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At least 55 records · Page 3

Long Island Steatite Sourcing from Rhode Island Quarries During the Late Holocene Era

This study aimed to investigate the possible sourcing of Long Island steatite artifacts from quarries in Rhode Island. Seven steatite samples from archeological sites on Long Island including Nassau County, Suffolk County (North Fork and South Fork) and Shelter Island were compared to two Rhode Island quarry sample putative sources using X-ray fluorescence (XRF) microscopy at the Submicron Resolution X-ray spectroscopy (SRX) beamline of the National Synchrotron Light Source II at Brookhaven National Laboratory. The site-derived steatite samples displayed numerous similarities in elemental composition compared to the two Rhode Island quarries, Oaklawn and Ochee Springs. This study provides new evidence to support the possible sourcing of Long Island steatite from Rhode Island during the late Holocene era.

54 ENVIRONMENTAL SCIENCES↗

The spectra of IceCube Neutrino (SIN) candidate sources – III. Optical spectroscopy and source characterization of the full sample

A correlation between astrophysical high-energy neutrinos and blazars has been suggested by various authors. In particular, a likely association between IceCube events and intermediate- and high-energy peaked BL Lac objects has led to a sample of 47 objects having a high probability of being neutrino sources. In the first paper of this series we reported optical spectroscopy of 17 objects, which together with data taken from the literature covered 80 per cent of the sample. Here, we present spectroscopy obtained at large aperture telescopes of a further 17 objects (plus four additional targets), which completes the sample coverage. For 12 objects we are able to determine the redshift (0.07 < z < 1.6), while for the others we set a lower limit on it, based on either the robust detection of intervening absorption systems or on an estimation derived from the absence of spectral signatures of the host galaxy. With these new data we expand and reinforce the main results of our previous papers, namely the fact that in terms of their broad-band properties our sources appear to be indistinguishable from the rest of the blazar population and the relatively large (>34 per cent and possibly as high as 80 per cent) fraction of masquerading BL Lac objects, for which the low equivalent width of the emission lines is due to the brightness of the boosted continuum, rather than being an intrinsic property, in our sample.

79 ASTRONOMY AND ASTROPHYSICS↗

Parsec-scale Properties of Steep- and Flat-spectrum Extragalactic Radio Sources from a VLBA Survey of a Complete North Polar Cap Sample

We observed with the Very Long Baseline Array (VLBA) at 2.3 and 8.6 GHz a complete flux-density-limited sample of 482 radio sources with decl. > +75° brighter than 200 mJy at 1.4 GHz drawn from the NVSS catalog. A total of 34% of the sources show parsec-scale emission above the flux density detection limit of 30 mJy; their accurate positions and parsec-scale structure parameters are determined. Among all the sources detected at least at the shortest VLBA baselines, the majority, or 72%, have a steep single-dish spectrum. The fraction of the sources with a detectable parsec-scale structure is above 95% among the flat-spectrum objects and close to 25% among the steep-spectrum objects. We identified 82 compact steep-spectrum source candidates, which make up 17% of the sample; most of them are reported for the first time. The compactness and the brightness temperature of the sources in our sample show a positive correlation with single-dish and VLBA spectral indices. All the sources with a significant 8 GHz variability were detected by the VLBA snapshot observations, which independently confirmed their compactness. We demonstrated that 54% of the sources detected by the VLBA at 2.3 GHz in our sample have a steep VLBA spectrum. The compact radio emission of these sources is likely dominated by optically thin jets or mini-lobes, not by an opaque jet core. These results show that future VLBI surveys aimed at searching for new sources with parsec-scale structure should include not only flat-spectrum sources but also steep-spectrum ones in order to reach an acceptable level of completeness.

