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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

New Anode Material for Rechargeable Li-ION Cells

Carbon materials, such as graphite, cokes, pitch and PAN fibers, are being evaluated in lithium batteries as alternate anode materials with some degree of success. There is an effort to look for other non-carbon anode materials which have larger Li capacity, higher rate capability, smaller first charge capacity loss and better mechanical stability during cycling. A Li-Mg-Si material is evaluated.

rechargeable batteries anode materials Li-ION cell↗

New Lithium-ion Polymer Battery for the Extravehicular Mobility Unit Suit

The Extravehicular Mobility Unit (EMU) suit currently has a silver-zinc battery that is 20.5 V and 45 Ah capacity. The EMU's portable life support system (PLSS) will draw power from the battery during the entire period of an EVA. Due to the disadvantages of using the silver-zinc battery in terms of cost and performance, a new high energy density battery is being developed for future use, The new battery (Lithium-ion battery or LIB) will consist of Li-ion polymer cells that will provide power to the EMU suit. The battery design consists of five 8 Ah cells in parallel to form a single module of 40 Ah and five such modules will be placed in series to give a 20.5 V, 40 Ah battery. Charging will be accomplished on the Shuttle or Station using the new LIB charger or the existing ALPS (Air Lock Power Supply) charger. The LIB delivers a maximum of 3.8 A on the average, for seven continuous hours, at voltages ranging from 20.5 V to 16.0 V and it should be capable of supporting transient pulses during start up and once every hour to support PLSS fan and pump operation. Figure 1 shows the placement of the battery in the backpack area of the EMU suit. The battery and cells will undergo testing under different conditions to understand its performance and safety characteristics.

Jeevarajan, J. A.↗

Performance and Safety of Lithium Ion Cells

This report evaluates the performance and safety of Lithium Ion (Li-Ion) cells when used in batteries. Issues discussed include the cycle life, energy efficiency, tolerance to higher charge voltage, tolerance to extended tapered charge voltage, charge on cycling, specific energy, low temperature discharge, low temperature charge, various charge characteristics, storage characteristics, and more of Li-Ion cells.

Ratnakumar, B. V.↗

An Overview of the NASA Aerospace Flight Battery Systems Program

Develop an understanding of the safety issues relating to space use and qualification of new Li-Ion technology for manned applications. Enable use of new technology batteries into GFE equipment - laptop computers, camcorders. Establish a data base for an optimized set of cells (and batteries) exhibiting acceptable performance and abuse characteristics for utilization as building blocks for numerous applications.

Manzo, Michelle↗

Performance Characteristics of Lithium-Ion Prototype Batteries for Mars Surveyor Program 2001 Lander

A viewgraph presentation outlines the scientific payload, expected launch date and tasks, and an image of the Mars Surveyor 2001 Lander components. The Lander's battery specifications are given. The program objectives for the Li-ion cells for the Lander are listed, and results performance evaluation and cycle life performance tests are outlined for different temperatures. Cell charge characteristics are described, and test data is presented for charge capacity at varying temperatures. Capacity retention and storage characteristics tests are described and results are shown.

Smart, M. C.↗

Lithium-Ion Battery Program Status

The objective of this program is to develop rechargeable Li-ion cells for future NASA missions. Applications that would benefit from this project are: new millenium spacecraft; rovers; landers; astronaut equipment; and planetary orbiters. The approach of this program is: select electrode materials and electrolytes; identify failure modes and mechanisms and enhance cycle life; demonstrate Li-ion cell technology with liquid electrolyte; select candidate polymer electrolytes for Li-ion polymer cells; and develop Li-ion polymer cell technology.

Surampudi, S.↗

Update on Development of 360V, 28kWh Lithium-Ion Battery

Engineering unit submodule batteries (EUSB) the 360V, 28kWh EAPU battery were designed and assembled by COM DEV. These submodules consist of Sony Li-Ion 18650HC cells in a 5P-41S array yielding 180V, 1.4 kWh. Tests of these and of substrings and single cells at COM DEV and at JSC under various performance and abuse conditions demonstrated that performance requirements can be met. The thermal vacuum tests demonstrated that the worst case hot condition is the design driver. Deficiencies in the initial diode protection scheme of the battery were identified as a result of test failures. Potential solutions to the scheme are under development and will be presented.

Davies, Francis↗

Development of Carbon Anode for Rechargeable Lithium Cells

Conventionally, rechargeable lithium cells employ a pure lithium anode. To overcome problems associated with the pure lithium electrode, it has been proposed to replace the conventional electrode with an alternative material having a greater stability with respect to the cell electrolytes. For this reason, several graphitic and coke based carbonaceous materials were evaluated as candidate anode materials...In this paper, we summarize the results of the studies on Li-ion cell development.

rechargeable batteries batteries lithium cells lit↗

NASA/GSFC Testing of Li-ion Cells: Update

A viewgraph presentation outlines: (1) cell characteristics, including capacity, self-discharge, and mid-discharge voltage; and (2) a determination of cycling performance as a battery pack, including details on number of cycles, charge voltage, and temperature, for prismatic cells (20 AH Yardney and 1.5 AH Wilson Greatbatch), cylindrical cells (12 AH, 4 AH, and 1.25 AH SAFT), and polymer cells (3 AH Alliant Tech and 8 AH Lithium Technology, Inc.).

