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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

A pulsed-power implementation of “Laser Gate” for increasing laser energy coupling and fusion yield in magnetized liner inertial fusion (MagLIF)

Magnetized Liner Inertial Fusion (MagLIF) at Sandia National Laboratories involves a laser preheating stage,where a few-ns laser pulse passes through a few-micron-thick plastic window to preheat gaseous fusion fuel contained within the MagLIF target. Interactions with this window reduce heating e ciency and mix window and target materials into the fuel. A recently proposed idea called \Laser Gate" involves removing the window well before the preheating laser is applied. In this article, we introduce experimental proof-of-principle results for a pulsed-power implementation of Laser Gate, where a thin current-carrying wire weakens the perimeter of the window, allowing the fuel pressure to push the window open and away from the preheating laser path. For this e ort, transparent targets were fabricated and a test facility capable of studying this version of Laser Gate was developed. A 12-frame bright- eld laser schlieren/shadowgraphy imaging system captured the window opening dynamics on microsecond timescales. The images exhibit that the window remains largely intact as it opens and detaches from the target. A column of escaping pressurized gas appears to prevent the detached window from inadvertently moving into the preheating laser path.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Pennsylvania and Delaware Energy Code Field Studies (Final Technical Report (FTR)

Led by Northeast Energy Efficiency Partnerships (NEEP) in partnership with Performance Systems Development (PSD), the project aimed to conduct energy code compliance field studies for single-family residential buildings in Pennsylvania and Delaware, as well as multifamily and commercial buildings in Pennsylvania. Using U.S. Department of Energy (DOE) approved methodologies, trained field teams conducted on-site observations and testing to document compliance with key energy efficiency measures, including building envelope insulation, air sealing, duct leakage, windows, and mechanical systems. Data from these studies would then be analyzed to identify construction trends and compliance gaps. The goals included published baseline data for each study, and a training roadmap tailored to each state’s needs. This roadmap would have guided outreach and training for builders, code officials, and other stakeholders on the specific code requirements that offered the greatest opportunity for improvement.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Structural magnetic glassiness in the spin ice Dy 2 Ti 2 O 7

The origin and nature of glassy dynamics presents one of the central enigmas of condensed-matter physics across a broad range of systems ranging from window glass to spin glasses. The spin-ice compound Dy 2 Ti 2 O 7 , which is perhaps best known as hosting a three-dimensional Coulomb spin liquid with magnetically charged monopole excitations, also falls out of equilibrium at low temperature. How and why it does so remains an open question. Based on an analysis of low-temperature diffuse neutron-scattering experiments employing different cooling protocols alongside recent magnetic noise studies, combined with extensive numerical modeling, we argue that upon cooling, the spins freeze into what may be termed a “structural magnetic glass,” without an a priori need for chemical or structural disorder. Specifically, our model indicates the presence of frustration on two levels, first producing a near-degenerate constrained manifold inside which phase ordering kinetics is in turn frustrated. A remarkable feature is that monopoles act as sole annealers of the spin network and their pathways and history encode the development of glass dynamics, allowing the glass formation to be visualized. Our results suggest that spin ice Dy 2 Ti 2 O 7 provides one prototype of magnetic glass formation specifically and a setting for the study of kinetically constrained systems more generally.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

AXEAP : a software package for X-ray emission data analysis using unsupervised machine learning

The Argonne X-ray Emission Analysis Package ( AXEAP ) has been developed to calibrate and process X-ray emission spectroscopy (XES) data collected with a two-dimensional (2D) position-sensitive detector. AXEAP is designed to convert a 2D XES image into an XES spectrum in real time using both calculations and unsupervised machine learning. AXEAP is capable of making this transformation at a rate similar to data collection, allowing real-time comparisons during data collection, reducing the amount of data stored from gigabyte-sized image files to kilobyte-sized text files. With a user-friendly interface, AXEAP includes data processing for non-resonant and resonant XES images from multiple edges and elements. AXEAP is written in MATLAB and can run on common operating systems, including Linux, Windows, and MacOS.

97 MATHEMATICS AND COMPUTING↗

Accessing Microsoft Access Databases Using ODBC and RODBC

ODBC (Open Database Connectivity) is an industry-standard API (Application Program Interface) that provides a standard interface, based on SQL (Structured Query Language) between applications and databases. This insulates applications from specific details of different database management systems (DBMS). Microsoft Windows TM provides an implementation of ODBC, which, along with drivers for various databases, supports the API. Windows also provides a driver for Access databases.

