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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Using stable isotopes in water vapor to study the interdependence of clouds, atmospheric aerosols, and precipitation processes

This project deployed water vapor isotope measurements at the La Porte, Texas TRACER site during June-September 2022 to quantify mixing processes in sea breeze circulations. Using a Picarro L2130 analyzer, we collected high-frequency measurements of δD and δ¹⁸O that revealed how marine and terrestrial air masses mix during 46 identified sea breeze events. The isotopic tracers showed systematic changes during frontal passages, with composite analyses demonstrating vertical mixing between cool marine air and warmer air aloft. We developed a transilient matrix model that explicitly treats non-local mixing and isotopic fractionation to interpret the observations. The work directly supports TRACER's core objective of understanding convective initiation by constraining the vertical transport of water vapor and its interaction with Houston's aerosol-laden urban plume during sea breeze-convection coupling.

58 GEOSCIENCES↗
DOE OSTI2026

Carbon dioxide, water vapor and methane soil efflux (soil respiration) in a Pinus palustris root exclusion in Georgetown, SC

This dataset contains processed data from a combination of survey flux chambers and long-term automated flux chambers. Soil flux measurements were conducted from June 2023 through December 2025 in a mature longleaf pine forest in Georgetown, SC. Soil respiration measurements were conducted approximately biweekly for two and a half years, before and after a root exclusion that took place on May 5, 2024. Processed, QAQC’d data for the treatment (root exclusion) and control (roots intact) before and after the root exclusion can be found in the file: 1_DATA_ESS_DOE_HR_RS_HB2_QAQC_Survey_Data_20260223.csv. Two multiday deployments were also conducted prior to the root exclusion using long-term automated chambers to continuously monitor greenhouse gas soil efflux. Processed, QAQC’d data for both long-term deployments can be found in the file: 2_DATA_ESS_DOE_HR_RS_HB2_QAQC_Longterm_Data_20260209.csv. Raw and working data files (.json, .81x, & .82z format) from LI-COR equipment are included for reference and can be accessed using SoilFluxPro software. CSV metadata files describe the raw data and modifications made using SoilFluxPro v5 and Matlab R2024b, as well as formatting and units for processed CSVs. Matlab code is included for reading in the processed CSVs, with sample figures comparing treatment and control. This research was performed as part of the project: “Improving models of stand and watershed carbon and water fluxes with more accurate representations of soil-plant-water dynamics in southern pine ecosystems”, which examines in part the effects hydraulic redistribution on soil efflux of carbon dioxide, water vapor and methane, as well as soil moisture and temperature in a southern pine ecosystem with sandy soils and high water table.

CARBON DIOXIDE FLUX↗
DOE OSTI2021

The Mechanism of Increasing Summer Water Vapor Over the Tibetan Plateau

Rapid warming over the Tibetan Plateau (TP) has been associated with a wetting trend in atmospheric water vapor content, which is critical for recharging the Asian water tower. However, the mechanism associated with the wetting phenomenon remains unclear. Long-term changes in moisture balance and precipitation recycling processes are investigated using the ERA5 reanalysis from 1979 to 2019. The wetting trend over TP is mainly due to the summer water vapor trend with signi?cantly increases over the western TP. Based on the moisture balance analysis, it is found that precipitation, evaporation, and the convergence of moisture are all increasing over the western TP but decreasing over the eastern TP. Based on the dynamical precipitation recycling model, the results suggest that both internal and external cycles contributes to the wetting over TP, with 63.87% and 36.13% contributions respectively. Further analysis found that the atmospheric heating source is also increasing over the western TP, which could shift the moisture transportation from east to west at the southern boundary of TP. The increasing moisture convergence could enhance precipitation, and the enhanced latent heating in the mid-atmosphere can further induced moisture convergence, which forms a positive feedback. However, an opposite situation occurred over the eastern TP. The internal and external cycle of the recycling process can stimulate (suppress) each other through precipitation over the western (eastern) TP. This mechanism linked the changes in the precipitation recycling and atmospheric circulation, and induced the wetting trend over TP in summer.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Oxidation behaviors of matrix-grade graphite during water vapor ingress accidents for high temperature gas-cooled reactors

