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Hand Calculations for Nuclear Criticality Safety – Primer Revision [Slides]

This presentation discusses progress on the revision of the Hand Calculations for Nuclear Criticality Safety Primer. The new Primer should be approved for unlimited release by the end of the summer 2022. ORNL and LLNL are working to incorporate the website complement onto the NCSP website.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

2022 Long-Term Hydrologic Monitoring Program Report for the Rio Blanco, Colorado Site

This report presents the monitoring data collected by the U.S. Department of Energy (DOE) Office of Legacy Management (LM) during the 2022 sampling event at the Rio Blanco, Colorado, Site, where an underground nuclear test was conducted in 1973. The test resulted in residual radionuclide contamination at the detonation depth. The 2022 sampling event included the collection of samples from onsite groundwater wells to monitor for any potential contamination that might be attributed to the Rio Blanco nuclear tests. This report summarizes the laboratory results obtained from the sampling along with the historical results since monitoring began in the 1970s. This annual report and previous reports are available on the LM public website at https://www.energy.gov/lm/rio-blanco-colorado-site. Data collected during this and previous monitoring events are available on the Geospatial Environmental Mapping System (GEMS) website at https://gems.lm.doe.gov/#site=RBL.

54 ENVIRONMENTAL SCIENCES↗

Applying 3D Geologic Modeling Workflows to the Argillite Reference Case (Rev. 1)

The objective of this short report is to document the application of our 3D geologic modeling workflow to an argillite (shale) host rock. Over the past four years, our team at Los Alamos National Laboratory has developed a geologic modeling workflow that can be applied to generic alluvial basins such as those found in the western United States. In “frontier” or “exploratory” basins where data are sparse, the first steps are to collect, evaluate and integrate available subsurface data into conceptual geologic models. Those models form the basis for constructing the geologic framework model, a 3D geocellular model ideally constrained by seismic and borehole data. To date we have constructed our models using “synthetic” well data derived from conceptual models, without the prospect of validating our workflow using “real” subsurface data. We were tasked to investigate whether our workflow designed for alluvial basin sediments could be applied to other potential repository host rocks. This task also provided the opportunity to work with high-quality subsurface data collected specifically for siting and evaluating a nuclear waste repository. Nagra, the Swiss governmental agency responsible for the disposal of the nation’s radioactive waste, generously provided us with data from two deep boreholes drilled through their argillaceous target formation. The aim of our proof-of-concept demonstration is to evaluate whether geostatistical methods offer a viable approach to property modeling in argillaceous rocks. Nagra provided us with the well data on the condition that we maintain confidentiality with all transferred information and results. Fortunately, Nagra posts numerous technical reports on its public website that describe the subsurface geology in great detail. All of the information and illustrations in this report related to the Swiss repository enterprise are taken from the Nagra public website.

58 GEOSCIENCES↗

Triton Initiative: FY22 Communications, Outreach, and Engagement End-of-Year Report

The Department of Energy (DOE) Water Power Technologies Office (WPTO) Triton Initiative supports the advancement of the marine energy (ME) industry through environmental monitoring research and technology development. This report presents the results and analysis of the Triton Initiative’s communications, outreach, and engagement (TCOE) efforts in fiscal year 2022. The primary TCOE goals were to: (1) educate and raise awareness of ME and the role of Triton's environmental monitoring research in supporting the industry; (2) build trust with audiences through transparent communications and outreach; and (3) evaluate and refine TCOE tactics based on feedback and metrics. To support these goals, the TCOE team used multiple platforms and approaches. Notable achievements include: (1) 12 newsletter issues sent to 185 subscribers with an average open rate of 56.4%. (2) 10 Triton Stories, resulting in 2,871 collective views contributing to 46% of all Triton website views. (3) 78 Triton-specific social media posts, which generated a total of 81,896 impressions, 1,037 post-clicks, and 7,814 video views. (4) 6,320 Triton website views with increased search engine optimization ranking in several categories. (5) 3 Triton researchers interviewed as guests on two different podcasts, Water Women and Big Deep: An Ocean Podcast. (6) A Triton special issue of the Journal of Marine Science and Engineering (JMSE) featuring 10 peer reviewed publications. All articles ranked in the top 25%, and two in the top 5%, for digital attention of all research outputs scored by Altmetric. (7) A seven-part webinar series called Triton Talks to share and discuss research and results from the research published in the JMSE special issue. Triton leveraged unique opportunities, particularly the JMSE special issue, to disseminate research results to end users, educate stakeholders, and gain valuable feedback. These concerted communication efforts increased exposure across platforms ultimately resulting in greater reach and access across audiences. Based on audience analyses of webinar attendees and newsletter subscribers, the TCOE team was able to successfully engage with general audiences, research partners, and ME stakeholders, including subject matter experts from government agencies, research organizations, and the regulatory community. The TCOE task established channels to gather input and create opportunities for two-way communication with people engaged with Triton’s outreach efforts. The feedback received will enable the TCOE team to support its goals for ongoing evaluation of outreach and engagement tools while continuing to build trust in the ME community and educate diverse audiences about the impactful research conducted by the Triton Initiative. This report is a Triton Initiative Fiscal Year 2022 Quarter 4 Milestone Deliverable due to the DOE WPTO Sponsor on 9/30/2022. An updated version to include data through 9/30/2022 will be delivered in October 2022.