97 MATHEMATICS AND COMPUTING↗

Iron-iminopyridine complexes as charge carriers for non-aqueous redox flow battery applications

Non-aqueous redox flow batteries (RFBs) have been gaining increased attention in the energy storage arena. Some of their attractive features include the promise for high energy densities, wider voltage windows compared to aqueous systems, as well as wider operating temperature ranges. One of the major challenges in the development of these systems is the lack of electroactive materials that can undergo reversible redox events within the larger potential window of organic solvents. In this paper, we present the design, synthesis, and measurement of electrochemical properties of some iron-based imine- and iminopyridine complexes as promising candidates for RFB applications. Synthesized complexes afforded three reversible redox couples over a ~3 V range. The redox events were also computationally explored and are in good agreement with experimental data. Theoretical calculations show that the redox event at the positive potential can be characterized as metal-centered event corresponding to Fe 3+ → Fe 2+ reduction, while the two redox events at negative potentials are associated with the consecutive reductions of iminopyridine or diimine moieties. This work has led to the identification of a promising anolyte material, [tris(imino)pyridine)Fe][OTf] 2 (1), which is soluble in acetonitrile and is synthesized in two simple steps. This species shows outstanding performance when cycled between 1.0 V and 2.35 V, with 93% coulombic efficiency, 84% energy efficiency, and a capacity decay rate of 0.61% per cycle at 5 mA cm –2 . Further modifications to this kind of charge carrier may lead to the development of high energy density materials for grid scale energy storage applications.

25 ENERGY STORAGE↗

Pathway to Zero Energy Windows: Advancing Technologies and Market Adoption

As of 2021, buildings account for 39.1% of total U.S. primary energy use and 75% of total U.S. electricity use. Much of this energy is used to maintain a comfortable indoor environment. The building envelope consists of transparent and opaque elements that serve as a controllable barrier to help maintain the indoor environment regardless of external conditions. The envelope also allows the exchange of light and air, as well as other transfers with the external environment when it is beneficial for the building occupants. By leveraging desirable external environmental conditions (e.g., fresh air and natural light) and mitigating the influence of undesirable conditions (e.g., moisture, hot or cold temperatures, wind), the building envelope can reduce the need for space conditioning and electric light, and thus reduce energy use associated with lighting and heating, cooling, and ventilation equipment. In turn, high-performance building envelopes can reduce the substantial CO 2 emissions associated with energy use to satisfy heating, cooling, and lighting needs in buildings. The U.S. Department of Energy (DOE) Building Technologies Office's (BTO's) Emerging Technologies program supports R&D for technologies, systems, and software tools that can contribute to reductions in building energy use. Emerging Technologies funding is distributed competitively through solicitations (e.g., Funding Opportunity Announcements and National Lab Calls, which in general are open to applications from industry, academia, national laboratories, and other entities) and other mechanisms. This document focuses on R&D for windows and window system technologies and will provide guidance for BTO's investments in developing the next generation of high-performance, affordable, cost competitive windows, as well as integrated daylighting and shading technologies in partnership with industry and researchers. This document also addresses areas where DOE invests in software and design tools that translate sophisticated and complex physics into easy-to-use energy performance and optimization methods used by industry and other stakeholders for implementation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Window obscuration sensors for mobile gas and chemical imaging cameras

An infrared (IR) imaging system for determining a concentration of a target species in an object is disclosed. The imaging system can include an optical system including a focal plane array (FPA) unit behind an optical window. The optical system can have components defining at least two optical channels thereof, said at least two optical channels being spatially and spectrally different from one another. Each of the at least two optical channels can be positioned to transfer IR radiation incident on the optical system towards the optical FPA. The system can include a processing unit containing a processor that can be configured to acquire multispectral optical data representing said target species from the IR radiation received at the optical FPA. One or more of the optical channels may be used in detecting objects on or near the optical window, to avoid false detections of said target species.

Mallery, Ryan↗

Window obscuration sensors for mobile gas and chemical imaging cameras

An infrared (IR) imaging system for determining a concentration of a target species in an object is disclosed. The imaging system can include an optical system including a focal plane array (FPA) unit behind an optical window. The optical system can have components defining at least two optical channels thereof, said at least two optical channels being spatially and spectrally different from one another. Each of the at least two optical channels can be positioned to transfer IR radiation incident on the optical system towards the optical FPA. The system can include a processing unit containing a processor that can be configured to acquire multispectral optical data representing said target species from the IR radiation received at the optical FPA. One or more of the optical channels may be used in detecting objects on or near the optical window, to avoid false detections of said target species.

Mallery, Ryan↗

Window obscuration sensors for mobile gas and chemical imaging cameras

An infrared (IR) imaging system for determining a concentration of a target species in an object is disclosed. The imaging system can include an optical system including a focal plane array (FPA) unit behind an optical window. The optical system can have components defining at least two optical channels thereof, said at least two optical channels being spatially and spectrally different from one another. Each of the at least two optical channels can be positioned to transfer IR radiation incident on the optical system towards the optical FPA. The system can include a processing unit containing a processor that can be configured to acquire multispectral optical data representing said target species from the IR radiation received at the optical FPA. One or more of the optical channels may be used in detecting objects on or near the optical window, to avoid false detections of said target species.

