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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Evolution of Programmatic Asset Lifecycle Planning at MESA

Early on in 2018 Sandia recognized the Microsystems Engineering, Science and Applications (MESA) Programmatic Asset Lifecycle Planning capability to be unpredictable, inconsistent, reactive, and unable to provide strong linkage to the sponsor's needs. The impetus for this report is to share learnings from MESA's journey towards maturing this capability. This report describes re-building the foundational elements of MESA's Programmatic Asset Lifecycle Planning capability using a risk-based, Multi-Criteria Decision Analysis (MCDA) approach. To begin, MESA's decades-old Piano Chart + Ad Hoc Hybrid Methodology is described with a narrative of its strengths and weaknesses. Then its replacement, the MCDA /Analytical Hierarchy Process, is introduced with a discussion of its strengths and weaknesses. To generate a realistic Programmatic Asset Lifecycle Planning budget outlook, MESA used its rolling 20-year Extended Life Program Plan (MELPP) as a baseline. The new MCDA risk-based prioritization methodology implements DOE/NNSA guidelines for prioritization of DOE activities and provides a reliable, structured framework for combining expert judgement and stakeholder preferences according to an established scientific technique. An in-house Hybrid Decision Support System (HDSS) software application was developed to facilitate production of several key deliverables. The application enables analysis of the prioritization decisions with charts to display and provide linkage of MESA's funding requests to the stakeholders' priorities, strategic objectives, nuclear deterrence programs, MESA priorities, and much more.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Evaluation of the Mechanical Properties of Cast and Wrought CF8C-Plus Relevant to ASME Code Case Qualification

The mechanical behavior of a cast form of an advanced austenitic stainless steel, CF8C-Plus, is compared with that of its wrought equivalent in terms of both tensile and creep-rupture properties and estimated allowable stress values for pressurized service at temperatures up to about 850°C. A traditional Larson-Miller parametric model is used to analyze the creep-rupture data and to predict long-term lifetimes for comparison of the two alloy types. The cast CF8C-Plus exhibited lower yield and tensile strengths, but higher creep strength compared to its wrought counterpart. Two welding methods, shielded-metal-arc welding (SMAW) and gas-metal-arc welding, met the weld qualification acceptance criteria in ASME BPVC Section IX for the cast CF8C-Plus. However, for the wrought CF8C-Plus, while SMAW and gas-tungsten-arc welding passed the tensile acceptance criteria, they failed the side bend tests due to lack of fusion or weld metal discontinuities.

Chen, Xiang↗

Rashba exciton in a 2D perovskite quantum dot

The Rashba effect has been proposed to give rise to a bright exciton ground state in halide perovskite nanocrystals (NCs), resulting in very fast radiative recombination at room temperature and extremely fast radiative recombination at low temperature. In this paper we find the dispersion of the “Rashba exciton”, i.e., the exciton whose bulk dispersion reflects large spin–orbit Rashba terms in the conduction and valence bands and thus has minima at non-zero quasi-momenta. Placing Rashba excitonsin quasi-2D cylindrical quantum dots, we calculate size-dependent levels of confined excitons and their oscillator transition strengths. Here, we consider the implications of this model for two-dimensional hybrid organic–inorganic perovskites, discuss generalizations of this model to 3D NCs, and establish criteria under which a bright ground exciton state could be realized.

36 MATERIALS SCIENCE↗

Demystify the 1.1 Factor for Ultimate Tensile Strength Above Room Temperature in Development of the Code Stress Tables

As the Boiler and Pressure Vessel Code increasingly gains popularity worldwide, it is not uncommon that many users are mystified by the 1.1 factor required for ultimate tensile strength above room temperature in developing the allowable design stresses of Section II Part D Stress Tables. Questions often arise about the origin and purpose of the factor, the reason for it not applied to the yield strength, its due considerations when evaluating an alloy for acceptance to construction use from the perspective of the alloy’s tested tensile strength value, and more. Not knowing reliable sources for explicit explanations, some users tend to misinterpret the factor, abuse its application, incorrectly define their alloy acceptance or qualification criteria, and mistakenly manipulate the safety margin in structural component design.To help the Code users who struggle with these frequent and confusing issues, particularly those in nuclear industry where rigorous criteria are required for component design and alloy acceptance or qualification, this paper is intended to demystify the 1.1 factor and facilitate knowledgeable interpretation and use of the Section II Part D Stress Tables as well as relevant Mandatory Appendices.A brief review is first given on the background of the 1.1 factor, followed by a summary of its application in the Stress Tables. The provenance and purpose of the factor are then discussed in detail with graphic examples. Finally, current applicability and necessity of the factor are considered through a demonstration using example alloys.

