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At least 55 records · Page 3

Biotube

Biotube was developed for plant gravitropic research investigating the potential for magnetic fields to orient plant roots as they grow in microgravity. Prior to flight, experimental seeds are placed into seed cassettes, that are capable of containing up to 10 seeds, and inserted between two magnets located within one of three Magnetic Field Chamber (MFC). Biotube is stored within an International Space Station (ISS) stowage locker and provides three levels of containment for chemical fixatives. Features include monitoring of temperature, fixative/ preservative delivery to specimens, and real-time video imaging downlink. Biotube's primary subsystems are: (1) The Water Delivery System that automatically activates and controls the delivery of water (to initiate seed germination). (2) The Fixative Storage and Delivery System that stores and delivers chemical fixative or RNA later to each seed cassette. (3) The Digital Imaging System consisting of 4 charge-coupled device (CCD) cameras, a video multiplexer, a lighting multiplexer, and 16 infrared light-emitting diodes (LEDs) that provide illumination while the photos are being captured. (4) The Command and Data Management System that provides overall control of the integrated subsystems, graphical user interface, system status and error message display, image display, and other functions.

Biotube↗

Chemistry-Climate Interactions in the Goddard Institute for Space Studies General Circulation Model: New Insights into Modeling the Pre-Industrial Atmosphere - 2

We investigate the chemical (hydroxyl and ozone) and dynamical response to changing from present day to pre-industrial conditions in the Goddard Institute for Space Studies General Circulation Model (GISS GMC). We identify three main improvements not included by many other works. Firstly, our model includes interactive cloud calculations. Secondly we reduce sulfate aerosol which impacts NOx partitioning hence Ox distributions. Thirdly we reduce sea surface temperatures and increase ocean ice coverage which impact water vapor and ground albedo respectively. Changing the ocean data (hence water vapor and ozone) produces a potentially important feedback between the Hadley circulation and convective cloud cover. Our present day run (run 1, control run) global mean OH value was 9.8 x 10(exp 5) molecules/cc. For our best estimate of pre-industrial conditions run (run 2) which featured modified chemical emissions, sulfate aerosol and sea surface temperatures/ocean ice, this value changed to 10.2 x 10(exp 5) molecules/cc. Reducing only the chemical emissions to pre-industrial levels in run 1 (run 3) resulted in this value increasing to 10.6 x 10(exp 5) molecules/cc. Reducing the sulfate in run 3 to pre-industrial levels (run 4) resulted in a small increase in global mean OH (10.7 x 10(exp 5) molecules/cc). Changing the ocean data in run 4 to pre-industrial levels (run 5) led to a reduction in this value to 10.3 x 10(exp 5) molecules/cc. Mean tropospheric ozone burdens were 262, 181, 180, 180, and 182 Tg for runs 1-5 respectively.

Grenfell, J. Lee↗

Nature of quasi-stellar objects

Quasar properties from cosmological nature, discussing red shift, luminosity, radiation intensity, absorption features, distribution, chemical composition, etc

Burbidge, G. R.↗

Plasma chemistry and organic synthesis

The characteristic features of chemical reactions using low temperature plasmas are described and differentiated from those seen in other reaction systems. A number of examples of applications of plasma chemistry to synthetic reactions are mentioned. The production of amino acids by discharge reactions in hydrocarbon-ammonia-water systems is discussed, and its implications for the origins of life are mentioned.

Tezuka, M.↗

Reacting flows

Features of chemically reacting separated hypersonic flows are identified and issues concerning their analysis and simulation are discussed. Emphasis is placed on flows of high temperature dissociating and ionizing air and current methods for studying and characterizing these flows, including separation, are reviewed. The aeroassist orbital transfer vehicle and its flight trajectory are used for illustration. Thermochemical nonequilibrium phenomena are emphasized and extension of continuum analysis to the high altitude slip-flow regime is considered.

