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At least 55 records · Page 3

Microfluidics, Chromatography, and Atomic-Force Microscopy

A Raman-and-atomic-force microscope (RAFM) has been shown to be capable of performing several liquid-transfer and sensory functions essential for the operation of a microfluidic laboratory on a chip that would be used to perform rapid, sensitive chromatographic and spectro-chemical analyses of unprecedentedly small quantities of liquids. The most novel aspect of this development lies in the exploitation of capillary and shear effects at the atomic-force-microscope (AFM) tip to produce shear-driven flow of liquids along open microchannels of a microfluidic device. The RAFM can also be used to perform such functions as imaging liquids in microchannels; removing liquid samples from channels for very sensitive, tip-localized spectrochemical analyses; measuring a quantity of liquid adhering to the tip; and dip-pen deposition from a chromatographic device. A commercial Raman-spectroscopy system and a commercial AFM were integrated to make the RAFM so as to be able to perform simultaneous topographical AFM imaging and surface-enhanced Raman spectroscopy (SERS) at the AFM tip. The Raman-spectroscopy system includes a Raman microprobe attached to an optical microscope, the translation stage of which is modified to accommodate the AFM head. The Raman laser excitation beam, which is aimed at the AFM tip, has a wavelength of 785 nm and a diameter of about 5 m, and its power is adjustable up to 10 mW. The AFM is coated with gold to enable tip-localized SERS.

Anderson, Mark↗

On-Demand Urine Analyzer

A lab-on-a-chip was developed that is capable of extracting biochemical indicators from urine samples and generating their surface-enhanced Raman spectra (SERS) so that the indicators can be quantified and identified. The development was motivated by the need to monitor and assess the effects of extended weightlessness, which include space motion sickness and loss of bone and muscle mass. The results may lead to developments of effective exercise programs and drug regimes that would maintain astronaut health. The analyzer containing the lab-on-a- chip includes materials to extract 3- methylhistidine (a muscle-loss indicator) and Risedronate (a bone-loss indicator) from the urine sample and detect them at the required concentrations using a Raman analyzer. The lab-on- a-chip has both an extractive material and a SERS-active material. The analyzer could be used to monitor the onset of diseases, such as osteoporosis.

Farquharson, Stuart↗

Blocking Losses With a Photon Counter

It was not known how to assess accurately losses in a communications link due to photodetector blocking, a phenomenon wherein a detector is rendered inactive for a short time after the detection of a photon. When used to detect a communications signal, blocking leads to losses relative to an ideal detector, which may be measured as a reduction in the communications rate for a given received signal power, or an increase in the signal power required to support the same communications rate. This work involved characterizing blocking losses for single detectors and arrays of detectors. Blocking may be mitigated by spreading the signal intensity over an array of detectors, reducing the count rate on any one detector. A simple approximation was made to the blocking loss as a function of the probability that a detector is unblocked at a given time, essentially treating the blocking probability as a scaling of the detection efficiency. An exact statistical characterization was derived for a single detector, and an approximation for multiple detectors. This allowed derivation of several accurate approximations to the loss. Methods were also derived to account for a rise time in recovery, and non-uniform illumination due to diffraction and atmospheric distortion of the phase front. It was assumed that the communications signal is intensity modulated and received by an array of photon-counting photodetectors. For the purpose of this analysis, it was assumed that the detectors are ideal, in that they produce a signal that allows one to reproduce the arrival times of electrons, produced either as photoelectrons or from dark noise, exactly. For single detectors, the performance of the maximum-likelihood (ML) receiver in blocking is illustrated, as well as a maximum-count (MC) receiver, that, when receiving a pulse-position-modulated (PPM) signal, selects the symbol corresponding to the slot with the largest electron count. Whereas the MC receiver saturates at high count rates, the ML receiver may not. The loss in capacity, symbol-error-rate (SER), and count-rate were numerically computed. It was shown that the capacity and symbol-error-rate losses track, whereas the count-rate loss does not generally reflect the SER or capacity loss, as the slot-statistics at the detector output are no longer Poisson. It is also shown that the MC receiver loss may be accurately predicted for dead times on the order of a slot.

Moision, Burce E.↗

Infrared emission of Novae

Nova Ser 1970 and Aql 1970 luminous IR emission, discussing stellar brightness, grain formation and optical decay

Geisel, S. L.↗

Detection of a lysosomal carboxypeptidase and a lysosomal dipeptidase in highly-purified dipeptidyl aminopeptidase I /cathepsin C/ and the elimination of their activities from preparations used to sequence peptides.

Description of the properties of a carboxypeptidase, termed 'catheptic carboxypeptidase C,' and a dipeptidase, termed 'Ser-Met dipeptidase.' Both were found in highly purified DAP I from either beef spleen or rat liver. Methods are described for the removal or selective inactivation of these contaminating enzymes.