Ren, Weiju↗

Exact solution of burst pressure for thick-walled pipes using the flow theory of plasticity

This paper develops an exact solution of burst pressure for defect-free, thick-walled pipes using the flow theory of plasticity in terms of the average shear stress yield criterion (or Zhu-Leis yield criterion). The pipe steel is assumed to obey the power-law strain hardening rule, and large plastic deformation is described by the finite strain theory. On this basis, internal pressure is obtained as a power series function of the effective strains on the inside and outside surfaces of the thick-walled pipe with use of the second Bernoulli numbers. At burst failure, the Zhu-Leis flow solution of burst pressure is determined as a power series solution, and the burst effective strains, the burst effective stresses, and the burst pressure are functions of the diameter ratio (D o / D i ), strain hardening exponent (n), and ultimate tensile strength (UTS). Similarly, the Tresca and von Mises flow solutions of burst pressure are also determined as a power series solution in terms of the Tresca and von Mises yield criteria. A general closed-from exact solution of burst pressure is then proposed for the three yield criteria, and the results showed that the proposed exact solution matches well with the power series solution for each yield criterion. Moreover, the von Mises flow solution is an upper bound prediction, the Tresca flow solution is a lower bound prediction, and the Zhu-Leis flow solution is an intermediate prediction that agrees well with the finite element analysis results of burst pressure for thick-walled pipes. Furthermore, two datasets of full-scale burst tests are then utilized to evaluate and validate the proposed flow solutions of burst pressure for both thin and thick-walled pipes.

42 ENGINEERING↗

Open-source simulation platform for air source heat pump integrated with thermal energy storage

Here, this article introduces a modular simulation platform for assessing thermal energy storage (TES) integrated with air source heat pumps (ASHP). The Python platform is an open-source library that includes classes for modeling air-air and air-water heat pumps, TES devices, and the heating load of residential buildings. To validate the ASHP model, the study utilized experimental data obtained from a commercial heat pump evaluated at the National Renewable Energy Laboratory (NREL). The results indicate a mean deviation of 0.7% for COP across the operating range, with a maximum relative deviation of 12.6%. In terms of system heating capacity, the model had an average deviation of 4.3% compared to experimental results, with a maximum deviation of 8.2%. Three classes were implemented for modeling distinct types of TES devices: a generic TES based on energy balances, a sensible isothermal water tank, and a stratified water tank. Details of the mathematical models are provided, along with their respective strengths and limitations. An example is provided showcasing the integration of a residential 10 kWh thermal storage unit with an ASHP operating in Denver, CO. The comparison of two different discharge criteria for the TES unit highlights the importance of control strategies in the system performance.

25 ENERGY STORAGE↗

Higher Order Multipole Analysis of Beam Crabbing Mode at 197 MHz for Electron-Ion Collider

In the local crabbing scheme for Electron Ion Collider interaction region, beam rotation is initiated by one set of crab cavities at a high beta region with near 90 deg phase advance to the interaction point (IP), and ceased by an identical set of cavities on the symmetrically opposite side. The fundamental mode of all crab cavities is designed to apply a momentum kick to the particle bunches to complete this half cycle of rotation in the horizontal plane, meanwhile the electromagnetic (EM) field can be expanded into a series of harmonics. Despite the lowest dipole mode, higher harmonics cause instabilities during beam operation and loss of particles. We used SimTrack, which is the 6-d symplectic element-by-element tracking code developed at Brookhaven National Laboratory in 2015, to study the threshold of each higher-order harmonic multipolar mode with the criteria of maintaining a dynamic aperture of 6 σ or greater for the Hadron Storage Ring (HSR). In this paper, we showed the threshold for each higher harmonic multipole and their comparison with the multipole strength for the current crab cavity design.

