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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

A Spaceborne Demonstration of P-Band Signals-of-Opportunity (SoOp) Reflectometry

Land-reflected signals from a geosynchronous communication satellite broadcasting in P-band (367.5 MHz) were captured in low Earth orbit (LEO) using a simple dipole antenna. A delay-Doppler map (DDM) was generated through autocorrelation. Estimates of the specular point delay were obtained from the lag of the second peak in the DDM with a bias of 239.4 m and a standard deviation of 44 m (12 m over a frozen lake) with respect to a predicted orbit model. Relative magnitudes of the first and second DDM peaks fell within the range of values predicted using dielectric models for the frozen ground and lake. Finally, retrievals of surface reflection coefficient were generated using a range of realistic values for the transmitter link budget G/T , and these also fell within the range of possible values for the antenna gain pattern. Given the lack of calibration and the large uncertainties in the receiver orbit and attitude, this agreement is sufficient to conclude a successful demonstration of the fundamental principle of single-antenna reflectometry in P-band. P-band reflectometry may offer a new approach to remote sensing of sub-canopy and root-zone soil moisture.

Delays↗
DOE OSTI2024

Quasi-Extended Range Optical Frequency Domain Reflectometry for Product Pipelines

Throughout the United States, large natural gas and product transmission pipelines exist. These pipelines are susceptible to failure through corrosion and cracking due to internal and external factors. As these transmission pipeline age, the likelihood of a catastrophic failure increases. The ability to the monitor corrosion and wall thickness of these pipelines is paramount to reduce risk of disastrous failure and increase reliability as well as safety. Optical frequency domain reflectometry can monitor distributed temperature and strain measurements along the natural gas and product pipelines. This measurement technique can provide valuable information of pipe structural health through hoop strain changes due to pipe wall thinning, temperature changes due to gas leaks based on Joule-Thomson effect. Since these pipelines are typically buried, the depth of the pipeline results in a potential loss in the sensing range where the fiber is not physically monitoring the hoop strain of the pipeline. A different configuration of the interferometer will allow for the distributed fiber measurement to start atop the pipeline itself. This configuration results in no loss of sensing range and maintains the sensing resolution of a typically interferometer for an optical frequency domain reflectometry measurement. The quasi-extended range distributed hoop strain measurements were demonstrated on an active transmission pipeline.

Brister, Matthew↗
DOE OSTI2024

Characterizing Hygroscopic Films of Polyzwitterions in Electric Fields Using Neutron and X-ray Reflectometries: Electrostriction or Mass Loss?

Herein we study responses of thermally annealed ultrathin films deposited on silicon substrates and containing polyzwitterions to applied electric fields by using specular neutron reflectometry (NR). In particular, we applied 7 kV under vacuum at 150 °C on the films containing poly(1-(3-sulfonatopropyl)-2-vinylpyridinium) (P2VPPS) and its blends with either a deuterated ionic liquid (EMIMBF 4 - d 11 ), potassium bromide (KBr), or deuterated sodium polystyrenesulfonate (NaPSS-d 7 ). The voltage was applied over an air gap, and the in situ neutron reflectivity measurements allowed us to measure changes in the films. In all the cases, we measured decreases in thicknesses of the films, which varied up to ~8% depending on the added salt. Posteriori X-ray reflectivity (XRR) measurements on the same films at room temperature reveal that these films were highly hygroscopic, which led to the presence of water in these films. Analysis of the NR and the XRR revealed that the decrease in the thickness of the films in the neutron reflectivity experiments on heating resulted from the loss of water and the ionic liquid but not from electrostrictive effects. The in situ NR and posteriori XRR experiments revealed not only the hygroscopic nature of these films but also depth-resolved structural rearrangements due to the applied electric fields in the films containing electrolytes and polyelectrolytes. This work shows that a combination of NR and XRR can be used to distinguish between mass loss and electrostriction in films containing charged polymers such as polyzwitterions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Surface Wave Based Non-conductor-contact Reflectometry Method for Insulation and Jacket Damage Detection in Multi-Conductor Cables

