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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

Development of Trace Contaminant Control Prototypes for the Primary Life Support System (PLSS)

Results are presented on the development of Trace Contaminant Control (TCC) Prototypes for use in Extravehicular Activities (EVAs), and more specifically in the Primary Life Support System (PLSS). The current TC-control technology involves the use of a packed bed of acid-impregnated granular charcoal, which is non-regenerable, and the carbon-based sorbent under development in this project can be regenerated by exposure to vacuum at room temperature. Data on sorption and desorption of ammonia and formaldehyde, which are major TCs of concern, as well as pressure-drop calculations were used to design and test 1/6-scale and full-scale trace contaminant control system (TCCS) prototypes. Carbon sorbents were fabricated in both the granular and foam-supported forms. Sorbent performance was tested for ammonia sorption and vacuum regeneration in 1/6-scale, and pressure-drop characteristics were measured at flow rates relevant to the PLSS application.

Wojtowicz, Marek↗
NASA NTRS1979

Design and development of a trace contaminant removal canister for Spacelab

The paper describes the overall approach used by NASA-MSFC to design and develop a trace contaminant removal canister for Spacelab. The elements of this approach include the establishment of a trace contaminant load model, analysis and testing to define a preliminary design, development testing to verify the adequacy of the selected design, and testing to define a suitable canister location in the transfer tunnel ventilation system. The canister utilizes a catalyst material which is effective in removing carbon monoxide at room temperature, as well as plain and acid treated charcoal. The canister alone will control all contaminants in the load model below their maximum allowable concentration (MAC) levels without assistance from the baseline environmental control system (ECS) except for methyl alcohol and ammonia.

Ray, C. D.↗
NASA NTRS1995

International Space Station Alpha trace contaminant control subassembly life test report

The Environmental Control and Life Support System (ECLSS) Life Test Program (ELTP) began with Trace Contaminant Control Subassembly (TCCS) Life Testing on November 9, 1992, at 0745. The purpose of the test, as stated in the NASA document 'Requirements for Trace Contaminant Control Subassembly High Temperature Catalytic Oxidizer Life Testing (Revision A)' was to 'provide for the long duration operation of the ECLSS TCCS HTCO (High Temperature Catalytic Oxidizer) at normal operating conditions... (and thus)... to determine the useful life of ECLSS hardware for use on long duration manned space missions.' Specifically, the test was designed to demonstrate thermal stability of the HTCO catalyst. The report details TCCS stability throughout the test. Graphs are included to aid in evaluating trends and subsystem anomalies. The report summarizes activities through the final day of testing, January 17, 1995 (test day 762).

Tatara, J. D.↗
NASA NTRS1978

Electric discharge for treatment of trace contaminants

A radio frequency glow discharge reactor is described for removing trace oxidizable contaminants from an oxygen bearing atmosphere. The reaction chamber is defined by an inner metal electrode facing a dielectric backed by an outer conductive electrode. In one embodiment, a conductive liquid forms the conductor of an outer electrode and cools the dielectric. A resonator coupled to a variable radio frequency source generates the high voltages for creating a glow discharge in the chamber at a predetermined pressure whereby the trace contaminants are oxidized into a few simple non-toxic products that may be easily recovered. The corresponding process for removal of trace contaminants from an oxygen-bearing atmosphere with high efficiency independent of the concentration level is also disclosed.

Flamm, D. L.↗
NASA NTRS1999

Demonstration of an Ultra-Short Channel Metal Monolith Catalytic Reactor for Trace Contaminant Control Applications

The International Space Station (ISS) Trace Contaminant Control Subassembly (TCCS) design is based upon proven, highly reliable technology. However, because its core unit operations rely upon expendable activated charcoal and an indirectly heated high temperature catalyst, annual logistics mass, crew time, and power consumption requirements are significant. To address this situation, a unique catalytic reactor design has been developed which is suitable for retrofit into the TCCS's high temperature catalytic oxidizer (HTCO) assembly. The unique design, which employs a metallic, ultra-short channel length monolith (USCM) catalyst substrate, was tested in a flight-like TCCS HTCO assembly to investigate its performance characteristics. Test results indicate that retrofitting the TCCS with a USCM-based catalytic reactor is feasible and that it may provide significant reductions in logistics mass, crew time, and power consumption. Savings indicated by test results are up to 81% for annual logistics, 56% for crew time, and 77% for startup transient duration. In addition, its demonstrated ability to operate in a power saving mode provides up to a 43% savings in average power consumption. A summary of the USCM demonstration test objectives, approach, results, and specific benefits to the TCCS's process economics are presented,

Perry, J. L↗
NASA NTRSDate not supplied

Design of an Adsorption Bed for Exploration Trace Contaminant Control

The state-of-the-art in long mission duration spacecraft trace contaminant control processes relies on physical and chemical adsorption for contaminant removal. Target species for adsorption include low and semivolatile organic compounds while chemisorption is utilized for metabolic ammonia control. When adsorption is employed in conjunction with a high temperature oxidation process, a complementary impact on cabin air quality may be realized. The adsorption bed also serves to guard the downstream oxidation catalyst from foulants and potential poisons which may decrease its lifetime and activity. To this end, a packed adsorption guard-bed was sized to control a statistical contaminant load model over a simulated Mars transit mission duration. The updated load model incorporates flight air-quality data and contemporary metabolic source emission literature. The guard-bed was operated in tandem with an exploration prototype thermal catalytic oxidizer. The exploration guard-bed prototype included design considerations from recent flight technology demonstrations and changes intended to improve compatibility with enriched oxygen exploration cabin environments as compared to the prior-art of contaminant control system design.

