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At least 55 records · Page 3

Low Earth orbital atomic oxygen and ultraviolet radiation effects on polymers

Because atomic oxygen and solar ultraviolet radiation present in the low earth orbital (LEO) environment can alter the chemistry of polymers resulting in degradation, their effects and mechanisms of degradation must be determined in order to determine the long term durability of polymeric surfaces to be exposed on missions such as Space Station Freedom. The effects of atomic oxygen on polymers which contain protective coatings must also be explored, since unique damage mechanisms can occur in areas where the protective coatings has failed. Mechanisms can be determined by utilizing results from previous LEO missions, by performing ground based LEO simulation tests and analysis, and by carrying out focussed space experiments. A survey is presented of the interactions and possible damage mechanisms for environmental atomic oxygen and UV radiation exposure of polymers commonly used in LEO.

Dever, Joyce A.↗

Vacuum Ultraviolet Radiation and Atomic Oxygen Durability Evaluation of HST Bi-Stem Thermal Shield Materials

Bellows-type thermal shields were used on the bi-stems of replacement solar arrays installed on the Hubble Space Telescope (HST) during the first HST servicing mission (SMI) in December 1993. These thermal shields helped reduce the problem of thermal gradient- induced jitter observed with the original HST solar arrays during orbital thermal cycling and have been in use on HST for eight years. This paper describes ground testing of the candidate solar array bi-stem thermal shield materials including backside aluminized Teflon(R)FEP (fluorinated ethylene propylene) with and without atomic oxygen (AO) and ultraviolet radiation protective surface coatings for durability to AO and combined AO and vacuum ultraviolet (VOV) radiation. NASA Glenn Research Center (GRC) conducted VUV and AO exposures of samples of candidate thermal shield materials at HST operational temperatures and pre- and post-exposure analyses as part of an overall program coordinated by NASA Goddard Space Flight Center (GSFC) to determine the on-orbit durability of these materials. Coating adhesion problems were observed for samples having the AO- and combined AO/UV-protective coatings. Coating lamination occurred with rapid thermal cycling testing which simulated orbital thermal cycling. This lack of adhesion caused production of coating flakes from the material that would have posed a serious risk to HST optics if the coated materials were used for the bi-stem thermal shields. No serious degradation was observed for the uncoated aluminized Teflon(R) as evaluated by optical microscopy, although atomic force microscopy (AFM) microhardness testing revealed that an embrittled surface layer formed on the uncoated Teflon(R) surface due to vacuum ultraviolet radiation exposure. This embrittled layer was not completely removed by AO erosion, No cracks or particle flakes were produced for the embrittled uncoated material upon exposure to VUV and AO at operational temperatures to an equivalent exposure of approximately five years in the HST environment. Uncoated aluminized FEP Teflon(R) was determined to be the most appropriate thermal shield material and was used on the bi-stems of replacement solar arrays installed on HST during SMI in December 1993. The SMI -installed solar arrays air scheduled to be replaced during MST's fourth servicing mission (SM3B) in early 2002.

Dever, Joyce↗

TOMS as a monitor of the ultraviolet radiation environment: Applications to photobiology

The flux of biologically relevant ultraviolet radiation that reaches the surface of the Earth varies with the ozone amount, surface reflectivity, and cloudcover. The Total Ozone Mapping Spectrometer (TOMS) provides information relevant to all three items. A recent application of satellite-based ozone measurements has been to develop climatologies of the biologically significant UV-B radiation reaching the Earth's surface. A growing body of research suggests that UV-B radiation tends to suppress the immune system of laboratory mice. At tropical latitudes, it is likely that parasitical diseases develop most readily in people who have experienced immune system suppression from UV-B exposure. The computed distribution of surface radiation combined with information on disease incidence may clarify the role of UV-B as a suppressor of the human immune system. TOMS used in conjunction with radiative transfer calculations can provide information of relevance in photobiology.

Frederick, John E.↗

Key issues of ultraviolet radiation of OH at high altitudes

Ultraviolet (UV) emissions radiated by hydroxyl (OH) is one of the fundamental elements in the prediction of radiation signature of high-altitude and high-speed vehicle. In this work, the OH A{sup 2}Σ{sup +}→X{sup 2}Π ultraviolet emission band behind the bow shock is computed under the experimental condition of the second bow-shock ultraviolet flight (BSUV-2). Four related key issues are discussed, namely, the source of hydrogen element in the high-altitude atmosphere, the formation mechanism of OH species, efficient computational algorithm of trace species in rarefied flows, and accurate calculation of OH emission spectra. Firstly, by analyzing the typical atmospheric model, the vertical distributions of the number densities of different species containing hydrogen element are given. According to the different dominating species containing hydrogen element, the atmosphere is divided into three zones, and the formation mechanism of OH species is analyzed in the different zones. The direct simulation Monte Carlo (DSMC) method and the Navier-Stokes equations are employed to compute the number densities of the different OH electronically and vibrationally excited states. Different to the previous work, the trace species separation (TSS) algorithm is applied twice in order to accurately calculate the densities of OH species and its excited states. Using a non-equilibrium radiation model, the OH ultraviolet emission spectra and intensity at different altitudes are computed, and good agreement is obtained with the flight measured data.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Average latitudinal variation in ultraviolet radiation at the earth's surface