16 TIDAL AND WAVE POWER↗

45Q Carbon Oxide Utilization LCA Training Workshop: Toolkit Overview

This training workshop was offered to inform stakeholders and LCA professionals of the tools and resources available from the Department of Energy’s National Energy Technology Laboratory (NETL) to support the development of an LCA that is compliant with the 45Q requirements. This presentation provides a descriptive overview which preceded a demonstration of the new and existing tools, available to view on the USEA website. A description and recording on USEA website here: https://usea.org/event/doenetl-45q-carbon-oxide-conversion-lca-training-workshop-hybrid.

Krynock, Michelle↗

Development and Validation of Smart Building Technology Modules for Academic and Professional Education (Final Technical Report)

Smart building technologies can improve building energy efficiency and resilience, reduce carbon emissions, and provide load flexibility to the grid. However, in both college curricula and building professionals’ continuing education, there is a lack of systematic instruction on smart building technologies. Slipstream, partnering with Texas A&M University (TAMU), the Society of Building Science Educators (SBSE), and the National Institute of Building Sciences (NIBS), developed a semester-long smart building curriculum for college students and 16 training videos for building professionals and the general public. The education and training cover the drivers and benefits of smart building technologies, key building energy systems, the latest sensor technologies and IoT devices, and focus on topics related to smart building controls (i.e., energy management information systems, smart building control platforms, cybersecurity, grid-interactive-efficient buildings [GEBs], smart building control methods, and occupant-centric control). The smart building curriculum for college students was taught at TAMU in the Spring semester of 2024 as part of the validation process. Student feedback was collected and summarized in a validation report by TAMU. The curriculum material was also reviewed by SBSE faculty who are interested in teaching smart building technology-related courses. Suggestions on revisions and better adoption of the materials by other faculty across the architectural, engineering, and construction (AEC) domains were compiled in a distinct validation report by SBSE. The SBSE validation report was used to create structured subsets of the curriculum material for adoption at different levels in different sub-disciplines. These subsets are categorized and offered on the SBSE website (https://www.sbse.org/courses/Smart-Building-Technologies). The 16 training videos for building professionals and the general public were previewed by 17 industry experts, and feedback and suggested changes were incorporated into the final version of these videos. The videos are organized into a smart building technology training course and published on the Whole Building Design Guide website (https://www.wbdg.org/ce/doe/bto/sbtt), which is hosted by the National Institute of Building Sciences (NIBS). Project team members created marketing materials to promote the awareness of these free, publicly available education and training resources. Outreach and marketing activities included creating short promotional videos, building project webpages, making project announcements on social media, conducting an email campaign, and directly reaching out to faculties and building professionals. This report describes the project approach, provides outlines of the training materials, along with links to resources, and identifies lessons learned in creating the content. We also suggest ways to scale the instruction of smart building concepts to empower the workforce to accelerate the adoption of smart building technologies in the real world.

99 GENERAL AND MISCELLANEOUS↗

AgriSolar Clearinghouse

The AgriSolar Clearinghouse (ASC) is a relationship-building, information-sharing network that promotes the co-location of solar energy systems and agriculture. The ASC website became accessible to the public after stakeholder approval, on October 27th, 2021. Phase 2 of the website was completed June 15, 2022, and includes an AgriSolar Atlas and a map of Financial Incentives.

