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Three-Dimensional Atmospheric Dynamics of Jupiter from Ground-Based Doppler Imaging Spectroscopy in the Visible
We present three-dimensional (3D) maps of Jupiter’s atmospheric circulation at cloud-top level from Doppler-imaging data obtained in the visible domain with JIVE, the second node of the JOVIAL network, which is mounted on the Dunn Solar Telescope at Sunspot, New Mexico. We report on 12 nights of observations between May 4 and May 30, 2018, representing a total of about 80 hours. Firstly, the average zonal wind profile derived from our data is compatible with that derived from cloud-tracking measurements performed on Hubble Space Telescope images obtained in April 2018 from the Outer Planet Atmospheres Legacy (OPAL) program. Secondly, we present the first ever two-dimensional maps of Jupiter’s atmospheric circulation from Doppler measurements. The zonal velocity map highlights well-known atmospheric features, such as the equatorial hot spots and the Great Red Spot (GRS). In addition to zonal winds, we derive meridional and vertical velocity fields from the Doppler data. The motions attributed to vertical flows are mainly located at the boundary between the equatorial belts and tropical zones, which could indicate active motion in these regions. Qualitatively, these results compare well to recent Juno data that have unveiled the three-dimensional structure of Jupiter’s wind field. To the contrary, the motions attributed to meridional circulation are very different from what is obtained by cloud tracking, except at the GRS. Because of limitations with data resolution and processing techniques, we acknowledge that our measurement of vertical or meridional flows of Jupiter are still to be confirmed.
Lunar Resources Using Moderate Spectral Resolution Visible and Near-infrared Spectroscopy: Al/si and Soil Maturity
Modern visible and near-infrared detectors are critically important for the accurate identification and relative abundance measurement of lunar minerals; however, even a very small number of well-placed visible and near-infrared bandpass channels provide a significant amount of general information about crucial lunar resources. The Galileo Solid State Imaging system (SSI) multispectral data are an important example of this. Al/Si and soil maturity will be discussed as examples of significant general lunar resource information that can be gleaned from moderate spectral resolution visible and near-infrared data with relative ease. Because quantitative-albedo data are necessary for these kinds of analyses, data such as those obtained by Galileo SSI are critical. SSI obtained synoptic digital multispectral image data for both the nearside and farside of the Moon during the first Galileo Earth-Moon encounter in December 1990. The data consist of images through seven filters with bandpasses ranging from 0.40 microns in the ultraviolet to 0.99 microns in the near-infrared. Although these data are of moderate spectral resolution, they still provide information for the following lunar resources: (1) titanium content of mature mare soils based upon the 0.40/0.56-micron (UV/VIS) ratio; (2) mafic mineral abundance based upon the 0.76/0.99-micron ratio; and (3) the maturity or exposure age of the soils based upon the 0.56-0.76-micron continuum and the 0.76/0.99-micron ratio. Within constraints, these moderate spectral resolution visible and near-infrared reflectance data can also provide elemental information such as Al/Si for mature highland soils.
Multi-Wavelength Observations of Asteroid 2100 Ra-Shalom: Visible, Infrared, and Thermal Spectroscopy Results
The August 2003 apparition of asteroid 2100 Ra-Shalom brought together a collaboration of observers with the goal of obtaining rotationally resolved multiwavelength spectra at each of 5 facilities: infrared spectra at the NASA Infrared Telescope Facility (Clark and Shepard), radar images at Arecibo (Shepard and Clark), thermal infrared spectra at Palomar (Lim, McConnochie and Bell), visible spectra at McDonald Observatory (Vilas, Lederer and Jarvis), and visible lightcurves at Ondrojev Observatory (Pravec). The radar data was to be used to develop a high spatial resolution physical model to be used in conjunction with spectral data to investigate compositional and textural properties on the near surface of Ra Shalom as a function of rotation phase. This was the first coordinated multi-wavelength investigation of any Aten asteroid. There are many reasons to study near-Earth asteroid (NEA) 2100 Ra-Shalom: 1) It has a controversial classification (is it a C- or K-type object)? 2) There would be interesting dynamical ramifications if Ra-Shalom is a K-type because most K-types come from the Eos family and there are no known dynamical pathways from Eos to the Aten population. 3) The best available spectra obtained previously may indicate a heterogeneous surface (most asteroids appear to be fairly homogeneous). 4) Ra-Shalom thermal observations obtained previously indicated a lack of regolith, minimizing the worry of space weathering effects in the spectra. 5) Radar observations obtained previously hinted at interesting surface structures. 6) Ra-Shalom is one of the largest Aten objects. And 7) Ra-Shalom is on a short list of proposed NEAs for spacecraft encounters and possible sample returns. Preliminary results from the visible, infrared, and thermal spectroscopy measurements will be presented here.