Tabulated values are presented for ultraviolet radiation at the earth's surface as a function of wavelength, latitude, and season, for clear sky and seasonally and latitudinally averaged ozone amounts. These tabulations can be combined with any biological sensitivity function in order to obtain the seasonal and latitudinal variation of the corresponding effective doses. The integrated dosages, based on the erythemal sensitivity curve and on the Robertson-Berger sunburn-meter sensitivity curve, have also been calculated, and these are found to vary with latitude and season in very nearly the same way as 307 and 314 nm radiation, respectively.

Johnson, F. S.↗

Ultraviolet radiation from evolved stellar populations. 2: The ultraviolet upturn phenomenon in elliptical galaxies

We discuss the far-ultraviolet upturn phenomenon (UVX) observed in elliptical galaxies and spiral galaxy bulges. Our premise is the UV radiation from these systems emanates primarily from extreme horizontal branch (EHB) stars and their progeny. We derive the broad-band UV colors 1500-V and 2500-V for globular clusters and elliptical galaxies from the available satellite data and investigate color-color and color-line strength correlation. Clusters can be bluer than any galaxy in 15-V and 25-V, implying larger hot star populations, but galaxies are significantly bluer than clusters in 15-25 at a given 15-V. We attribute this primarily to the effect of metal abundance on the mid-UV (2500 A) light. These redder colors of the galaxies also imply that the UVX in galaxies is not produced by metal-poor subpopulations similar to the clusters. We devlop a simple spectral synthesis formulation for all phases of single star evolution from the zero-age main sequence (ZAMS) to the white dwarf cooling track that requires only one or two parameters for each choice of age and abundance. We provide the ingredients necessary for constructing models with arbitrary horizontal branch (HB) morphologies in the age range 2 less than t less than 20 Gyr and for six metallicities in the range -2.26 less than (Fe/H) less than 0.58; we also consider the efect of enhanced Y in metal-rich models. The maximum lifetime UV output is produced by EHB stars with (M(sub env))(sup 0) approximately 0.02 solar mass and can be up to 30 times higher than for post-asymptotic giant branch (P-AGB) stars. The ultraviolet output of old populations is governed primarily by the distribution of (M(sub env))(sup 0)P(M(sub env))(sup 0), on the ZAHB. The UV output is not very sensitive to (Fe/H) or to Y, but it can change very rapidly with (M(sub env))(sup 0). Thus it is extremely sensitive to the precise nature of giant-branch mass loss. Our models use simple descriptions of P(M(sub env))(sup 0) to bracket the colors produced from any real distribution of stars. Our models accurately predict the range of UV colors observed for the globular clusters, given known constraints on their age, abundances, and HB morphologies. We find that models with (Fe/H) greater than or = 0 that do not contain EHB stars cannot reproduce the colors of most of the galaxies. The models also predict that the fraction of the far-UV light from P-AGB stars, which are spatially resolvable in nearby galaxies, is approximately 70% and approximately 20% for moderate UVX and strong UVX systems, respectively. We find that 25-V, but not 15-V, is sensitive to the age and abundance, though these cannot always be cleanly distinguished. The galaxy colors place limits of (Fe/H) greater than -0.5 and less than 15% on the contribution of globular cluster-type populations to the V light. Galaxy colors are consistent with solar-abundance models with ages in the range 6-14 Gyr. We discuss several implications of the observations and the models, including the question of light metal versus iron peak enhancements in galaxies, whether the UV color-Mg(sub 2) correlation is continuous or discrete, effects of helium abundnace on the UVX, and the key question of whether red giant branch mass loss can be large enough to produce the necessary EHB population in the strong UVX galaxies.

Dorman, Ben↗

Generation of coherent phonons by coherent extreme ultraviolet radiation in a transient grating experiment

In this work, we investigate the excitation of coherent acoustic and optical phonons by ultrashort extreme ultraviolet (EUV) pulses produced by a free electron laser. Two crossed femtosecond EUV (wavelength 12.7 nm) pulses are used to excite coherent phonons at a wavelength of 280 nm, which are detected via diffraction of an optical probe beam. Longitudinal and surface acoustic waves are measured in BK-7 glass, diamond, and Bi 4 Ge 3 O 12 ; in the latter material, the excitation of a coherent optical phonon mode is also observed. We discuss probing different acoustic modes in reflection and transmission geometries and frequency mixing of surface and bulk acoustic waves in the signal. The use of extreme ultraviolet radiation will allow the creation of tunable GHz to THz acoustic sources in any material without the need to fabricate transducer structures.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The acute effects of ultraviolet radiation on the blood transcriptome are independent of plasma 25OHD{sub 3}

