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At least 55 records · Page 3

Phase locking of field sequential color wheel for small TV camera

System employs synchronous motor driven by deflection waveform of TV and connected directly to color filter wheel to phase lock wheel to deflection unit. Innovation stabilizes color response of small TV cameras and allows for small, lightweight installations. Problems associated with motor phase changes are cited.

Niemyer, L. L.↗

SWUIS-A: A Versatile, Low-Cost UV/VIS/IR Imaging System for Airborne Astronomy and Aeronomy Research

We have developed and successfully flight-tested on 14 different airborne missions the hardware and techniques for routinely conducting valuable astronomical and aeronomical observations from high-performance, two-seater military-type aircraft. The SWUIS-A (Southwest Universal Imaging System - Airborne) system consists of an image-intensified CCD camera with broad band response from the near-UV to the near IR, high-quality foreoptics, a miniaturized video recorder, an aircraft-to-camera power and telemetry interface with associated camera controls, and associated cables, filters, and other minor equipment. SWUIS-A's suite of high-quality foreoptics gives it selectable, variable focal length/variable field-of-view capabilities. The SWUIS-A camera frames at 60 Hz video rates, which is a key requirement for both jitter compensation and high time resolution (useful for occultation, lightning, and auroral studies). Broadband SWUIS-A image coadds can exceed a limiting magnitude of V = 10.5 in <1 sec with dark sky conditions. A valuable attribute of SWUIS-A airborne observations is the fact that the astronomer flies with the instrument, thereby providing Space Shuttle-like "payload specialist" capability to "close-the-loop" in real-time on the research done on each research mission. Key advantages of the small, high-performance aircraft on which we can fly SWUIS-A include significant cost savings over larger, more conventional airborne platforms, worldwide basing obviating the need for expensive, campaign-style movement of specialized large aircraft and their logistics support teams, and ultimately faster reaction times to transient events. Compared to ground-based instruments, airborne research platforms offer superior atmospheric transmission, the mobility to reach remote and often-times otherwise unreachable locations over the Earth, and virtually-guaranteed good weather for observing the sky. Compared to space-based instruments, airborne platforms typically offer substantial cost advantages and the freedom to fly along nearly any groundtrack route for transient event tracking such as occultations and eclipses.

Durda, Daniel D.↗

Absolute calibration of optical streak cameras on picosecond time scales using supercontinuum generation

Here we report a new method using high stability, laser-driven supercontinuum generation in a liquid cell to calibrate the absolute photon response of fast optical streak cameras as a function of wavelength when operating at fastest sweep speeds. A stable, pulsed white light source based around the use of self-phase modulation in a salt solution was developed to provide the required brightness on picosecond timescales, enabling streak camera calibration in fully dynamic operation. The measured spectral brightness allowed for absolute photon response calibration over a broad spectral range (425-650nm). Calibrations performed with two Axis Photonique streak cameras using the Photonis P820PSU streak tube demonstrated responses which qualitatively follow the photocathode response. Peak sensitivities were 1 photon/count above background. The absolute dynamic sensitivity is less than the static by up to an order of magnitude. We attribute this to the dynamic response of the phosphor being lower.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Investigation of responsivity and noise in a direct-coupled photodetector-preamplifier for facsimile cameras

The direct-coupled (DC) mode of detector operation is evaluated for use in a facsimile camera. Photodiode-preamplifier sensitivity is described in terms of photodiode responsivity and possible noise sources resulting from the photodiode and preamplifier. Responsivity and noise limitations are experimentally verified and used to predict photodiode-preamplifier sensitivity under a wide range of operating conditions. Results demonstrate that the DC mode offers advantages in sensitivity and reduced mechanical complexity for facsimile cameras over the more common technique of chopping the radiation and ac amplifying the resultant signal.

Kelly, W. L., IV↗

Apparatus for photographing meteors

Apparatus for photographing meteors in a selected area of the sky is described. A photomultiplier is pointed in the direction of the area. When a meteor passes through the area the signal output of the photomultiplier increases. Means are provided that activate a camera, pointed at the area, in response to an increased signal from the photomultiplier. Hence, the camera photographs the selected are only while meteors are likely to be passing through the area.