Characterization of Thermal Protection Systems: An Analysis of Optical & Thermal Properties
Thermal Protection System Materials & thermal control coatings were characterized by a variety of methodologies including heat flow meter method (HFM), dynamic scanning calorimetry (DSC), fourier transform infrared spectroscopy (FTIR), and Ultra-Violet & Visible light spectroscopy (UV-VIS). Physical properties were measured to aid in the construction of thermal response models for a number a projects including MEDLI and MEDLI2. Comparing pre-flight predictions with actual flight data can allow for a reduction of margins and improve designs. The models enable design of TPS for flight missions and analysis of flight data to understand aerothermal environments experienced on the mission. This presentation reveals critical information: heat capacity (cp vs T), thermal conductivity ( vs T), and emissivity (E vs T) for Super Lightweight Ablative (SLA), Phenolic Impregnated Carbon Ablative (PICA-D), & Heatshield for Extreme Entry Environment Technology (HEEET). These properties were also measured for various thermal control coatings manufactured by AZ Technology. A portion of this work is incomplete and highlights questions to investigate in the future.
Mapping the Gold Butte Block with Visible Through Thermal Infrared Spectroscopy
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Prediction of leaf chemistry by the use of visible and near infrared reflectance spectroscopy
The chemical content of dry, ground leaf material sampled from deciduous and conifer tree species from sites in Alaska, Wisconsin, and California was estimated using visible and shortwave IR spectroscopy. Seven chemical components - sugar, starch, protein, cellulose, total chlorophyll, lignin, and total nitrogen - were analyzed by wet chemical methods and their concentrations regressed against log 1/rho and first and second differences of log 1/rho (where rho is measured reflectance) at wavelengths selected by stepwise regression. Predictions of chemical concentrations based on cross validation suggest that this technique may be useful for extracting vegetation canopy biochemical information by remote sensing.
Visible and near-ultraviolet spectroscopy at Thule AFB (76.5 N) from January 28 - February 15, 1988
Near-ultraviolet and visible spectrographs identical to those employed at McMurdo Station, Antarctica (77.8 S) during the austral spring seasons of 1986 and 1987 were used to study the stratosphere above Thule, Greenland (76.5 N) during early spring, 1988. Observations were carried out both at night using the direct moon as a light source, and during the day by collecting the scattered light from the zenith sky when solar zenith angles were less than about 94.5 degrees. Excellent meteorological conditions prevailed in the troposphere and stratosphere at Thule. Surface weather was extremely clear over most of the period, facilitating measurements of the direct light from the moon. The lower stratospheric arctic polar vortex was located very near Thule throughout the observing period, and temperature at the 30 mbar level were typically below -80 C above Thule, according to the National Meteorological Center daily analyses. Thus conditions were favorable for polar stratospheric cloud formation above Thule. Total column ozone abundances were about 350 to 400 Dobson units, and did not suggest a clear temporal trend over the observing period. Stratospheric nitrogen dioxide measurements were complicated by the presence of a large component of tropospheric pollution on many occasions. Stratospheric nitrogen dioxide could be identified on most days using the absorption in the scattered light from the zenith sky, which greatly enhances the stratospheric airmass while suppressing the tropospheric contribution. These measurements suggest that the total vertical column abundance of nitrogen dioxide present over Thule in February was extremely low, sometimes as low as 3 x 10 to the 14th per sq cm. The abundance of nitrogen dioxide increased systemically from about 3 x 10 to the 14th in late January to 1.0 x 10 to the 15th per sq cm in mid-February, perhaps because of photolysis of N2O5 in the upper part of the stratosphere, near 25 to 35 km.