14 SOLAR ENERGY↗

Low-Income Energy Affordability Data - LEAD Tool - 2022 Update

The Low-Income Energy Affordability Data (LEAD) Tool was created by the Better Building's Clean Energy for Low Income Communities Accelerator (CELICA) to help state and local partners understand housing and energy characteristics for the low- and moderate-income (LMI) communities they serve. The LEAD Tool provides estimated LMI household energy data based on income, energy expenditures, fuel type, housing type, and geography, which stakeholders can use to make data-driven decisions when planning for their energy goals. From the LEAD Tool website, users can also create and download customized heat-maps and charts for various geographies, housing, energy characteristics, and population demographics and educational attainment. Datasets are available for 50 states plus Puerto Rico and Washington D.C., along with their cities, counties, and census tracts, as well as tribal areas. The file below, "01. Description of Files," provides a list of all files included in this dataset. A description of the abbreviations and units used in the LEAD Tool data can be found in the file below titled "02. Data Dictionary 2022". A list of geographic regions used in the LEAD Tool can be found in files 04-11. The Low-Income Energy Affordability Data comes primarily from the 2022 U.S. Census American Community Survey 5-Year Public Use Microdata Samples and is calibrated to 2022 U.S. Energy Information Administration electric utility (Survey Form-861) and natural gas utility (Survey Form-176) data. The methodology for the LEAD Tool can viewed below (3. Methodology Document). For more information, and to access the interactive LEAD Tool platform, please visit the "10. LEAD Tool Platform" resource link below. For more information on the Better Building's Clean Energy for Low Income Communities Accelerator (CELICA), please visit the "11. CELICA Website" resource below.

AMI↗

Auto Stop-Start Fuel Consumption Benefits

With increasingly stringent regulations mandating the improvement of vehicle fuel economy, automotive manufacturers face growing pressure to develop and implement technologies that improve overall system efficiency. One such technology is an automatic (auto) stop-start feature. Auto stop-start reduces idle time and reduces fuel use by temporarily shutting the engine off when the vehicle comes to a stop and automatically re-starting it when the brake is released, or the accelerator is pressed. As mandated by the U.S. Congress, the U.S. Environmental Protection Agency (EPA) is required to keep the public informed about fuel saving practices. This is done, in partnership with the U.S. Department of Energy (DOE), through the fueleconomy.gov website. The “Fuel-Saving Technologies” and “Gas Mileage Tips” sections of the website are focused on helping the public make informed purchasing decisions and encouraging fuel-saving driving habits. Here, in order to provide users with accurate information about the auto stop-start feature, experiments were conducted to determine its fuel economy effect. Four vehicles were tested both with and without the feature enabled under three test cycles: the Federal Test Procedure (FTP) city fuel economy test, the US06 high acceleration aggressive driving schedule that is often identified as the “Supplemental FTP” driving schedule, and the EPA New York City Cycle (NYCC). The results were compared to measure the fuel economy and consumption effects of using the auto stop-start feature. It was found that the fuel economy improvement varied significantly between drive cycles depending on the amount and percentage of idle time during the test. The largest fuel economy improvements were 7.27% and 26.4% for the FTP and NYCC, respectively.

33 ADVANCED PROPULSION SYSTEMS↗

Small UAS radiological survey flights at the NNSS

News highlight intended for a new publication, the "LDRD Quarterly Highlights." The quarterly newsletter contains highlights from LDRD and SDRD programs and will be published on a LANL-hosted website. This story was previously featured on the NNSS.gov website

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

NNSS Plumbs the Bright Side of Dark-Field X-ray Microscopy

Article to be included in the second quarter, FY 2021, issue of the LDRD Quarterly Highlights. website: https://www.lanl.gov/projects/ldrd-tri-lab/quarterly-highlights.php. The article may also be used internally on the MSTS Science and Technology website and on the NNSS.gov SDRD news highlights page.

36 MATERIALS SCIENCE↗

NNSS Designs New Lab Apparatus for Studying Particle-Laden Supersonic Gas Flows

Article to be included in the second quarter, FY 2021, issue of the LDRD Quarterly Highlights. website: https://www.lanl.gov/projects/ldrd-tri-lab/quarterly-highlights.php. The article may also be used internally on the MSTS Science and Technology website and on the NNSS.gov SDRD news highlights page.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Smart Semi-Supervised Accumulation of Large Repositories for Industrial Control Systems Device Information