This paper presents a non-conductor-contact surface wave reflectometry technique to locate insulation and jacket damage on multi-conductor cables at a distant location from the sensor. Simulation studies were conducted using Ansys high frequency structure simulator (HFSS). A GHz range surface wave launcher was employed such that maximum surface wave energies were confined in the insulation layer while minimizing attenuation. The wave launcher can potentially be mounted on the outer surface of live cables or cable conduits and requires no physical connection to the conductors. Multiple simulations involving a 4 GHz wave launcher and a three-conductor cable with an 8 mm outer diameter were carried out demonstrating the efficacy of the proposed method. Water leak and different types of insulation/jacket damage were simulated and detected.

reflectometry, multi-conductor cable, frequency do↗
DOE OSTI2020

Detection and Localization of Damaged Photovoltaic Cells and Modules Using Spread Spectrum Time Domain Reflectometry

The operating efficiency of photovoltaic (PV) plants can be improved if damaged or degraded modules can be detected and identified. Currently, string-level power electronics can detect problems with modules or cabling but not locate them, which would facilitate addressing these issues. Here, we investigate the ability of spread spectrum time domain reflectometry (SSTDR) to both detect and locate/identify damaged cells and modules within a series-connected PV string. We tested the ability of SSTDR to detect and locate single-cell mini-modules and full-sized PV modules, which were intentionally damaged by impacts with a hammer (breaking the glass and damaging the silicon below) or by cutting through some or all busbars. Damage to the glass and silicon of cells was detected and located within a small string of minimodules. Busbar damage was detectable only if an open was created by cutting through all intercell busbars. Furthermore, physical impact damage to the glass and silicon of a full-sized PV module could be detected, but further development of signal processing is needed to achieve localization of such damaged modules within a string.

14 SOLAR ENERGY↗
DOE OSTI2023

Capability of Impedance Measurement Using Spread Spectrum Time-Domain Reflectometry

Spread spectrum time-domain reflectometry (SSTDR) has been proposed for measuring electrical impedance on live, energized systems, in electrically noisy environments, or for measuring multiple channels simultaneously. Here we evaluate the capability of SSTDR for impedance measurement from near dc to 96 MHz and find that they agree very well with measurements from a vector network analyzer (VNA). Time gating is used to remove (calibrate out) transmission line effects. We evaluate the frequency ranges over which SSTDR at different modulation frequencies is accurate for the measurement of series resistive–capacitive ( RC ) loads and observe that fusing measurements from multiple modulation frequencies can broaden the effective measurement bandwidth.

14 SOLAR ENERGY↗
DOE OSTI2021

Graphical Optimization of Spectral Shift Reconstructions for Optical Backscatter Reflectometry

Optical backscatter reflectometry (OBR) is an interferometric technique that can be used to measure local changes in temperature and mechanical strain based on spectral analyses of backscattered light from a singlemode optical fiber. The technique uses Fourier analyses to resolve spectra resulting from reflections occurring over a discrete region along the fiber. These spectra are cross-correlated with reference spectra to calculate the relative spectral shifts between measurements. The maximum of the cross-correlated spectra—termed quality—is a metric that quantifies the degree of correlation between the two measurements. Recently, this quality metric was incorporated into an adaptive algorithm to (1) selectively vary the reference measurement until the quality exceeds a predefined threshold and (2) calculate incremental spectral shifts that can be summed to determine the spectral shift relative to the initial reference. Using a graphical (network) framework, this effort demonstrated the optimal reconstruction of distributed OBR measurements for all sensing locations using a maximum spanning tree (MST). By allowing the reference to vary as a function of both time and sensing location, the MST and other adaptive algorithms could resolve spectral shifts at some locations, even if others can no longer be resolved.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Adsorption of Non-Ionic Surfactant and Monoclonal Antibody on Siliconized Surface Studied by Neutron Reflectometry

