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At least 55 records · Page 3

Geomechanical Characterization of the Mount Simon Sandstone and Eau Claire Formation of Northern Illinois Basin

The purpose of this paper is to analyze publicly available geomechanical data from two carbon storage sites in the Illinois Basin: the Illinois Basin-Decatur Project (IBDP) in Macon County, IL and the FutureGen2.0 project in Morgan County, IL, cancelled before injection began. This study estimates the magnitudes and directions of the least compressive principal stress gradient using hydraulic fracture-based stress measurement tests, borehole breakouts, and sonic logs in the Eau Claire Formation (primary confining zone) and the Mount Simon Sandstone (targeted reservoir). The range of stresses expected in the underlying Precambrian basement is also investigated. The evaluation of the state of stress is carried out in a probabilistic manner using the State of Stress Analysis Tool (SOSAT) developed under the National Risk Assessment Partnership (NRAP) program. Finally, the paper also provides a discussion on distinctions between fracture initiation pressure, propagation pressure, and fracture closure pressure, given that hydraulic fracture testing results show a significant difference between these three values. The discussion also addresses why the fracture closure pressure should be preferred in injection pressure determinations, a critical point in geological carbon storage projects.

de Toledo Camargo, Julia↗

From subsidies to stressors: Positively skewed ecological gradients alter biological responses to nutrients in streams

Abstract Subsidy–stress gradients offer a useful framework for understanding ecological responses to perturbation and may help inform ecological metrics in highly modified systems. Historic, region‐wide shifts from bottomland hardwood forest to row crop agriculture can cause positively skewed impact gradients in alluvial plain ecoregions, resulting in tolerant organisms that typically exhibit a subsidy response (increased abundance in response to environmental stressors) shifting to a stress response (declining abundance at higher concentrations). As a result, observed biological tolerance in modified ecosystems may differ from less modified regions, creating significant challenges for detecting biological responses to restoration efforts. Using the agriculturally dominated Mississippi Alluvial Plain (MAP) ecoregion in Mississippi, USA, as a case study, we tested the hypothesis that macroinvertebrate taxa that typically display a subsidy response to nutrient enrichment in less modified ecoregions (i.e., nutrient‐tolerance) shift to a stress response to increasing nutrients in highly modified watersheds with elevated baseline nutrient conditions (i.e., nutrient intolerance). The abundance and diversity of MAP‐specific intolerant taxa identified with threshold indicator taxa analysis were either unresponsive or exhibited a subsidy response to increasing nutrients in less modified ecoregions in Mississippi with less land alteration and lower nutrient concentrations, but declined at higher concentrations, providing evidence for a stress response to elevated nutrients in the MAP. Additionally, MAP‐specific tolerant and intolerant taxa richness responded to increased nutrients predictably and consistently across space and time within the MAP. However, in MAP streams, elevated specific conductance was predicted to dampen the response of tolerant and intolerant taxa richness to increasing nutrient concentrations, highlighting the importance of considering multistressor interactions when interpreting biological data. Lastly, we demonstrate the efficacy of this approach with sediment bacterial communities characterized with amplicon sequencing, which lack sufficient life history characteristics necessary for the development of multimetric indices. Both macroinvertebrate and bacterial communities responded similarly to increasing nutrient concentrations, suggesting DNA‐based approaches may provide an efficient biological assessment tool for monitoring water quality improvements in highly modified watersheds.

DeVilbiss, Stephen E. [U.S. Geological Survey Lowe↗

Thickness dependence of Al 0.88 Sc 0.12 N thin films grown on silicon

The thickening behavior of aluminum scandium nitride (Al 0.88 Sc 0.12 N) films grown on Si(111) substrates has been investigated experimentally using X-ray diffraction (XRD), transmission electron microscopy (TEM), atomic force microscopy, and residual stress measurement. Al 0.88 Sc 0.12 N films were grown with thicknesses spanning 14 nm to 1.1 um. TEM analysis shows that the argon sputter etch used to remove the native oxide prior to deposition produced an amorphous, oxygen-rich surface, preventing epitaxial growth. XRD analysis of the films show that the A1ScN(002) orientation improves as the films thicken and the XRD A1ScN(002) rocking curve full width half maximum decreases to 1.34 q for the 1.1 pm thick film. XRD analysis shows that the unit cell is expanded in both the a- and c-axes by Sc doping; the a-axis lattice parameter was measured to be 3.172 ± 0.007 A and the c-axis lattice parameter was measured to be 5.000 ± 0.001 A, representing 1.96% and 0.44% expansions over aluminum nitride lattice parameters, respectively. The grain size and roughness increase as the film thickness increases. A stress gradient forms through the film; the residual stress grows more tensile as the film thickens, from -1.24 GPa to +8.5MPa.