Industrial Control Systems device manufacturers frequently add new features to improve their product performance. Oftentimes, these changes are mainly vendor-driven initiatives, and customers may not be aware of the full impact of these new capabilities on their cybersecurity posture. In the energy sector, this can lead to considerable dissonance between vendor-provided cybersecurity claims and a customer’s responsibility for Operation Technology cybersecurity compliance. Thus, the resulting dynamic verification burden is shifted towards the customer and may pose a significant cybersecurity risk to the energy sector landscape. We found that there is very limited research into cybersecurity auditing for Operational Technology. However, a solution is needed for vetting the vendor-supplied feature claims and their adherence to cybersecurity requirements and standards. We are presently engaged in an effort to develop such a system. This paper demonstrates one vital aspect of this effort in proposing an end-to-end framework to accumulate a large repository of ICS device information for this vetting system, curate the dataset, and conduct extensive processing. This framework is designed to use web scraping, data analytics and Natural Language Processing (NLP) techniques to identify vendor websites, automate the collection of website-accessible documents and automatically derive metadata from them for identification of product documents relevant to the repository. We have found that this automated approach to vendor identification, document extraction into a product repository, and NLP pre-processing is unique and has not been previously presented in the literature. The preliminary work shows that this is feasible and can produce reliable results with minimum supervision. Future work will be built upon this foundation in order to achieve semi-supervised vetting of device technical information – a vital capability for ensuring that vendor-claimed device cybersecurity capabilities match industry requirements.

Ameri, Kimia↗

Automation of Vulnerability and Patch Management: Information Extraction, Association, and Optimization

Vulnerability and patch management is an integral part of a robust cybersecurity program, yet it grows increasingly complex due to the sheer amount of data that must be analyzed. Particularly in Operational Technology (OT) environments, analysis must be done manually because of the lack of automated solutions. Additionally, there are many steps in this process, from the initial discovery of the vulnerability to the implementation of its remediation, and each step in the process requires different data in order to be performed effectively. In this work, we provide approaches and strategies to assist operators in industrial or OT environments throughout the vulnerability management cycle. Security advisories provide key information about mitigation strategies, or actions that can be taken when a patch is unavailable or cannot be installed. Details of these strategies are not shared in public vulnerability databases and must be found manually. We approach this problem by designing a solution to automatically identify that information within vendor security advisories and retrieve it for operator use. We start with an approach that requires domain-specific knowledge of certain frequently-seen reference websites. Next, an approach that can work on an arbitrary website but relies on certain keywords. Finally, an approach that uses Natural Language Processing (NLP) methods and does not require specific knowledge or keywords. Each of these approaches is more general than its predecessor; we demonstrate high accuracy for all approaches Advisories also often contain details of affected products in non-standard or natural language formats. While this information can be easily understood when read by an operator, the non-standard format acts as a barrier to effective automation. We provide an approach for the first step in this process: identifying vendors in security advisories and mapping them to a standard framework for representing digital assets and software products. We evaluate five established string similarity algorithms, plus one of our own design that combines string similarity and information theory, on the task of mapping vendors to their corresponding entries in the Common Platform Enumeration (CPE) repository. Our results show that our proposed metric outperforms all others. Due to the constraints on time, finances, and personnel for organizations, Large Language Models (LLMs) may seem like attractive opportunities for security operators to speed up information gathering; however, it is still not clear whether LLMs can handle vulnerability management tasks well. To answer this question, we perform an empirical study of LLMs’ ability to provide consistent, accurate information about vulnerabilities in order to guide organizations in their adoption of LLMs. We observe poor performance for all models tested, suggesting that these models are not well-suited to the consistent retrieval of accurate vulnerability information. Finally, once vulnerabilities have been identified and any additional information has been obtained, operators must decide which remediation actions to implement based on their available resources. This already-complex problem becomes even more so when we consider that a vulnerability may have multiple avenues for remediation. We formulate this scenario as two knapsack problems and provide solutions, which we then compare against several existing strategies for vulnerability prioritization seen in real operational environments.

McClanahan, Kylie↗

The Kimberlina synthetic multiphysics dataset for CO 2 monitoring investigations

Abstract We present a synthetic multi‐scale, multi‐physics dataset constructed from the Kimberlina 1.2 CO 2 reservoir model based on a potential CO 2 storage site in the Southern San Joaquin Basin of California. Among 300 models, one selected reservoir‐simulation scenario produces hydrologic‐state models at the onset and after 20 years of CO 2 injection. Subsequently, these models were transformed into geophysical properties, including P‐ and S‐wave seismic velocities, saturated density where the saturating fluid can be a combination of brine and supercritical CO 2 , and electrical resistivity using established empirical petrophysical relationships. From these 3D distributions of geophysical properties, we have generated synthetic time‐lapse seismic, gravity and electromagnetic responses with acquisition geometries that mimic realistic monitoring surveys and are achievable in actual field situations. We have also created a series of synthetic well logs of CO 2 saturation, acoustic velocity, density and induction resistivity in the injection well and three monitoring wells. These were constructed by combining the low‐frequency trend of the geophysical models with the high‐frequency variations of actual well logs collected at the potential storage site. In addition, to better calibrate our datasets, measurements of permeability and pore connectivity have been made on cores of Vedder Sandstone, which forms the primary reservoir unit. These measurements provide the range of scales in the otherwise synthetic dataset to be as close to a real‐world situation as possible. This dataset consisting of the reservoir models, geophysical models, simulated time‐lapse geophysical responses and well logs forms a multi‐scale, multi‐physics testbed for designing and testing geophysical CO 2 monitoring systems as well as for imaging and characterization algorithms. The suite of numerical models and data have been made publicly available for downloading on the National Energy Technology Laboratory's (NETL) Energy Data Exchange (EDX) website.