43 PARTICLE ACCELERATORS↗

Quantifying the Relevance of Prompt Dissociations of Resonance Stabilized Free Radicals in Flames

In prior studies from our laboratory we have shown that weakly-bound free radicals have a propensity to promptly dissociate at elevated temperatures relevant to flames. Dissociation can occur so rapidly at high temperatures in such weakly-bound radicals that it interferes with collisional relaxation of internal energies leading to prompt dissociation. While prompt dissociation is a ubiquitous feature in such free radical dissociations, we have hypothesized that its relevance to global combustion observables such as flame speeds depends on satisfying specific criteria. Two criteria that motivate the present study are that the free radicals must play a central role in the oxidation mechanism and that their thermal dissociation rate coefficients should be small enough. Resonance stabilized radicals have bond strengths ~ 50 kcal/mol (or larger) and consequently are known to dissociate slowly and persist even in high temperature environments. In this work we have calculated prompt dissociation probabilities for some simple allylic (allyl, methyl allyl, and dimethyl allyl) radicals. Flame simulations were performed to quantify the relevance of including prompt dissociations of these allylic radicals.

Allyl Radicals↗

Oxidation of ultrahigh temperature ceramics: kinetics, mechanisms, and applications

Materials capable of oxidizing in a protective manner at ultrahigh (>1700 °C) temperatures are needed to push beyond this barrier defined by SiC. Although possessing attractive mechanical properties and oxidation resistance, SiC-based materials are ultimately temperature limited by the melting point of SiO 2 . The vast array of ultra-high and high temperature ceramic literature indicates the majority of these materials, like borides, carbides, MAX-phases, and high-entropy ceramics, fall woefully short regarding oxidation resistance. However, for specific applications, like low-orbit aeropropulsion, high ballistics coefficient atmospheric re-entry, and hypersonic cruise, there are a few promising materials. Here, oxidation criteria are gathered to build application specific heuristics and are then applied to a multitude of ultra-high temperature ceramics to gauge material efficacy. Discussion of oxidation kinetics, mechanisms and reaction products is offered for each material, identifying strengths, weaknesses, and the remaining gaps in our knowledge.

36 MATERIALS SCIENCE↗

Application Deconfliction Characterization and Alternatives Analysis

This report provides an overview of the domain space and solution techniques that could be used to create a robust, flexible app deconfliction service. Three approaches are reviewed with summaries of the characteristics, elements, and results from preliminary demonstrations of solution techniques based on each approach: 1) rules and heuristics, 2) cooperation, and 3) optimization. The strengths and weaknesses of each solution technique were explored through a set of numerical demonstrations on modified IEEE 123 node and 9500 node test feeders. An alternatives analysis of individual deconfliction elements was performed with each solution technique element evaluated against criteria reflecting the dynamic app environment, need to balance app objectives, and scalability issues versus the number of applications, setpoints, and distributed control areas. It is anticipated that a combined solution for a GridAPPS-D Deconfliction Service can be formulated using a combination of elements from each solution technique. The combined solution would combine 1) device control budgets to reduce the size of the solution space by constraining system setpoints to those will not result in accelerated degradation of physical assets, 2) system operations rules to constrain the solution space by eliminating setpoints that result in violations of system limits or operational best practices, 3) contextual status signals shared with or among apps such that they could update their desired setpoints based on the evolving context, 4) a mediator that incentivizes apps to come to a cooperative solution, and 5) Setpoint-informed optimization as a fallback mechanism if a cooperative solution cannot be agreed upon by applications.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Advanced High-Strength Steel - Basics and Applications in the Automotive Industry