Deiwert, George S.↗

Coronagraphic Observations of the Lunar Sodium Exosphere Near the Lunar Surface

The sodium exosphere of the Moon was observed using a solar coronagraph to occult the illuminated surface of the Moon. Exceptionally dust-free atmospheric conditions were required to allow the faint emission from sunlight scattered by lunar sodium atoms to be distinguished from moonlight scattered from atmospheric dust. At 0300 UT on April 22, 1994, ideal conditions prevailed for a few hours, and one excellent image of the sodium exosphere was measured, with the Moon at a phase angle of 51 deg, 81 % illuminated. Analysis of the image data showed that the weighted mean temperature of the exosphere was 1280 K and that the sodium column density varied approximately as cosine-cubed of the latitude. A cosine-cubed variation is an unexpected result, since the flux per unit area of solar photons and solar particles varies as the cosine of latitude. It is suggested that this can be explained by a temperature dependence for the sputtering of sodium atoms from the surface. This is a characteristic feature of chemical sputtering, which has been previously proposed to explain the sodium exosphere of Mercury. A possible interaction between chemical sputtering and solar photons is suggested.

Potter, A. E.↗

Capsule Aerothermodynamics. CFD Prediction Methodology; Database for CFD Validation; Capsule Flight Programs: AFE and Apollo Lessons Learned

Features of chemically reacting separated hypersonic flows are identified and issues concerning their analysis and simulation are discussed. Emphasis is placed on flows of high temperature dissociating and ionizing air and current methods for studying and characterizing these flows, including separation, are reviewed. The aeroassist orbital transfer vehicle and its flight trajectory are used for illustration. Thermochemical nonequilibrium phenomena are emphasized and extension of continuum analysis to the high altitude slip-flow regime is considered.

Deiwert, George S.↗

Complex Formation History of Highly Evolved Basaltic Shergottite, Zagami

Zagami, a basaltic shergottite, contains several kinds of lithologies such as Normal Zagami consisting of Fine-grained (FG) and Coarse-grained (CG), Dark Mottled lithology (DML), and Olivine-rich late-stage melt pocket (DN). Treiman and Sutton concluded that Zagami (Normal Zagami) is a fractional crystallization product from a single magma. It has been suggested that there were two igneous stages (deep magma chamber and shallow magma chamber or surface lava flow) on the basis of chemical zoning features of pyroxenes which have homogeneous Mg-rich cores and FeO, CaO zoning at the rims. Nyquist et al. reported that FG has a different initial Sr isotopic ratio than CG and DML, and suggested the possibility of magma mixing on Mars. Here we report new results of petrology and mineralogy for DML and the Olivine-rich lithology (we do not use DN here), the most evolved lithology in this rock, to understand the relationship among lithologies and reveal Zagami s formation history

Niihara, T.↗

Investigating the Geological History of Asteroid 101955 Bennu Through Remote Sensing and Returned Sample Analyses

The NASA New Frontiers Mission OSRIS-REx will return surface regolith samples from near-Earth asteroid 101955 Bennu in September 2023. This target is classified as a B-type asteroid and is spectrally similar to CI and CM chondrite meteorites [1]. The returned samples are thus expected to contain primitive ancient Solar System materials that formed in planetary, nebular, interstellar, and circumstellar environments. Laboratory studies of primitive astromaterials have yielded detailed constraints on the origins, properties, and evolutionary histories of a wide range of Solar System bodies. Yet, the parent bodies of meteorites and cosmic dust are generally unknown, genetic and evolutionary relationships among asteroids and comets are unsettled, and links between laboratory and remote observations remain tenuous. The OSIRIS-REx mission will offer the opportunity to coordinate detailed laboratory analyses of asteroidal materials with known and well characterized geological context from which the samples originated. A primary goal of the OSIRIS-REx mission will be to provide detailed constraints on the origin and geological and dynamical history of Bennu through coordinated analytical studies of the returned samples. These microanalytical studies will be placed in geological context through an extensive orbital remote sensing campaign that will characterize the global geological features and chemical diversity of Bennu. The first views of the asteroid surface and of the returned samples will undoubtedly bring remarkable surprises. However, a wealth of laboratory studies of meteorites and spacecraft encounters with primitive bodies provides a useful framework to formulate priority scientific questions and effective analytical approaches well before the samples are returned. Here we summarize our approach to unraveling the geological history of Bennu through returned sample analyses.