58 GEOSCIENCES↗

Long-term hydrological, biogeochemical, and climatological data from Walker Branch Watershed, East Tennessee, USA

In 1967, the original Walker Branch Watershed (WBW) project was established to study elemental cycling and mass balances in a relatively unimpacted watershed. Over the next 50+ years, findings from additional experimental studies and long-term observations on WBW advanced understanding of catchment hydrology, biogeochemistry, and ecology and established WBW as a seminal site for catchment science. The 97.5-ha WBW is located in East Tennessee, USA, on the U.S. Department of Energy's Oak Ridge Reservation. Vegetation on the watershed is characteristic of an eastern deciduous, second-growth forest. The watershed is divided into two subcatchments: the West Fork (38.4 ha) and the East Fork (59.1 ha). Headwater streams draining these subcatchments are fed by multiple springs, and thus flow is perennial. Stream water is high in base cations due to weathering of dolomite bedrock and nutrient concentrations are low. Long-term observations of climate, hydrology, and biogeochemistry include daily (1969–2014) and 15-min (1994–2014) stream discharge and annual runoff (1969–2014); hourly, daily, and annual rainfall (1969–2012); daily climate and soil temperature (1993–2010); and weekly stream water chemistry (1989–2013). These long-term datasets are publicly available on the WBW website (https://walkerbranch.ornl.gov/long-term-data/). While collection of these data has ceased, related long-term measurements continue through the National Ecological Observatory Network (NEON), where WBW is the core terrestrial and aquatic site in the Appalachian and Cumberland Plateau region (NEON's Domain 7) of the United States. These long-term datasets have been and will continue to be important in evaluating the influence of climatic and environmental drivers on catchment processes.

54 ENVIRONMENTAL SCIENCES↗

The MolSSI QCArchive project: An open-source platform to compute, organize, and share quantum chemistry data

The Molecular Sciences Software Institute's (MolSSI) Quantum Chemistry Archive (QCArchive) project is an umbrella name that covers both a central server hosted by MolSSI for community data and the Python-based software infrastructure that powers automated computation and storage of quantum chemistry (QC) results. The MolSSI-hosted central server provides the computational molecular sciences community a location to freely access tens of millions of QC computations for machine learning, methodology assessment, force-field fitting, and more through a Python interface. Facile, user-friendly mining of the centrally archived quantum chemical data also can be achieved through web applications found at the website. The software infrastructure can be used as a standalone platform to compute, structure, and distribute hundreds of millions of QC computations for individuals or groups of researchers at any scale. The QCArchiveInfrastructure is open-source (BSD-3C), code repositories can be found at github, and releases can be downloaded via PyPI and Conda. This article is categorized under: Electronic Structure Theory > Ab Initio Electronic Structure Methods Software > Quantum Chemistry Data Science > Computer Algorithms and Programming

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Life Cycle Analysis of Thermoelectric Power Generation in the United States

In this article, the basics of performing a life cycle analysis of thermoelectric power generation are discussed, with three examples of life cycle greenhouse gas (GHG) balances for thermoelectric power generation forms: coal, natural gas, and nuclear. The final section compares multiple electricity generation methods in the United States. Results are presented on the basis of 1 megawatt-hour (MWh) of electricity delivered to the end user. Environmental life cycle results for greenhouse gas (GHG) emissions are presented as carbon dioxide equivalents, based on 100-year global warming potentials (GWPs) established by the 6th Assessment Report from the Intergovernmental Panel on Climate Change in 2021, commonly referred to as AR6 GWP values (IPCC, 2021). Additional details on other environmental life cycle impacts from non-GHG emissions to air, emissions to water, solid waste generation, and land use are available on the Department of Energy, National Energy Technology Laboratory’s Life Cycle Analysis website: www.netl.doe.gov/LCA.

Cutshaw, Ashley↗