47 OTHER INSTRUMENTATION↗

Joint Survey Processing. II. Stellar Proper Motions in the COSMOS Field from Hubble Space Telescope ACS and Subaru Telescope HSC Observations

We analyze stellar proper motions in the COSMOS field to assess the presence of bulk motions. At bright magnitudes (G-band 18.5–20.76 AB), we use the proper motions of 1010 stars in the Gaia DR2 catalog. At the faint end, we compute proper motions of 11,519 pointlike objects at i-band magnitudes 19–25 AB using Hubble ACS and Subaru HSC data, which span two epochs about 11 yr apart. In order to measure these proper motions with unprecedented accuracy at faint magnitudes, we developed a foundational set of astrometric tools that will be required for joint survey processing of data from the next generation of optical/infrared surveys. The astrometric grids of Hubble ACS and Subaru HSC mosaics were corrected at the catalog level using proper motion–propagated and parallax-corrected Gaia DR2 sources. These astrometric corrections were verified using compact extragalactic sources. Upon comparison of our measured proper motions with Gaia DR2, we estimate the uncertainties in our measurements to be ~2–3 mas yr –1 axis –1 , down to 25.5 AB mag. We correct proper motions for the mean motion of the Sun, and we find that late-type main-sequence stars predominantly in the thin disk in the COSMOS field have space velocities mainly toward the Galactic center. We detect candidate high-velocity (≥220 km s –1 ) stars, six of them at ~0.4–6 kpc, from the Gaia sample, and five of them at ~20 kpc, from the faint star HSC and ACS sample. The sources from the faint star sample may be candidate halo members of the Sangarius stream.

79 ASTRONOMY AND ASTROPHYSICS↗

Absolute decay counting of 146 Sm with 4π cryogenic microcalorimetry

We present a methodology for absolute activity counting of long-lived isotopes based on cryogenic Decay Energy Spectroscopy. A 146 Sm source was produced at the TRIUMF Laboratory and then processed and purified at Lawrence Livermore National Laboratory, yielding a pure sample. The source was embedded within a 4π thermal absorber coupled to a magnetic microcalorimeter achieving nearly 100% counting efficiency. Experimental uncertainties were studied and modeled, including thermal coupling of the source to the absorber, pulse pile-up, trigger, and event selection efficiencies. Here, the absolute activity of the pure 146 Sm source was measured to better than 1% uncertainty.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Probing circular polarization and magnetic field structure in active galactic nuclei

The composition and magnetic field morphology of relativistic jets can be studied using circular polarization (CP) measurement. Recent three-dimensional relativistic magnetohydrodynamic (3D RMHD) simulations coupled with radiative transfer (RT) calculations make strong predictions about the level (and morphology) of the jet’s CP emission. These simulations show that the sign of CP and the electric vector position angle (EVPA) are both sensitive to the jet’s magnetic field morphology within the radio core. We probe this theory by exploring whether the jet’s radio core EVPA orientation is consistent with the observed sign of the core CP in deep full-track polarimetric observations. Based on a selection of sources from earlier MOJAVE observations, we aim to probe the nature of linear polarization (LP) and CP in the innermost regions of jets from a small sample of nine blazars. This sample includes sources that have exhibited: (i) positive CP; (ii) negative CP; or (iii) positive and negative CP simultaneously in the radio core region. By coupling deep polarimetric observations of a carefully selected sample of blazars with state-of-the-art RMHD and RT calculations, we hope to gain a deeper understanding of the physics of blazar jets.

79 ASTRONOMY AND ASTROPHYSICS↗

CRITICAL MINERAL RESOURCE ASSESSMENT OF COALS FROM THE POWDER RIVER BASIN, WYOMING, USA

Coal and associated sediments are potential sources of Rare Earth Elements (REE) and other critical minerals necessary for many consumer and defense-related products and development of energy technologies. For this study, 15 samples were sourced from Dry Fork Mine within the Powder River Basin near Gillette, Wyoming, to determine REE content along with select transition metals (t-metals) of interest in non-combusted coals and associated sediments. An excavator collected samples along a mine highwall, within benched intervals representing a foot to a few feet of coal strata. Homogenized sample subsets were crushed in an aluminum-ceramic vial, then passed through a 106-micron sieve. Sieved samples were pyrolyzed by a LECO TGA-108, which concurrently measured sample moisture, volatile, and ash content. Residual ash was then fused into a glass bead with lithium metaborate at a 6:1 Li-metaborate to sample ratio and then dissolved in 20% nitric acid. The nitric acid solutions containing digested beads were then diluted and passed through a 0.45 micron syringe filter. Filtered samples were analyzed by ICP-MS for REE and select t-metals. Reagent blanks were analyzed to assess for any potential contamination. Total REE plus Y (REE+Y) concentrations across the 15 samples range from 52 ppm to 1015 ppm with an average of 477 ppm on a dry ash basis. When normalized to upper continental crust (UCC; Taylor and McLennan, 1985) values, 13 of the 15 samples show average enrichment factors (EF) for REE+Y greater than 1. EF values indicate M-type enrichment (Sm through Er), as opposed to distinct preferential enrichment of light or heavy REE. T-metals with the highest average concentrations are V, Cu, Ni, and Zr at 215, 243, 123, and 118 ppm, respectively. Multiple t-metals had EF>1; however, Cu, Ge, and Sb have the highest average EF relative to UCC for t-metals, at 9.7, 8.0, and 17.0, respectively.