Messenger, S.↗

SIMS chemical and isotopic analysis of impact features from LDEF experiments AO187-1 and AO187-2

Previous secondary ion mass spectrometry (SIMS) studies of extended impact features from LDEF capture cell experiment AO187-2 showed that it is possible to distinguish natural and man-made particle impacts based on the chemical composition of projectile residues. The same measurement technique has now been applied to specially prepared gold target impacts from experiment AO187-1 in order to identify the origins of projectiles that left deposits too thin to be analyzed by conventional energy-dispersive x-ray (EDX) spectroscopy. The results indicate that SIMS may be the method of choice for the analysis of impact deposits on a variety of sample surfaces. SIMS was also used to determine the isotopic compositions of impact residues from several natural projectiles. Within the precision of the measurements all analyzed residues show isotopically normal compositions.

Stadermann, Frank J.↗

Chemical state of pre-solar matter

Consideration is given to several features of the chemical state of interstellar matter that may be relevant to the observed properties of chondrules if they are formed from aggregates of pre-existing particles. First, a brief summary of the numbers and types of interstellar particles as indicated by the extinction of starlight is given. Second, a model of the free decay interval required by the low solar abundance of 129-I is advanced. This model can support variations in the 129-I/127-I ratio that are larger than typical isotopic anomalies. Third, a new steady-state model of the chemical state of the interstellar medium is presented as a first step toward a quantitative distribution of the abundances among different chemical forms. Last, the advantages of fusing chondrules from aggregates of pre-solar dust by the action of exothermic chemistry are enumerated.

Clayton, D. D.↗

Moessbauer spectrometer for mineralogical analysis of the Mars surface: Moessbauer source considerations

Development of space rocketry and cosmic instrument making has made it possible to create interplanetary stations to be sent to the solar system bodies. In the last decade of the century the planet Mars will be in the focus of planetary science problems. Russia, USA (the NASA) and Europe (the ESA) plan to do a new step in the study of the planetary system by spacecraft missions to Mars. One part of the programs of these missions is Martian surface measurements of iron, which is a dominant element in both the Martian soil and rocks (about 13 percent by weight). The chemistry of iron in space is strongly coupled to the chemistry of abundant elements (to begin with hydrogen, carbon, oxygen) and it is this coupling of chemical cycles of abundant elements that gives us the possibility of understanding some features of the chemical evolution of matter. In this connection of extremely great importance for the understanding of the evolution of the solar system are the oxidation state of the iron and its mineral composition of the Mars surface. Being highly successful, the Viking landers had no instrumentation to answer these questions. Such instrumentation has to be specifically sensitive to mineralogy. For this purpose the back scattering Moessbauer spectrometer (MS-96) was proposed to be installed on a rover to be launched on board the Russian spacecraft Mars-96 mission to Mars. Due to power and mass restrictions three systems of the device MS-96 (velocity transducer, detector and electronic components) have been extremely miniaturized in comparison to a standard system. In this paper we intend to place for consideration a radioactive source to find out what characteristics it should have to be suitable for purposes of the experiment.

Evlanov, E. N.↗

Is Tridymite at Gale Crater Evidence for Silicic Volcanism on Mars?