Trace Contaminant Control↗
NASA NTRS2019

Monolithic Trace-Contaminant Sorbents Fabricated from 3D-Printed Polymer Precursors

The current trace-contaminant (TC) removal technology for use in Extravehicular Activities (EVAs) involves the use of a packed bed of acid-impregnated granular charcoal, which is difficult to regenerate. In this paper, results are presented on the development of vacuum-regenerable TC sorbents for use in the Portable Life Support System (PLSS). The sorbents are derived from 3D-printed polymer monoliths (e.g., honeycomb structures), which are then carbonized and activated in order to develop porosity, and also to enhance the TC-sorption capacity. Results are presented on the following aspects of carbon-sorbent development: (1) precursor selection; (2) monolith fabrication; (3) shape retention and strength; (4) carbon surface and porosity characterization; (5) TC-sorption capacity and vacuum-regeneration; (6) pressure drop; and (7) sub-scale sorbent prototype. The use of predominantly microporous monolithic carbon is associated with the following benefits: (a) high TC-sorption capacity; (b) low pressure drop; (c) rapid vacuum (pressure-swing) desorption due to thin monolith walls and low pressure drop; (d) good thermal management (high thermal conductivity and low adsorption/desorption thermal effects associated with physisorption); and (e) good resistance to dusty environments.

Portable Life Support System (PLSS)↗
NASA NTRSDate not supplied

Development of a Microlith® Catalytic Oxidizer for Exploration Trace Contaminant Control

The state-of-the-art in long mission duration spacecraft trace contaminant control processes rely on high-temperature catalytic oxidation for light contaminant removal. Target compounds for oxidation include metabolic methane, carbon monoxide, and low molecular weight volatile organics such as formaldehyde and methanol. Precision Combustion, Inc. and NASA Marshall Space Flight Center have been developing and testing prototype high temperature catalytic oxidizers based on PCI’s patented Microlith® technology to meet the requirements of future spaceflight exploration missions. To this end, our latest generation Microlith oxidizer, featuring an integrated heat recuperator, was subjected to endurance testing to simulate catalyst ageing over a Mars transit mission duration. Periodic reactor health testing indicates our approach results in a robust contaminant control solution for exploration missions beyond low earth orbit. Based on the demonstrated performance of this unit, a next-generation prototype was designed to meet exploration contaminant load control demands while upgrading the prototype form and fit to match flight-compatible interfaces. Prototype design considerations intended to reduce power consumption, impacting process thermal and hydraulic performance, are discussed herein.

Trace Contaminant Control↗
NASA NTRS2017

Trace Contaminant Control During the International Space Station's On-Orbit Assembly and Outfitting

During the International Space Station’s (ISS’s) on-orbit assembly and outfitting, a series of engineering analyses was conducted to evaluate how effective the passive trace contaminant control (TCC) methods were relative to providing adequate operational margin for the active TCC equipment’s capabilities aboard the ISS. These analyses were based on habitable module and cargo vehicle offgassing test results. The offgassing test for the fully assembled module or cargo vehicle is an important preflight spacecraft evaluation method that has been used successfully during all crewed spacecraft programs to provide insight into how effectively the passive contamination control methods limit the equipment offgassing component of the overall trace contaminant generation load. The progression of TCC assessments beginning in 1998 with the ISS’s first habitable element launch and continuing through the final pressurized element’s arrival in 2010 are presented. Early cargo vehicle flight assessments between 2008 and 2011 are also presented as well as a discussion on predictive methods for assessing cargo via a purely analytical technique.

Contamination control↗
NASA NTRS1993

Computerized atmospheric trace contaminant control simulation for manned spacecraft

Buildup of atmospheric trace contaminants in enclosed volumes such as a spacecraft may lead to potentially serious health problems for the crew members. For this reason, active control methods must be implemented to minimize the concentration of atmospheric contaminants to levels that are considered safe for prolonged, continuous exposure. Designing hardware to accomplish this has traditionally required extensive testing to characterize and select appropriate control technologies. Data collected since the Apollo project can now be used in a computerized performance simulation to predict the performance and life of contamination control hardware to allow for initial technology screening, performance prediction, and operations and contingency studies to determine the most suitable hardware approach before specific design and testing activities begin. The program, written in FORTRAN 77, provides contaminant removal rate, total mass removed, and per pass efficiency for each control device for discrete time intervals. In addition, projected cabin concentration is provided. Input and output data are manipulated using commercial spreadsheet and data graphing software. These results can then be used in analyzing hardware design parameters such as sizing and flow rate, overall process performance and program economics. Test performance may also be predicted to aid test design.