Copeland, Grant↗

2D-to-3D image translation of complex nanoporous volumes using generative networks

Image-based characterization offers a powerful approach to studying geological porous media at the nanoscale and images are critical to understanding reactive transport mechanisms in reservoirs relevant to energy and sustainability technologies such as carbon sequestration, subsurface hydrogen storage, and natural gas recovery. Nanoimaging presents a trade off, however, between higher-contrast sample-destructive and lower-contrast sample-preserving imaging modalities. Furthermore, high-contrast imaging modalities often acquire only 2D images, while 3D volumes are needed to characterize fully a source rock sample. In this work, we present deep learning image translation models to predict high-contrast focused ion beam-scanning electron microscopy (FIB-SEM) image volumes from transmission X-ray microscopy (TXM) images when only 2D paired training data is available. We introduce a regularization method for improving 3D volume generation from 2D-to-2D deep learning image models and apply this approach to translate 3D TXM volumes to FIB-SEM fidelity. We then segment a predicted FIB-SEM volume into a flow simulation domain and calculate the sample apparent permeability using a lattice Boltzmann method (LBM) technique. Results show that our image translation approach produces simulation domains suitable for flow visualization and allows for accurate characterization of petrophysical properties from non-destructive imaging data.

58 GEOSCIENCES↗

Searching for the Highest- z Dual Active Galactic Nuclei in the Deepest Chandra Surveys

We present an analysis searching for dual active galactic nuclei (AGN) among 62 high-redshift (2.5 < z < 3.5) X-ray sources selected from the X-UDS, AEGIS-XD, CDF-S, and COSMOS-Legacy Chandra surveys. We aim to quantify the frequency of dual AGN in the high-redshift Universe, which holds implications for black hole merger timescales and low-frequency gravitational wave detection rates. We analyze each X-ray source using BAYMAX, an analysis tool that calculates the Bayes factor for whether a given archival Chandra AGN is more likely a single or dual point source. We find no strong evidence for dual AGN in any individual source in our sample. We increase our sensitivity to search for dual AGN across the sample by comparing our measured distribution of Bayes factors to that expected from a sample composed entirely of single point sources and find no evidence for dual AGN in the sample distribution. Although our analysis utilizes one of the largest Chandra catalogs of high-z X-ray point sources available to study, the findings remain limited by the modest number of sources observed at the highest spatial resolution with Chandra and the typical count rates of the detected sources. Our nondetection allows us to place an upper limit on the X-ray dual AGN fraction at 2.5 < z < 3.5 of 4.8% at the 95% confidence level. Expanding substantially on these results at X-ray wavelengths will require future surveys spanning larger sky areas and extending to fainter fluxes than has been possible with Chandra. We illustrate the potential of the AXIS mission concept in this regard.

