. Silicon MOS technology is emphasized. Several reviews of radiation effects and silicon processing exist.

Washington, Kenneth↗

Representation of Leaf-to-Canopy Radiative Transfer Processes Improves Simulation of Far-Red Solar-Induced Chlorophyll Fluorescence in the Community Land Model Version 5

Recent advances in satellite observations of solar-induced chlorophyll fluorescence (SIF) provide a new opportunity to evaluate and constrain the simulation of terrestrial gross primary productivity (GPP). Accurate representation of the processes driving SIF emission and the radiative transfer of SIF to remote sensing sensors is an essential prerequisite for the evaluation and data assimilation. Recently, SIF simulations have been incorporated into several land surface models, but the scaling of SIF from leaf-level to canopy level is usually not well-represented. In this work, we incorporate the simulation of far-red SIF observed at nadir into the Community Land Model version 5 (CLM5). An efficient and accurate method based on escape probability is developed to scale SIF from leaf-level to top-of-canopy while taking clumping and the radiative transfer processes into account. SIF simulated by CLM5 and a canopy-level model agreed well at sites except one in needle leaf forest (R2>0.91, root-mean-square error < 0.19W m -2 sr -1 um -1 ), and captured the day-to-day variation of tower-measured SIF at temperate forest sites (R 2 >0.68). At the global scale, simulated SIF generally captured the spatial and seasonal pat37 terns of satellite-observed SIF (R2 > 0.76 except for tropical forest). Factors including the fluorescence emission model, clumping, bidirectional effect, and canopy properties (leaf optical properties and leaf area index) had considerable impacts on SIF simulation, and the discrepancies between simulated and observed SIF varied with plant functional type. By improving the representation of radiative transfer for SIF simulation, our model allows better comparisons between simulated and observed SIF towards constraining and evaluating GPP simulations.

59 BASIC BIOLOGICAL SCIENCES↗

Atmospheric Ozone 1985. Assessment of Our Understanding of the Processes Controlling Its Present Distribution and Change, Volume 1: Global Ozone Research and Monitoring Project - Report No. 16

Topics addressed include: stratospheric chemistry; tropospheric trace gas (sources, distributions, and trends); tropospheric chemistry (processes, controlling the ozone and hydroxyl radicals); stratosphere-troposphere exchange; dynamic processes; and radiative processes (solar and terrestrial).

Source record↗

The suppression of convective wavebreaking by radiative transfer processes, part 1.3C

Schoeberl et al. (1983) suggested that convective wavebreaking of monochromatic gravity waves might be suppressed by radiative transfer processes if the vertical wavelength waves were sufficiently short. As the vertical wavelength or the gravity wave decreases, radiative transfer between adjacent vertical layers becomes increasingly important. This exchange can increase the radiative relaxation time scale so that the wave will no longer grow with altitude. Thus, very short vertical wavelength waves may dissipate radiatively rather than become convectively unstable. Apruzese and Strobel (1984) have revised the exchange coefficients used in Schoeberl et al. (1983). Also, Chao and Schoeberl (1984) pointed out that the computation made by LINDZEN (1981) of the convective diffusion rate may be a factor of two too low as the convective adjustment processes tends to minimize the thermal transport by the wave. The purpose here is to revise the values given in Schoeberl et al. (1983). These results also suggest that the very thin turbulent layers observed by mesosphere-stratosphere-troposphere (MST) radars (e.g., WOODMAN, 1980) cannot be produced by the convective instability of monochromatic gravity waves with large horizontal scales.

Schoeberl, M. R.↗

Impacts of Aerosol Direct Effects on the South Asian Climate: Assessment of Radiative Feedback Processes Using Model Simulations and Satellite/Surface Measurements

Current assessment of aerosol radiative effect is hindered by our incomplete knowledge of aerosol optical properties, especially absorption, and our current inability to quantify physical and microphysical processes. In this research, we investigate direct aerosol radiative effect over heavy aerosol loading areas (e.g., Indo-Gangetic Plains, South/East Asia) and its feedbacks on the South Asian climate during the pre-monsoon season (March-June) using the Purdue Regional Climate Model (PRCM) with prescribed aerosol data derived by the NASA Goddard Earth Observing System Model (GEOS-5). Our modeling domain covers South and East Asia (60-140E and 0-50N) with spatial resolutions of 45 km in horizontal and 28 layers in vertical. The model is integrated from 15 February to 30 June 2008 continuously without nudging (i.e., only forced by initial/boundary conditions). Two numerical experiments are conducted with and without the aerosol-radiation effects. Both simulations are successful in reproducing the synoptic patterns on seasonal-to-interannual time scales and capturing a pre-monsoon feature of the northward rainfall propagation over Indian region in early June which shown in Tropical Rainfall Measuring Mission (TRMM) observation. Preliminary result suggests aerosol-radiation interactions mainly alter surface-atmosphere energetics and further result in an adjustment of the vertical temperature distribution in lower atmosphere (below 700 hPa). The modifications of temperature and associated rainfall and circulation feedbacks on the regional climate will be discussed in the presentation.

