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Ultraviolet Radiation-induced Alteration of Martian Surface Materials

The nature and origin of martian surface materials cannot be fully characterized without addressing the unusual reactivity of the soil and the effects of exposure to the unique martian environment. Our laboratory experiments show that ultraviolet radiation at the martian surface can result in the oxidation of metal atoms and the creation of reactive oxygen species on grain surfaces. This process is important in understanding the nature and evolution of martian soils. It can explain the reactivity discovered by the Viking Landers and possibly the origin of the ferric component of the soil.

Yen, A. S.↗

Canadian Experiment for Soil Moisture in 2010 (CanEX-SM10): Overview and Preliminary Results

The Canadian Experiment for Soil Moisture in 2010 (CanEx-SM10) was carried out in Saskatchewan, Canada from 31 May to 16 June, 2010. Its main objective was to contribute to Soil Moisture and Ocean salinity (SMOS) mission validation and the pre-launch assessment of Soil Moisture and Active and Passive (SMAP) mission. During CanEx-SM10, SMOS data as well as other passive and active microwave measurements were collected by both airborne and satellite platforms. Ground-based measurements of soil (moisture, temperature, roughness, bulk density) and vegetation characteristics (Leaf Area Index, biomass, vegetation height) were conducted close in time to the airborne and satellite acquisitions. Besides, two ground-based in situ networks provided continuous measurements of meteorological conditions and soil moisture and soil temperature profiles. Two sites, each covering 33 km x 71 km (about two SMOS pixels) were selected in agricultural and boreal forested areas in order to provide contrasting soil and vegetation conditions. This paper describes the measurement strategy, provides an overview of the data sets and presents preliminary results. Over the agricultural area, the airborne L-band brightness temperatures matched up well with the SMOS data. The Radio frequency interference (RFI) observed in both SMOS and the airborne L-band radiometer data exhibited spatial and temporal variability and polarization dependency. The temporal evolution of SMOS soil moisture product matched that observed with the ground data, but the absolute soil moisture estimates did not meet the accuracy requirements (0.04 m3/m3) of the SMOS mission. AMSR-E soil moisture estimates are more closely correlated with measured soil moisture.

Magagi, Ramata↗

Laboratory simulations of the Viking Labeled Release experiment - Kinetics following second nutrient injection and the nature of the gaseous end product

Injection of (C-14)-labeled nutrient onto Mars soil produced an evolution of C-14 gas in the Viking Labeled Release (LR) experiment. However, a second injection of nutrient seven days later was followed by an abrupt diminution of the amount of radioactive gas in the test cell. Simulation experiments performed in the LR Test Standards Module (TSM) have yielded a plausible explanation for this diminution. Radioactive carbon gases were injected into the TSM test cell in the presence and absence of two Mars analog soils. After equilibration, water was injected and its effect observed. The results indicate that the flight data following second nutrient injection can be explained on a physico-chemical basis involving a carbon dioxide/water/soil equilibrium in the test cell. The results also suggest that the gaseous end product of the Labeled Release reaction on Mars is more likely carbon dioxide than carbon monoxide.

Levin, G. V.↗

A scheme for computing surface layer turbulent fluxes from mean flow surface observations

A physical model and computational scheme are developed for generating turbulent surface stress, sensible heat flux and humidity flux from mean velocity, temperature and humidity at some fixed height in the atmospheric surface layer, where conditions at this reference level are presumed known from observations or the evolving state of a numerical atmospheric circulation model. The method is based on coupling the Monin-Obukov surface layer similarity profiles which include buoyant stability effects on mean velocity, temperature and humidity to a force-restore formulation for the evolution of surface soil temperature to yield the local values of shear stress, heat flux and surface temperature. A self-contained formulation is presented including parameterizations for solar and infrared radiant fluxes at the surface. Additional parameters needed to implement the scheme are the thermal heat capacity of the soil per unit surface area, surface aerodynamic roughness, latitude, solar declination, surface albedo, surface emissivity and atmospheric transmissivity to solar radiation.