Mcdonald, J. K.↗

On the nature of BD-10 deg 4662

Attention was first called to BD-10 deg 4662 (now assigned variable-star designation FK Ser) by Stienon (1971), who reported a temporary brightening in the blue on a Case objective-prism plate, accompanied by Balmer emission and a strong ultraviolet continuum. In its normal state the star appeared to be an ordinary late K-type object without emission features. Infrared observations show that BD-10 deg 4662 has excesses in the H - K and K - L colors similar to ordinary T Tauri stars. Emission at Ca II H and K confirms the close relationship to that group of objects.

Zappala, R. R.↗

The light curve of CV Serpentis, the sometimes-eclipsing Wolf-Rayet star

New photoelectric observations of the B-magnitude of CV Ser made in 1973 and 1974 show no clear evidence of an eclipse, but they establish night-to-night variability of several percent, a systematic brightness change of 0.035 mag during a portion of the single orbit observed in 1973, and irregular flaring in 1974. We made iris photometer measurements of Harvard patrol plates taken between 1905 June and 1953 July, and find no evidence of a very deep eclipse such as observed by Hjellming and Hiltner. We present several new light curves and discuss then in the light of the recent results of Cowley et al.

Schild, R.↗

CNO abundances and hydrodynamic models of the Nova outbursts. 4: Comparison with observations

A variety of observations of novae are discussed in light of theoretical models. It is proposed that the nearly constant bolometric luminosity of FH Ser originates in the non-degenerate hydrogen-burning region at the bottom of the hydrogen-rich envelope which remains after the primary ejection. The shift of the wavelength of peak emission from the visual to shortward of the ultraviolet is caused by the decrease of the photospheric radius of the remnant envelope as the bolometric luminosity stays nearly constant. The oscillations in the light curve of GK Per during the transition stage can be explained by a pulsation of the remnant envelope when it is the size of the Roche lobe. The CNO over-abundances in novae reported by various observers are strongly suggestive of this nova mechanism. Finally, the implications of the upper limits of C-13 and N-15 in DQ Her are discussed.

Sparks, W. M.↗

On the total energy output of the nova outburst

It is shown that the postmaximum decline in optical light during the outburst of a normal classical nova is caused by a shift in the wavelength of maximum energy to the ultraviolet. The constant-luminosity phase which was directly observed in Nova FH Ser 1970 may, therefore, be common to all novae, regardless of speed class. This implies that all speed classes of novae have similar energy budgets and that it is the total energy involved in the outburst which produces the variation in the observed characteristics of the novae. Recent thermonuclear runaway models for the outburst also show an extended period of high luminosity and high effective temperature following the initial outburst.

Gallagher, J. S.↗

CNO abundances and hydrodynamic models of the nova outburst. IV - Comparison with observations

A variety of observations of novae are discussed in light of theoretical models. It is proposed that the nearly constant bolometric luminosity of FH Ser originates in the nondegenerate hydrogen-burning region at the bottom of the hydrogen-rich envelope which remains after the primary ejection. The shift of the wavelength of peak emission from the visual to shortward of the ultraviolet is caused by the decrease of the photospheric radius of the remnant envelope as the bolometric luminosity stays nearly constant. The oscillations in the light curve of GK Per during the transition stage can be explained by a pulsation of the remnant envelope when it is larger than the semimajor axis of the binary system. The CNO overabundances in novae reported by various observers are strongly suggestive of the proposed nova mechanism. Implications of the upper limits on C-13 and N-15 found in DQ Her are discussed.

Sparks, W. M.↗

X-ray bursts from MXB 1837+05

Results are reported for SAS 3 observations of 22 bursts from the X-ray source designated MXB 1837+05. Assuming that all the bursts come from one source, the source position is determined to be right ascension (1950) 18 hr 37.9 min, declination (1950) 5 deg 4.2 min. Integrated burst intensities are listed along with ratios of counts in different energy channels, and it is found that there are significant variations in these ratios from burst to burst. The bursts are also shown to exhibit a variety of temporal structures (including double peaks) and changes in spectral hardness. No regularity was detected in the burst occurrence times during one observing period, but four bursts during another period seemed to recur at regular intervals of about 6.3 hr. It is concluded that an intensity-interval correlation similar to that for a rapid burster does not exist for MXB 1837+05 and that this source is probably identical with the relatively strong and steady source Ser X.1.

Li, F. K.↗

The X-ray source Serpens X-1 - Ariel 5 observations and discussion of models for the spectrum and time variability

Experimental data from Ariel 5 on the spectral shape and time variability of Ser X-1 are presented, and possible explanations for the observations are discussed in terms of current theoretical suggestions for source emission. The observations are summarized in the form of a light curve for 3-7.6-keV photons. The data are fitted with a power law of index -2.3, which yields a hydrogen column density of (1.1 + or - 0.4) x 10 to the 22nd power atoms/sq cm. No persistent periodicity of amplitude greater than 5% of the steady flux is found, but evidence of statistically significant burst activity is obtained. Various emission mechanisms are considered for the time-averaged spectrum and the X-ray bursts. It is suggested that the inverse Compton mechanism is a likely cause for the emission from this source and that the source is radiating near the Eddington limit.