Challenged to improve safety and fuel economy, automakers continually search for new materials to meet high standards. Several factors drive the material R&D and selection for automotive applications, including safety, fuel efficiency, environmentalism, manufacturability, durability, and quality. In the highly competitive automotive industry, cost is an extremely important factor in material selection. As the motivation to reduce the mass of vehicles continues to grow, automakers seek to maximize the efficiency of their materials selection. Materials in automotive applications are selected to minimize weight while meeting key criteria, including crash performance, stiffness, and forming requirements. Since the 1920s, steel has been the material of choice for automakers worldwide. The weight percentage of steel used in vehicles relative to other materials has grown from around 50% in the early 1980s to about 60% in 2010 for North American light vehicles. Today, steel makes up around 65% of an average automobile’s weight and is the backbone of the entire vehicle. On average, that is 900 kg of steel used per vehicle. To further enhance passenger safety, vehicle performance, and fuel efficiency, reducing the weight of vehicles has become one of the top priorities for the automotive industry. Advanced high-strength steels (AHSSs) are a new generation of steel grades that provide much higher strength and other advantageous properties than other materials while maintaining the high formability required for manufacturing. AHSSs help engineers meet requirements for safety, efficiency, emissions, manufacturability, durability, and quality at a low cost. The relevance of AHSSs is quickly increasing in the automotive industry, and AHSSs are the key material for vehicle mass reduction. Different types of AHSS help parts meet the varied performance demands in different areas of the vehicle, including both the crumple zone and passenger compartment.

36 MATERIALS SCIENCE↗

Blast Effects on Buildings (Final Report)

Lawrence Livermore National Laboratory (LLNL) has conservatively reduced the explosive safety standards suggested by the Small Quantities in Research Laboratories (SQRL) program testing by 60%. For this reason, further research into the detailed effects of small amounts of explosives in typically constructed rooms is needed in order to improve their factor of safety. The team was tasked with designing an experiment to investigate the effect of different variables on drywall under explosive blasts. In order to meet this objective, the team conducted a comprehensive literature review to gain an understanding of industry-standard construction practices and review previous tests conducted by the Army corp of engineers. Since the team used PBXN-5 rather than C4, as in SQRL, an initial shot was conducted to compare damage levels. From those results and the physical constraints of the testing chamber, the team redesigned multiple single-panel drywall frames to capture the entirety of the incurred damage. Proposed designs were narrowed down using a decision matrix. From the study of previous tests and literature review, variables were chosen that the team hypothesized to have an impact on drywall strength. The variables that were tested were chosen from the results of that work and specific variables the sponsor was interested in, and they were paint, humidity/moisture content, and explosive positioning relative to the studs. Detailed plans were made for each variable according to what conditions the team wanted to investigate. For humidity, this involved testing low, ambient, and high conditions by treating the panels in a chamber. Preliminary shots were performed to test the structural integrity of the frame and streamline the test diagnostics which involved a high-speed camera placed behind the drywall, outside of the chamber, and a pressure probe placed behind the drywall, inside the chamber. Once the instrumentation, diagnostics, and frame design were finalized, a quantitative damage criteria matrix was created to categorize the results of the main shot series. In conjunction with evidence from the high-speed video, the achieved damage levels indicate that high moisture content drywall is better able to withstand explosive blasts. Larger stud damage and lower drywall damage occurred when the explosive was located directly in front of a stud. Paint had no noticeable impact on strength. Ultimately, the team conducted a total of 17 tests, leaving the door open for future in-depth research into the impact of humidity.

36 MATERIALS SCIENCE↗

Flow and heat transfer in the wake of a triangular arrangement of spheres

This research work seeks to investigate the influence of spacing and heat transfer on the wake behavior of a triangular arrangement of spheres. Four experimental configurations have been investigated at three Reynolds numbers, Re 1 = 350, Re 2 = 700, and Re 3 = 1050. Two isothermal cases were investigated with spacing between the spheres of zero and one sphere diameter, and two cases were investigated with an applied heat flux at the same spacing conditions. The time resolved particle image velocimetry results revealed various flow phenomena including flow separations, von Karman vortex shedding, and Kelvin–Helmholtz instabilities. The turbulent statistics reveal the effect of proximity and heat transfer on the time averaged values of the wake size, turbulent strengths, and Reynolds shear stress in the wake of each sphere, namely, the laminarization effects from the addition of heat and the suppression of the lead sphere wake from the proximity of the trailing spheres. These results are complemented by the application of proper orthogonal decomposition (POD) to the flow fields, which extracts the coherent structures from the flow. Here the modes that describe the coherent structures are extracted and described in detail, which provide further insight into effects of the experimental conditions on the temporal behavior of the flow. Many of the low order modes are found to be associated in pairs, corresponding to asymmetric structures or advection of a given structure downstream. The capability of POD to produce reduced order models of the flow is then utilized to facilitate vortex identification analysis. A turbulent kinetic energy based mode truncation criteria, which has been found to enhance vortex identification capability, is applied to select the POD modes and temporal coefficients to be used in the reduced order modeling. The reconstructed velocity fields are then analyzed with vortex identification algorithms to extract the vortex cores and boundaries. The combination of these approaches allows the study of the effect of proximity and heat transfer on the vortex characteristics, such as size, strength, and distribution.