36 MATERIALS SCIENCE↗

Advances in Non-contact Measurement of Creep Properties

Our team has developed a novel approach to measuring creep at extremely high temperatures using electrostatic levitation (ESL). This method has been demonstrated on niobium up to 2300 C, while ESL has melted tungsten (3400 C). High-precision machined spheres of the sample are levitated in the NASA MSFC ESL, a national user facility, and heated with a laser. The laser is aligned off-center so that the absorbed photons transfer their momentum to the sample, causing it to rotate at up to 250,000+ RPM. The rapid rotation loads the sample through centripetal acceleration, causing it to deform. The deformation of the sample is captured on high-speed video, which is analyzed by machine-vision software from the University of Massachusetts. The deformations are compared to finite element models to determine the constitutive constants in the creep relation. Furthermore, the noncontact method exploits stress gradients within the sample to determine the stress exponent in a single test. This method was validated in collaboration with the University of Tennessee for niobium at 1985 C, with agreement within the uncertainty of the conventional measurements. A similar method is being employed on Ultra-High-Temperature ZrB2- SiC composites, which may see application in rocket nozzles and sharp leading edges for hypersonic vehicles.

Hyers, Robert W.↗

Improved Creep Measurements for Ultra-High Temperature Materials

Our team has developed a novel approach to measuring creep at extremely high temperatures using electrostatic levitation (ESL). This method has been demonstrated on niobium up to 2300 C, while ESL has melted tungsten (3400 C). This method has been extended to lower temperatures and higher stresses and applied to new materials, including a niobium-based superalloy, MASC. High-precision machined spheres of the sample are levitated in the NASA MSFC ESL, a national user facility and heated with a laser. The samples are rotated with an induction motor at up to 30,000 revolutions per second. The rapid rotation loads the sample through centripetal acceleration, producing a shear stress of about 60 MPa at the center, causing the sample to deform. The deformation of the sample is captured on high-speed video, which is analyzed by machine-vision software from the University of Massachusetts. The deformations are compared to finite element models to determine the constitutive constants in the creep relation. Furthermore, the non-contact method exploits stress gradients within the sample to determine the stress exponent in a single test.

Hyers, Robert W.↗

Data from: "Colonisation of the alpine tundra by trees: alpine neighbours assist late-seral but not early-seral conifer seedlings"

This archive contains data used to support conclusions made in “Colonisation of the alpine tundra by trees: alpine neighbours assist late-seral but not early-seral conifer seedlings”, by Jabis et al., 2020. Data were collected in the alpine field location of the Alpine Treeline Warming Experiment (ATWE), on Niwot Ridge, in the Front Range of the Colorado Rocky Mountains, USA.This package includes survivorship and physiology data for limber pine (Pinus flexilis), Engelmann spruce (Picea engelmannii), and Rocky Mountain snowlover (Chionophila jamesii). Site climate data such as soil moisture and temperature are also included. This data package contains ten comma-separated-values (.csv) files, and two rich-text-format (.rtf) files all compressed within one folder named “Neighbor_data_repository.zip”. Both file types can be opened by text-edit softwares such as TextEdit (Mac) and Notepad (Windows). The files are also compatible with analyses softwares such as R. .csv files can also be opened by Microsoft Excel. Two geospatial datasets are also included in this archive: one keyhole markup language (.kml) file with four points marking the corners of the study site, and a compressed file containing two ESRI shapefiles (.shp). The .kml files can be opened with Google Earth or Google Maps, and the shapefiles can be opened using any geographic information system applications, including the entire ArcGIS suite, and QGIS. -------------------------------------------------------------------------------------------------------------------------------------------------------The elevation mountain treeline is expected to shift upward with climate warming, and seed germination and seedling survival are critical local controls on treeline expansion. Neighboring alpine plants, either through competition for resources or through altering the microclimate, can also affect seedling emergence and survival. We asked whether establishing tree seedlings and an alpine herb are similarly sensitive to alpine plant neighbours under ambient and altered climate. We imposed active heating, watering, and neighbor removal experiments for emerging conifer seedlings and an alpine herb.We compared target plant survival, photosynthetic efficiency, and water use efficiency under ambient and experimental conditions. Picea engelmannii seedlings showed lower survival compared with Pinus flexilis three weeks following neighbour removal, and after 1 year only survived in watered plots. Pinus seedlings responded to neighbour removal by lowering the quantum yield of photosynthesis (ϕPSII). Contrary to expectations from the stress gradient hypothesis, survival was reduced without neighbours near the low-elevation range limit of Chionophila jamesii.

