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43 records · Page 3

PAVC Gridded 20m Alaska NGEE Tier3 PFTs v1.0

These 20-meter spatial resolution gridded products provide per-pixel fractional cover (%) of Next Generation Ecosystem Experiments (NGEE) Arctic Plant Functional Types (PFTs) Tier 3 across Alaska, north of the boreal treeline. The products were developed for the NGEE Arctic project, which is improving Arctic vegetation representation and parameterization of the E3SM Land Model. This dataset includes 8 files containing fractional cover for NGEE Tier 3 PFTs (https://data.ess-dive.lbl.gov/view/doi:10.15485/2529470): (1) bryophytes; (2) lichens; (3) non-vascular plants, i.e., the sum of lichens and bryophytes; (4) deciduous shrubs, (5) evergreen shrubs, (6) forbs, (7) graminoids, and a non-PFT class, (8) litter. Each pixel contains the percent cover (expressed as a fraction of total ground cover) that was predicted by random-forest regression models. The random-forest models were trained on cover data collected at 978 plots from 2010 to 2021, of which are archived in the Pan-Arctic Vegetation Cover (PAVC) database (https://data.ess-dive.lbl.gov/datasets/doi:10.15485/2483557). The plot cover was linked to 20-meter spatial resolution, satellite-derived predictor variables: Sentinel-2 spectra and Sentinel-1 polarizations averaged over the 2019 growing season, as well as topographical features derived from ArcticDEM. Then, spatio-temporally anomalous plot data that introduced large variability to the regression outcomes were dropped using the Cook’s distance outlier detection method, and the models were re-created using high-quality plots and their associated satellite derived explanatory variables per each PFT. The correlations between plot-observed and satellite-derived fractional cover for all PFTs were well correlated (R2 = 0.69–0.95 and 0.5 for litter) and had low RMSE bias (0.02–0.11). This research was performed as a part of the NGEE Arctic project. The NGEE Arctic project was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.

54 ENVIRONMENTAL SCIENCES↗

Uptake, Efflux, and Sequestration of Mercury in the Asian Clam, Corbicula fluminea , at Environmentally Relevant Concentrations, and the Implications for Mercury Remediation

(1) Mercury (Hg) is a persistent, ubiquitous contaminant that readily biomagnifies into higher trophic level species in aquatic environments across the globe. It is crucial to understand the movement of environmentally relevant concentrations of Hg in impacted freshwater streams to minimize risks to ecological and human health. (2) The bioconcentration kinetics of aqueous Hg exposure (20, 100, and 200 ng/L) in the invasive Asian Clam, Corbicula fluminea, were measured. A toxicokinetic model, the first parameterized for Hg accumulation in freshwater clams, was developed to estimate uptake and efflux parameters and compared to previous parameter values estimated for other mollusk species. (3) Results demonstrated that even at low Hg concentrations, Corbicula record signals of contamination through bioconcentration, and both direct measurement and toxicokinetic models demonstrate large Hg bioconcentration factors (as high as 1.34 × 10 5 mL/g dry tissue), similar to partitioning coefficients seen in engineered Hg sorbents. (4) Our study found that Corbicula accumulated Hg at aqueous concentrations relevant to impacted streams, but well below regulatory drinking water limits, demonstrating their utility as a sensitive sentinel species and potential bioremediator.

bioaccumulation↗

Brain-implantable multifunctional probe for simultaneous detection of glutamate and GABA neurotransmitters