42 ENGINEERING↗

Energy-Storing Cryogenic Carbon Capture™ for Utility and Industrial-scale Processes (Final Report)

This project leverages work completed under funding from previous U.S. Department of Energy (DOE) projects and other sources of funding around the Cryogenic Carbon Capture Process™ (CCC). The purpose of this project is to further develop a perturbation of the CCC process that stores energy called the Cryogenic Carbon Capture™ Energy Storing (CCC-ES) process. The successful completion of the tasks in this project has prepared the CCC-ES process for scaling and developed initial plans and a feasibility analysis for an engineering-scale or small-commercial scale system that can store at least 10 MWh of energy. The specific areas of work in this project are: (1) Develop a conceptual, site-specific integrated process flow diagram: Sustainable Energy Solutions (SES) developed a conceptual, site-specific plan including a process flow diagram for integrating CCC-ES at a specific location. The proposed system was based on a typical engineering-scale CCC system designed to capture 30-50 metric tonnes of CO 2 per day (TPD), with modifications and additional changes and equipment put in place to add the energy storage element to the system. The 30-50 TPD scale corresponds to the required 10 MWh of stored energy. This task includes updating simulation software for transient analysis. SES also coordinated with the Jim Bridger Power Plant in Point of Rocks, Wyoming to get site-specific data. Using these data, SES completed site-specific preliminary process flow diagrams, estimated capital and operating costs for the CCC-ES system, and used the upgraded software package to estimate the primary figures of merit. (2) Complete a technoeconomic analysis (TEA): SES completed a full-scale TEA of the CCC-ES system to meet specific success criteria. This TEA used process information from the host site selected above. (3) Technology and data gap assessment for the CCC-ES process: As part of the technology gap assessment, SES performed an assessment of the best alternative energy storage solutions including figures of merit and operational strengths and weaknesses. SES then compared the proposed system with a discussion of how it addresses the weaknesses of alternative systems, showing for example a cost of stored energy at less than $50/MWh and with a roundtrip efficiency of greater than 95%. This assessment includes technical and other risk analyses and technology gaps with research and development needs to commercialize the process by 2030. Finally, work includes a commercialization roadmap/development pathway outlining the major milestones to move to a commercially operating CCC-ES system. (4) Phase II pre-FEED project plan: SES completed a project plan for the Phase II pre-FEED analysis using the same host site as in the Phase I conceptual study.

03 NATURAL GAS↗

Weakly solvating electrolytes: a solvation-centric paradigm for rechargeable metal batteries

Electrolyte design has long followed a solvation-first paradigm that prioritizes solvents capable of maximizing salt dissociation and ionic conductivity, while treating interfacial degradation and rheological limitations as secondary constraints. Although this approach has enabled significant progress in lithium-ion and sodium-ion batteries, it inherently favors solvent-dominated solvation structures that destabilize reactive metal interfaces. Weakly solvating electrolytes (WSEs) offer a fundamentally different strategy. By using solvents with intrinsically low donor strength and minimal electrostatic affinity for cations, WSEs suppress cation–solvent coordination and promote anion-rich solvation shells without relying on salt superconcentration. This shift lowers desolvation barriers, redirects interfacial decomposition pathways, and supports the formation of inorganic-rich, stable interphases. In this review, we discuss the molecular and solvation criteria that distinguish WSEs from conventional and concentrated or locally concentrated electrolyte systems, examine their implementation across different chemistries, and identify unresolved design challenges. WSEs are presented not as a niche formulation, but as a solvation-centric framework for rethinking electrolyte function in metal battery technologies.