The adsorption of monoclonal antibodies (mAbs) on hydrophobic surfaces is known to cause protein aggregation and degradation. Therefore, surfactants, such as Poloxamer 188, are widely used in therapeutic formulations to stabilize mAbs and protect mAbs from interacting with liquid-solid interfaces. Here, the adsorption of Poloxamer 188, one mAb and their competitive adsorption on a model hydrophobic siliconized surface is investigated with neutron scattering coupled with contrast variation to determine the molecular structure of adsorbed layers for each case. Small angle neutron scattering measurements of the affinity of Poloxamer 188 to this mAb indicate that there is negligible binding at these solution conditions. Neutron reflectometry measurements of the mAb show irreversible adsorption on the siliconized surface, which cannot be washed off with neat buffer. Poloxamer 188 can be adsorbed on the surface already occupied by mAb, which enables partial removal of some adsorbed mAb by washing with buffer. The adsorption of the surfactant introduces significant conformational changes for mAb molecules that remain on the surface. In contrast, if the siliconized surface is first saturated with the surfactant, no adsorption of mAb is observed. Competitive adsorption of mAb and Poloxamer 188 from solution leads to a surface dominantly occupied with surfactant molecules, whereas only a minor amount of mAb absorbs. These findings clearly indicate that Poloxamer 188 can protect against mAb adsorption as well as modify the adsorbed conformation of previously adsorbed mAb.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Structural properties of aqueous grown polydopamine thin films determined by neutron reflectometry

Here, in this work, neutron reflectometry (NR) studies of the bio-mimetic polymer, polydopamine (PDA), deposited from differing initial concentrations of precursor material dopamine hydrochloride for a range of polymerization times, is reported. PDA can form a complex and highly versatile polymer film, with many structure studies having been performed previously, but a comprehensive structural determination of PDA by NR is lacking in the literature. It was found that simple box models were incapable of fully explaining the observed data, necessitating the use of a composite model consisting of the weighted average of both the 1 and 2 box models to fully capture the heterogeneous nature of the PDA film structure. Confocal laser scanning microscopy (CLSM) and atomic force microscopy (AFM) were performed to capture the surface structure and relative mechanical difference between the separate domains of the PDA. The CLSM results provide evidence that the PDA domains are larger than the coherent scattering length of a neutron used in these measurements, 10μm, supporting the need for a composite model. The AFM measurements show complex structure below the coherence length provide physical justification for the two box model. It was determined that film structure and quality are both heavily impacted by the initial concentration of dopamine hydrochloride and the polymerization time, giving confidence to the highly customizable nature of PDA as an adhesion promoting interface treatment in composite systems, such as plastic bonded explosives (PBX).

36 MATERIALS SCIENCE↗
DOE OSTI2021

A next generation ultra short pulse reflectometry (USPR) diagnostic

Ultrashort Pulse Reflectometry (USPR) is a plasma diagnostic technique involving the propagation and reflection of ultrashort duration (~few ns) chirps. The reflected packets pass through a multichannel filter with time-of-flight measurements performed on each of the filtered packets. A next generation USPR system is under development, spanning 28–75 GHz, for use on compact, short duration, magnetically confined fusion devices. This system presents a dramatic increase in performance compared with an earlier USPR system employed on the LLNL Sustained Spheromak Physics Experiment device more than a decade ago. The new system replaces upconverting mixers with higher power active multiplier chains to generate mm-wave transmitter chirps, with custom time-of-flight electronics reducing the time per measurement by a factor of 3X. Finally, the system is equipped with a field programmable gate array for data acquisition and analysis.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Controlling magnetic configuration in soft–hard bilayers probed by polarized neutron reflectometry

Hard/soft magnetic bilayer thin films have been widely used in data storage technologies and permanent magnet applications. The magnetic configuration and response to temperatures and magnetic fields in these heterostructures are considered to be highly dependent on the interfacial coupling. However, the intrinsic properties of each of the layers, such as the saturation magnetization and layer thickness, also strongly influence the magnetic configuration. Changing these parameters provides an effective method to tailor magnetic properties in composite magnets. Here, we use polarized neutron reflectometry (PNR) to experimentally probe the interfacial magnetic configurations in the hard/soft bilayer thin films: L1 0 -FePt/A1-FePt, [Co/Pd]/CoPd, [Co/Pt]/FeNi, and L1 0 -FePt/Fe, all of which have a perpendicular magnetic anisotropy in the hard layer. These films were designed with different soft and hard layer thicknesses (t soft and t hard ) and saturation magnetization (M$_s^{soft}$ and M$_s^{hard}$). The influences of an in-plane magnetic field (H ip ) and temperature (T) are also studied using a L1 0 -FePt/A1-FePt bilayer sample. Comparing the PNR results to the micromagnetic simulations reveals that the interfacial magnetic configuration is highly dependent on t soft , M$_s^{soft}, and the external factors (H ip and T) and has a relatively weak dependence on t hard and M$_s^{hard}$. Key among these results, for thin t soft , the hard and soft layers are rigidly coupled in the out-of-plane direction and then undergo a transition to relax in-plane. This transition can be delayed to larger t soft by decreasing M$_s^{soft}$. Understanding the influence of these parameters on the magnetic configuration is critical to designing functional composite magnets for applications.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Interpreting radial correlation Doppler reflectometry using gyrokinetic simulations