54 ENVIRONMENTAL SCIENCES↗

Vacancy-mediated transport and segregation tendencies of solutes in fcc nickel under diffusional creep: A density functional theory study

The Nabarro-Herring (NH) diffusional creep theory postulates the vacancy-mediated transport of atoms under a stress gradient as the creep mechanism under low-stress and high-temperature conditions. In multicomponent alloys, we premise that this stress-assisted flow of vacancies to and from grain boundaries will produce elemental segregation. An observation of such segregation, validated with theoretical predictions, can provide the necessary experimental evidence for the occurrence of NH creep. Theoretical calculations of the segregation tendencies via analyzing the dominant solute diffusion mechanisms and the difference in diffusivities of the elements are therefore essential. To this end, this study applies density functional theory calculations of migration barriers and solute-vacancy binding energies as input to the self-consistent mean-field theory to assess the vacancy-mediated diffusion mechanisms, transport coefficients, and segregation tendencies of Co, Cr, Mo, Re, Ta, and W solutes in face-centered-cubic Ni. We find Co, Re, and W to be slow diffusers at high temperatures and Cr, Mo, and Ta to be fast diffusers. Further analysis shows that the slow diffusers tend to always enrich at vacancy sinks over a wide range of temperatures. In contrast, the fast diffusers show a transition from depletion to enrichment as the temperature lowers. Furthermore, our analysis of the segregation tendencies under tensile hydrostatic strains shows that slow diffusers are largely unaffected by the strain and favor enrichment. On the other hand, the fast diffusers exhibit high sensitivity to strain and their segregation tendency can transition from depletion to enrichment at a given temperature. Finally, the transport coefficients calculated in this work are expected to serve as input to mesoscale microstructure models to provide a more rigorous assessment of solute segregation under NH creep conditions.

36 MATERIALS SCIENCE↗

Electrochemical-Mechanical Coupling Strongly Affects the Performance of Nanopore, Thin-Film, and Solid-State Batteries

Here, the present study focuses on the electrochemical-mechanical (ECM) coupling effects of a thin-film, solid-state battery with only stiff, ceramic materials, in contrast to prior investigations that focus on individual active material particles or aggregations of particles. We model the impacts of ECM couplings including stress-transport and stress-equilibrium potential on the full-cell performance and potential mechanical failure modes of a thin-film battery conformally deposited in a nanopore scaffold, which is an experimentally achievable device. Model results indicate electrode volume changes due to lithium insertion or removal, along with mechanical boundary conditions, result in stress gradients that alter the lithium-ion flux, reduce lithium concentration gradients, and improve cell rate capability. However, the high stress levels in the cell can also lead to mechanics-related failure such as the separation of cell layers. For the parameter set in this work, stress-transport coupling has a much greater influence on rate capability than stress-potential coupling. Optimization of thin-film batteries to harness the benefits of ECM coupling effects requires leveraging geometric design and material selection. The current work underscores the need for further theoretical and experimental investigation into ECM coupling effects in thin-film batteries to enhance their understanding and design optimization.

25 ENERGY STORAGE↗

High-Frequency, High-Temperature Fretting Experiments

Fretting is a structural damage mechanism observed when two nominally clamped surfaces are subjected to an oscillatory loading. A critical location for fretting induced damage has been identified at the blade/disk and blade/damper interfaces of gas turbine engine turbomachinery and space propulsion components. The high-temperature, high-frequency loading environment seen by these components lead to severe stress gradients at the edge-of-contact. These contact stresses drive crack nucleation and propagation in fretting and are very sensitive to the geometry of the contacting bodies, the contact loads, materials, temperature, and contact surface tribology (friction). To diagnose the threat that small and relatively undetectable fretting cracks pose to damage tolerance and structural integrity of in-service components, the objective of this work is to develop a well-characterized experimental fretting rig capable of investigating fretting behavior of advanced aerospace alloys subjected to load and temperature conditions representative of such turbomachinery components.