Harvey, G. A.↗

Low-Earth Flight Test of an Inflatable Decelerator (LOFTID) Aeroshell Flight Performance

On November 10, 2022, NASA launched the Low-earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) vehicle as a secondary payload mounted inside the launch vehicle adaptor on an Atlas V 401 out of the Vandenburg Space Force Base (VSFB). The primary payload, Joint Polar Satellite System-2 (JPSS-2), was delivered successfully to a sun synchronous trajectory shortly after launch, at which point the Centaur upper stage performed a burn to de-orbit the system. Once on the desired trajectory to enter the atmosphere the top of the payload adaptor was ejected to expose the LOFTID vehicle, then the LOFTID aeroshell, a Hypersonic Inflatable Aerodynamic Decelerator (HIAD), was deployed and inflated without issue. The Centaur pointed the LOFTID to the desired attitude to enter the atmosphere, spun the assembly to three rpm, separated the reentry vehicle, and finally performed a collision avoidance maneuver to prevent the Centaur from re-contacting the LOFTID after atmospheric entry. The LOFTID vehicle maintained the design attitude and spin rate from separation to atmospheric entry, roughly 30 minutes, demonstrating the aeroshell did not experience any energy damping from inflatable structure flexibility. The LOFTID vehicle entered the atmosphere over Alaska at >8km/sec and decelerated as designed demonstrating stable flight from hypersonic entry through subsonic parachute deployment. On-board visible light cameras captured the reactions of the heatshield through all phases of flight and co-located infrared light cameras captured the temperature distribution of the aft side of the heat shield anchored to a distribution of thermocouples on the inflatable structure (IS) in the field of view. Thermocouples were also embedded in the forward side of the aeroshell both in the Flexible Thermal Protection System (FTPS) as well as the IS. This presentation will discuss aeroshell response to the atmospheric entry. The visible light cameras captured mechanical response of the IS to the loads applied in the different phases of entry. Events seen on the visible light cameras correlate with the response of the load cell pins on webbing elements that attach the aeroshell to the centerbody structure. Thermocouple data captured verifies the aerothermal response of the aeroshell was in-kind with pre-flight analysis predictions although some-what lower in most locations. This data will allow the improvement of the aeroshell modeling tools predictive capability. Post-flight inspection of the aeroshell after splash down and ocean recovery shows that all the aeroshell materials and manufacturing techniques developed over the past 15 years of HIAD technology development performed as de-signed at large scale, a scale which cannot be replicated in ground test facilities. The HIAD supported the LOFTID vehicle high in the water after touching down under parachute and maintained buoyancy and integrity for the hour it took to position the recovery vessel near the LOFTID after splash down. There was no indication the HIAD would have experienced an issue maintaining buoyancy for many more hours after water impact as the component maintained adequate inflation pressure more than 12 hours after water extraction with no additional inflation gas in tanks, as the inflation gas remaining in the tank was vented prior to impact. The LOFTID aeroshell was an unqualified success and has opened up opportunities for commercial application.

LOFTID Aeroshell Flight Performance↗

Low-Earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) Aeroshell Performance

On November 10, 2022, NASA launched the Low-earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) vehicle as a secondary payload mounted inside the launch vehicle adaptor on an Atlas V 401 out of the Vandenburg Space Force Base (VSFB). The primary payload, Joint Polar Satellite System-2 (JPSS-2), was delivered successfully to a sun synchronous trajectory shortly after launch, at which point the Centaur upper stage performed a burn to de-orbit the system. Once on the desired trajectory to enter the atmosphere the top of the payload adaptor was ejected to expose the LOFTID vehicle, then the LOFTID aeroshell, a Hypersonic Inflatable Aerodynamic Decelerator (HIAD), was deployed and inflated without issue. The Centaur pointed the LOFTID to the desired attitude to enter the atmosphere, spun the assembly to three rpm, separated the reentry vehicle, and finally performed a collision avoidance maneuver to prevent the Centaur from re-contacting the LOFTID after atmospheric entry. The LOFTID vehicle maintained the design attitude and spin rate from separation to atmospheric entry, roughly 30 minutes, demonstrating the aeroshell did not experience any energy damping from inflatable structure flexibility. The LOFTID vehicle entered the atmosphere over Alaska at >8km/sec and decelerated as designed demonstrating stable flight from hypersonic entry through subsonic parachute deployment. On-board visible light cameras captured the reactions of the heatshield through all phases of flight, and co-located infrared light cameras captured the temperature distribution of the aft side of the heat shield anchored to a distribution of thermocouples on the inflatable structure (IS) in the field of view. Thermocouples were also embedded in the forward side of the aeroshell both in the Flexible Thermal Protection System (FTPS) as well as the IS. This paper will discuss aeroshell response to the atmospheric entry. The visible light cameras captured mechanical response of the deployable aeroshell to the loads applied in the different phases of entry. Events seen on the visible light cameras correlate with the response of the load cell pins on webbing elements that attach the aeroshell to the centerbody structure. Thermocouple data captured verifies the aerothermal response of the aeroshell was in-kind with pre-flight analysis predictions although somewhat lower in most locations. This data will allow the improvement of the aeroshell modeling tools predictive capability. Post-flight inspection of the aeroshell after splash down and ocean recovery shows that all the aeroshell materials and manufacturing techniques developed over the past 15 years of HIAD technology development performed as designed at large scale, a scale which cannot be replicated in ground test facilities. The HIAD supported the LOFTID vehicle high in the water after touching down under parachute and maintained buoyancy and integrity for the hour it took to position the recovery vessel near the LOFTID after splash down. There was no indication the HIAD would have experienced an issue maintaining buoyancy for many more hours after water impact as the component maintained adequate inflation pressure more than 24 hours after water extraction with no additional inflation gas in tanks, as the inflation gas remaining in the tank was vented prior to impact.