Hoffert, M. I.↗

A scheme for computing surface fluxes from mean flow observations

A computational method for estimating turbulent surface stress, sensible heat flux, and humidity flux from mean velocity, temperature, and humidity at a single height in the atmospheric surface layer is presented. The method is based on coupling a Monin-Obukhov similarity profile to a 'force-restore' formulation for the evolution of surface soil temperature to yield the local values of shear stress, heat flux, and surface temperature. In addition to reference-level mean flow properties, the parameters required to implement this method are the thermal heat capacity of the soil, the surface aerodynamic roughness, latitude, solar declination, surface albedo, surface emissivity, and atmospheric transmissivity. Sample calculations are presented for (1) constant atmospheric forcing at the reference level, and (2) variable atmospheric forcing corresponding to Kahle's (1977) measurements of windspeed, air temperature, and radiometer soil surface temperature under dry vegetatively sparse conditions in the Mohave Desert, Calif.

Hoffert, M. I.↗

Labeled Release - An experiment in radiorespirometry

The Labeled Release extraterrestrial life detection experiment onboard the Viking spacecraft is described as it will be implemented on the surface of Mars in 1976. This experiment is designed to detect heterotrophic life by supplying a dilute solution of radioactive organic substrates to a sample of Martian soil and monitoring for evolution of radioactive gas. A significantly attenuated response by a heat-sterilized control sample of the same soil would confirm a positive metabolic response. Experimental assumptions as well as criteria for the selection of organic substrates are presented. The Labeled Release nutrient has been widely tested, is versatile in eliciting terrestrial metabolic responses, and is stable to heat sterilization and to the long-term storage required before its use on Mars. A testing program has been conducted with flight-like instruments to acquire science data relevant to the interpretation of the Mars experiment. Factors involved in the delineation of a positive result are presented and the significance of the possible results discussed.

Levin, G. V.↗

LASE measurements of convective boundary layer development during SGP97

The Southern Great Plains 1997 (SGP97) field experiment was conducted in Oklahoma during June-July 1997 to validate the models used for computing remote soil moisture using measurements by microwave radiometers. One of the objectives of SGP97 was to examine the effect of soil moisture on the evolution of the Atmospheric Boundary Layer (ABL) and clouds over the Southern Great Plains (SGP) during the warm season. The LASE (Lidar Atmospheric Sensing Experiment) airborne DIAL (Differential Absorption Lidar) system, which was flown autonomously on the NASA ER-2 aircraft during previous missions, was reconfigured to fly on the NASA P3 research aircraft. During SGP97 LASE was used to study the morning evolution of the ABL, particularly as manifested in the development of the convective boundary layer, and to study the influence of soil moisture variations on the development of ABL. The ABL development is strongly influenced by the surface energy budget, which is in turn influenced by soil moisture, mesoscale meteorology, clouds, and solar insolation. LASE data acquired during this mission are being used to study the ABL water vapor budget, the development of the ABL, spatial and temporal variabilities in the ABL, and the meteorological factors that influence the ABL development. This field experiment also permitted comparisons of LASE water vapor measurements with water vapor profiles acquired by radiosondes launched at the DOE (Department of Energy) Atmospheric Radiation Measurement (ARM) Southern Great Plain (SGP) site and at NASA/Wallops Flight Facility, as well as with measurements from other SGP97 aircraft.

Ismail, Syed↗

Assessing the Impact of SMAP Soil Moisture Data Assimilation on the Simulation and Prediction of Tropical Cyclone Idai