The X-ray diffraction (XRD) instrument (CheMin) onboard the MSL rover Curiosity detected 17 wt% of the SiO2 polymorph tridymite (relative to bulk sample) for the Buckskin drill sample (73 wt% SiO2) obtained from sedimentary rock in the Murray formation at Gale Crater, Mars. Other detected crystalline materials are plagioclase, sanidine, cristobalite, cation-deficient magnetite, and anhydrite. XRD amorphous material constitutes approx. 60 wt% of bulk sample, and the position of its broad diffraction peak near approx. 26 deg. 2-theta is consistent with opal-A. Tridymite is a lowpressure, high-temperature mineral (approx. 870 to 1670 deg. C) whose XRD-identified occurrence on the Earth is usually associated with silicic (e.g., rhyolitic) volcanism. High SiO2 deposits have been detected at Gale crater by remote sensing from martian orbit and interpreted as opal-A on the basis H2O and Si-OH spectral features. Proposed opal-A formation pathways include precipitation of silica from lake waters and high-SiO2 residues of acid-sulfate leaching. Tridymite is nominally anhydrous and would not exhibit these spectral features. We have chemically and spectrally analyzed rhyolitic samples from New Mexico and Iwodake volcano (Japan). The glassy (by XRD) NM samples have H2O spectral features similar to opal-A. The Iwodake sample, which has been subjected to high-temperature acid sulfate leaching, also has H2O spectral features similar to opal-A. The Iwodake sample has approx. 98 wt% SiO2 and 1% wt% TiO2 (by XRF), tridymite (>80 wt.% of crystalline material without detectable quartz by XRD), and H2O and Si-OH spectral features. These results open the working hypothesis that the opal-A-like high-SiO2 deposits at Gale crater detected from martian orbit are products of alteration associated with silicic volcanism. The presence or absence of tridymite will depend on lava crystallization temperatures (NM) and post crystallization alteration temperatures (Iwodake).

Morris, Richard V.↗

Upper limit to the mass of pulsationally stable stars with uniform chemical composition

Nuclear-energized pulsational instability is a well-known feature of models of chemically homogeneous stars above a critical mass. With the Rogers-Iglesias opacities, the instability occurs above 120-150 solar mass for normal Galactic Population I chemical compositions, and above approximately 90 solar mass for stars in metal-poor environments like the outer Galaxy and the Small Magellanic Cloud. Models of homogeneous helium-burning stars are unstable above masses of 19 and 14 solar mass, respectively. These significant increases of the critical masses, in the normal metallicity cases, over the values derived previously with the Los Alamos opacities can explain the stability of the brightest observed O-type stars, but they do not exclude the possibility that the most luminous hydrogen-deficient Wolf-Rayet stars are experiencing this type of instability.

Stothers, Richard B.↗

Melas Chasma: A Mars Pathfinder view of Valles Marineris

A Mars Pathfinder landing site in Melas Chasma (Valles Marineris) would yield significant science return, but is outside present mission constraints. In Melas Chasma, Mars Pathfinder could investigate minimally altered basaltic material, sedimentary deposits, chemical weathering, tectonic features, the highland crust, equatorial weather, and Valles mists. Critical issues include the following: (1) nature and the origin of the Valles interior layered deposits, important for understanding water as a sedimentary and chemical agent, and for the past existence of of environments favorable for life; (2) compositions of little-altered basaltic sands, important for understanding magma genesis and weathering on Mars, and the martian meteorites; and (3) structure and composition of the highland crust, important for understanding Mars' early history .

Treiman, Allan H.↗

Dust in the solar nebula

The chemical and mineralogical features of the white, Ca-rich inclusions in Allende and other carbonaceous chondrites are strikingly similar to those predicted from thermodynamic models for the highest temperature condensates from the solar nebula. Many of the physical and chemical properties of the chondritic minerals may thus be quite like those of the dust in interstellar regions. The oxygen isotopic composition of meteoritic condensates suggests that they contain a component of interstellar dust that survived the birth of the solar system.

Grossman, L.↗

Primitive material surviving in chondrites - Matrix

A logical place to search for surviving pristine nebular material is in the fine-grained matrices of ordinary and carbonaceous chondrites of petrographic type 3. Unfortunately, many of these chondrites have experienced brecciation, thermal metamorphism, and aqueous alteration, so that interpreting individual features in terms of specific nebular conditions and/or processes is difficult. It follows that the origin and evolutionary history of such matrix phases are controversial, and a consensus is difficult to define. In this chapter, therefore, after summarizing the salient mineralogical, petrographic, chemical, and isotopic features of matrix in apparently primitive chondrites, an attempt is made to provide an overview both of areas of agreement and of topics that are currently in dispute.

Scott, E. R. D.↗