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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

A statistical analysis of developing knock intensity in a mixture with temperature inhomogeneities

Knock formation and its intensity for a stoichiometric ethanol/air mixture under a representative end-gas auto-ignition condition in IC engines with temperature inhomogeneities are investigated using multi-dimensional direct numerical simulations (DNS) with a 40-species skeletal mechanism of ethanol. Two- and three-dimensional simulations are performed by systematically varying temperature fluctuations and its most energetic length scale, l T . The volumetric fraction of the mixture regions that have the propensity to detonation development, F D , is proposed as a metric to predict the amplitude of knock intensity. It is found that with increasing l T , F D shows a good agreement with the heat release fraction of the mixture regions with pressure greater than equilibrium pressure, F H . The detonation peninsula is well captured by F D and F H when plotting them as a function of the volume-averaged ξ, ξ, (ξ= a/S sp is the ratio of the acoustic speed, a to the ignition front speed, S sp ) Decreasing l T is found to significantly reduce the super-knock intensity. The results suggest that decreasing l T , as in engines with tumble designs resulting in a smaller turbulence scale, will be effective in mitigating the the super-knock development.

42 ENGINEERING↗

Predicting Catalytic Pyrolysis Aromatic Selectivity from Pyrolysis Vapor Composition Using Mass Spectra Coupled with Statistical Analysis

The behavior of fast pyrolysis (FP) and catalytic FP (CFP) of 20 renewable feedstocks was studied in a microscale reactor with molecular beam mass spectral analysis of products generated. A partial least-squares (PLS) model was constructed based on the FP vapor spectra that predicts the aromatic selectivity when upgrading over a ZSM-5 catalyst. Additionally, principal component analysis of both FP and CFP spectra was performed for comprehensive spectral analysis. This work highlighted the value of vapor-phase mass spectral screening to predict the subsequent feedstock performance and demonstrated that the quantity of coke deposited on the catalyst is not a reliable measure of catalyst deactivation when the feedstock type is varied.

09 BIOMASS FUELS↗

Statistical Analysis of Trans‐Ionospheric Pulse Pairs and Inferences on Their Characteristics

Trans-ionospheric pulse pairs (TIPPs), first observed in 1993, are signatures of in-cloud lightning discharges observed by satellite-based broadband very high frequency (VHF) receivers. It has been definitively shown that TIPPs are the space-based signatures of compact intracloud discharges (CIDs), and that the associated pair of pulses that comprise a TIPP result from the direct VHF pulse from the discharge, followed by a pulse reflected from the Earth's surface. However, the ratio of the peak amplitudes of these two pulses can vary widely, with the second pulse often having considerably higher peak amplitude than the first. This observation has not been satisfactorily explained. Using data collected from geostationary orbit by the Radio Frequency Sensor (RFS) and matched to locations reported by the Global Lightning Dataset (GLD360), we assemble the largest database to date of 76,348 TIPPs with associated location, altitude, and amplitude ratio of the two pulses in the TIPP. We show that the amplitude ratio of TIPPs is strongly correlated to the altitude of the associated discharges and the geometry of the source location with respect to the Earth's surface and the receiver. These observations strongly suggest that the difference in amplitude of the two pulses is driven by a nondipole radiated beam pattern that is dependent on the polarity of the CID, velocity of the current wavefront, and viewing angle.

58 GEOSCIENCES↗

Statistical analysis of Al III and C III ] emission lines as virial black hole mass estimators in quasars

We test the usefulness of the intermediate ionisation lines Al IIIλ1860 and C III]λ1909 as reliable virial mass estimators for quasars. We identified a sample of 309 quasars from the Sloan Digital Sky Survey Data Release 16 (SDSS DR16) in the redshift range 1.2 ≤ z ≤ 1.4 that have [O II]λ3728 recorded on the same spectrum as Al IIIλ1860, Si III]λ1892, and C III]λ1909. We set the systemic quasar redshift using careful measurements of [O II]λ3728. We then classified the sources as Population A (Pop. A), extreme Population A (Pop. xA), and Population B (Pop. B), and analysed the 1900 Å blend using multi-component models to look for systematic line shifts of Al IIIλ1860 and C III]λ1909 along the quasar main sequence. We do not find significant shifts of the Al IIIλ1860 line peak in Pop. B or in the vast majority of Pop. A. For Pop. xA, a small median blueshift of -250 km s -1 was observed, motivating a decomposition of the Al III line profile into a virialised component centred at rest frame and a blueshifted component for an outflow emission. For Pop. B objects, we proved the empirical necessity to fit a redshifted very broad component, clearly seen in C III], and analysed the physical implications on a Pop. B composite spectrum using CLOUDY simulations. We find consistent black hole mass estimations using Al III and C III] as virial estimators for the bulk of Pop. A. Al III (and even C III]) is a reliable virial black hole mass estimator for Pop. A and Pop. B objects. The Pop. xA sources deserve special attention due to the significant blueshifted excess observed in the line profile of Al III, although it is not as large as the excess observed in C IVλ1549.