Visible to Short Wavelength Infrared Spectroscopy on Rovers: Why We Need it on Mars and What We Need to do on Earth
The next stage of Mars exploration will include the use of rovers to seek out specific mineralogies. Understanding the mineralogical diversity of the locale will be used to determining which targets should be investigated with the full suite of in situ capability on the rover. Visible to Short Wavelength Infrared (VSWIR) spectroscopy is critical in evaluating the mineralogical diversity and to validate the global remote sensing data sets to be collected by Mars Express and the Mars Reconnaissance Orbiter. However, spectroscopy on mobile platforms present challenges in both the design of instruments and in the efficient operation of the instrument and mission. Field-testing and validation on Earth can be used to develop instrument requirements analysis tools needed for used on Mars.
A Spectrographic Receiver for Laser Spectrometers
Multiband LiDAR systems, which are typically single wavelength in transmission and reception, are becoming more applicable for scientific use. However, traditional LiDAR receivers do not scale well to tens or hundreds of received bands. We introduce the design for a spectrographic receiver using an array detector for laser spectrometers and present two of the many possible applications: fluorescence spectroscopy in the visible range and IR reflectance spectroscopy. Each laser pulse has the capability of exciting a target in various wavelengths, and a spectrographic receiver would be able to interpret this excitation, while a typical LiDAR consisting of single wavelength receiver would not. Using a spectrograph in a system with a pulsed laser in the visible or UV range is capable of the detection of fluorescent signal. These spectra reveal the presence of organics and is an applicable technology for planetary science. A spectrograph coupled with a pulsed laser in the IR range shows capability of detecting the presence of water in various forms also applicable technology for both Earth and planetary science. Both systems utilize a Czerny-Turner spectrograph design with a ZnSe prism for the dispersion of light onto an Avalanche Photo Diode (APD). This paper introduces the concept and design of a spectrographic receiver for laser spectrometers, as well as two possible applications.
HabEx Space Telescope Exoplanet Instruments
The HabEx (Habitable Exoplanet) space telescope mission concept carries two complementary optical systems as part of its baseline design, a coronagraph and a starshade, that are designed to detect and characterize planetary systems around nearby stars. The starshade is an external occulter which would be 72 m in diameter and fly some 124,000 km ahead of the telescope. A starshade instrument on board the telescope enables formation flying to maintain the starshade within 1 m of the line of sight to the star. The starshade instrument has various modes, including imaging from the near UV through to the near infrared and integral field spectroscopy in the visible band. The coronagraph would provide imaging and integral field spectroscopy in the visible band and would reach out to 1800 nm for low resolution spectroscopy in the near infrared. To provide the necessary stability for the coronagraph, the telescope would be equipped with a laser metrology system allowing measurement and control of the relative positions of the principal mirrors. In addition, a fine guidance sensor is needed for precision attitude control. The requirements for telescope stability for coronagraphy are discussed. The design and requirements on the starshade will also be discussed.
Investigating the Role of Incident Ion Flux in Solar Wind Space Weathering of Carbon-Rich Asteroidal Regolith Via H+ and He+ Irradiation of the Murchison Meteorite
We present results from a set of low and high flux 1 keV/amu H + and He + irradiation experiments performed on slabs of the Murchison CM2 carbonaceous chondrite. The low flux conditions for H + and He + irradiation were ~1-1.5 orders of magnitude lower than the high flux conditions, and each experiment was irradiated to a total fluence between ~3 × 10 16 to ~6 × 10 16 ions/cm 2 . Irradiation-induced changes in the surface chemistry and optical properties of the Murchison samples were evaluated using in situ X-ray photoelectron spectroscopy (XPS) and visible and near-infrared spectroscopy (VNIR). We characterized the microstructure and composition of ion damaged rims in focused ion beam (FIB) cross-sections extracted from olivine and matrix material in each irradiated Murchison slab using transmission electron microscopy (TEM). XPS results suggest that both low flux and high flux H + and He + irradiation cause minor sputtering of surface carbon as well as a reduction in the valence state of iron, from Fe 3+ to Fe 2+ . Slope bluing is observed in VNIR spectra of the irradiated samples which may reflect carbonization and dehydrogenation of organic species and contrasts with reddening trends associated with npFe 0 formation. Although we do not observe a strong flux-dependence on the crystallinity of ion-damaged olivine, TEM analyses reveal a variety of microstructures in all olivine FIB-sections, suggesting that crystallographic orientation affects amorphization efficiency. Analyses of matrix FIB-sections indicate that phyllosilicate alteration is mainly driven by He+ irradiation, where the higher incident flux leads to greater amorphization and the formation of more distinct ion-damaged layers, similar to smooth layers in returned Ryugu particles. TEM results also provide some evidence that higher ion flux leads to greater vesiculation, with He + irradiation being more efficient at vesiculation than H + irradiation, and that higher ion flux may promote the segregation of Mg and Si into laterally extensive lenses and layers in olivine samples. We discuss the implications of these findings for constraining the role that ion flux plays in the development of space weathering characteristics in silicate phases present in carbonaceous asteroidal regoliths. These results will be important for understanding the complexity of this process and how it operates on carbon-rich airless bodies like asteroids Bennu and Ryugu.
