Single crystal surface work function and desorption studies Final report
Single crystal surface work function and desorption studies
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Single crystal surface work function and desorption studies
Electron emission characteristics of low work function surfaces from magnetic deflection probe measurements of cesium adsorption on tungsten
Formation and electron emission characteristics of low work function surfaces
Electron emission characteristics of low work function surfaces - total energy distributions for five crystallographic directions of tungsten
Interfacial polarization – charge accumulation at the heterointerface – is a well-established tool in semiconductors, but its influence in metals remains unexplored. Here, we demonstrate that interfacial polarization can robustly modulate surface work function in metallic rutile RuO 2 layers in epitaxial RuO 2 /TiO 2 heterostructures grown by hybrid molecular beam epitaxy. Using multislice electron ptychography, we directly visualize polar displacements of transition metal ions relative to oxygen octahedra near the interface, despite the conductive nature of RuO 2 . This interfacial polarization enables over 1 eV modulation of the RuO 2 work function, controlled by small thickness variations (2-3 nm), as measured by Kelvin probe force microscopy, with a critical thickness of ~4 nm – corresponding to the transition from fully-strained to relaxed film. These results establish interfacial polarization as a powerful route to control electronic properties in metals and have implications for designing tunable electronic, catalytic, and quantum devices through interfacial control in polar metallic systems.
Vacuum thermionic work functions of polycrystalline Be, Ti, Cr, Fe, Ni, Cu, Pt and type 304 stainless steel
Literature search of physical property data and composite surface work function models
Photoelectric scanning device maps the work function of a metal surface by scanning it with a light spot and measuring the resulting photocurrent. The device is capable of use over a range of surface temperatures.
Quality and stability of electron emission characteristics of low work function surfaces - tungsten
Thermionic work function of refractory intermetallic compounds and their electronic and crystal structures
Radioactive tracer and work function of chemisorption of gas on metal
Work function and desorption energy measurements of alkali metals from metallic substrates with modulated molecular beam, noting surface contamination
Self-heating hollow cathodes are central components in modern electric thrusters. The plasma discharge inside these devices heats the internal components, thus maintaining the temperatures required for electron emission. Precise knowledge of the physical phenomena governing hollow cathode operation is key to predict their lifetime, specifically, their thermionic emission characteristics. A simulation platform has been built to couple plasma and thermal models of the self-heating hollow cathode to produce a self-consistent solution. A self-consistent solution has been found for a LaB6 hollow cathode operating at 25A and 13 sccm where the work function is assumed to be spatially uniform along the emitter with a value which is allowed to vary as the coupled model iterates to a self-consistent solution. The emitter temperature from the converged solution does not agree with experimental temperature measurements, however. The results of a sensitivity analysis suggest that none of the tolerances in the measurement are responsible for the discrepancy. We hypothesize that either the work function needs to be a function of position along the emitting surfaces or the heat fluxes have been overestimated in the plasma solver.
Vacuum thermionic work function and thermal stability measurements on crystal surfaces, discussing results on carbides, diborides and disilicades
Desorption, mobility and work function change of mercury on tungsten and molybdenum substrates
Electric fields and electron work functions, surface potentials and number density distributions in selected metals surfaces determined using free electron model
Coadsorption of cesium and fluorine on tungsten, and analysis of mechanisms leading to decay of field emission current from low work function zirconium/oxygen coated tungsten emitter
Total energy distribution of field emitted electrons and single plane work functions for tungsten, discussing correspondence with Fowler-Nordheim models for field emission