79 ASTRONOMY AND ASTROPHYSICS↗

Statistical analysis of magnetic divertor configuration influence on H-mode transitions

DIII-D plasmas are compared for two upper divertor configurations: with the outer strike point on the small angle slot (SAS) divertor target and with the outer strike point on the horizontal divertor target (HT). Scanning the vertical distance between the magnetic null point and the divertor target over a range 0.10–0.16 m is shown to increase the threshold power, $P_\mathrm{th}$, and edge plasma power, $P_\mathrm{Loss},$ for the low-to-high confinement (L–H) and H–L transitions respectively, by up to a factor of 1.4. The X-point height scans were performed at three L-mode core plasma line average electron densities, $\bar{n}_\mathrm{e} = $ 1.2, 2.2 and 3.6 $\times 10^{19}\,\mathrm{m}^{-3}$, to investigate the density dependence of divertor magnetic configuration influence on $P_\mathrm{th}$. The X-point height, $Z_\textrm{x-pt}$, was further extended across the range 0.16–0.22 m with the more open HT divertor configuration, for which a clear decrease in $P_\mathrm{th}$ with increasing $Z_\textrm{x-pt}$ is observed. The dependence of $P_\textrm{th}$ on divertor magnetic geometry is further investigated using a time-dependent probability density function (PDF) model and information geometry to elucidate the roles played by pedestal plasma turbulence and perpendicular velocity flows. The degree of stochasticity of the plasma turbulence is observed to be sensitive to the plasma heating rate. The calculated square of the information rate shows changes in the relative density fluctuations and perpendicular velocity PDFs begin 2–5 ms prior to the L–H transition for three plasmas; providing a crucial measurement of the dynamic timescale of external transport barrier formation. Additionally, both information length and rate provide potential predictors of the L–H transition for these plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A robust statistical analysis of the role of hydropower on the system electricity price and price volatility

Abstract Hydroelectric power (hydropower) is unique in that it can function as both a conventional source of electricity and as backup storage (pumped hydroelectric storage and large reservoir storage) for providing energy in times of high demand on the grid (S. Rehman, L M Al-Hadhrami, and M M Alam), (2015 Renewable and Sustainable Energy Reviews , 44 , 586–98). This study examines the impact of hydropower on system electricity price and price volatility in the region served by the New England Independent System Operator (ISONE) from 2014-2020 (ISONE, ISO New England Web Services API v1.1 .” https://webservices.iso-ne.com/docs/v1.1/ , 2021. Accessed: 2021-01-10). We perform a robust holistic analysis of the mean and quantile effects, as well as the marginal contributing effects of hydropower in the presence of solar and wind resources. First, the price data is adjusted for deterministic temporal trends, correcting for seasonal, weekend, and diurnal effects that may obscure actual representative trends in the data. Using multiple linear regression and quantile regression, we observe that hydropower contributes to a reduction in the system electricity price and price volatility. While hydropower has a weak impact on decreasing price and volatility at the mean, it has greater impact at extreme quantiles (>70th percentile). At these higher percentiles, we find that hydropower provides a stabilizing effect on price volatility in the presence of volatile resources such as wind. We conclude with a discussion of the observed relationship between hydropower and system electricity price and volatility.

13 HYDRO ENERGY↗

Statistical analysis of the fluctuations of an initial-state model with independently distributed hot spots

Abstract We determine the uncorrelated modes that characterize the fluctuations in a semi-realistic model for the initial state of high-energy nuclear collisions, consisting of hot spots whose positions are distributed independently. Varying the number of hot spots, their size, and the weights with which they contribute to the initial state, we find that the parameter that has the largest influence on the relative importance of the fluctuation modes is the source size, with more extended hot spots leading to a more marked predominance of the principal modes.

Borghini, Nicolas↗

Bayesian Statistical Analysis for Mass Spectrometric Data Processing

• Thermal ionization mass spectrometry (TIMS) is a “gold standard’ technique for actinide isotope amount ratio and assay measurements. • Ubiquitously used in: • Nuclear Nonproliferation • Nuclear Safeguards • Nuclear Forensics • Basic Science • Savannah River National Laboratory (SRNL) installed a new Thermo Scientific TRITON Plus TIMS in early 2024.