The role of soil moisture in the evolution of tropical cyclones (TCs) approaching land has long been recognized. Dry land surface conditions can lead to faster dissipation of a TC over land (often associated with changes in precipitation structure), whereas very wet conditions can help sustain or even re-intensify a TC. The ability to forecast post-landfall TC evolution and mitigate the associated socio-economic impact thus hinges on accurate knowledge of land surface conditions prior to landfall. The NASA Soil Moisture Active Passive (SMAP) mission provides accurate observations of soil moisture globally and at high revisit times of 2-3 days. It has been shown that the assimilation of SMAPbrightness temperatures (Tb) significantly improves modeled land surface states and thus has the potential to constrain land surface initial conditions in TC forecasts. In this presentation, we investigate this potential through an extensive set of Observing System Experiments that systematically assess the impact of assimilating SMAP Tbs on TC forecast skill in the Goddard Earth Observing System. Focusing on the case of TC Idai, we show that the assimilation of SMAP generally leads to a drier soil moisture analysis for the land surface underneath much of the storm’s circulation. An exception is the direct TC track, where SMAP assimilation increases soil moisture. These changes are reflected in the surface fluxes, which propagate the land surface state changes to the atmosphere. This results a TC that is overall weaker with lower winds, but with a better-defined eye and a slightly smaller track error than a simulation without SMAP DA. The changes in soil moisture resulting from the assimilation of SMAP also impact the total precipitation amounts as well as the precipitation structure associated with TC Idai.

SMAP↗

Origin and Reactivity of the Martian Soil: A 2003 Micromission

The role of water in the development of the martian surface remains a fundamental scientific question. Did Mars have one or more "warm and wet" climatic episodes where liquid water was stable at the surface? If so, the mineral phases present in the soils should be consistent with a history of aqueous weathering. More generally, the formation of hydrated mineral phases on Mars is a strong indicator of past habitable surface environments. The primary purpose of this investigation is to help resolve the question of whether such aqueous indicators are present on Mars by probing the upper meter for diagnostic mineral species. According to Burns [1993], the formation of the ferric oxides responsible for the visible color of Mars are the result of dissolution of Fe (+2) phases from basalts followed by aqueous oxidation and precipitation of Fe" mineral assemblages. These precipitates likely included iron oxyhydroxides such as goethite (a-FeOOH) and lepidocrocite (g-FeOOH), but convincing evidence for these phases at the surface is still absent. The stability of these minerals is enhanced beneath the surface, and thus we propose a subsurface search for hydroxylated iron species as a test for a large-scale chemical weathering process based on interactions with liquid water. It is also possible that the ferric minerals on Mars are not aqueous alteration products of the rocks. A chemical study of the Pathfinder landing site concluded that the soils are not directly derived from the surrounding rocks and are enhanced in Mg and Fe. The additional source of these elements might be from other regions of Mars and transported by winds, or alternatively, from exogenic sources. Gibson [1970] proposed that the spectral reflectivity of Mars is consistent with oxidized meteoritic material. Yen and Murray [1998] further extend Gibson's idea and show, in the laboratory, that metallic iron can be readily oxidized to maghemite and hematite under present-day martian surface conditions (in the absence of liquid water). A test for a meteoritic component of the soil can be conducted, as described below, by searching for the presence of Ni at the martian surface. The average abundance of nickel in an Fe-Ni meteorite is about 7% and, if present at measurable levels in the soil, would be indicative of an exogenic contribution. In addition, it may be possible to directly search for mineral phases common in meteorites. An understanding of the formation and evolution of the martian soil would not be complete without addressing the unusual reactivity discovered by the Viking Landers The presence of an inorganic oxidant, possibly one produced as a results of photochemical processes, is the most widely accepted explanation of the Viking results. Are these chemical species simply adsorbed on soil grains, or have they reacted with the metal oxide substrates and altered the mineral structures? Could a completely different (non-photochemical) process be responsible for the soil reactivity? The various ideas for the nature of this putative oxidant could be constrained by a measurement of the change in reactivity with depth. Different compositions will have different lifetimes and mobilities and thus will have different vertical profiles. Because the oxidizing compounds are believed to actively destroy organic molecules, determination of the reactivity gradient also has significant implications for the search for life on Mars. A DS2-based microprobe system can be instrumented for a 2003 micromission to investigate the origin and reactivity of the martian soil. These measurements would provide invaluable information regarding the climate history and exobiological potential of the planet. The NMR, X ray and chemiresistor measurement approach described embodies a highly synergistic and general set of soil interrogation methods for elements, compounds, and crystal structures and can also be applied to other geologic questions of interest. For example, if the capability for precise targeting of the probes is available, then in-situ investigations of suspected evaporite and hydrothermal deposits would be possible with the same set of instruments. Additional information is contained in the original.

