Development of High Capacity Cathodes for Rechargeable Alkaline Zinc Batteries
Poster presentation at DOE OE Peer Review 2024 in Bellevue Washington
Zimmerer, Eric↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Research and development of a high capacity nonaqueous secondary battery second quarterly report
Lithium and copper electrode studies in research and development of high capacity nonaqueous secondary battery
ELECTRODE↗
Technical feasibility study for the development of a large capacity wind powered electrical generating system
The engineering feasibility of developing a basic mechanical system necessary for extracting large amounts of power (on the order of 10 to 20 MW) from the wind is considered using the concept of vertical airfoils moving along a closed horizontal track system. Attention is focused on those components necessary for the conversion of wind energy to mechanical energy, although the general characteristics and critical aspects of other components are also considered. The four phases of this program are: (1) Establishment of component specifications and interface requirements for major system components; (2) formulation of alternative sets of conceptual designs for major system components; (3) engineering analysis of various components and systems; and (4) re-examination of basic concept and identification of any desirable follow-up work.
Powe, R. E.↗
Bench-Scale Development of Promoted High-Capacity Structured Sorbents (Final Technical Report)
The project objective was to develop high-capacity structured sorbent capable of achieving low CO 2 removal from air. The sorbent framework consists of an amine-functionalized onto hydrophobic polymer backbone with an added promoter. The functionalized amine provides high CO 2 capacity and adsorption rates and the polymer backbone to reduce water uptake. For the sorbent development, multiple functionalized amines and promoters were assessed to select a candidate that achieved high CO 2 capacity, high adsorption rate, and high stability. A sorbent-coated filter design was selected as the structured sorbent, which provides high sorbent loading capacity and contains an electrically conductive nonwoven filter substrate that can be Joule-heated to provide efficient utilization of available electricity for sorbent regeneration. A commercial partner operated a pilot filter manufacturing line to produce the filter panels coated with the developed sorbent. A 1 kg CO 2 /day bench unit was designed and fabricated to test the structured filter sorbent. The key achievements from the structured sorbent development activity were demonstrating that existing filter industrial-scale processes can be used for manufacturing Susteon’s structured sorbent and completing a proof-of-concept demonstration of the commercially manufactured structured sorbent filters for CO 2 capture from air with direct, Joule-heated regeneration. A techno-economic assessment with sensitivity analysis was conducted on a 100,000 TPY facility with 85% operating capacity. Through sorbent optimization and process design improvements, it is estimated that the cost of capture was reduced from $\$$349/tCO 2 to $\$$241/tCO 2 . The TEA projects further reductions to $165/tCO 2 through enhancements in CO 2 adsorption rate and sorbent capacity and reducing manufacturing and scale up risks. A life cycle analysis was conducted on the same 100,000 TPY facility and confirmed that the facility’s electricity demand drives its greenhouse gas impact. It was determined that electricity supplied through the current grid mix would result in net-positive CO 2 emissions and that achieving net-negative emissions is only possible by powering the system with renewable electricity or fossil fuel sources equipped with carbon capture and sequestration.
36 MATERIALS SCIENCE↗
NASA's Professional DEVELOPment - Evaluating 10 Weeks of Capacity Building
Under NASA’s Applied Sciences, the NASA DEVELOP Program is centered on dual capacity building. Projects bring together partners and participants to learn how Earth observation data can enhance environmental decision-making practices and inform action. During their time with DEVELOP, participants build technical skills around remotely sensed data and professional skills through interactions with team members, science advisors, and partners. To further refine the participant experience, DEVELOP explores which technical and professional skills individuals report improving during the 10-week program. An analysis of self-reported assessments from 2018 to 2021 included projects that were conducted in-person and virtually. Participants consistently indicated a strong improvement in technical and professional skills yet there was clear variation between in-person and virtual opportunities. When comparing between 2019 and 2021, self-reporting showed a higher percentage of participants reporting an increase in networking in the virtual environment and an increase in building professional relationships with project partners virtually. This analysis suggests that professional opportunities available in the virtual environment may in fact bolster early career scientists’ networking abilities. This presentation will identify DEVELOP’s approach to monitoring and evaluation, highlight interesting trends introduced by the pandemic, and lessons learned.
Sarah Payne↗
Development of High-Capacity Cathodes and Robust Solid Electrolytes
In Phase 1, the University of Texas at Austin explored many methods of cathode design, synthesis, and modification, while also developing an understanding of the relationships among the cathode, anode, and electrolyte. Some of the major accomplishments are highlighted in this report.