McLarty, Ellis C. [Savannah River National Laborat↗

Statistical Analysis of Imaging Laser Scan Data of an Exhaust Tunnel at the SRS

• The SRS H-Canyon Building is a critical facility under the responsibility of DOE-EM. • It includes an Air Exhaust Tunnel (HCAEX) that allows for ventilation of the process airflow. • Inspections are performed remotely because of hazards, e.g. radioactivity, debris, high airflow, and nitric acid vapors.

Wells, William Willie [Savannah River National Lab↗

STATISTICAL ANALYSIS OF IN-SERVICE ULTRASONIC INSPECTION DATA OF WASTE TANKS AT THE SAVANNAH RIVER Site-25021

CONCLUSIONS AND RECOMMENDATIONS •“There is no evidence of pit depth growth over the last 15-years demonstrating the effectiveness of the corrosion control program. •“Incipient pits” are not growing and are likely pre-service pits. • No need to continue measuring these tiny pits. However, due to the random nature of pit initiation and the potentially accelerated growth of a pit, periodic monitoring for pit growth is prudent. 1. No reportable pits were identified. All identified pits are far less than the reportable depth of 25% of the nominal wall thickness. 2. No cracking was identified. 3. There is no evidence that active, systemic corrosion has occurred in Tank 29 during its 38-year service history as of 2009.

Harris, Stephen P. [Savannah River National Labora↗

Bayesian Statistical Analysis for Mass Spectrometric Data Processing

Thermal ionization mass spectrometry (TIMS) is a “gold standard’ technique for actinide isotope amount ratio and assay measurements. • Ubiquitously used in: • Nuclear Nonproliferation • Nuclear Safeguards • Nuclear Forensics • Basic Science • Savannah River National Laboratory (SRNL) installed a new Thermo Scientific TRITON Plus TIMS in early 2024.

McLarty, Ellis C. [Savannah River National Laborat↗

Designing Quaternary and Quinary Refractory-Based High-Entropy Alloys: Statistical Analysis of Their Lattice Distortion, Mechanical, and Thermal Properties

The rapid evolution in materials science has resulted in a significant interest in high-entropy alloys (HEAs) for their unique properties. This study focuses on understanding both quaternary and quinary body-centered cubic (BCC) of 12 refractory-based HEAs, and on analysis of their electronic structures, lattice distortions, mechanical, and thermal properties. A comprehensive assessment is undertaken by means of density functional theory (DFT)-based first principles calculations. It is well known that multiple constituents lead to notable lattice distortions, especially in quinary HEAs. This distortion, in turn, has significant implications on the electronic structure that ultimately affect mechanical and thermal behaviors of these alloys such as ductility, lattice thermal conductivity, and toughness. Our in-depth analysis of their electronic structures revealed the role of valence electron concentration and its correlation with bond order and mechanical properties. Local lattice distortion (LD) was investigated for these 12 HEA models. M1 (WTiVZrHf), M7 (TiZrHfW), and M12 (TiZrHfVNb) have the highest LD whereas the models M3 (MoTaTiV), M5 (WTaCrV), M6 (MoNbTaW), and M9 (NbTaTiV) have the less LD. Furthermore, we investigated the thermal properties focusing on Debye temperature (ΘD), thermal conductivity (κ), Grüneisen parameter (γα), and dominant phonon wavelength (λdom). The NbTaTiV(M9) and TiVNbHf(M10) models have significantly reduced lattice thermal conductivities (κL). This reduction is due to the mass increase and strain fluctuations, which in turn signify lattice distortion. The findings not only provide an understanding of these promising materials but also offer guidance for the design of next-generation HEAs with properties tailored for potential specific applications.

Materials Science↗

Non-Parametric Statistical Analysis of Current Waveforms through Power System Sensors

The protection, control, and monitoring of the power grid is not possible without accurate measurement devices. As the percentage of renewable energy sources penetrating the existing grid infrastructure increases, so do uncertainties surrounding their effects on the everyday operation of the power system. Many of these devices are sources of high-frequency transients. These transients may be useful for identifying certain events or behaviors otherwise not seen in traditional analysis techniques. Therefore, the ability of sensors to accurately capture these phenomena is paramount. In this work, two commercial-grade power system distribution sensors are investigated in terms of their ability to replicate high-frequency phenomena by studying their responses to three events: a current inrush, a microgrid “close-in”, and a fault on the terminals of a wind turbine. Kernel density estimation is used to derive the non-parametric probability density functions of these error distributions and their adequateness is quantified utilizing the commonly used root mean square error (RMSE) metric. It is demonstrated that both sensors exhibit characteristics in the high harmonic range that go against the assumption that measurement error is normally distributed.

47 OTHER INSTRUMENTATION↗