Perry, J. L.↗
NASA NTRSDate not supplied

Ammonia-Removal Efficiency By Full-Scale Carbon-Based Trace-Contaminant Sorbent Monoliths Integrated With the Rapid-Cycle Amine (RCA) Swing Bed

Results are presented on full-scale performance testing of vacuum-regenerable, carbon based sorbent monoliths for trace-contaminant (TC) removal integrated with the Rapid-Cycle Amine (RCA) swing bed for use in the Portable Life Support System (PLSS) during Extravehicular Activities (EVAs). The current state-of-art in TC-control technology involves the use of a packed bed of acid-impregnated granular charcoal, which is difficult to regenerate. The carbon-based sorbent under development in this project can be regenerated by exposure to vacuum at room temperature. Data on cyclic sorption-desorption of ammonia, which is a major TC of concern, were collected in a simulated PLSS ventilation loop which involved the RCA placed upstream of the Trace Contaminant Control System (TCCS). Results of testing involving pressure-swing operation of the integrated TCCS/RCA system indicate ammonia-removal efficiency exceeding 80% throughout multiple sorption-desorption cycles. This paper presents an overview of the TCCS research, the favorable results obtained, and provides insight into future work needed to further the technology development.

Marek A Wójtowicz↗
NASA NTRS1986

Airborne trace contaminants of possible interest in CELSS

One design goal of Closed Ecological Life Support Systems (CELSS) for long duration space missions is to maintain an atmosphere which is healthy for all the desirable biological species and not deleterious to any of the mechanical components in that atmosphere. CELESS design must take into account the interactions of at least six major components; (1) humans and animals, (2) higher plants, (3) microalgae, (4) bacteria and fungi, (5) the waste processing system, and (6) other mechanical systems. Each of these major components can be both a source and a target of airborne trace contaminants in a CELSS. A range of possible airborne trace contaminants is discussed within a chemical classification scheme. These contaminants are analyzed with respect to their probable sources among the six major components and their potential effects on those components. Data on airborne chemical contaminants detected in shuttle missions is presented along with this analysis. The observed concentrations of several classes of compounds, including hydrocarbons, halocarbons, halosilanes, amines and nitrogen oxides, are considered with respect to the problems which they present to CELSS.

Garavelli, J. S.↗
NASA NTRS2009

Status of the ISS Trace Contaminant Control System

A habitable atmosphere is a fundamental requirement for human spaceflight. To meet such a requirement, the cabin atmosphere must be constantly scrubbed to maintain human life and system functionality. The primary system for atmospheric scrubbing of the US on-orbit segment (USOS) of the International Space Station (ISS) is the Trace Contaminant Control System (TCCS). As part of the Environmental Control and Life Support Systems (ECLSS) atmosphere revitalization rack in the US Lab, the TCCS operates continuously, scrubbing trace contaminants generated primarily by two sources: the metabolic offgassing of crew members and the offgassing of equipment in the ISS. It has been online for approximately 95% since activated in February 2001. The TCCS is comprised of a charcoal bed, a catalytic oxidizer, and a lithium hydroxide post-sorbent bed, all of which are designed to be replaced onorbit when necessary. In 2006, all three beds were replaced following an observed increase in the system resistance that occurred over a period several months. The beds were returned to ground and subjected to a test, teardown and evaluation to investigate the root cause(s) of the decrease in flow rate through the system. In addition, various chemical and physical analyses of the bed materials were performed to determine contaminant loading and any changes in performance. This paper will mainly focus on the results of these analyses and how this correlates with what has been observed from archival sampling and onorbit events. This may provide insight into the future performance of the TCCS and rate of change for orbital replacement units in the TCCS.

Macatangay, Ariel V.↗
NASA NTRS1993

Heterogeneous photocatalytic oxidation of atmospheric trace contaminants

The progress report on heterogeneous photocatalytic oxidation of atmospheric trace contaminants covering the period from 1 May - 31 Oct. 1992 is presented. The two topics discussed are photoreactor monolith fundamental studies and monolith reactor operation: batch recirculation system. Concentration profiles are shown.

Ollis, David F.↗
NASA NTRS2005

Development of an Amine-based System for Combined Carbon Dioxide, Humidity, and Trace Contaminant Control

A number of amine-based carbon dioxide (CO2) removal systems have been developed for atmosphere revitalization in closed loop life support systems. Most recently, Hamilton Sundstrand developed an amine-based sorbent, designated SA9T, possessing approximately 2-fold greater capacity compared to previous formulations. This new formulation has demonstrated applicability for controlling CO2 levels within vehicles and habitats as well as during extravehicular activity (EVA). System volume is competitive with existing technologies. Further enhancements in system performance can be realized by incorporating humidity and trace contaminant control functions within an amine-based atmosphere revitalization system. A 3-year effort to develop prototype hardware capable of removing CO2, H2O, and trace contaminants from a cabin atmosphere has been initiated. Progress pertaining to defining system requirements and identifying alternative amine formulations and substrates is presented.

Nalette, Tim↗