Karbak, Mehdi [Pacific Northwest National Laborato↗

Applying ALARA Principles in the Design of New Radiological Facilities

The application of ALARA (As Low As Reasonably Achievable) principles to the design of new radiological facilities at Argonne National Laboratory provides a consistent radiation safety basis for future facility operations. The Department of Energy Rule 10 CFR 835 specifies design objectives to be adopted during the design of new facilities for controlling personal radiation exposure. One is to keep exposure levels below 20% of the applicable standards in 10 CFR 835.202. For a radiation worker 20% of the standard corresponds to 5 µSv hr -1 for a 2,000 hour work year. For a member of the public the DOE design objective corresponds to 0.2 mSv in a calendar year. For a new facility worst case radionuclides and their source strengths are chosen. Local shielding is specified to reduce exposure rates to less than 50 µSv hr -1 at 30 cm from the shielding. The current version MCNP6 of the Los Alamos radiation shielding computer program MCNP is then used to calculate the exposure rates elsewhere. Design modifications are made to meet the criteria. The calculations and resulting facility design modifications are discussed for two new radiological facilities.

61 RADIATION PROTECTION AND DOSIMETRY↗

Influence of cementation on the yield surface of rocks numerically determined from digital microstructures

Digital Rock Physics has reached a level of maturity on the characterisation of primary properties that depend on the microstructure – such as porosity, permeability or elastic moduli – by numerically solving field equations on μCT scan images of rock. After small deformations or at depth though, most rocks eventually reach their limit of elasticity and the complementary plastic properties are needed to describe the full mechanical behaviour. Currently, determination of a rock’s yield surface from its microstructure is often restricted to semi-analytical criteria derived by limit analysis or numerical simulations performed on idealised geometries. Such simplification lacks representativeness, particularly for processes that affect directly the pore-grain interface such as the cementation phenomenon, happening during diagenesis. Eventually, only direct numerical simulation of elasto-plasticity performed on digitalised microstructures can be used to assess the strength of different cemented materials and its evolution with the alteration of the microstructure. In this study, we provide a comprehensive parametric study on the impact of cementation on rock strength for real microstructures of cemented granular materials. Compared to most previous studies, the whole yield surface is determined numerically (using Finite Element Method) in order to assess the influence of cementation for different stress-paths. The previously known tendency of rock to strengthen with increasing cementation volume is verified. New results on the influence of cement property namely Young’s modulus, friction and cohesion on the rock’s yield surface are explored. The envelopes obtained are compared to the ones obtained by experimental data and existing models. Finally, the framework presented in this study showcases the wider possibility of determining any rock’s or porous material’s yield surface from its microstructure.

36 MATERIALS SCIENCE↗

Steady state thermo-mechanics and material property definition framework for analyzing DCLL blanket in the fusion nuclear science facility

In this work, a thermo-mechanics model that relies on creating the material property definition framework (MPDF) and multiphysics coupling of the heat transfer and the solid mechanics modules is developed to determine the structural integrity of the recently designed dual cooled lead lithium (DCLL) inboard blanket (IB) for the Fusion Nuclear Science Facility under steady state loads. The MPDF is called to supply fusion relevant neutron irradiation and temperature induced changes in material properties during multiphysics finite element runs, and PbLi temperature profiles are used to approximate Magnetohydrodynamics effect and the nuclear volumetric heating on the PbLi. Neutron irradiation and temperature induced reduction of the yield and ultimate strengths of F82H steel at the first wall (FW) are quantified for one year. A blanket in an assembly with gaps between blanket sectors and another blanket in an assembly with no gaps between blanket sectors, both exposed to radiation damage that lasted for one year are analyzed. Analysis using the elastic ITER structural design criteria for in-vessel components (ITER SDC-IC) design rules and a linear isotropic-hardening-type elastoplastic material model are used where most appropriate. The IB blanket with gaps between blanket sectors will withstand the steady state combined thermal and coolant loads for one year operational period but will fail if no gaps are allowed between blanket sectors. It is recommended that a gap of about 7.62 mm should be provided between IB blanket sectors during assembly which would close up during service, stop neutron streaming, reduce stresses and reduce bending of the FW into the scrape-off layer.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