We report Glutamate (GLU) and gamma-aminobutyric acid (GABA) are neurotransmitters (NTs) with an essential role in signal transmission in the brain. Brain disorders, such as epilepsy, Alzheimer's and Parkinson's diseases, and traumatic brain injury can be linked to imbalances in the GLU-GABA homeostasis that occurs in sub-second to seconds time frames. Current measurement techniques can detect these two NT concentrations simultaneously only in vitro. The present work reports on the fabrication of a silicon multifunctional biosensor microarray probe for sub-second simultaneous GLU-GABA detection in real-time, with excellent analyte sensitivity and selectivity and in vivo capabilities. The novel Si probes feature four surface-functionalized platinum ultramicroelectrodes (UMEs) for simultaneous amperometric detection of GLU and GABA with a sentinel, and a built-in microfluidic channel for the introduction of neurochemicals in the proximity of the UMEs. The microchannel also allows functioning of an On-Demand In-situ Calibrator that runs in-situ biosensor calibration. The probe exhibited excellent robustness at insertion in agarose-gel brain-tissue-mimicking test, and remarkably high hydrogen peroxide sensitivity (a by-product of GLU-GABA enzyme biosensor) with values on the order of 5000 nA μM -1 cm -2 and maximum sensitivities of 204 ± 15 nA μM -1 cm -2 and 37 ± 7 nA μM -1 cm -2 for GLU and GABA, respectively. Furthermore, the limit of detection of the biosensors reached as low as 7 nM, 165 nM and 750 nM for H 2 O 2 , GLU and GABA, respectively and a temporal resolution of hundreds of milliseconds during in vivo studies using freely moving rats.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Global 10 m Land Use Land Cover Datasets: A Comparison of Dynamic World, World Cover and Esri Land Cover

The European Space Agency’s Sentinel satellites have laid the foundation for global land use land cover (LULC) mapping with unprecedented detail at 10 m resolution. We present a cross-comparison and accuracy assessment of Google’s Dynamic World (DW), ESA’s World Cover (WC) and Esri’s Land Cover (Esri) products for the first time in order to inform the adoption and application of these maps going forward. For the year 2020, the three global LULC maps show strong spatial correspondence (i.e., near-equal area estimates) for water, built area, trees and crop LULC classes. However, relative to one another, WC is biased towards over-estimating grass cover, Esri towards shrub and scrub cover and DW towards snow and ice. Using global ground truth data with a minimum mapping unit of 250 m 2 , we found that Esri had the highest overall accuracy (75%) compared to DW (72%) and WC (65%). Across all global maps, water was the most accurately mapped class (92%), followed by built area (83%), tree cover (81%) and crops (78%), particularly in biomes characterized by temperate and boreal forests. The classes with the lowest accuracies, particularly in the tundra biome, included shrub and scrub (47%), grass (34%), bare ground (57%) and flooded vegetation (53%). When using European ground truth data from LUCAS (Land Use/Cover Area Frame Survey) with a minimum mapping unit of <100 m 2 , we found that WC had the highest accuracy (71%) compared to DW (66%) and Esri (63%), highlighting the ability of WC to resolve landscape elements with more detail compared to DW and Esri. Although not analyzed in our study, we discuss the relative advantages of DW due to its frequent and near real-time data delivery of both categorical predictions and class probability scores. We recommend that the use of global LULC products should involve critical evaluation of their suitability with respect to the application purpose, such as aggregate changes in ecosystem accounting versus site-specific change detection in monitoring, considering trade-offs between thematic resolution, global versus. local accuracy, class-specific biases and whether change analysis is necessary. We also emphasize the importance of not estimating areas from pixel-counting alone but adopting best practices in design-based inference and area estimation that quantify uncertainty for a given study area.

54 ENVIRONMENTAL SCIENCES↗

Evaluating the state-of-the-art in remote volcanic eruption characterization Part I: Raikoke volcano, Kuril Islands

Raikoke, a small, unmonitored volcano in the Kuril Islands, erupted in June 2019. We integrate data from satellites (including Sentinel-2, TROPOMI, MODIS, Himawari-8), the International Monitoring System (IMS) infrasound network, and global lightning detection network (GLD360) with information from local authorities and social media to retrospectively characterize the eruptive sequence and improve understanding of the pre-, syn- and post- eruptive behavior. In this work, we observe six infrasound pulses beginning on 21 June at 17:49:55 UTC as well as the main Plinian phase on 21 June at 22:29 UTC. Each pulse is tracked in space and time using lightning and satellite imagery as the plumes drift eastward. Post-eruption visible satellite imagery shows expansion of the island's surface area, an increase in crater size, and a possibly-linked algal bloom south of the island. We use thermal satellite imagery and plume modeling to estimate plume height at 10–12 km asl and 1.5–2 × 10 6 kg/s mass eruption rate. Remote infrasound data provide insight into syn-eruptive changes in eruption intensity. Our analysis illustrates the value of interdisciplinary analyses of remote data to illuminate eruptive processes. However, our inability to identify deformation, pre-eruptive outgassing, and thermal signals, which may reflect the relatively short duration (~12 h) of the eruption and minimal land area around the volcano and/or the character of closed-system eruptions, highlights current limitations in the application of remote sensing for eruption detection and characterization.