Entry Descent Landing Atmospheric Entry Deployable↗

Overview and Performance of the LOFTID Instrumentation Suite

NASA’s Hypersonic Inflatable Aerodynamic Decelerator (HIAD) is an enabling technology that facilitates atmospheric entry of heavy payloads to planets such as Earth and Mars using a deployable aeroshell. The deployable nature of the HIAD technology allows it to overcome the size constraints imposed on current rigid aeroshell entry systems. This enables use of larger aeroshells resulting in increased entry system performance (e.g. higher payload mass and/or volume, higher landing altitude at Mars). On November 10th, 2022 the Low-Earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) was launched out of Vandenberg Air Force Base as a secondary payload on an Atlas V rocket. After the primary payload was delivered to its orbit, the LOFTID reentry vehicle was inflated, positioned, and then separated to reenter Earth’s atmosphere at a velocity of 8.1km/s, ultimately splashing down safely in the Pacific Ocean. The flight successfully demonstrated a 6m diameter, 70-deg sphere-cone HIAD on a high-energy orbital reentry. This demonstration has provided invaluable fight data essential to characterize the vehicle performance and support the ongoing effort to further scale the HIAD technology to vehicles of 10m in diameter or greater. Aeroshells of this scale are applicable to near-term commercial applications and future NASA robotic and human exploration missions. LOFTID incorporated an extensive instrumentation suite totaling over 150 science measurements. This included thermocouples, total heat flux sensors, and a radiometer to characterize the aeroheating environment and aeroshell thermal response. An Inertial Measurement Unit (IMU), Global Positioning System (GPS), and flush air data system was included to allow post-flight reconstruction of the vehicle trajectory including a decoupling of the aerodynamics from the atmospheric density. Loadcells were used to measure HIAD structural response during entry, and cameras (both visual-spectrum and infrared) were mounted on the aft segment looking at the aeroshell to monitor structural deflection and surface temperature distribution. Finally, a single up-look camera was included which has provided a surprising amount of science potential from the spectacular footage. In addition to the primary instrumentation suite, a new Fiber Optic Sensing System (FOSS) was used to provide global temperature distributions as a technology demonstration. The system provided over 200 thermal measurements creating a thermal map for the backside of the nose Flexible Thermal Protection System. Another pair of FOSS cables were run along the rigid center structure and measured the temperature response to the vehicle wake environment. The LOFTID instrumentation suite leveraged Agency-wide expertise, with hardware development occurring at Ames Research Center, Langley Research Center, Marshall Space Flight Center, and Armstrong Flight Research Center. This presentation will discuss the instrumentation selected for LOFTID to capture the HIAD performance during the high-energy orbital reentry flight test, provide examples of data products, and snippets of the spectacular reentry video.