The molecular basis of many health outcomes attributed to solar ultraviolet radiation (UVR) is unknown. We tested the hypothesis that they may originate from transcriptional changes in blood cells. This was determined by assessing the effect of fluorescent solar simulated radiation (FSSR) on the transcriptional profile of peripheral blood pre- and 6 h, 24 h and 48 h post-exposure in nine healthy volunteers. Expression of 20 genes was down-regulated and one was up-regulated at 6 h after FSSR. All recovered to baseline expression at 24 h or 48 h. These genes have been associated with immune regulation, cancer and blood pressure; health effects attributed to vitamin D via solar UVR exposure. Plasma 25-hydroxyvitamin D{sub 3} [25OHD{sub 3}] levels increased over time after FSSR and were maximal at 48 h. The increase was more pronounced in participants with low basal 25OHD{sub 3} levels. Mediation analyses suggested that changes in gene expression due to FSSR were independent of 25OHD{sub 3} and blood cell subpopulations. - Highlights: • Exposure to UVR induced transient changes in gene expression in blood cells. • Affected genes are related to immune regulation, cancer and blood pressure. • UVR increased 25OHD{sub 3} over time, especially in participants with low baseline levels. • The acute effects of UVR on the blood transcriptome are independent of 25OHD{sub 3}.

60 APPLIED LIFE SCIENCES↗

Pregnancy outcome and ultraviolet radiation; A systematic review

Background: Season and vitamin D are indirect and direct correlates of ultraviolet (UV) radiation and are associated with pregnancy outcomes. Further to producing vitamin D, UV has positive effects on cardiovascular and immune health that may support a role for UV directly benefitting pregnancy. Objectives: To investigate the effects of UV exposure on pregnancy; specifically fetal growth, preterm birth and hypertensive complications. Methods: We conducted a systematic review of Medline, EMBASE, DoPHER, Global Health, ProQuest Public Health, AustHealth Informit, SCOPUS and Google Scholar to identify 537 citations, 8 of which are included in this review. This review was registered on PROSPERO and a. narrative synthesis is presented following PRISMA guidance. Results: All studies were observational and assessed at high risk of bias. Higher first trimester UV was associated with and improved fetal growth and increased hypertension in pregnancy. Interpretation is limited by study design and quality. Meta-analysis was precluded by the variety of outcomes and methods. Discussion: The low number of studies and risk of bias limit the validity of any conclusions. Environmental health methodological issues are discussed with consideration given to design and analytical improvements to further address this reproductive environmental health question. Conclusions: The evidence for UV having benefits for pregnancy hypertension and fetal growth is limited by the methodological approaches utilized. Future epidemiological efforts should focus on improving the methods of modeling and linking widely available environmental data to reproductive health outcomes. - Highlights: • Biologically plausible pathways support an association between ultraviolet radiation (UV) and pregnancy outcomes. • This study is the first systematic review of prevailing literature on the relationship between UV and singleton pregnancy outcomes. • It focuses on both substantive findings and the methodologies that were used. • Only seven studies met the search criteria and these were methodologically heterogeneous demonstrating a paucity of evidence. • Given the plausibility of the UV pathway, more studies examining this hypothesis are needed.

54 ENVIRONMENTAL SCIENCES↗

Effects of ultraviolet radiation on lattice imperfections in pyrolytic boron nitride.

Pyrolitic boron nitride was exposed to 310 equivalent sun hours of ultraviolet radiation in a space environment simulator with the objective to evaluate its applicability as a pigment for a thermal control coating and to identify radiation damage using X-ray diffraction techniques. Lattice parameter comparisons show a definite increase in lattice imperfections in the crystal structure resulting from the ultraviolet irradiation. This sensitivity to radiation damage makes pyrolitic boron nitride unsuitable as a pigment for thermal control coating.

Buckley, J. D.↗

Escherichia coli tolerance of ultraviolet radiation by in vivo expression of a short peptide designed from late embryogenesis abundant protein

Highlights: • A peptide of late embryogenesis abundant (LEA) protein was expressed in E. coli. • LEA peptide expression was induced with IPTG in a concentration-dependent manner. • LEA peptide expression improved E. coli growth under ultraviolet radiation. • LEA peptide could be used to genetically modify organisms for ultraviolet resistance. Ultraviolet (UV) radiation causes damage in all living organisms, including DNA damage that leads to cell death. Herein, we provide a new technique for UV radiation protection through intracellular short peptide expression. The late embryogenesis abundant (LEA) peptide, which functions as a shield that protects macromolecules from various abiotic stress, was obtained from the Polypedilum vanderplanki group 3 LEA protein. Recombinant Escherichia coli BL21 (DE3) expressing functional LEA short peptide in vivo were exposed to UVA and UVC radiation for 4, 6, and 8 h. E. coli transformants expressing the LEA peptide showed higher cell viability under both UVA and UVC treatment at all time points as compared with that of the control. Furthermore, the cells expressing LEA peptide showed a higher number of colony-forming units per dilution under UVA and UVC treatment. These results suggested that expression of the short peptide could be useful for the development of genetically modified organisms and in applications that require resilience of organisms to UV radiation.

60 APPLIED LIFE SCIENCES↗