58 GEOSCIENCES↗

Shallow Aseismic Slip in the Delaware Basin Determined by Sentinel-1 InSAR

The Delaware Basin, Texas is currently a hot-spot of induced seismicity and ground deformation due to fluid extraction and injection associated with horizontal drilling techniques; however, the driving mechanism behind the seismicity and deformation remains under debate. Here, using vertical and east-west horizontal surface deformation measurements derived from Sentinel-1 interferometric synthetic aperture radar (InSAR), we show that the subsurface responds differently to oil and gas activity in the northern and southeastern portions of the basin. In the north, where there is little seismicity, deformation patterns display long-wavelengths and equidimensional patterns. In contrast, the southeast region hosts most of the seismicity and displays spatial deformation patterns with narrow linear features that strike parallel to the maximum principal horizontal stress and to trends in seismicity, suggesting movement along normal faults. We model a linear deformation feature using edge dislocations and show that the InSAR observations can be reproduced by slip on normal faults contained within the Delaware Mountain Group (DMG), the formation that hosts local wastewater injection and the majority of earthquakes. Our model consists of three parallel, high-angle normal faults, with two dipping toward one another in a graben structure. Slip magnitudes reach up to 25 cm and are spatially correlated with injection wells. Measured seismicity can only explain ~2% of the fault motion predicted by our fault model, suggesting that slip leading to the deformation is predominantly aseismic. We conclude that seismic and aseismic fault motion in the southeastern Delaware Basin is likely driven by wastewater injection near critically-stressed normal faults within the DMG.

58 GEOSCIENCES↗

Multi-scale integration of satellite remote sensing improves characterization of dry-season green-up in an Amazon tropical evergreen forest

In tropical forests, leaf phenology-particularly the pronounced dry-season green-up-strongly regulates biogeochemical cycles of carbon and water fluxes. However, uncertainties remain in the understanding of tropical forest leaf phenology at different spatial scales. Phenocams accurately characterize leaf phenology at the crown and ecosystem scales but are limited to a few sites and time spans of a few years. Time-series satellite observations might fill this gap, but the commonly used satellites (e.g. MODIS, Landsat and Sentinel-2) have resolutions too coarse to characterize single crowns. To resolve this observational challenge, we used the PlanetScope constellation with a 3m resolution and near daily nadir-view coverage. We first developed a rigorous method to cross-calibrate PlanetScope surface reflectance using daily BRDF-adjusted MODIS as the reference. We then used linear spectral unmixing of calibrated PlanetScope to obtain dry-season change in the fractional cover of green vegetation (GV) and non-photosynthetic vegetation (NPV) at the PlanetScope pixel level. We used the Central Amazon Tapajos National Forest k67 site, as all necessary data (from field to phenocam and satellite observations) was available. For this proof of concept, we chose a set of 22 dates of PlanetScope measurements in 2018 and 16 in 2019, all from the six drier months of the year to provide the highest possible cloud-free temporal resolution. Our results show that MODIS-calibrated dry-season PlanetScope data (1) accurately assessed seasonal changes in ecosystem-scale and crown-scale spectral reflectance; (2) detected an increase in ecosystem-scale GV fraction (and a decrease in NPV fraction) from June to November of both years, consistent with local phenocam observations with R 2 around 0.8; and (3) monitored large seasonal trend variability in crown-scale NPV fraction. Finally, our results highlight the potential of integrating multi-scale satellite observations to extend fine-scale leaf phenology monitoring beyond the spatial limits of phenocams.

54 ENVIRONMENTAL SCIENCES↗