Water ingress into cores of high temperature gas-cooled reactors (HTGRs) can cause serious safety problems in graphitic components, especially for matrix graphite, which is more vulnerable than nuclear graphite. Here in this study, oxidation behaviors of a matrix-grade graphite, ARB-B1, were investigated under simulated water ingress accidental conditions. The oxidation tests were conducted in water vapor/helium mixed atmospheres at elevated temperatures up to 1200 °C. Oxidation rates and activation energy were evaluated by mass loss measurements. The activation energy was 121.5 kJ/mol in the considered temperature range, indicating only one oxidation regime-in-pore diffusion assisted by cracks. The cracks originated from the fabrication process, acting as penetration paths for the oxidant, played an important role in the oxidation behaviors. Ungraphitized binder oxidation occurred at all temperatures, while apparent oxidation of filler particles started from 1100 °C. Moreover, oxidation effects on compressive properties and hardness of the matrix graphite were discussed in terms of oxidized microstructures. This first detailed study on matrix graphite oxidation in water vapor provides important kinetics knowledge and microstructural and mechanical data for accidental scenarios of HTGRs as well as for development of new matrix graphite materials.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Evaluation of Mechanical and Thermomechanical Water Vapor Compression Techniques for Enabling High Temperature Lift Hydration-Based Chemical Heat Pumps

Achieving high temperature lifts (>200 K) via a chemical heat pump based on salt hydration/dehydration reactions requires the transport of water vapor from low to high pressure. Alternative compression approaches require condensing of low-pressure water vapor, pumping of liquid water, and subsequent evaporation when the low-side pressure corresponds to sub-ambient water saturation temperatures. Thus, this study compares four steam compression methods for use within a chemical heat pump system based on a reversible calcium oxide hydration/dehydration reaction with a temperature lift from 350 °C heat to >600 °C. Purely mechanical and thermochemical/mechanical compression technologies are considered. A parametric study of maximum allowable temperature, the isentropic efficiency of mechanical compressors, the effectiveness of heat exchangers, and the assumed allowable heat exchanger pressure drop is conducted to determine the mechanical and thermal energy consumed per kilogram of compressed steam. The system complexity in terms of the number of main system components, maximum pressure ratio, and maximum allowable temperature is estimated. Model results show an absorption-based steam compressor has the highest exergetic efficiency for the required chemical heat pump required conditions. As a result, this system configuration was then experimentally demonstrated to illustrate the impact of system performance on component effectiveness.

Advanced reactors↗
DOE OSTI2022

Amazonian Moisture Recycling Revisited Using WRF With Water Vapor Tracers

Previous studies have estimated that 25%–35% of Amazonian precipitation comes from evapotranspiration (ET) within the basin. However, due to simplifying assumptions of traditional models, these studies primarily focus on large spatial and temporal scales. This study is the first to analyze the moisture of Amazonian origin at the annual to daily timescale in four different subregions of the Amazon. We analyze the sources, sinks and stores of moisture that originates as Amazonian ET. To do this, we use the Weather Research and Forecast (WRF) regional meteorological model with the added capability of water vapor tracers to track this moisture. Moisture of Amazonian origin shows strong annual and semi-annual signals, with contrasting behavior between the northern and southern parts of the basin. The tracers reveal a strong diurnal cycle of Amazonian water vapor which had not been previously reported. This signal is related to the diurnal cycle of ET, convective precipitation and advected moisture. ET's contribution to atmospheric moisture increases from early morning into the afternoon. Some of this moisture is rained out through convective storms in the early evening. Later in the night and following morning, strong winds associated with the South American Low Level Jet advect moisture downwind. Overall, the beating pattern becomes apparent when visualizing the Amazonian water vapor as an animation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Water Vapor Isotopic Measurements during CAPE-K Field Campaign Report

CAPE-K_ISO deployed a Picarro L-2130 water vapor isotope analyzer to the Kennaook/Cape Grim Baseline Air Pollution Station in northwest Tasmania as a guest instrument within the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) User Facility’s Cloud and Precipitation Experiment at Kennaook (CAPE-K). The project was led by Joseph Galewsky at the University of New Mexico and supported the second ARM Mobile Facility (AMF2) deployment by adding continuous measurements of water vapor mixing ratio, delta-18O, delta-D, and deuterium excess in marine boundary-layer air.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Microwave radiometer, sun-photometer and GNSS multi-comparison of integrated water vapor in Southwestern Europe