79 ASTRONOMY AND ASTROPHYSICS↗

Towards a Robust Sampling Approach: A Computational Review and Design

As pointed out in several other works, the estimation of the reliability of the electrical grid can not be conducted without the estimation of the stochastic phenomena of electicity demand and electricity production by variable renewable sources. Therefore, sampling procedures have become integral in the design of engineering structures and analysis. Commonly referred to as Monte Carlo uncertainty analysis or integration, the general objective of these procedures is to establish specifics about the uncertainty of an output characteristic of such an engineering system, given uncertainty about its input characteristics. These sampling procedures are applied in a context in which establishing such specifics cannot be performed through other means. Variance-reduction techniques are designed to lessen the variability among estimators to estimate statistics of those output uncertainties. Importance-sampling techniques, on the other hand, are designed to reduce the number of samples needed to estimate a particular statistic—e.g., a tail probability. The combination of these approaches can reduce the computational burden considerably for a particular estimator and statistic. Importance sampling—geared and designed as it is toward improving a particular estimator—suffers, unfortunately, from the unintended consequence of reducing the performance of other estimators in terms of their variance. The objective of this paper is to offer an alternative sampling procedure where this variance does not grow unacceptably large for a suite of estimators. Moreover, it is anticipated that, with additional knowledge of how an engineering output characteristic responds to its input characteristics, tuning parameters of the input’s sampling procedure can be set to improve the output characteristic’s estimation. This work proves the effectiveness of the suggested alternative approach. Such positive outcome will lead to a decrease of the computational burden of performing stochastic optimization of integrated energy systems (e.g., components dispatch, and portfolio composition). In particular, capturing the contribution to the overall system cost of rare and unlikely events and patterns of the electricity demand and production will become less computationally expensive. This is due to the fact that the approach demonstrated here will allow the sampling of those rare occurrences more frequently without misrepresenting their probabilistic impacts.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Strong detection of the CMB lensing and galaxy weak lensing cross-correlation from ACT-DR4, Planck Legacy, and KiDS-1000

Here we measured the cross-correlation between galaxy weak lensing data from the Kilo Degree Survey (KiDS-1000, DR4) and cosmic microwave background (CMB) lensing data from the Atacama Cosmology Telescope (ACT, DR4) and the Planck Legacy survey. We used two samples of source galaxies, selected with photometric redshifts, (0.1 < z B < 1.2) and (1.2 < z B < 2), which produce a combined detection significance of the CMB lensing and weak galaxy lensing cross-spectrum of 7.7σ. With the lower redshift galaxy sample, for which the cross-correlation was detected at a significance of 5.3σ, we present joint cosmological constraints on the matter density parameter, Ω m , and the matter fluctuation amplitude parameter, σ 8 , marginalising over three nuisance parameters that model our uncertainty in the redshift and shear calibration as well as the intrinsic alignment of galaxies. We find our measurement to be consistent with the best-fitting flat ΛCDM cosmological models from both Planck and KiDS-1000. We demonstrate the capacity of CMB weak lensing cross-correlations to set constraints on either the redshift or shear calibration by analysing a previously unused high-redshift KiDS galaxy sample (1.2 < z B < 2), with the cross-correlation detected at a significance of 7σ. This analysis provides an independent assessment for the accuracy of redshift measurements in a regime that is challenging to calibrate directly owing to known incompleteness in spectroscopic surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

Electromagnetic shower reconstruction and energy validation with Michel electrons and π 0 samples for the deep-learning-based analyses in MicroBooNE

This article presents the reconstruction of the electromagnetic activity from electrons and photons (showers) used in the MicroBooNE deep learning-based low energy electron search. The reconstruction algorithm uses a combination of traditional and deep learning-based techniques to estimate shower energies. We validate these predictions using two v μ -sourced data samples: charged/neutral current interactions with final state neutral pions and charged current interactions in which the muon stops and decays within the detector producing a Michel electron. Both the neutral pion sample and Michel electron sample demonstrate agreement between data and simulation. Finally, the absolute shower energy scale is shown to be consistent with the relevant physical constant of each sample: the neutral pion mass peak and the Michel energy cutoff.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Hundreds of weak lensing shear-selected clusters from the Hyper Suprime-Cam Subaru Strategic Program S19A data

Abstract We use the Hyper Suprime-Cam Subaru Strategic Program S19A shape catalog to construct weak lensing shear-selected cluster samples. From aperture mass maps covering ∼510 deg2 created using a truncated Gaussian filter, we construct a catalog of 187 shear-selected clusters that correspond to mass map peaks with signal-to-noise ratio larger than 4.7. Most of the shear-selected clusters have counterparts in optically selected clusters, from which we estimate the purity of the catalog to be higher than 95%. The sample can be expanded to 418 shear-selected clusters with the same signal-to-noise ratio cut by optimizing the shape of the filter function and by combining weak lensing mass maps created with several different background galaxy selections. We argue that dilution and obscuration effects of cluster member galaxies can be mitigated by using background source galaxy samples and adopting a filter function with its inner boundary larger than about 2′. The large samples of shear-selected clusters that are selected without relying on any baryonic tracer are useful for detailed studies of cluster astrophysics and cosmology.