Vaidyanathan, Hari↗

Thermal Aspects of Lithium Ion Cells

This viewgraph presentation outlines the development of a thermal model of Li-ion cells in terms of heat generation, thermal mass, and thermal resistance. Intended for incorporation into battery model. The approach was to estimate heat generation: with semi-theoretical model, and then to check accuracy with efficiency measurements. Another objective was to compute thermal mass from component weights and specific heats, and to compute the thermal resistance from component dimensions and conductivities. Two lithium batteries are compared, the Cylindrical lithium battery, and the prismatic lithium cell. It reviews methodology for estimating the heat generation rate. Graphs of the Open-circuit curves of the cells and the heat evolution during discharge are given.

Frank, H.↗

Summary of JPL Activities

A viewgraph presentation outlines the Jet Propulsion Laboratory (JPL) flight programs, including past, present and future missions targeting Solar System exploration. Details, including launch dates and batteries used, are given for Deep Space 1 (Asteroid Rendezvous), Deep Space 2 (Mars Penetrator), Mars Global Surveyor, Mars Surveyor '98, Stardust, Europa Orbiter, Mars Surveyor 2001, Mars 2003 Lander and Rover, and Genesis (Solar Dust Return). Earth science projects are also outlined: Active Cavity Radiometer Irradiance Monitor (ARIMSAT), Ocean Topography Experiment (TOPEX/Poseidon), Jason-1 (TOPEX follow-on), and QuikScat/Seawinds (Ocean Winds Tracking). The status, background, and plans are given for several batteries: (1) 2.5 inch common pressure vessel (CPV), (2) 3.5 inch CPV, (3) Ni-H2, and (4) Li-Ion.

Timmerman, Paul J.↗

Electrolytes for Li-Ion Cells in Low Temperature Applications

A number of upcoming NASA missions require energy storage devices which display high energy density and can effectively operate at low temperature. Lithium-ion batteries have been identified as the most promising technology which can meet these stringent requirements.

electrolytes↗

Specification For ST-5 Li Ion Battery

This Specification defines the general requirements for rechargeable Space Flight batteries intended for use in the ST-5 program. The battery chemistry chosen for this mission is lithium ion (Li-Ion).

Castell, Karen D.↗

Improved low temperature performance of lithium ion cells with quaternary carbonate-based electrolytes

In order to enable future missions involving the exploration of the surface of Mars with Landers and Rovers, NASA desires long life, high energy density rechargeable batteries which can operate well at very low temperature (down to 40(deg)C). Lithium-ion technology has been identified as being the most promising chemistry, due to high gravimetric and volumetric energy densities, as well as, long life characteristics. However, the state-of-art (SOA) technology is not sufficient to meet the needs of many applications that require excellent low temperature capabilities. To further improve this technology, work at JF'L has been focused upon developing electrolytes that result in lithium-ion cells with wider temperature ranges of operation. These efforts have led to the identification of a number of ternary and quaternary, all carbonate-based electrolytes that have been demonstrated to result in improved low temperature performance in experimental three-electrode MCMB carbon/LiNio.sCoo.zOz cells. A number of electrochemical characterization techniques were performed on these cells (i.e., Tafel polarization measurements, linear polarization measurements, and electrochemical impedance spectroscopy (EIS)) to further enhance our understanding of the performance limitations at low temperature. The most promising electrolyte formulations, namely 1 .O M LiPF6EC+DEC+DMC+EMC (1 : 1: 1 :2 v/v) and 1 .O M LiPF6 EC+DEC+DMC+EMC (1 : 1 : 1 :3 v/v), were incorporated into SAFT prototype DD-size (9 Ahr) lithium- cells for evaluation. A number of electrical tests were performed on these cells, including rate characterization as a function of temperature, cycle life characterization at different temperatures, as well as, many mission specific characterization test to determine their viability to enable future missions to Mars. Excellent performance was observed with the prototype DD-size cells over a wide temperature range (-50 to 4OoC), with high specific energy being delivered at very low temperatures (i.e, over 95 WHrKg being delivered at 40(deg)C using a C/10 discharge rate).

Li-ion low temperature electrolytes↗

Li-ion cells for terrestrial robots

SAFT prismatic wound 5 Ahr MP series cells were evaluated for potential application in a lithium ion battery designed for Tactical Mobile Robots (TMR). In order to satisfy battery design requirements, a 10 Ahr battery containing two parallel 8-cell strings was proposed. The proposed battery has a weight and volume of approximately 3.2kg and 1.6 liters, respectively. Cell qualification procedures include initial characterization, followed by charge/discharge cycling at 100% DOD with intermittent EIS measurements at various state of charge. Certain cells were also subjected to extreme operational temperatures for worst-case analysis. Excellent specific energy (>130 Whr/kg) was obtained with initial characterization cycles. Even at abusive thermal conditions, the cell capacity fade was less than Ahr after 300 cycles. Rate characterization showed good cell discharge behavior with minimal decrease in capacity. At various state of charge, impedance measurements suggest that the cathode play a more significant role in capacity. At various state of charge impedance measurements suggest that the cathode play a more significant role in capacity fade than the anode.

robots↗