Strategies to Support Exploration of Mars' Surface
Surface Visible infrared spectroscopy has a long history of providing fundamental compositional discoveries in the solar system. However, we are entering a new era of Mars exploration in which missions will take place nearly every 2 years.The visible infrared spectral community thus faces a more rapid influx in data volume and variety than it has previously handled.Visible- infrared instruments are on the 1996 Mars Global Surveyor, 2001 Mars Odyssey 2003 Mars Exploration Rovers, 2003 Mars Express, 2005 Mars Reconnaissance Orbiter; and likely on the 2007 and 2009 missions. Interpretations of those data sets provide a critical foundation for geologic and climatic interpretations as well as an opportunity to select landing sites.
Design Through Integration of On-Board Calibration Device with Imaging Spectroscopy Instruments
The main purpose of the Airborne Visible and Infrared Imaging Spectroscopy (AVIRIS) project is to "identify, measure, and monitor constituents of the Earth's surface and atmosphere based on molecular absorption and particle scattering signatures." The project designs, builds, and tests various imaging spectroscopy instruments that use On-Board Calibration devices (OBC) to check the accuracy of the data collected by the spectrometers. The imaging instrument records the spectral signatures of light collected during flight. To verify the data is correct, the OBC shines light which is collected by the imaging spectrometer and compared against previous calibration data to track spectral response changes in the instrument. The spectral data has the calibration applied to it based on the readings from the OBC data in order to ensure accuracy.
Chromium basalts - Experimental determination of redox states and partitioning among synthetic silicate phases
Experiments were performed on silicate compositions in the forsterite-anorthite-silica and forsterite-anorthite-diopside systems to determine the relative amounts of Cr(II), Cr(III), and Cr(VI) over a wide range of oxygen partial pressures from 10 to the -10th to 1 atm at 1500 and 1550 C. Redox states were measured by visible absorption spectroscopy and electron paramagnetic resonance spectroscopy and titration. It was found that Cr is present almost exclusively as Cr(III) in terrestrial basaltic liquids and as a mixture of Cr(III) and Cr(II) in lunar basaltic liquids.
A critical study of the role of the surface oxide layer in titanium bonding
The molecular understanding of the role which the surface oxide layer of the adherend plays in titanium bonding is studied. The effects of Ti6-4 adherends pretreatment, bonding conditions, and thermal aging of the lap shear specimens were studied. The use of the SEM/EDAX and ESCA techniques to study surface morphology and surface composition was emphasized. In addition, contact angles and both infrared and visible reflection spectroscopy were used in ancillary studies.
Seasonal and diurnal variation of the atmospheric NO2 at Syowa Station, Antarctica
Extensive attention has been directed to nitrogen dioxide (NO2) since its important role in the atmospheric chemistry relating to the stratospheric ozone (e.g., WMO, 1982) has been pointed out. However, the behavior of NO2 in the atmosphere has still not been fully confirmed, although ground-based, balloon and satellite measurements of NO2 have been reported by many scientists. Especially, only a few measurements made at high latitude in the Southern Hemisphere have been reported. The total atmospheric NO2 by ground-based visible absorption spectroscopy at Syowa Station (69 deg S, 39.6 deg E), Antarctica. The observation continued from March 1983, to January 1984. The principles of measurement, instrumentation and the method of data analysis are described in detail.
Optical signatures of molecular particles via mass-selected cluster spectroscopy
A new molecular beam apparatus was developed to study optical absorption in cold (less than 100 K) atomic clusters and complexes produced by their condensation with simple molecular gases. In this instrument, ionized clusters produced in a laser vaporization nozzle source are mass selected and studied with photodissociation spectroscopy at visible and ultraviolet wavelengths. This new approach can be applied to synthesize and characterize numerous particulates and weakly bound complexes expected in planetary atmospheres and in comets.