Oguri, Masamune↗

Atomic resolution convergent beam electron diffraction analysis using convolutional neural networks

Two types of convolutional neural network (CNN) models, a discrete classification network and a continuous regression network, were trained to determine local sample thickness from convergent beam diffraction (CBED) patterns of SrTiO 3 collected in a scanning transmission electron microscope (STEM) at atomic column resolution. Acquisition of atomic resolution CBED patterns for this purpose requires careful balancing of CBED feature size in pixels, acquisition speed, and detector dynamic range. The training datasets were derived from multislice simulations, which must be convolved with incoherent source broadening. Sample thicknesses were also determined using quantitative high-angle annular dark-field (HAADF) STEM images acquired simultaneously. The regression CNN performed well on sample thinner than 35 nm, with 70% of the CNN results within 1 nm of HAADF thickness, and 1.0 nm overall root mean square error between the two measurements. The classification CNN was trained for a thicknesses up to 100 nm and yielded 66% of CNN results within one classification increment of 2 nm of HAADF thickness. Our approach depends on methods from computer vision including transfer learning and image augmentation.

36 MATERIALS SCIENCE↗

SAIL-Isotopologue (SAIL-iso) Field Campaign Report

The SAIL-iso project took place from November 19, 2022 to June 3, 2023 as part of the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Surface Atmosphere Integrated Field Laboratory (SAIL) project at the main project site in Gothic, Colorado. The project sought to use measurements of the stable isotopic composition of water vapor to better understand cloud-aerosol interactions in a remote mountainous watershed. Water vapor isotopologue and humidity measurements were determined using a Los Gatos Research Triple Water Vapor Isotope Analyzer (TWVIA). The instrument was deployed in the guest van and consists of three main components: a water vapor isotope analyzer, a Los Gatos Research Water Vapor Isotope Standard Source (WVISS), and a Los Gatos Research Dry Air Source. Ambient air samples were collected through an inlet located about one meter above roof of the shipping container. Samples were then delivered to the analyzer through Teflon tubing by use of an external pump to minimize the transport time between the inlet and analyzer. The inlet tubing was surrounded by a Briskheat heat trace and insulating material to ensure ambient air samples did not fall below the dew point and result in condensation. The analyzer uses cavity ringdown spectroscopy to report isotopic ratios of ambient air samples at a frequency of 1 Hz. The calibration unit of the instrument was used in conjunction with the dry air source to periodically measure the δ values of standard waters. It uses a nebulizer to push small water droplets into a hot chamber that vaporizes the water without fractionation. This vapor was then transported to the analyzer using a built-in compressor and the dry air source, which allows each standard with known δ values to be measured at a wide range of humidity values for post-measurement calibration of ambient air samples. Multiple sources of uncertainty are introduced at different stages during the data collection and processing. These include (1) instrument precision, (2) uncertainty in the secondary standards, (3) humidity-correction uncertainty, and (4) Vienna Standard Mean Ocean Water – Standard Light Antarctic Precipitation (VSMOW-SLAP) calibration uncertainty. Uncertainty from each step is propagated in quadrature to calculate a total uncertainty of each isotopologue. Uncertainty was determined to be 2.3‰ for δD and 0.4‰ for δ 18 O.

54 ENVIRONMENTAL SCIENCES↗

HIMU geochemical signature originating from the transition zone

Plume volcanism may sample mantle sources deeper than mid-ocean ridge and arc volcanism. Ocean island basalts (OIBs) are commonly related to plume volcanism, and their diverse isotopic and elemental compositions can be described using a limited number of mantle endmembers. However, the origins and depths of these mantle endmembers are highly debated. Here we show that the HIMU (high μ, μ = 238 U/ 204 Pb) endmember may reside in the transition zone. Specifically, we report the geochemical signature of a high-pressure multiphase diamond inclusion, entrapped at 420–440 km depth and 1450 ±50 K, which matches exactly the geochemical patterns of the HIMU-rich OIBs. Since the HIMU component is variably sampled by almost all OIBs, our finding implies that the transition zone causes a major overprint of the geochemical features of mantle plumes. Furthermore, some mantle plumes, like those feeding Bermuda, St Helena, Tubuai and Mangaia, appear to be dominated by this source. Furthermore, our finding highlights the importance of the transition zone in highly incompatible element budget of the mantle.