Yen, Albert S.↗

Utilization of remote sensing observations in hydrologic models

Most of the remote sensing related work in hydrologic modeling has centered on modifying existing models to take advantage of the capabilities of new sensor techniques. There has been enough success with this approach to insure that remote sensing is a powerful tool in modeling the watershed processes. Unfortunately, many of the models in use were designed without recognizing the growth of remote sensing technology. Thus, their parameters were selected to be map or field crew definable. It is believed that the real benefits will come through the evolution of new models having new parameters that are developed specifically to take advantage of our capabilities in remote sensing. The ability to define hydrologically active areas could have a significant impact. The ability to define soil moisture and the evolution of new techniques to estimate evoportransportation could significantly modify our approach to hydrologic modeling. Still, without a major educational effort to develop an understanding of the techniques used to extract parameter estimates from remote sensing data, the potential offered by this new technology will not be achieved.

Ragan, R. M.↗

Evaluation of Terms in the Water Vapor Budget Using Airborne Dial and In Situ Measurements from the Southern Great Plans 1997 Experiment

The Southern Great Plains (SGP97) field experiment was conducted in Oklahoma during June and July 1997 primarily to validate soil moisture retrieval algorithms using microwave radiometer measurements from aircraft as well as in situ surface measurements. One important objective of the SGP97 experiment plan was to examine the effect of soil moisture on the evolution of the atmospheric boundary layer (ABL) and clouds over the Southern Great Plains during the warm season. To support boundary layer studies during SGP97. the NASA Langley Research Center's Lidar Atmospheric Sensing Experiment (LASE) was flown on a NASA-P3 aircraft in conjunction with the Electronically Scanned Thinned Array Radiometer (ESTAR). The LASE instrument is an airborne, downward-looking differential absorption lidar (DIAL) system capable of measuring water vapor concentration as well as aerosol backscatter with high horizontal and vertical resolution in the ABL. Here, we will demonstrate how the LASE data can be used to determine water vapor statistics and most of the water vapor budget terms in the ABL. This information can then be related to spatial variations in soil moisture and the surface energy budget. The extensive surface and aircraft in situ measurements conducted during SGP97 provide information on the ABL that cannot be retrieved from the LASE data alone and also offer an excellent opportunity to validate the remote water vapor budget measurements with LASE.