G T Swanson↗

Overview and Performance of the LOFTID Instrumentation Suite

NASA’s Hypersonic Inflatable Aerodynamic Decelerator (HIAD) is an enabling technology that facilitates atmospheric entry of heavy payloads to planets such as Earth and Mars using a deployable aeroshell. The deployable nature of the HIAD technology allows it to overcome the size constraints imposed on current rigid aeroshell entry systems. This enables use of larger aeroshells resulting in increased entry system performance (e.g. higher payload mass and/or volume, higher landing altitude at Mars). On November 10th, 2022 the Low-Earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) was launched out of Vandenberg Air Force Base as a secondary payload on an Atlas V rocket. After the primary payload was delivered to its orbit, the LOFTID reentry vehicle was inflated, positioned, and then separated to reenter Earth’s atmosphere at a velocity of 8.1km/s, ultimately splashing down safely in the Pacific Ocean. The flight successfully demonstrated a 6m diameter, 70-deg sphere-cone HIAD on a high-energy orbital reentry. This demonstration has provided invaluable fight data essential to characterize the vehicle performance and support the ongoing effort to further scale the HIAD technology to vehicles of 10m in diameter or greater. Aeroshells of this scale are applicable to near-term commercial applications and future NASA robotic and human exploration missions. LOFTID incorporated an extensive instrumentation suite totaling over 150 science measurements. This included thermocouples, total heat flux sensors, and a radiometer to characterize the aeroheating environment and aeroshell thermal response. An Inertial Measurement Unit (IMU), Global Positioning System (GPS), and flush air data system was included to allow post-flight reconstruction of the vehicle trajectory including a decoupling of the aerodynamics from the atmospheric density. Loadcells were used to measure HIAD structural response during entry, and cameras (both visual-spectrum and infrared) were mounted on the aft segment looking at the aeroshell to monitor structural deflection and surface temperature distribution. Finally, a single up-look camera was included which has provided a surprising amount of science potential from the spectacular footage. In addition to the primary instrumentation suite, a new Fiber Optic Sensing System (FOSS) was used to provide global temperature distributions as a technology demonstration. The system provided over 200 thermal measurements creating a thermal map for the backside of the nose Flexible Thermal Protection System. Another pair of FOSS cables were run along the rigid center structure and measured the temperature response to the vehicle wake environment. The LOFTID instrumentation suite leveraged Agency-wide expertise, with hardware development occurring at Ames Research Center, Langley Research Center, Marshall Space Flight Center, and Armstrong Flight Research Center. This paper will discuss the instrumentation selected for LOFTID, a summary of sensor in-flight performance, and will provide examples of data products from the post-flight analysis effort.

Gregory T Swanson↗

Overview and Performance of the LOFTID Instrumentation Suite

NASA’s Hypersonic Inflatable Aerodynamic Decelerator (HIAD) is an enabling technology that facilitates atmospheric entry of heavy payloads to planets such as Earth and Mars using a deployable aeroshell. The deployable nature of the HIAD technology allows it to overcome the size constraints imposed on current rigid aeroshell entry systems. This enables use of larger aeroshells resulting in increased entry system performance (e.g. higher payload mass and/or volume, higher landing altitude at Mars). On November 10th, 2022 the Low-Earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) was launched out of Vandenberg Air Force Base as a secondary payload on an Atlas V rocket. After the primary payload was delivered to its orbit, the LOFTID reentry vehicle was inflated, positioned, and then separated to reenter Earth’s atmosphere at a velocity of 8.1km/s, ultimately splashing down safely in the Pacific Ocean. The flight successfully demonstrated a 6m diameter, 70-deg sphere-cone HIAD on a high-energy orbital reentry. This demonstration has provided invaluable fight data essential to characterize the vehicle performance and support the ongoing effort to further scale the HIAD technology to vehicles of 10m in diameter or greater. Aeroshells of this scale are applicable to near-term commercial applications and future NASA robotic and human exploration missions. LOFTID incorporated an extensive instrumentation suite totaling over 150 science measurements. This included thermocouples, total heat flux sensors, and a radiometer to characterize the aeroheating environment and aeroshell thermal response. An Inertial Measurement Unit (IMU), Global Positioning System (GPS), and flush air data system was included to allow post-flight reconstruction of the vehicle trajectory including a decoupling of the aerodynamics from the atmospheric density. Loadcells were used to measure HIAD structural response during entry, and cameras (both visual-spectrum and infrared) were mounted on the aft segment looking at the aeroshell to monitor structural deflection and surface temperature distribution. Finally, a single up-look camera was included which has provided a surprising amount of science potential from the spectacular footage. In addition to the primary instrumentation suite, a new Fiber Optic Sensing System (FOSS) was used to provide global temperature distributions as a technology demonstration. The system provided over 200 thermal measurements creating a thermal map for the backside of the nose Flexible Thermal Protection System. Another pair of FOSS cables were run along the rigid center structure and measured the temperature response to the vehicle wake environment. The LOFTID instrumentation suite leveraged Agency-wide expertise, with hardware development occurring at Ames Research Center, Langley Research Center, Marshall Space Flight Center, and Armstrong Flight Research Center. This paper will discuss the instrumentation selected for LOFTID, a summary of sensor in-flight performance, and will provide examples of data products from the post-flight analysis effort.