58 GEOSCIENCES↗

End-Use Savings Shapes Measure Documentation: Boiler Replacement with Air-Source Heat Pump Boiler and Natural Gas Boiler Backup

Building on the successfully completed effort to calibrate and validate the U.S. Department of Energy's ResStock (™) and ComStock (™) models over the past three years, the objective of this work is to produce national data sets that empower analysts working for federal, state, utility, city, and manufacturer stakeholders to answer a broad range of analysis questions. The goal of this work is to develop energy efficiency, electrification, and demand flexibility end-use load shapes (electricity, gas, propane, or fuel oil) that cover a majority of the high-impact, market-ready (or nearly market-ready) measures. "Measures" refers to energy efficiency variables that can be applied to buildings during modeling. An end-use savings shape is the difference in energy consumption between a baseline building and a building with an energy efficiency, electrification, or demand flexibility measure applied. It results in a time-series profile that is broken down by end use and fuel (electricity or on-site gas, propane, or fuel oil use) at each timestep. ComStock is a highly granular, bottom-up model that uses multiple data sources, statistical sampling methods, and advanced building energy simulations to estimate the annual subhourly energy consumption of the commercial building stock across the United States. The baseline model intends to represent the U.S. commercial building stock as it existed in 2018. The methodology and results of the baseline model are discussed in the final technical report of the End-Use Load Profiles project. This documentation focuses on a single end-use savings shape measure - boiler replacement with air-source heat pump boiler with natural gas boiler backup. This measure replaces natural gas boilers for HVAC application by air-source heat pump boilers when applicable and use natural gas boiler backup when the heat pump boiler could not operate due to outdoor air conditions which are below its cutoff temperature. This measure helps to quantify the decarbonization as well as the energy savings potential from the replacement. The measure resulted higher savings in natural gas consumption compared to the increase in electricity consumption, with a ratio of 3. The total natural gas energy consumption was reduced by 41%, whereas the total electricity consumption was increased by 5.3%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

End-Use Savings Shapes Measure Documentation: Boiler Replacement with Air-Source Heat Pump Boiler and Electric Boiler Backup

Building on the successfully completed effort to calibrate and validate the U.S. Department of Energy's ResStock TM and ComStock TM models over the past three years, the objective of this work is to produce national data sets that empower analysts working for federal, state, utility, city, and manufacturer stakeholders to answer a broad range of analysis questions. The goal of this work is to develop energy efficiency, electrification, and demand flexibility end-use load shapes (electricity, gas, propane, or fuel oil) that cover a majority of the high-impact, market-ready (or nearly market-ready) measures. "Measures" refers to energy efficiency variables that can be applied to buildings during modeling. An end-use savings shape is the difference in energy consumption between a baseline building and a building with an energy efficiency, electrification, or demand flexibility measure applied. It results in a time-series profile that is broken down by end use and fuel (electricity or on-site gas, propane, or fuel oil use) at each timestep. ComStock is a highly granular, bottom-up model that uses multiple data sources, statistical sampling methods, and advanced building energy simulations to estimate the annual sub hourly energy consumption of the commercial building stock across the United States. The baseline model intends to represent the U.S. commercial building stock as it existed in 2018. The methodology and results of the baseline model are discussed in the final technical report of the End-Use Load Profiles project. This documentation focuses on a single end-use savings shape measure—boiler replacement by air-source heat pump boiler. This measure replaces space heating natural gas boilers by air-source heat pump boilers when applicable and helps quantify the decarbonization as well as the energy savings potential from the replacement. The measure resulted higher savings in natural gas consumption compared to the increase in electricity consumption, with a ratio of 2.9. The total natural gas energy consumption was reduced by 20%, whereas the total electricity consumption was increased by 2.5%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