Senff, Christoph J.↗

Proceedings of the 40th Lunar and Planetary Science Conference

The 40th Lunar and Planetary Science Conference included sessions on: Phoenix: Exploration of the Martian Arctic; Origin and Early Evolution of the Moon; Comet Wild 2: Mineralogy and More; Astrobiology: Meteorites, Microbes, Hydrous Habitats, and Irradiated Ices; Phoenix: Soil, Chemistry, and Habitability; Planetary Differentiation; Presolar Grains: Structures and Origins; SPECIAL SESSION: Venus Atmosphere: Venus Express and Future Missions; Mars Polar Caps: Past and Present; SPECIAL SESSION: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1, Part I; 5 Early Nebula Processes and Models; SPECIAL SESSION: Icy Satellites of Jupiter and Saturn: Cosmic Gymnasts; Mars: Ground Ice and Climate Change; SPECIAL SESSION: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1, Part II; Chondrite Parent-Body Processes; SPECIAL SESSION: Icy Satellites of Jupiter and Saturn: Salubrious Surfaces; SNC Meteorites; Ancient Martian Crust: Primary Mineralogy and Aqueous Alteration; SPECIAL SESSION: Messenger at Mercury: A Global Perspective on the Innermost Planet; CAIs and Chondrules: Records of Early Solar System Processes; Small Bodies: Shapes of Things to Come; Sulfur on Mars: Rocks, Soils, and Cycling Processes; Mercury: Evolution and Tectonics; Venus Geology, Volcanism, Tectonics, and Resurfacing; Asteroid-Meteorite Connections; Impacts I: Models and Experiments; Solar Wind and Genesis: Measurements and Interpretation; Mars: Aqueous Processes; Magmatic Volatiles and Eruptive Conditions of Lunar Basalts; Comparative Planetology; Interstellar Matter: Origins and Relationships; Impacts II: Craters and Ejecta Mars: Tectonics and Dynamics; Mars Analogs I: Geological; Exploring the Diversity of Lunar Lithologies with Sample Analyses and Remote Sensing; Chondrite Accretion and Early History; Science Instruments for the Mars Science Lander; . Martian Gullies: Morphology and Origins; Mars: Dunes, Dust, and Wind; Mars: Volcanism; Early Solar System Chronology; Seek Out and Explore: Upcoming and Future Missions; Mars: Early History and Impact Processes; Mars Analogs II: Chemical and Spectral; Achondrites and their Parent Bodies; and Planning for Future Exploration of the Moon The poster sessions were: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1; LRO and LCROSS; Geophysical Analysis of the Lunar Surface and Interior; Remote Observation and Geologic Mapping of the Lunar Surface; Lunar Spectroscopy; Venus Geology, Geophysics, Mapping, and Sampling; Planetary Differentiation; Bunburra and Buzzard Coulee: Recent Meteorite Falls; Meteorites: Terrestrial History; CAIs and Chondrules: Records of Early Solar System Processes; Volatile and Organic Compounds in Chondrites; Crashing Chondrites: Impact, Shock, and Melting; Ureilite Studies; Petrology and Mineralogy of the SNC Meteorites; Martian Meteorites; Phoenix Landing Site: Perchlorate and Other Tasty Treats; Mars Polar Atmospheres and Climate Modeling; Mars Polar Investigations; Mars Near-Surface Ice; Mars: A Volatile-Rich Planet; Mars: Geochemistry and Alteration Processes; Martian Phyllosilicates: Identification, Formation, and Alteration; Astrobiology; Instrument Concepts, Systems, and Probes for Investigating Rocks and Regolith; Seeing is Believing: UV, VIS, IR, X- and Gamma-Ray Camera and Spectrometer Instruments; Up Close and Personal: In Situ Analysis with Laser-Induced Breakdown Spectroscopy and Mass Spectrometry; Jupiter and Inscrutable Io; Tantalizing Titan; Enigmatic Enceladus and Intriguing Iapetus; Icy Satellites: Cryptic Craters; Icy Satellites: Gelid Geology/Geophysics; Icy Satellites: Cool Chemistry and Spectacular Spectroscopy; Asteroids and Comets; Comet Wild 2: Mineralogy and More; Hypervelocity Impacts: Stardust Models, LDEF, and ISPE; Presolar Grains; Early Nebular Processes: Models and Isotopes; Solar Wind and Genesis: Measurements and Interpretation; Education and Public Outreach; Mercury; Pursuing Lunar Exploration; Sources and Eruptionf Lunar Basalts; Chemical and Physical Properties of the Lunar Regolith; Lunar Dust and Transient Surface Phenomena; Lunar Databases and Data Restoration; Meteoritic Samples of the Moon; Chondrites, Their Clasts, and Alteration; Achondrites: Primitive and Not So Primitive; Iron Meteorites; Meteorite Methodology; Antarctic Micrometeorites; HEDs and Vesta; Dust Formation and Transformation; Interstellar Organic Matter; Early Solar System Chronology; Comparative Planetology; Impacts I: Models and Experiments; Impacts II: Craters and Ejecta; Mars: Volcanism; Mars: Tectonics and Dynamics; Martian Stratigraphy: Understanding the Geologic History of Mars Through the Sedimentary Rock Record; Mars: Valleys and Valley Networks; Mars: Aqueous Processes in Valles Marineris and the Southern Highlands; Mars: Aqueous Geomorphology; Martian Gullies: Morphology and Origins; Mars: Dunes, Dust, and Wind; Mars: Remote Sensing; Mars: Geologic Mapping, Photogrammetry, and Cratering; Martian Mineralogy: Constraints from Missions and Laboratory Investigations; Mars Analogs: Chemical and Physical; Mars Analogs: Sulfates and Sulfides; Missions: Approaches, Architectures, Analogs, and Actualities; Not Just Skin Deep: Electron Microscopy, Heat Flow, Radar, and Seismology Instruments and Planetary Data Systems, Techniques, and Interpretation.