Greg Swanson↗

U.S. Domestic Security-by-Design: On Site Response Force Strategies

U.S. nuclear power facilities face increasing challenges in meeting dynamic security requirements caused by evolving and expanding threats while keeping cost reasonable to make nuclear energy competitive. The past approach has often included implementing security features after a facility has been designed and without attention to optimization, which can lead to cost overruns. Incorporating security in the design process can provide robust, cost- effective, and sufficient physical protection systems. The purpose of this work is both to develop a framework for the integration of security into the design phase of High Temperature Gas Reactors (HTGRs) that utilize pebble-based fuels and microreactors. Specifically, this effort focuses on integrating security into the design phase of a model HTGR and microreactor that meets current Nuclear Regulatory Commission (NRC) physical protection requirements and providing advanced solutions to improve physical protection and decrease costs. A suite of tools, including SCRIBE3D©, PATHTRACE© and Blender© were used to model a hypothetical, generic domestic HTGR facility and microreactor facility. Physical protection elements such as sensors, cameras, barriers, and onsite response forces were added to the model based on best practices for physical protection systems. Multiple outsider sabotage scenarios were examined with four-to-eight adversaries to determine security metrics. The results of this work will influence physical protection system designs and facility designs for U.S. domestic HTGRs and microreactors. This work will also demonstrate how a series of experimental and modeling capabilities across the Department of Energy (DOE) Complex can lead to efficient security systems that utilize an onsite response force. The conclusions and recommendations in this document may be applicable to all SMR designs.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Image inversion analysis of the HST OTA (Hubble Space Telescope Optical Telescope Assembly), phase A

Technical work during September-December 1990 consisted of: (1) analyzing HST point source images obtained from JPL; (2) retrieving phase information from the images by a direct (noniterative) technique; and (3) characterizing the wavefront aberration due to the errors in the Hubble Space Telescope (HST) mirrors, in a preliminary manner. This work was in support of JPL design of compensating optics for the next generation wide-field planetary camera on HST. This digital technique for phase retrieval from pairs of defocused images, is based on the energy transport equation between these image planes. In addition, an end-to-end wave optics routine, based on the JPL Code 5 prescription of the unaberrated HST and WFPC, was derived for output of the reference phase front when mirror error is absent. Also, the Roddier routine unwrapped the retrieved phase by inserting the required jumps of +/- 2(pi) radians for the sake of smoothness. A least-squares fitting routine, insensitive to phase unwrapping, but nonlinear, was used to obtain estimates of the Zernike polynomial coefficients that describe the aberration. The phase results were close to, but higher than, the expected error in conic constant of the primary mirror suggested by the fossil evidence. The analysis of aberration contributed by the camera itself could be responsible for the small discrepancy, but was not verified by analysis.

Litvak, M. M.↗

The Chandra X-Ray Observatory-Overview and Status

The Chandra X-Ray Observatory was launched early in the morning of 1999, July 23 by the Space Shuttle Columbia. The Shuttle launch was only the first step in placing NASA's latest great observatory into orbit. After release from the cargo bay, the Inertial Upper Stage performed two firings and separated from the observatory as planned. Finally, after five firings of Chandra's own Integral Propulsion System - the last of which took place 15 days after the initial launch - the observatory was placed in its highly elliptical orbit of 140,000 km apogee and 10,000 km perigee. After Observatory activation, the first x-rays focussed by the telescope were observed on 1999, August 12. Beginning with this initial observation one could conclude that the telescope had survived the launch environment and was operating as expected. The month following the opening of the sunshade door was spent adjusting the focus for each set of instrument configurations, determining the optical axis, calibrating the star camera, establishing the relative response functions, determining the energy scale(s), and performing a series of "publicity" images. Each observation proved to be far more revealing than was expected. Preliminary results will be presented and the status of the instrumentation on the observatory will be discussed.

