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At least 55 records · Page 3

Protracted oxygenation across the Cambrian–Ordovician transition: A key initiator of the Great Ordovician Biodiversification Event?

Fluctuations in marine oxygen concentrations have been invoked as a primary driver for changes in biodiversity throughout Earth history. Expansions in reducing marine conditions are commonly invoked as key causal mechanisms for mass extinctions, while increases in marine oxygenation are becoming an increasingly common causal mechanism invoked for biodiversification events. Here we utilize a multiproxy approach to constrain local and global marine paleoredox conditions throughout the late Cambrian–Early Ordovician from two drill core successions in Baltoscandia. Local paleoredox proxies such as manganese concentrations and iron speciation reveal that both sites in the Baltic paleobasin had persistently anoxic and predominantly euxinic (anoxic and sulfidic) bottom water conditions throughout the study interval. Corresponding trace metal datasets indicate nuanced contraction and expansion of global anoxic and euxinic conditions along continental margins during the late Cambrian–Early Ordovician. Lastly, thallium isotope data from these locally reducing sections suggest a global expansion of oxygenated shelf and deeper marine environments from the late Cambrian into the Early Ordovician. This evidence for increasingly oxic marine environments coincides with increases in burrowing depth and tiering in marine animals, as well as diversification of body fossils throughout this ~8-million-year interval. The collective geochemical datasets provide some of the first direct paleoredox evidence for an increase in marine oxygen concentrations as a key mechanism for the Ordovician radiation of marine life

anoxia↗

Mass-spectrometry

Mass spectrometric analyses of meteoritic and lunar samples containing lead and thallium

Black, L. P.↗

High-temperature, long-life thyratron

Thallium and xenon filled thyratron was developed that operates at tube envelope temperatures up to 750 C. This tube performs at peak voltage ratings of 2000 V forward and reverse and at an average current rating of 15 A for up to 11,000 hours.

Baum, E. A.↗

Use of radiation in preparative chemistry

A summary and updating of previous work on the use of radiation chemistry for the preparation of pure materials are presented. Work was chiefly concerned with the reduction of metal salts in solution to the free metal using 2 MeV electrons. Metals deposited from aqueous solution are copper, silver, zinc, cadmium, thallium, tin, lead, antimony, iron, nickel, cobalt, and palladium. Dry organic solvents were evaluated for the deposition of metals based on a study involving deposition of antimony from soltions of antimony (III) chloride. The use of organic liquids for the preparation of anhydrous metal halides is also presented. Reaction mechanisms for both organic liquids and aqueous system are discussed.

Philipp, W. H.↗

Heavy ion plasma confinement in an RF quadrupole trap

The confinement of an electron free plasma in a pure quadrupole RF electric trap was considered. The ultimate goal was to produce a large density of mercury ions, in order to realize a trapped ion frequency standard using the hyperfine resonance of 199 Hg(+) at 40.7 GHz. An attempt was made to obtain an iodine plasma consisting of equal numbers of positive and negative ions of atomic iodine, the positive iodine ions, being susceptible to charge-exchange with mercury atoms, will produce the desired mercury ions. The experiment showed that the photoproduction of ions pairs in iodine using the necessary UV radiation occurs with a small cross-section, making it difficult to demonstrate the feasibility of space charge neutralization in a quadrupole trap. For this reason it was considered expedient to choose thallium iodide, which has a more favorable absorption spectrum (in the region of 2000 to 2100 A). The results indicate that, although the ionic recombination is a serious limiting factor, a considerable improvement can be obtained in practice for the density of trapped ions, with a considerable advantage in lifetimes for spectroscopic purposes. The ion pair formation by photoionization is briefly reviewed.

Schermann, J.↗

Characteristics of cesium iodide for use as a particle discriminator for high energy cosmic rays

The possible use of CsI to discriminate between high energy cosmic ray electrons and interacting protons has been investigated. The pulse-shape properties as a function of ionization density, temperature, and spectral response are presented for thallium-activated CsI and as a function of ionization density for sodium-activated CsI. The results are based on previously published data and on corroborative measurements from the present work. Experimental results on the response of CsI to electron-induced electromagnetic cascades and to interacting hadrons are described. Bibliographies of publications dealing with the properties of CsI and with pulse-shape discrimination techniques are presented.

Crannell, C. J.↗

Volatile elements in Apollo 16 samples - Possible evidence for outgassing of the moon.

Several Apollo 16 breccias, including one containing goethite, are strikingly enriched in volatile elements such as bromine, cadmium, germanium, antimony, thallium, and zinc. Similar but smaller enrichments are found in all highland soils. It appears that volcanic processes took place in the lunar highlands, involving the release of volatiles including water. The lunar thallium/uranium ratio is .0002 of the cosmic ratio, which suggests that the moon's original water content could not have exceeded the equivalent of a layer 22 meters deep. The cataclastic anorthosites at the Apollo 16 site may represent deep ejecta from the Nectaris basin.

Krahenbuhl, U.↗

Gamma ray spectrometer experiment, NaI(Tl) detector crystal activation

Preliminary results are presented of data on the extent of the cosmic ray-induced activity obtained by a sodium iodide thallium-activated crystal flown onboard the Apollo 17 command module. Qualitative identification is reported for the following: Na-24, I-123, I-124, I-125, I-126, and Xe-127.

Trombka, J. I.↗