Source record↗

Origin and evolution of the lunar regolith; Proceedings of the Symposium, Houston, Tex., November 13-15, 1974

The papers consider the origin and evolution of the lunar regolith utilizing data obtained during American and Soviet manned and unmanned lunar missions as well as surface and orbital observations, photography, sample collections, and experimental studies. Topics include the transport and emplacement of crater and basin deposits, development of the mare regolith, the shallow lunar structure as determined from the passive seismic experiment, horizontal transport of the regolith, the origin of the exotic component and KREEP-rich materials, the influx of interplanetary materials onto the moon, stratification in the lunar regolith, catastrophic rupture of lunar rocks, cosmic-ray exposure ages of surface features, breccia formation by sintering and crystallization, evolution of the lunar soil, and effects of maturation on the reflectance of the regolith. Individual items are announced in this issue.

Source record↗

Fe(VI) as a Possible Oxidant on the Martian Surface

The essential findings of the three biological experiments (Gas Exchange, Labeled Released, and Pyrolitic Release) aboard the Viking Mars landers were the discovery of the presence of one or more strong oxidants on the Martian surface. The Gas Exchange experiments showed that wetting Martian soil leads to the evolution of oxygen, while in the Labeled Release experiment addition of a nutrient solution containing C-14-labeled formate, glycine, lactate, alanine, and glycolic acid induced CO2 evolution. A general consensus was reached that all data taken together pointed to the presence on Martian surface of a strong oxidant, or most probably several different types of oxidants. Several candidates have been proposed as oxidants, including superoxides, hydrogen peroxide, and iron oxides (possibly gamma-Fe2O3). Additional information is contained in the original extended abstract.

Tsapin, A. I.↗

RFI and Remote Sensing of the Earth from Space

Passive microwave remote sensing of the Earth from space provides information essential for understanding the Earth's environment and its evolution. Parameters such as soil moisture, sea surface temperature and salinity, and profiles of atmospheric temperature and humidity are measured at frequencies determined by the physics (e.g. sensitivity to changes in desired parameters) and by the availability of suitable spectrum free from interference. Interference from manmade sources (radio frequency interference) is an impediment that in many cases limits the potential for accurate measurements from space. A review is presented here of the frequencies employed in passive microwave remote sensing of the Earth from space and the associated experience with RFI.

RFI↗

Microphysical, microchemical, and adhesive properties of lunar material. III - Gas interaction with lunar material.

Gas adsorption measurements on an Apollo 12 ultrahigh vacuum-stored sample and Apollo 14 and 15 N2-stored samples, show that the cosmic ray track and solar wind damaged surface of lunar soil is very reactive. Room temperature monolayer adsorption of N2 by the Apollo 12 sample at 0.0001 atm was observed. Gas evolution of Apollo 14 lunar soil at liquid nitrogen temperature during adsorption/desorption cycling is probably due to cosmic ray track stored energy release accompanied by solar gas release from depths of 100-200 nm.

Grossman, J. J.↗

Chemistry of Rocks and Soils in Gusev Crater from the Alpha Particle X-ray Spectrometer

The alpha particle x-ray spectrometer on the Spirit rover determined major and minor elements of soils and rocks in Gusev crater in order to unravel the crustal evolution of planet Mars. The composition of soils is similar to those at previous landing sites, as a result of global mixing and distribution by dust storms. Rocks (fresh surfaces exposed by the rock abrasion tool) resemble volcanic rocks of primitive basaltic composition with low intrinsic potassium contents. High abundance of bromine (up to 170 parts per million) in rocks may indicate the alteration of surfaces formed during a past period of aqueous activity in Gusev crater.

Gellert, R.↗