A linear response, local model for the DBS amplitude applied to gyrokinetic simulations shows that radial correlation Doppler reflectometry measurements (RCDR, Schirmer et al 2007 Plasma Phys. Control. Fusion 49 1019) are not sensitive to the average turbulence radial correlation length, but to a correlation length that depends on the binormal wavenumber $k_{\perp}$ selected by the Doppler backscattering (DBS) signal. Nonlinear gyrokinetic simulations show that the turbulence naturally exhibits a nonseparable power law spectrum in wavenumber space, leading to a power law dependence of the radial correlation length with binormal wavenumber $l_r \sim C k_{\perp}^{-\alpha} (\alpha \approx 1)$ which agrees with the inverse proportionality relationship between the measured $l_r$ and $k_{\perp} $ observed in experiments (Fernández-Marina et al 2014 Nucl. Fusion 54 072001). This new insight indicates that RCDR characterizes the eddy aspect ratio in the perpendicular plane to the magnetic field. It also motivates future use of a nonseparable turbulent spectrum to quantitatively interpret RCDR and potentially other turbulence diagnostics. The radial correlation length is only measurable when the radial resolution at the cutoff location $W_\text n$ satisfies $W_\text n \ll l_r$, while the measurement becomes dominated by $W_\text n$ for $W_\text n \gg l_r$. This suggests that $l_r$ is likely to be inaccessible for electron-scale DBS measurements (${k_{\perp}}{\rho_{\text s}} \gt 1$). The effect of $W_\text n$ on ion-scale radial correlation lengths could be nonnegligible.

radial correlation Doppler reflectometry↗
DOE OSTI2020

An Adaptive Reference Scheme to Extend the Functional Range of Optical Backscatter Reflectometry in Extreme Environments

Optical frequency domain reflectometry (OFDR) measurements are performed by recording the interference pattern of light backscattered by density fluctuations or Bragg gratings along the length of an optical fiber. Changes in local temperature or strain in the fiber cause shifts in the backscattered light spectrum, which can be calibrated to the applied temperature or strain. Comparing the backscattered optical spectra from each reflection site with a reference (unstrained) spectrum allows for quantification of local spectral shifts. While mature OFDR-based technologies can provide high-precision spatially distributed measurements over kilometer lengths, the post-processing approaches used to recover spectral shifts from raw optical intensity data can limit the use of OFDR in harsh environments. This paper presents a novel approach to post-processing OFDR data which extends the usability of optical fibers exposed to harsh environments. This approach is the first to use the spectral shift quality, calculated for two OFDR measurements, to identify an appropriate reference scan from which the spectral shift can be determined. Here, three experimental data sets are used to test the algorithm: (1) an optical fiber heated to >950°C, (2) an aluminum-embedded optical fiber under strain from differential thermal expansion, and (3) an optical fiber exposed to a total neutron flux of 2×10 13 n/cm 2 /s over 40 hours in a nuclear test reactor. Results show that using a metric of quality to select an appropriate reference measurement extends the functional range of OFDR strain and temperature sensors. Furthermore, this algorithm can be applied to existing OFDR data.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Non-Conductor-Contact Surface Wave Reflectometry for Cable Insulation Damage Detection

Here, this paper presents a non-conductor-contact surface wave-based reflectometry technique to detect and locate missing or damaged insulation and/or jacket of electrical cables. The described sensor may be uniquely and practically implemented on live cables as a non-destructive evaluation (NDE) method since it may be applied to the outer insulation/jacket of a cable and requires no direct contact to the conductor. The innovation lies in a high-frequency surface wave launcher that can introduce broadband signals in the GHz frequencies that insure maximum electromagnetic (EM) energy localization within the insulation and/or jacket material. By further processing the reflection data in the frequency domain, the location and severity of insulation damage is detected. Simulated results of thin, thick, short, and long cables show the results expected from small, medium, and large damage regions. For example, the detection of 40 mm-long damage region at 40 m distance on a 50 m long cable (2.44 cm diameter) is demonstrated. Experimental results are presented that validate simulation findings.