This work presents a comparison of integrated water vapor (IWV) data recorded from microwave radiometer (MWR) and sun-photometer (SP) using global navigation satellite system (GNSS) IWV as reference in five mid-latitude sites of Portugal and Spain (2003–2021). A very high correlation is obtained for both instruments (R2 between 0.94 and 0.98), although, while MWR shows a wet bias, SP exhibits a dry one. In addition, a dependence of mean bias error (MBE) and standard deviation (SD) on IWV has been observed, increasing (larger discrepancies) both indices as IWV increases. The solar zenith angle (SZA) dependence is also studied, finding slightly larger discrepancies for the MWR than for SP in comparison with GNSS for very high values of SZA. Finally, a marked seasonal dependence is observed for SP-GNSS differences, modulated by the IWV dependence explained above. In contrast, the seasonal dependence for MWR is quite weaker than it is for SP. Therefore, in spite of the excellent agreement found among the different instruments, it is recommended that: i) the dependence with IWV be studied and corrected to further increase the performance of the instruments, and ii) metadata be used to filter out situations in which the instrument cannot operate properly.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Intercomparison of MJO Column Moist Static Energy and Water Vapor Budget among Six Modern Reanalysis Products

This study conducts an intercomparison of the column-integrated moist static energy (MSE) and water vapor budget of the Madden–Julian oscillation (MJO) among six modern global reanalysis products (RAs). Inter-RA differences in the mean MSE, MJO MSE anomalies, individual MSE budget terms, and their relative contributions to the propagation and maintenance of MJO MSE anomalies are examined. Also investigated is the relationship between the MJO column water vapor (CWV) budget residuals with the other CWV budget terms as well as with the two parameters that characterize cloud–radiation feedback and moisture–convection coupling. Results show a noticeable inter-RA spread in the mean-state MSE, especially its vertical structure. In all RAs, horizontal MSE advection dominates the propagation of the MJO MSE while column-integrated longwave radiative heating and vertical MSE advection are found to be the key processes for MJO maintenance. The MSE budget terms directly affected by the model parameterization schemes exhibit high uncertainty. The differences in anomalous vertical velocity mainly contribute to the large differences in vertical MSE advection among the RAs. The budget residuals show large inter-RA differences and have nonnegligible contributions to MJO maintenance and propagation in most RAs. RAs that underestimate (overestimate) the strength of cloud–radiation feedback and the convective moisture adjustment time scale tend to have positive (negative) MJO CWV budget residual, indicating the critical role of these processes in the maintenance of MJO CWV anomalies. Our results emphasize that a correct representation of the interactions among moisture, convection, cloud, and radiation is the key for an accurate depiction of the MJO MSE and CWV budget in RAs.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

An Experimental Study of the Solubility of Rare Earth Chloride Salts (La, Nd, Er) in HCl Bearing Water Vapor from 350 – 425 °C

In this work, the solubilities of the rare earth chlorides REECl 3 , where REE = (La, Nd, Er), were measured in HCl bearing water vapor from 350 – 425°C with water partial pressures ranging from 8 – 170 bar. Solubility data were fit to the Pitzer-Pabalan quasi-chemical model in order to extract thermodynamic parameters for the formation of the gaseous REE-chloride-water clusters REECl 3 (H 2 O) n . The data show that the solubility of the REE chlorides are orders of magnitude higher than salts such as NaCl or CuCl at low water fugacities, despite their sublimation energies being substantially higher. This enhanced solubility is likely due to the high enthalpy associated with binding a single water molecule to form the species REECl 3 (H 2 O), with derived enthalpies ranging from –378 to –465 kJ/mol. Addition of further water molecules to form higher order clusters (n > 1) involves enthalpy changes of ~ -20 kJ/mol, and are in effect thermodynamically suppressed over the temperature range 350 – 425°C. Despite the enhanced solubility of small REECl 3 water clusters, simulations of boiling processes demonstrate that the REE show highly conservative behavior, partitioning strongly into the dense aqueous phase. Not surprisingly, the presence of phosphates in the system makes this effect even more pronounced, completely immobilizing the REE. This would reduce transport in both the vapor and aqueous phase to negligible levels. However, we suggest that vapor phase transport of the REE may play a significant role in systems having a relatively low partial pressure of water (below the saturation point), where the relatively high stability of the first hydrated REE chloride clusters (REECl 3 (H 2 O) and REECl 3 (H 2 O) 2 ) will give a preference for gas transport of the REE relative to other elements. This can likely happen in systems involving a gas/melt exchange in fumarolic exhalations, where water vapor discharges at relatively low (close to atmospheric) pressures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Simultaneously Enhanced Hydrophilicity and Stability of a Metal-Organic Framework via Post-Synthetic Modification for Water Vapor Sorption/Desorption