Mallery, Ryan↗

Window obscuration sensors for mobile gas and chemical imaging cameras

An infrared (IR) imaging system for determining a concentration of a target species in an object is disclosed. The imaging system can include an optical system including a focal plane array (FPA) unit behind an optical window. The optical system can have components defining at least two optical channels thereof, said at least two optical channels being spatially and spectrally different from one another. Each of the at least two optical channels can be positioned to transfer IR radiation incident on the optical system towards the optical FPA. The system can include a processing unit containing a processor that can be configured to acquire multispectral optical data representing said target species from the IR radiation received at the optical FPA. One or more of the optical channels may be used in detecting objects on or near the optical window, to avoid false detections of said target species.

Mallery, Ryan↗

Window obscuration sensors for mobile gas and chemical imaging cameras

An infrared (IR) imaging system for determining a concentration of a target species in an object is disclosed. The imaging system can include an optical system including a focal plane array (FPA) unit behind an optical window. The optical system can have components defining at least two optical channels thereof, said at least two optical channels being spatially and spectrally different from one another. Each of the at least two optical channels can be positioned to transfer IR radiation incident on the optical system towards the optical FPA. The system can include a processing unit containing a processor that can be configured to acquire multispectral optical data representing said target species from the IR radiation received at the optical FPA. One or more of the optical channels may be used in detecting objects on or near the optical window, to avoid false detections of said target species.

Mallery, Ryan↗

Window obscuration sensors for mobile gas and chemical imaging cameras

An infrared (IR) imaging system for determining a concentration of a target species in an object is disclosed. The imaging system can include an optical system including a focal plane array (FPA) unit behind an optical window. The optical system can have components defining at least two optical channels thereof, said at least two optical channels being spatially and spectrally different from one another. Each of the at least two optical channels can be positioned to transfer IR radiation incident on the optical system towards the optical FPA. The system can include a processing unit containing a processor that can be configured to acquire multispectral optical data representing said target species from the IR radiation received at the optical FPA. One or more of the optical channels may be used in detecting objects on or near the optical window, to avoid false detections of said target species.

Mallery, Ryan↗

Choline chloride-formic acid mixture as a medium for the reduction of pertechnetates – electrochemical and spectroscopic studies

In this work, physicochemical properties of the choline chloride (ChCl) and formic acid (FA) mixture (1:2 molar ratio) have been studied over a broad range of temperatures (-140°C – 60 °C). Differential scanning calorimetry has shown that the examined system remains in liquid state at very low temperatures - a glass transition is observed in the range of -125 °C to - 90 °C. The kinematic viscosity, ionic conductivity and the width of the electrochemical window determined for this system revealed its beneficial electrochemical properties. This indicates suitability of ChCl:FA electrolytes in electrochemical measurements. In this non-aqueous electrolyte, the electrochemical reduction of Tc(VII) ions has been studied for the first time. Cyclic voltammetry and chronopotentiometry experiments revealed that the electroreduction of the pertechnetates is a multi-path process which leads to formation of a Tc(IV) ionic form. X-ray absorption spectroscopy of the latter revealed its structure as a TcCl 6 2- complex.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High Energy Aqueous Lithium-Ion Batteries (Final Report)

Lithium-ion batteries (LIBs) are a widely used energy storage device. For decades, researchers have been studying aqueous electrolytes due to their non-flammability and environmental friendless. However, the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) of water greatly limit the voltage window of the aqueous electrolyte. The recent concept of ‘solvent-in-salt’ electrolytes, namely ‘water-in-salt’ electrolytes (WISE) for aqueous batteries and ‘super-concentrated’ electrolytes for non-aqueous batteries, greatly expands the electrochemical window of these battery systems and consequently their energy density. This expansion occurs because the large number of salt aggregates in ‘solvent-in-salt’ electrolytes enables preferential salt decomposition over solvent decomposition to form robust interphase layers on electrodes, thus enhancing their stability in a wide range of operating voltages. However, even when the salt concentration reached 63m, regardless of cost, the cathodic potential of the WISE expanded only to 1.75V with an overall electrochemical stability window of <3.25V. To design the next generation of high energy aqueous LIBs, electrolytes that possess a wider electrochemical stability window and lower cost but still maintain the merit of non-flammability are much needed. In this project, we designed the aqueous LIBs with widened voltage window. We reported a cheap and non-flammable ternary eutectic electrolyte that can form a robust solid electrolyte interface (SEI)so that the cathodic limiting potential can be decreased to <1.5 V for Li 4 Ti 5 O 12 anodes, while maintaining both a high ionic conductivity of >10 -3 S cm –1 and a low viscosity. We demonstrated the super-stable2.5V LiMn 2 O 4 ||Li 4 Ti 5 O 12 pouch cell with mass loading of 2.5 mAh/cm. Further, LiCl-LiBr-Graphite/Li full cells were designed with high energy density. Finally, we use a bi-layer design to enlarge the voltage window of aqueous electrolyte, which can endow the stable cycling of aqueous Lithium metal batteries.