Wang, Sheng-Hsiang↗

Bremsstrahlung in GRMHD Models of Accreting Black Holes

Here, the role of bremsstrahlung in the emission from hot accretion flows around slowly accreting supermassive black holes is not thoroughly understood. In order to appraise the importance of bremsstrahlung relative to other radiative processes, we compute spectral energy distributions (SEDs) of accretion disks around slowly accreting supermassive black holes including synchrotron radiation, inverse Compton scattering, and bremsstrahlung. We compute SEDs for (i) four axisymmetric radiative general relativistic magnetohydrodynamics (RadGRMHD) simulations of 10 8 M ⊙ black holes with accretion rates between 10 -8 $\dot{M}$ Edd and 10 -5 $\dot{M}$ Edd , (ii) four axisymmetric RadGRMHD simulations of M87* with varying dimensionless spin a$_*$ and black hole mass, and (iii) a 3D GRMHD simulation scaled for Sgr A*. At 10 -8 $\dot{M}$ Edd , most of the luminosity is synchrotron radiation, while at 10 -5 $\dot{M}$ Edd the three radiative processes have similar luminosities. In most models, bremsstrahlung dominates the SED near 512 keV. In the M87* models, bremsstrahlung dominates this part of the SED if a$_*$ = 0.5, but inverse Compton scattering dominates if a$_*$ = 0.9375. Since scattering is more variable than bremsstrahlung, this result suggests that 512 keV variability could be a diagnostic of black hole spin. In the appendix, we compare some bremsstrahlung formulæ found in the literature.

79 ASTRONOMY AND ASTROPHYSICS↗

Clinical Natural Language Processing for Radiation Oncology: A Review and Practical Primer

Natural language processing (NLP), which aims to convert human language into expressions that can be analyzed by computers, is one of the most rapidly developing and widely used technologies in the field of artificial intelligence. Natural language processing algorithms convert unstructured free text data into structured data that can be extracted and analyzed at scale. In medicine, this unlocking of the rich, expressive data within clinical free text in electronic medical records will help untap the full potential of big data for research and clinical purposes. Recent major NLP algorithmic advances have significantly improved the performance of these algorithms, leading to a surge in academic and industry interest in developing tools to automate information extraction and phenotyping from clinical texts. Thus, these technologies are poised to transform medical research and alter clinical practices in the future. Radiation oncology stands to benefit from NLP algorithms if they are appropriately developed and deployed, as they may enable advances such as automated inclusion of radiation therapy details into cancer registries, discovery of novel insights about cancer care, and improved patient data curation and presentation at the point of care. However, challenges remain before the full value of NLP is realized, such as the plethora of jargon specific to radiation oncology, nonstandard nomenclature, a lack of publicly available labeled data for model development, and interoperability limitations between radiation oncology data silos. Successful development and implementation of high quality and high value NLP models for radiation oncology will require close collaboration between computer scientists and the radiation oncology community. Here, we present a primer on artificial intelligence algorithms in general and NLP algorithms in particular; provide guidance on how to assess the performance of such algorithms; review prior research on NLP algorithms for oncology; and describe future avenues for NLP in radiation oncology research and clinics.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Tools for Atmospheric Radiative Transfer: Streamer and FluxNet

Two tools for the solution of radiative transfer problems are presented. Streamer is a highly flexible medium spectral resolution radiative transfer model based on the plane-parallel theory of radiative transfer. Capable of computing either fluxes or radiances, it is suitable for studying radiative processes at the surface or within the atmosphere and for the development of remote-sensing algorithms. FluxNet is a fast neural network-based implementation of Streamer for computing surface fluxes. It allows for a sophisticated treatment of radiative processes in the analysis of large data sets and potential integration into geophysical models where computational efficiency is an issue. Documentation and tools for the development of alternative versions of Fluxnet are available. Collectively, Streamer and FluxNet solve a wide variety of problems related to radiative transfer: Streamer provides the detail and sophistication needed to perform basic research on most aspects of complex radiative processes while the efficiency and simplicity of FluxNet make it ideal for operational use.

Key, Jeffrey R.↗

An elementary theory of eclipsing depths of the light curve and its application to Beta Lyrae

An elementary theory of the ratio of depths of secondary and primary eclipses of a light curve has been proposed for studying the nature of component stars. It has been applied to light curves of Beta Lyrae in the visual, blue, and far-ultraviolet regions with the purpose of investigating the energy sources for the luminosity of the disk surrounding the secondary component and determining the dominant radiative process in the disk. No trace of the spectrum of primary radiation has been found in the disk. Therefore, it is suggested that LTE is the main radiative process in the disk, which radiates at a temperature of approximately 12,000 K in the portion that undergoes eclipse. A small source corresponding to 14,500 K has also been tentatively detected and may represent a hot spot caused by hydrodynamic flow of matter from the primary component to the disk.

Huang, S.-S.↗

A New Look into the Effect of Large Drops on Radiative Transfer Process

Recent studies indicate that a cloudy atmosphere absorbs more solar radiation than any current 1D or 3D radiation model can predict. The excess absorption is not large, perhaps 10-15 W/sq m or less, but any such systematic bias is of concern since radiative transfer models are assumed to be sufficiently accurate for remote sensing applications and climate modeling. The most natural explanation would be that models do not capture real 3D cloud structure and, as a consequence, their photon path lengths are too short. However, extensive calculations, using increasingly realistic 3D cloud structures, failed to produce photon paths long enough to explain the excess absorption. Other possible explanations have also been unsuccessful so, at this point, conventional models seem to offer no solution to this puzzle. The weakest link in conventional models is the way a size distribution of cloud particles is mathematically handled. Basically, real particles are replaced with a single average particle. This "ensemble assumption" assumes that all particle sizes are well represented in any given elementary volume. But the concentration of larger particles can be so low that this assumption is significantly violated. We show how a different mathematical route, using the concept of a cumulative distribution, avoids the ensemble assumption. The cumulative distribution has jumps, or steps, corresponding to the rarer sizes. These jumps result in an additional term, a kind of Green's function, in the solution of the radiative transfer equation. Solving the cloud radiative transfer equation with the measured particle distributions, described in a cumulative rather than an ensemble fashion, may lead to increased cloud absorption of the magnitude observed.

Marshak, Alexander↗