25 ENERGY STORAGE↗
Using concentrating-solar-power plants as economic carbon-free capacity resources
Deep decarbonization of electricity systems raises concerns about the need for generating capacity that can maintain reliable energy supply. Given this concern, we explore the ability of concentrating-solar-power plants with thermal energy storage to provide a carbon-free source of such capacity. We develop an approach to assessing the capacity contribution of concentrating-solar-power plants that considers future systems. Such considerations are important, because of potential differences in net-load patterns compared to today (e.g., due to higher renewable-energy penetrations). Using historical data spanning an 18-year period, we demonstrate that concentrating-solar-power plants with thermal energy storage can provide this necessary capacity with little impact on their financial viability. We examine the impact of myopic decisions and imperfect foresight of future system conditions on the operation of concentrating-solar-power plants and the resultant impact on their capacity contributions. We find that imperfect foresight can have limited impacts on such a use of concentrating-solar-power plants, so long as proper forecasting techniques are developed and used. Overall, our work shows that concentrating-solar-power plants with thermal energy storage may have a role to play in delivering reliable electricity supply in a decarbonized energy system.
14 SOLAR ENERGY↗
Review of the development of small- and medium-capacity gas turbines at the Motoren- und Turbinen Union
Small- and medium-capacity gas turbines under development for turboprop aircraft and helicopter, as well as for armored and commercial vehicle propulsion, are discussed. Design problems related to axial turbines, ceramic components, regenerative gas turbines, and the optimal expansion ratios for turbines with capacities from 250 to greater than 800 kW are considered; in addition, combustion chamber technology is mentioned. Prototype gas turbines with capacities of 500 to 600 kW or 800 to 1800 kW are described.
Heilmann, W.↗
NASA DEVELOP’s Approach to Building Capacity to Apply Earth Observations for Coastal and Marine Decision Making
Part of NASA’s Applied Sciences, the DEVELOP Program builds capacity through 10-week interdisciplinary feasibility studies that identify how NASA Earth observations can be integrated into decision making processes. The program is a dual capacity building effort that fosters programmatic participants (early and transitioning career professionals, students, and recent graduates) to apply Earth observations to partner organizations’ decision making needs. The program conducts 50-60 projects annually, with about 10-15% of those focused on coastal and marine community concerns. These projects explore the use of satellite data and model outputs for measuring and mapping shoreline delineation, barrier island transgression, mangrove health and extent, sedimentation and water quality, and tropical cyclone impacts to coastal regions. This presentation will introduce DEVELOP and a series of project case studies, an overview of the organizations engaged and Earth observations utilized, and lessons learned.
Capacity Building↗
Addressing Regulatory Challenges to Tribal Solar Deployment
This project, Addressing Regulatory Challenges to Tribal Solar Deployment, seeks to unlock some of this potential by bringing Tribal, regulatory, utility, and other stakeholders together to articulate key barriers to Tribal solar adoption and develop replicable solutions. By increasing institutional capacity and developing frameworks, trainings, and a technical document repository for regulatory bodies, utilities, and Tribes, this project can help expand an emerging market.
14 SOLAR ENERGY↗
Addressing Regulatory Challenges to Tribal Solar Deployment: Key Findings
Tribal land in the United States represents approximately 2% of the country's total landmass and holds more than 5% of solar photovoltaic potential (Doris, Lopez, and Beckley 2013). This resource is largely untapped. Many Tribes note that regulatory challenges often are roadblocks to taking advantage of solar potential. This report serves as a summary of a larger project, Addressing Regulatory Challenges to Tribal Solar Deployment. The project seeks to unlock some of this potential by bringing Tribal, regulatory, utility, and other stakeholders together to articulate key barriers to Tribal solar adoption and develop replicable solutions. By increasing institutional capacity and developing frameworks, trainings, and a technical document repository for regulatory bodies, utilities, and Tribes, this project can help expand an emerging market.
14 SOLAR ENERGY↗
Reliability model for planetary gear
A reliability model is presented for planetary gear trains in which the ring gear is fixed, the Sun gear is the input, and the planet arm is the output. The input and output shafts are coaxial and the input and output torques are assumed to be coaxial with these shafts. Thrust and side loading are neglected. This type of gear train is commonly used in main rotor transmissions for helicopters and in other applications which require high reductions in speed. The reliability model is based on the Weibull distribution of the individual reliabilities of the transmission components. The transmission's basic dynamic capacity is defined as the input torque which may be applied for one million input rotations of the Sun gear. Load and life are related by a power law. The load life exponent and basic dynamic capacity are developed as functions of the component capacities.
Savage, M.↗
Life and reliability models for helicopter transmissions
Computer models of life and reliability are presented for planetary gear trains with a fixed ring gear, input applied to the sun gear, and output taken from the planet arm. For this transmission the input and output shafts are co-axial and the input and output torques are assumed to be coaxial with these shafts. Thrust and side loading are neglected. The reliability model is based on the Weibull distributions of the individual reliabilities of the in transmission components. The system model is also a Weibull distribution. The load versus life model for the system is a power relationship as the models for the individual components. The load-life exponent and basic dynamic capacity are developed as functions of the components capacities. The models are used to compare three and four planet, 150 kW (200 hp), 5:1 reduction transmissions with 1500 rpm input speed to illustrate their use.