25 ENERGY STORAGE↗

Search for solar axions produced through the axion-electron coupling gae using a new GridPix detector at CAST

We present a search for solar axions produced through the axion-electron coupling (g ae ) using data from a novel 7-GridPix detector installed at the CERN Axion Solar Telescope (CAST). The detector, featuring ultra-thin silicon nitride windows and multiple veto systems, collected approximately 160 hours of solar tracking data between 2017–2018. Using machine learning techniques and the veto systems, we achieved a background rate of 1.06 × 10 −5 keV −1 cm −2 s −1 at a signal efficiency of about 80% in the 0.2 to 8 keV range. Analysis of the data yielded no significant excess above background, allowing us to set a new upper limit on the product of the axion-electron and axion-photon couplings of g ae · g aγ < 7.35 × 10 −23 GeV −1 at 95% confidence level for axion masses below 10 meV. This result improves upon the previous best helioscope limit and demonstrates the potential of GridPix technology for rare event searches. Additionally, we derived a limit on the axion-photon coupling of g aγ < 9.0 × 10 −11 GeV −1 at 95% CL, which, while not surpassing CAST’s best limit, provides complementary constraints on axion models.

Beyond Standard Model↗

FAST-1.0: A Computer Code for Thermal-Mechanical Nuclear Fuel Analysis under Steady-state and Transients: Developed under NQA-1-2017

Fuel Analysis under Steady-state and Transients (FAST) is the US Nuclear Regulatory Commission (NRC)’s computer code that calculates the steady-state and transient response of nuclear reactor fuel rods during long-term in-reactor burnup, anticipated operational occurrences (AOOs), design basis accidents (DBAs), and dry storage conditions. The code calculates the temperature, pressure, and deformation of a fuel rod as functions of time-dependent fuel rod power and coolant boundary conditions. The phenomena modeled by the code include: heat conduction through the fuel and other materials, heat transfer from the cladding-to-coolant, cladding elastic and plastic deformation, including creep, fuel-cladding mechanical interaction, fission gas release from the fuel, rod internal pressure and void volume, and cladding oxidation. The code contains necessary material and coolant properties, as well as clad-to-coolant heattransfer correlations, for normal operation through postulated accidents for today’s US-based light water reactor (LWR) fuel designs. FAST-1.0 also contains preliminary materials and models for new LWR fuel concepts, such as accident tolerant fuel (ATF), and non-LWR fuel concepts such as metallic fuels for sodium fast reactors (SFRs). FAST has been developed for use on Windows and Linux operating systems. This document describes FAST-1.0, which is the first official version of this code. This document is one of a series of documents on FAST; the other documents detail the material properties used by FAST as well as its integral assessment to experiments and commercial data.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

FAST-1.1: A Computer Code for Thermal-Mechanical Nuclear Fuel Analysis under Steady-state and Transients (Developed under NQA-1-2017)

Fuel Analysis under Steady-state and Transients (FAST) is the U.S. Nuclear Regulatory Commission (NRC)’s computer code that calculates the steady-state and transient response of nuclear reactor fuel rods during long-term in-reactor burnup, anticipated operational occurrences (AOOs), design basis accidents (DBAs), and dry storage conditions. The code calculates the temperature, pressure, and deformation of a fuel rod as functions of time-dependent fuel rod power and coolant boundary conditions. The phenomena modeled by the code include: * heat conduction through the fuel and other materials * heat transfer from the cladding-to-coolant * cladding elastic and plastic deformation, including creep * fuel-cladding mechanical interaction * fission gas release from the fuel * rod internal pressure and void volume * cladding oxidation The code contains necessary material and coolant properties, as well as clad-to-coolant heat transfer correlations, for normal operation through postulated accidents and AOOs for today’s U.S.-based light water reactor (LWR) fuel designs. FAST-1.1 also contains preliminary materials and models for new LWR fuel concepts, such as accident tolerant fuel (ATF), and non-LWR fuel concepts such as metallic fuels for sodium fast reactors (SFRs). FAST has been developed for use on Windows and Linux operating systems. This document describes FAST-1.1 and is one of a series of documents on the code; the other documents detail the material properties used by FAST as well as its integral assessment to experiments and commercial data.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