Matlik, J. F.↗

A mechanism for tectonic deformation on Venus

In the absence of identifiable physiographic features directly associated with plate tectonics, alternate mechanisms are sought for the intense tectonic deformation observed in radar images of Venus. One possible mechanism is direct coupling into an elastic lithosphere of the stresses associated with convective flow in the interior. Spectral Green's function solutions have been obtained for stresses in an elastic lithosphere overlying a Newtonian interior with an exponential depth dependence of viscosity, and a specified surface-density distribution driving the flow. At long wavelengths and for a rigid elastic/fluid boundary condition, horizontal normal stresses in the elastic lid are controlled by the vertical shear stress gradient and are directly proportional to the depth of the density disturbance in the underlying fluid. The depth and strength of density anomalies in the Venusian interior inferred by analyses of long wavelength gravity data suggest that stresses in excess of 100 MPa would be generated in a 10 km thick elastic lid unless a low viscosity channel occurring beneath the lid or a positive viscosity gradient uncouples the flow stresses. The great apparent depth of compensation of topographic features argues against this, however, thus supporting the importance of the coupling mechanism. If there is no elastic lid, stresses will also be very high near the surface, providing also that the viscosity gradient is negative.

Phillips, Roger J.↗

Design Considerations for Ceramic Matrix Composite Vanes for High Pressure Turbine Applications

Issues associated with replacing conventional metallic vanes with Ceramic Matrix Composite (CMC) vanes in the first stage of the High Pressure Turbine (HPT) are explored. CMC materials have higher temperature capability than conventional HPT vanes, and less vane cooling is required. The benefits of less vane coolant are less NOx production and improved vane efficiency. Comparisons between CMC and metal vanes are made at current rotor inlet temperatures and at an vane inlet pressure of 50 atm.. CMC materials have directionally dependent strength characteristics, and vane designs must accommodate these characteristics. The benefits of reduced NOx and improved cycle efficiency obtainable from using CMC vanes. are quantified Results are given for vane shapes made of a two dimensional CMC weave. Stress components due to thermal and pressure loads are shown for all configurations. The effects on stresses of: (1) a rib connecting vane pressure and suction surfaces; (2) variation in wall thickness; and (3) trailing edge region cooling options are discussed. The approach used to obtain vane temperature distributions is discussed. Film cooling and trailing edge ejection were required to avoid excessive vane material temperature gradients. Stresses due to temperature gradients are sometimes compressive in regions where pressure loads result in high tensile stresses.

Boyle, Robert J.↗

Measurement of Residual Stresses by X-ray Diffraction Near Simulated Heat Affected Zones in Austenitic Stainless Steels

Simulated heat-affected zones (HAZs) were made in austenitic stainless steel specimens using a Gleeble. The samples were heated to temperatures as high as 1100°C by computer controlled resistance heating. By controlling the heating rate, maximum temperature, and cooling rate, a wide range of residual stresses were introduced in the specimens. Stress measurements were made using X-ray diffraction. It was found that significant stress gradients were produced in the simulated HAZs, and that all stresses were compressive in nature, both in the longitudinal and transverse directions. These results are not representative of the residual stresses determined in the HAZs of real welds, thus calling into question some aspects of the role of the Gleeble in such simulations.

36 MATERIALS SCIENCE↗

Comparison of boundary element and finite element methods in spur gear root stress analysis

The boundary element method (BEM) is used to compute fillet stress concentration in spur gear teeth. The results are shown to compare favorably with analogous results obtained using the finite element method (FEM). A partially supported thin rim gear is studied. The loading is applied at the pitch point. A three-dimensional analysis is conducted using both the BEM and FEM (NASTRAN). The results are also compared with those of a two-dimensional finite element model. An advantage of the BEM over the FEM is that fewer elements are needed with the BEM. Indeed, in the current study the BEM used 92 elements and 270 nodes whereas the FEM used 320 elements and 2037 nodes. Moreover, since the BEM is especially useful in problems with high stress gradients it is potentially a very useful tool for fillet stress analyses.

Sun, H.↗

Review of SiC material development for nuclear fusion applications: Cross-cutting research and emerging opportunities

The SiC-based materials, particularly SiC-fiber-reinforced SiC matrix (SiC/SiC) composites, show strong potential for structural and functional applications in future fusion power plants because they can operate at high temperatures with a range of coolants and breeders, thereby enabling higher energy conversion efficiency. Here, this paper presents recent advancements in the development of SiC-based materials, focusing on processing techniques and material performance and resistance under fusion-relevant environments. The processing activities have emphasized near-net-shape fabrication and the joining of SiC subcomponents, with processing methods and material compositions informed by previous irradiation experiments on various grades of SiC. Research on irradiation effects has remained focused on degradation mechanisms and the microstructural optimization of SiC/SiC composites irradiated to high neutron damage levels. Analysis of irradiation defects in SiC has advanced via the application of cutting-edge characterization methods, among which Raman spectroscopy is becoming a common tool to assess atomic-scale chemical disorder. Fusion–fission crosscutting irradiation research has explored combined effects in SiC/SiC composites with application-relevant geometries, including bowing of SiC/SiC composite channels under neutron flux gradients, stress evolution in SiC/SiC composite tubes under through-thickness temperature gradients, and irradiation-enhanced corrosion in SiC. Finally, research opportunities for component testing and assessment under fusion-relevant conditions, in support of emerging concepts from the private fusion sector, are discussed.