With increasing demands for high-performance water sorption materials, metal-organic frameworks (MOFs) have gained considerable attention due to their high maximum uptake capacities. In many cases, however, high overall capacity is not necessarily accomplishing high working capacity under operating conditions, due to insufficient hydrophilicity and/or water stability. Herein, we present a post-synthetic modification (PSM) of MOF-808, with di-sulfonic acids enhancing simultaneously its hydrophilicity and water stability without sacrificing its uptake capacity of ≈30 mmol g -1 . Further, di-sulfonic acid PSM enabled a shift of the relative humidity (RH) associated with a sharp step in water vapor sorption from 35–40 % RH in MOF-808 to below 25 % RH. While MOF-808 lost uptake capacity and crystallinity over multiple sorption/desorption cycles, the di-sulfonic acid PSM MOF-808 retained >80 % of the original capacity. PSM MOF-808 exhibited good hydrothermal stability up to 60 °C and high swing capacity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Simultaneously Enhanced Hydrophilicity and Stability of a Metal‐Organic Framework via Post‐Synthetic Modification for Water Vapor Sorption/Desorption

Abstract With increasing demands for high‐performance water sorption materials, metal‐organic frameworks (MOFs) have gained considerable attention due to their high maximum uptake capacities. In many cases, however, high overall capacity is not necessarily accomplishing high working capacity under operating conditions, due to insufficient hydrophilicity and/or water stability. Herein, we present a post‐synthetic modification (PSM) of MOF‐808, with di‐sulfonic acids enhancing simultaneously its hydrophilicity and water stability without sacrificing its uptake capacity of ≈30 mmol g −1 . Di‐sulfonic acid PSM enabled a shift of the relative humidity (RH) associated with a sharp step in water vapor sorption from 35–40 % RH in MOF‐808 to below 25 % RH. While MOF‐808 lost uptake capacity and crystallinity over multiple sorption/desorption cycles, the di‐sulfonic acid PSM MOF‐808 retained >80 % of the original capacity. PSM MOF‐808 exhibited good hydrothermal stability up to 60 °C and high swing capacity.

Luo, Tian‐Yi↗
DOE OSTI2020

Surface Chemistry of Liquid Bismuth under Oxygen and Water Vapor Studied by Ambient Pressure X-ray Photoelectron Spectroscopy

Bismuth (Bi) has a fairly low melting point of 544 K making it practical as a liquid metal medium in a number of applications. Under ambient atmospheric conditions the surface of solid Bi oxidizes. While the solid Bi interface has been fairly well characterized with surface science studies upon exposure to oxygen, to date little is known about the molecular level reactivity of the liquid interface. Here, using ambient pressure X-ray photoelectron spectroscopy the liquid-gas interfacial chemistry of Bi was examined upon exposure to oxygen gas and water vapor at 550 K up to a maximum pressure of 0.5 Torr. Water vapor remained unreactive towards the liquid interface over the entire pressure range. Oxygen remined unreactive up to 10 –4 Torr, whereas above this pressure oxidation was observed forming Bi 2 O 3 . The oxidation exposure onset was > 5 x 10 5 Langmuirs, significantly higher than what is required for solid Bi interfaces.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Analysis of defects in In 2 O 3 :H synthesized in presence of water vapor and hydrogen gas mixture

Using hybrid functional-based density functional theory calculations, we analyze the structure and kinetics of defects formed in two competing synthesis routes to prepare hydrogen-doped In 2 O 3 films, using a hydrogen and oxygen gas mixture vs synthesis in the presence of water vapor. For both of these synthesis routes, we find that H + is the dominant defect species: when the Fermi level is close to the conduction band, H + has a lower formation energy than other intrinsic or extrinsic defects. Our results also suggest that water molecules spontaneously split into H + (which occupies octahedral voids) and OH – interstitials (which occupies vacant oxygen lattice sites or oxygen vacancies). From the analysis of the binding energies between these different defects, we conclude that these defects do not cluster and are most likely to stay spatially distributed throughout the films. In addition, the sum of formation energies of an oxygen (i.e., O$^{2–}_i$) and a H + interstitial is close to the formation energy of a OH – interstitial, meaning that water molecules are completely split into 2H + and O$^{2–}_i$ at the synthesis conditions. Further, in the presence of H 2 + O 2 gas mixture, oxygen interstitials occupy oxygen vacancies while hydrogen interstitials occupy vacant oxygen lattice sites and form bonds with lattice oxygens. Our analysis of the defect equilibria suggests that the hydrogen content in films synthesized in the presence of water vapor is higher than films synthesized in the presence of a hydrogen gas mixture. At high dopant concentrations, a hydrogen bond network is formed in the system and this leads to large distortions in the lattice.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Water Vapor Resistant SiC/SiC Composite for Hydrogen-Based Turbines (Final Scientific Technical Report)