Weisskopf, Martin C.↗

The Chandra X-Ray Observatory Overview

The Chandra X-Ray Observatory was launched early in the morning of July 23, 1999 by the Space Shuttle Columbia. The Shuttle launch was only the first step in placing NASA's latest great observatory into orbit. After release from the cargo bay, the Inertial Upper Stage performed two firings and separated from the observatory as planned. Finally, after five firings of Chandra's own Integral Propulsion System - the last of which took place 15 days after the initial launch - the observatory was placed in its highly elliptical orbit of 140,000 km apogee and 10,000 km perigee. After Observatory activation, the first x-rays focussed by the telescope were observed on August 12, 1999. Beginning with this initial observation one could conclude that the telescope had survived the launch environment and was operating as expected. The month following the opening of the sunshade door was spent adjusting the focus for each set of instrument configurations, determining the optical axis, calibrating the star camera, establishing the relative response functions, determining the energy scale(s), and performing a series of "publicity" images. Each observation proved to be far more revealing than was expected. Preliminary results will be presented and the status of the instrumentation on the observatory will be discussed.

Weisskopf, Martin C.↗

The Chandra X-Ray Observatory: An Overview

The Chandra X-Ray Observatory was launched early in the morning of July 23, 1999, by the Space Shuttle Columbia. The Shuttle launch was only the first step in placing NASA's latest great observatory into orbit. After release from the cargo bay, the Inertial Upper Stage performed two firings and separated from the observatory as planned. Finally, after five firings of Chandra's own Integral Propulsion System - the last of which took place 15 days after the initial launch - the observatory was placed in its highly elliptical orbit of 140,000 km apogee and 10,000 km perigee. After Observatory activation, the first x-rays focussed by the telescope were observed on 1999, August 12. Beginning with this initial observation one could conclude that the telescope had survived the launch environment and was operating as expected. The month following the opening of the sunshade door was spent adjusting the focus for each set of instrument configurations, determining the optical axis, calibrating the star camera, establishing the relative response functions, determining the energy scale(s), and performing a series of "publicity" images. Each observation proved to be far more revealing than was expected. Preliminary results will be presented and the status of the instrumentation on the observatory will be discussed.

Weisskopf, Martin C.↗

The Chandra X-Ray Observatory Overview

The Chandra X-Ray Observatory was launched early in the morning of July 23, 1999 by the Space Shuttle Columbia. The Shuttle launch was only the first step in placing NASA's latest great observatory into orbit. After release from the cargo bay, the Inertial Upper Stage performed two firings and separated from the observatory as planned. Finally, after five firings of Chandra's own Integral Propulsion System - the last of which took place 15 days after the initial launch - the observatory was placed in its highly elliptical orbit of 140,000 km apogee and 10,000 km perigee. After Observatory activation, the first x-rays focused by the telescope were observed on August 12, 1999. Beginning with this initial observation one could conclude that the telescope had survived the launch environment and was operating as expected. The month following the opening of the sunshade door was spent adjusting the focus for each set of instrument configurations, determining the optical axis, calibrating the star camera, establishing the relative response functions, determining the energy scale(s), and performing a series of "publicity" images. Each observation proved to be far more revealing than was expected. Preliminary results will be presented and the status of the instrumentation on the observatory will be discussed.

Weisskopf, Martin C.↗

Characterizing the Quantum-Confined Stark Effect in Semiconductor Quantum Dots and Nanorods for Single-Molecule Electrophysiology

We optimized the performance of quantum-confined Stark effect (QCSE)-based voltage nanosensors. A high-throughput approach for single-particle QCSE characterization was developed and utilized to screen a library of such nanosensors. Type-II ZnSe/CdS-seeded nanorods were found to have the best performance among the different nanosensors evaluated in this work. The degree of correlation between intensity changes and spectral changes of the exciton's emission under an applied field was characterized. An upper limit for the temporal response of individual ZnSe/CdS nanorods to voltage modulation was characterized by high-throughput, high temporal resolution intensity measurements using a novel photon-counting camera. The measured 3.5 μs response time is limited by the voltage modulation electronics and represents ~30 times higher bandwidth than needed for recording an action potential in a neuron.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