Advanced manufacturing↗

Applications of a new wall function to turbulent flow computations

A new wall function approach is developed based on a wall law suitable for incompressible turbulent boundary layers under strong adverse pressure gradients. This wall law was derived from a one-dimensional analysis of the turbulent kinetic energy equation with gradient diffusion concept employed in modeling the near-wall shear stress gradient. Numerical testing cases for the present wall functions include turbulent separating flows around an airfoil and turbulent recirculating flows in several confined regions. Improvements on the predictions using the present wall functions are illustrated. For cases of internal recirculating flows, one modification factor for improving the performance of the k-epsilon turbulence model in the flow recirculation regions is also included.

Chen, Y. S.↗

Multiscale mechanical fatigue damage of stainless steel investigated by neutron diffraction and X-ray microdiffraction

Mechanical fatigue behavior of AL6XN stainless steel as a typical type of planar slip alloy was investigated by in situ neutron diffraction and synchrotron-based X-ray microdiffraction methods. Under cyclic loading at a high strain amplitude (+/- 0.8%), the fatigue damage originated mainly from the accumulation of statistical stored dislocations, as clearly evidenced from a continuous increase in diffraction peak width with increasing the number of load cycles. However, under cyclic loading at a low strain amplitude (+/- 0.3%), the density of statistical stored dislocations became saturated just after a hundred loading cycles and the fatigue damage was mainly dominated by the accumulation of persistent [Alders bands (PLBs) and the complex interactions among various PLBs as evidenced through X-ray microdiffraction measurements. It was further found that there exists obvious grain-orientation-dependent local damage in the low-strain-amplitude fatigued sample. In particular, fatigued grains orientated with [001] paralleling the loading direction are subjected to compressive stress and contain a large number of broad PLBs in boundaries arraying the edge dislocation pile-ups, which generate a large stress gradient leading to local plastic instability. As a result, the highly localized stress field at PLBs in the cyclically-deformed sample at a low strain amplitude may explain the obvious cyclic stress softening.

36 MATERIALS SCIENCE↗

In-Situ Stress Measurements at the Utah Frontier Observatory for Research in Geothermal Energy (FORGE) Site

A scientific injection campaign was conducted at the Utah Frontier Observatory for Research in Geothermal Energy (FORGE) site in 2017 and 2019. The testing included pump-in/shut-in, pump-in/flowback, and step rate tests. Various methods have been employed to interpret the in-situ stress from the test dataset. This study focuses on methods to interpret the minimum in-situ stress from step rate, pump-in/extended shut-in tests data obtained during the stimulation of two zones in Well 58-32. This well was drilled in low-permeability granitoid. A temperature of 199 °C was recorded at the well’s total depth of 2297 m relative to the rotary Kelly bushing (RKB). The lower zone (Zone 1) consisted of 46 m of the openhole at the toe of the well. Fractures in the upper zone (Zone 2) were stimulated between 2123–2126 m measured depths (MD) behind the casing. The closure stress gradient variation depended on the depth and the injection chronology. The closure stress was found to increase with the pumping rate/volume. This stress variation could indicate that poroelastic effects (“back stress”) and the presence of adjacent natural fractures may play an important role in the interpretation of fracture closure stress. Further, progressively increasing local total stresses may, consequently, have practical applications when moderate volumes of fluid are injected in a naturally fractured or high-temperature reservoir. The alternative techniques that use pump-in/flowback tests and temperature signatures provide a valuable perspective view of the in-situ stress measurements.

15 GEOTHERMAL ENERGY↗

Analysis of notched metal matrix composites under tension loading

Presented are techniques based on 3-D finite-element analysis for the examination of continuous fiber reinforced metal matrix composites. Examples are shown for specific metal matrix composites such as boron/aluminum and silicon-carbide/aluminum. Specimen stress-strain behavior and stress at first fiber failure were predicted for boron/aluminum laminates containing circular holes and crack-like slits. The predictions compared very well for (+ or - 45) sub 2s laminates. Mesh configuration was shown to have an effect on the calculation of stresses local to the notch. The presence of thin interface layers of matrix material had a significant influence on the slit-tip stress state, causing sharper stress gradients near the notch. Interface layers reduced the slit-tip fibers stresses in a (+ or - 45) sub s silicon-carbide/aluminum laminate but increased them in a (0/90) sub s laminate.

Bigelow, C. A.↗