Savage, M.↗
Technology Development of a High-Capacity High-Assay Low Enriched Uranium Transportation Concept
This paper discusses the technology development (TD) efforts that led to the development of a High-Capacity High-Assay Low Enriched Uranium Transportation (HALEU) transportation concept. In 2018, the Department of Energy (DOE) Office of Nuclear Technology and Research Development tasked Idaho National Laboratory (INL) to investigate strategies to transport large quantities of HALEU. To complete this task, INL collaborated with Pacific Northwest National Laboratory and Oak Ridge National Laboratory. The project was completed in 2020, and one of the project outcomes was a transportation concept that consisting of five individual Type B packages transported on a single legal-weight truck (LWT). The total payload capacity of this concept is 1,881 kg (4,149 lb) of HALEU in the form of uranium dioxide (UO2) powder. The concept utilizes an existing Type B packaging design carrying a novel fuel basket design with an incorporated flux trap. The basket can be loaded with 18 individual fuel canisters. The research collaboration investigated the U.S. certification potential of this concept. This part of the project included evaluations of criticality safety, radiological safety, thermal safety, structural integrity, and confinement under hypothetical accident scenarios of transport. The results of these evaluations demonstrated a promising potential for U.S. certification of this concept. Eventually, the described efforts led to the pursuance and issuance of a U.S. patent, thus, protecting the associated intellectual property (IP). Current short-term goals include making this IP available to private industry partners for licensing, directly supporting DOE’s objectives of accelerating commercialization of national laboratory-generated IP. If additional funding becomes available, long-term research goals could include exploring the feasibility of transporting other uranium chemical forms (e.g., UF4) with this concept, or refining operational procedures to load or unload the packagings.
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
Battery500 Consortium: Development of High-Capacity Cathodes and Robust Solid Electrolytes
The goal off this EERE-BMR-Battery 500 consortium project was to provide the supporting science and to lead the Keystone 1 project. Key findings include: identification of 1st cycle loss of high nickel NMC materials as a major opportunity to increase the capacity of these cathode materials. The selective use of substituents and surface coatings was identified as a potential way of decreasing the 1st cycle loss and in increasing capacity retention. Niobium at around the 1% level was found to be optimum. In addition, operando DSC was utilized to scope out the stability range of electrolytes developed by the Battery 500 team.
25 ENERGY STORAGE↗
Development of a high capacity toroidal Ni/Cd cell
A nickel cadmium battery design which can offer better thermal management, higher energy density and much lower cost than the state-of-the-art is emphasized. A toroidal Ni/Cd cell concept is described. It was critically reviewed and used to develop two cell designs for practical implementation. One is a double swaged and the other a swaged welded configuration.
Holleck, G. L.↗
Development of a high capacity bubble domain memory element and related epitaxial garnet materials for application in spacecraft data recorders. Item 2: The optimization of material-device parameters for application in bubble domain memory elements for spacecraft data recorders
Bubble domain materials and devices are discussed. One of the materials development goals was a materials system suitable for operation of 16 micrometer period bubble domain devices at 150 kHz over the temperature range -10 C to +60 C. Several material compositions and hard bubble suppression techniques were characterized and the most promising candidates were evaluated in device structures. The technique of pulsed laser stroboscopic microscopy was used to characterize bubble dynamic properties and device performance at 150 kHz. Techniques for large area LPE film growth were developed as a separate task. Device studies included detector optimization, passive replicator design and test and on-chip bridge evaluation. As a technology demonstration an 8 chip memory cell was designed, tested and delivered. The memory elements used in the cell were 10 kilobit serial registers.
Besser, P. J.↗
Makah Tribe Strategic Energy Plan
The U.S. Department of Energy’s (DOE) Energy Transitions Initiative Partnership Project (ETIPP) connects remote and island communities, regional partners, and the DOE national laboratories to support communities as they seek to build resilience in their energy systems. The Makah Tribe faces several energy challenges, including frequent power outages and the potential for an extended outage due to an earthquake or tsunami. The Tribe joined ETIPP in 2022 to address those challenges, seeking to build energy resilience and sovereignty in the community. The Makah Tribe, Spark Northwest, the Pacific Northwest National Laboratory (PNNL), and the National Renewable Energy Laboratory (NREL) collaborated to develop a strategic energy plan as part of the second cohort of ETIPP communities. The long-term energy vision of the Makah Tribe includes increasing energy efficiency in the community, improving energy management capacity, and developing the renewable energy generation and storage sufficient to independently power the Reservation for one year. Additionally, the ETIPP team worked with Makah leadership, staff, and community members to identify a set of community priorities, values, and goals to guide energy development as the Tribe takes the incremental steps toward their vision for energy sovereignty. Those energy values include ecosystem-based management, energy sovereignty and project ownership, workforce development and capacity, economic opportunity, community wellbeing and priorities, and emergency disaster resilience. To understand what would be needed for a year for energy independence, the PNNL team conducted an assessment to determine the current energy usage of the Tribe and also modeled several scenarios for future energy use. Using the energy usage values, the team estimated how two types of renewable energy technology, specifically locally deployed solar and small-scale wind, could contribute towards the energy independence goal. The energy baseline and resource assessment produced the following key findings:
29 ENERGY PLANNING, POLICY, AND ECONOMY↗