Non Destructive Evaluation↗
DOE OSTI2024

Dynamic Graph Sequence Data from Simulated Neutron Reflectometry Measurements

This dataset comprises dynamic graph sequences derived from simulated in-situ neutron reflectometry measurements, capturing the gradual evolution of a layer structure over time. Each graph sequence represents a synthetic sample, with node features detailing the scattering vector and corresponding reflectivity measurements, while adjacency matrices have corresponding reference material parameters attached as metadata. The dataset spans multiple sets, each with a different number of sequences, offering a comprehensive basis for training models that handle dynamic input sequences with embedded physics. This dataset is particularly suited for tackling inverse problems with hidden physical states that evolve over time, challenges that are typically difficult to address using conventional iterative fitting methods.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Reflectometry with Polarized Neutrons on In Situ Grown Thin Films

Originating from the demand for obtaining depth-resolved magnetization profiles from thin films and heterostructures, polarized neutron reflectometry (PNR) has developed into a unique research tool, which also finds application in the analysis of superconducting or soft matter thin films. While certain in situ sample environments such as gas-loading or humidity cells were quickly realized after PNR first emerged, preparing and growing thin magnetic films directly in the neutron beam could only be realized in recent years. Herein, a dedicated insight is given on the history and development of in situ thin film growth capabilities for PNR, from early pioneering experiments to the present day. The scientific and technological challenges as well as the advances of neutron sources, neutronics, and data treatment that have led to its realization are highlighted together with the unique research opportunities that it provides and recently obtained experimental results.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Electrolyte/Dye/TiO 2 Interfacial Structures of Dye-Sensitized Solar Cells Revealed by In Situ Neutron Reflectometry with Contrast Matching

The nature of an interfacial structure buried within a device assembly is often critical to its function. For example, the dye/TiO 2 interfacial structure that comprises the working electrode of a dye-sensitized solar cell (DSC) governs its photovoltaic output. These structures have been determined outside of the DSC device, using ex situ characterization methods; yet, they really should be probed while held within a DSC since they are modulated by the device environment. Dye/TiO 2 structures will be particularly influenced by a layer of electrolyte ions that lies above the dye self-assembly. We show that electrolyte/dye/TiO 2 interfacial structures can be resolved using in situ neutron reflectometry with contrast matching. Here, we find that electrolyte constituents ingress into the self-assembled monolayer of dye molecules that anchor onto TiO 2 . Some dye/TiO 2 anchoring configurations are modulated by the formation of electrolyte/dye intermolecular interactions. These electrolyte-influencing structural changes will affect dye-regeneration and electron-injection DSC operational processes. This underpins the importance of this in situ structural determination of electrolyte/dye/TiO 2 interfaces within representative DSC device environments.

14 SOLAR ENERGY↗
DOE OSTI2022

Smooth Modified Surfaces of Silicon for the Study of Ionic Liquid Interfaces by Neutron Reflectometry

Silicon surfaces with termination of hydrogen (H–Si), quartz, native silicon (native-Si), and chemically deposited (Au–Si) cd and sputtered gold (Au–Si) s were fabricated with roughness less than 6 Å to study the solid–liquid interface of the ionic liquid (IL) methyltrioctylammonium bis(trifluoromethylsulfonyl)imide, [N 1888 ][TFSI], by neutron reflectometry (NR). The modifications made to the silicon surface were to obtain a native positive or negative charge similar to a charged surface in electrochemical systems. The differences in scattering length density (SLD) based on mass density and composition of IL were examined. Perpendicular to the substrate surface, a distinct transition between the first ion layer and the bulk liquid is resolved out of the reflectivity data for the gold surfaces and in particular the chemically deposited Au–Si. Other interfaces are best described by a diffuse transition between regions of different SLDs. The diffuse transitions between SLDs observed here suggest that the interfacial structure of IL, while ordered, is best described by a continuous variation in composition as opposed to distinct layers of ions.

25 ENERGY STORAGE↗