New material innovations are needed for the extreme environments of next generation, hydrogen-fueled turbine engines. Ceramic matrix composites (CMCs) offer high-temperature capability but are susceptible to degradation in high-temperature water vapor. Pratt & Whitney’s (P&W) baseline silicon carbide (SiC)/SiC CMC was initially applied to design a component in a hydrogen-fueled engine, verifying the existence of a design space and extracting boundary conditions to inform testing parameters. Several material innovations, including two fibers, interface coatings (IFC), and self-healing matrices (SHM), were investigated to improve high-temperature performance in water vapor. A boron-doped pyrocarbon (B-PyC) IFC and a SHM matrix with layers of zirconium nitride (ZrN) or zirconium diboride (ZrB 2 ) were developed to fabricate minicomposites with either standard Hi-Nicalon™ Type S (HNS) fibers or new Tyranno® SA4 fibers (SA4). The B-PyC IFC is functional but lacks in providing improved durability. A matrix consisting of thick layers of SiC and thin layers of ZrB 2 shows promise as a SHM that can effectively seal matrix cracks in this extreme environment. Minicomposites with HNS fibers generally outperform those with SA4 fibers.

08 HYDROGEN↗
DOE OSTI2025

Quantitative phase imaging around water vapor microbubbles under pulsed laser illumination

We measured water temperature around a self-oscillating water vapor-rich bubble using diffraction phase microscopy equipped with a pulsed laser. The water vapor-rich bubble, which causes a strong water flow around it, was generated by locally heating degassed water through the photothermal conversion properties of an FeSi2 thin film. The generation of the flow is related to the self-oscillation of the bubble at sub-MHz frequencies and the temperature distribution around it. Here, the refractive index of the surrounding water was measured using a pulsed laser with a 3.5-ns pulse duration, which guarantees a time resolution of less than 1/200 of the oscillation cycle of the bubble. The temperature distribution around the bubble was calculated from the measured refractive index.

Narihira, Kyoshiro [Kyoto University, Japan]↗
DOE OSTI2023

A Process Model for ITCZ Narrowing under Warming Highlights Clear-Sky Water Vapor Feedbacks and Gross Moist Stability Changes in AMIP Models

Tropical areas with mean upward motion—and as such the zonal-mean intertropical convergence zone (ITCZ)—are projected to contract under global warming. To understand this process, a simple model based on dry static energy and moisture equations is introduced for zonally symmetric overturning driven by sea surface temperature (SST). Processes governing ascent area fraction and zonal mean precipitation are examined for insight into Atmospheric Model Intercomparison Project (AMIP) simulations. Bulk parameters governing radiative feedbacks and moist static energy transport in the simple model are estimated from the AMIP ensemble. Uniform warming in the simple model produces ascent area contraction and precipitation intensification—similar to observations and climate models. Contributing effects include stronger water vapor radiative feedbacks, weaker cloud-radiative feedbacks, stronger convection-circulation feedbacks, and greater poleward moisture export. The simple model identifies parameters consequential for the inter-AMIP-model spread; an ensemble generated by perturbing parameters governing shortwave water vapor feedbacks and gross moist stability changes under warming tracks inter-AMIP-model variations with a correlation coefficient ~0.46. Here, the simple model also predicts the multimodel mean changes in tropical ascent area and precipitation with reasonable accuracy. Furthermore, the simple model reproduces relationships among ascent area precipitation, ascent strength, and ascent area fraction observed in AMIP models. A substantial portion of the inter-AMIP-model spread is traced to the spread in how moist static energy and vertical velocity profiles change under warming, which in turn impact the gross moist stability in deep convective regions—highlighting the need for observational constraints on these quantities.

54 ENVIRONMENTAL SCIENCES↗