Coe, M. J.↗

Optical observations of X-ray bursts from MXB 1837 + 05

Optical observations of the X-ray burst source MXB 1837 + 05 (Ser X-1) made at different observatories are discussed. Six X-ray bursts were detected with SAS-3 X-ray Observatory during these observations, but no simultaneous optical signals were seen during or after any of these bursts. For an assumed burst duration of 10 sec, the 3-sigma upper limits of the ratio of the detected energy in an optical burst to that in an X-ray burst range from 3 x 10 to the minus fifth to 6 x 10 to the minus fifth.

Bernacca, P. L.↗

X-ray burst sources

Current knowledge of sources of X-ray bursts, defined as having rise times of less than a few seconds, durations of a few seconds to a few minutes and a generally regular recurrence pattern, is reviewed. An examination of the galactic distribution of X-ray burst sources, which has been confirmed by SAS-3 rotating modulation collimator observations, reveals that the burst sources are spread along the galactic equator and clustered near low galactic longitudes, unlike the distribution of globular clusters. At least four X-ray burst sources have been associated with steady X-ray sources based on positional coincidence, and it has been found that the X-ray bursts are less intense but harder than steady X-ray emission from these sources. Individual burst sources, including MXB1659-29, which has not been identified with a steady X-ray source, the source in NGC6624 which has been identified with 3U1820-30, MXB1837+05, associated with Ser X-1, three burst sources near the galactic center and the rapid burster MXB1730-335 are briefly discussed.

Lewin, W. H. G.↗

The detection of an optical burst coincident with an X-ray burst from MXB 1837 + 05 /Ser X-1/

The detection of a simultaneous optical and X-ray burst from MXB 1837 + 05 (4U 1837 + 04 = Ser X-1) is reported. A similar detection was made earlier from MXB 1735-44. These are the only two burst sources that have been optically observed (simultaneous with X-ray observations) at a high level of sensitivity. Therefore, it may well be that optical bursts commonly accompany X-ray bursts. The relative timing and flux ratio of the optical and X-ray bursts imply that the optical radiation is probably reemission from X-ray-heated matter within 1-2 light seconds of the X-ray source and no more than a few light seconds in extent. This matter may be in an accretion disk around the X-ray source or possibly in the atmosphere of a dwarf companion.

Hackwell, J. A.↗

IUE observations of long period eclipsing binaries - A study of accretion onto non-degenerate stars

IUE observations made in 1978-1979 recorded a whole class of interacting long-period binaries similar to beta Lyrae, which includes RX Cas, SX Cas, V 367 Cyg, W Cru, beta Lyr, and W Ser, called the W Serpentis stars. These mass-transferring binaries with relatively high mass transfer rate show two prominent features in the far ultraviolet: a continuum with a color temperature higher than the one observed in the optical region (about 12,000 K), and a strong emission line spectrum with the N V doublet at 1240 A, C IV doublet at 1550 A and lines of Si II, Si III, Si IV, C II, Fe III, AI III, etc. These phenomena are discussed on the assumption that they are due to accretion onto non-degenerate stars.

Plavec, M. J.↗

IUE spectroscopic investigation of interacting binary systems

The IUE observations of binaries consisting of at least one early type star, to the Algol systems, and to W Serpentis systems are discussed. The OB close binaries almost invaribly show a stellar wind. The difference between an unevolved early type system and a slightly evolved system is difficult to discern observationally and probably not meaningful in terms of Roche lobes. the zeta Aur stars show complex gas motions and shocks. Many of the Algol systems show peculiarities in their ultraviolet continua and the resonance lines, particularly Si IV, are of abnormal and variable strength. Emission lines were detected in several systems during the total eclipse. The W Ser stars are characterized by numerous strong emission lines in their ultraviolet spectra. It appears that these systems may be related to beta Lyrae as they seem to be in a phase of rapid mass transfer and their spectra show similarities to that of beta Lyrae.

Mccluskey, G. E., Jr.↗

The W Serpentis binaries with a few words on epsilon Aurigae

The Algol systems, U-Cephei and V356 Sagittarii, which should be included among the W Serpentis stars, characterized by strong ultraviolet emission lines are discussed. The spectra of the W-Ser stars are similar to those of the T-Tauri stars, and a similarity of physical conditions is indicated. A model of W-Serpentis, a B-star embedded in a thick disk, may be relevant to other exotic eclipsing systems, possibly even to obliquity of ecliptic Aurigae. The obliquity of ecliptic and the relationship to Aur, BM Orionis is reviewed; the system probably contains a pre main sequence star highly flattened by differential rotation.

Plavec, M. J.↗