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Amino Acid Chemistry as a Link Between Small Solar System Bodies and Carbonaceous Chondrites

Establishing chemical links between meteorites and small solar system bodies, such as comets and asteroids, provides a tool for investigating the processes that occurred during the formation of the solar system. Carbonaceous meteorites are of particular interest, since they may have seeded the early Earth with a variety of prebiotic organic compounds including amino acids, purines and pyrimidines, which are thought to be necessary for the origin of life. Here we report the results of high-performance liquid chromatography (HPLC) based amino acid analyses of the acid-hydrolyzed hot water extracts from pristine interior pieces of the CI carbonaceous chondrites Orgueil and Ivuna and the CM meteorites Murchison and Murray. We found that the CI meteorites Orgueil and Ivuna contained high abundances of beta-alanine and glycine, while only traces of other amino acids like alanine, alpha-amino-n-butryic acid (ABA) and alpha-aminoisobutyric acid (AIB) were detected in these meteorites. Carbon isotopic measurements of beta-alanine and glycine in Orgueil by gas chromatography combustion-isotope ratio mass spectrometry clearly indicate an extraterrestrial origin of these amino acids. The amino acid composition of Orgueil and Ivuna was strikingly different from the CM chondrites Murchison and Murray. The most notable difference was the high relative abundance of B-alanine in Orgueil and Ivuna compared to Murchison and Murray. Furthermore, AIB, which is one of the most abundant amino acids found in Murchison and Murray, was present in only trace amounts in Orgueil and Ivuna. Our amino acid data strongly suggest that the CI meteorites Orgueil and Ivuna came from a different type of parent body than the CM meteorites Murchison and Murray, possibly from an extinct comet. It is generally thought that carbonaceous meteorites are fragments of larger asteroidal bodies delivered via near Earth objects (NEO). Orbital and dynamic studies suggest that both fragments of main belt asteroids and comets replenish the NEO population, therefore extinct comets may contribute up to half of all NEO's. A comparison of an amino acid analysis of a returned NEO sample to CI and CM carbonaceous chondrites would help establish a link between small solar system bodies and meteorites. Based on our amino acid measurements of CI and CM chondrites, amino acid chemistry can be included as an additional set of criteria to constrain the nature of meteorite parent bodies.

Glavin, Daniel P.↗

Review of results on Halley's comet

Since its recovery in 1982, Comet Halley has been the focus of an unparalleled global scientific effort of exploration. Remote and in situ measurements were conducted from the ground, from earth orbit, from Venus orbit, from interplanetary space, and from the comet itself. Many discoveries, such as the presence of an unexpectedly large and dark nucleus or the abundance of organic material, have led to major changes in the ideas about the general nature of comets. In this report, results of various studies are summarized.

Rahe, Jurgen↗

The in-situ cometary particulate size distribution measured for one comet: P/Halley

The close approach of Giotto to comet Halley during its 1986 apparition offered an opportunity to study the particulate mass distribution to masses of up to one gram. Data acquired by the front end channels of the highly sensitive mass spectrometer PIA and the dust shield detector system, DIDSY, provide definition to the detected distribution as close as 1000 km to the nucleus. Dynamic motion of the particulates after emission leads to a spatial differentiation affecting the size distribution in several forms: (1) ejecta velocity dispersion; (2) radiation pressure; (3) varying heliocentric distance; and (4) anisotropic nucleus emission. Transformation of the in-situ distribution from PIA and DIDSY weighted heavily by the near-nucleus fluxes leads to a presumed nucleus distribution. The data lead to a puzzling distribution at large masses, not readily explained in an otherwise monotonous power law distribution. Although temporal changes in nucleus activity could and do modify the in-situ size distribution, such an explanation is not wholly possible, because the same form is observed at differing locations in the coma where the time of flight from the nucleus greatly varies. Thus neither a general change in comet activity nor spatial variations lead to a satisfactory explanation.

Mcdonnell, J. A. M.↗

Distribution and activity of discrete emission areas on the nucleus of periodic Comet Swift-Tuttle

A general model is proposed which accounts for the dynamical evolution of the observed jets, envelopes and tail bands of periodic Comet Swift-Tuttle, the parent comet of the Perseid meteor stream, in terms of dust ejection from discrete active regions on the rotating nucleus. High-resolution drawings and measurements of cometary jets made upon the comet's first appearance in 1862 are used to infer a nuclear rotation period of 2.77 days, obliquity of 80 deg, and spin axis orientation with respect to the solar direction of 60 deg. The observed jets are attributed to eight discrete active regions covering not more than 1% of the cometary surface and producing bursts of duration of about 0.1 day. Calculations show that waning dust jets develop into envelopes and that old envelopes in turn become the observed tail bands. No evidence of truly violent explosions is found, and effects of active region outgassing on cometary orbital motion are negligible. Potential applications of the model to periodic Comet Halley and other comets are noted.

Sekanina, Z.↗

Reality of comet nucleus.

The prime problem of a comet mission must be to settle whether the cometary nucleus has an actual tangible material existence, or whether it arises from some optical effect present only at times within comets. The absence of any large particles in a comet seems to be demonstrated by certain meteor showers. A feature that would seem to indicate that a comet consists primarily of a swarm of particles is that the coma in general contracts as the comet approaches the sun, roughly in proportion within the distance, and then expands again as it recedes.

Lyttleton, R. A.↗

The chemistry of comets

Comets appear to represent a population of rather homogeneous objects. In particular, the original size distribution peaks at a mean diameter of the order of 10 km. Cometary dust grains appear to be made of clusters of extremely fine particles (0.1-1.0 micron) sintered by heat at a variable degree during their perihelion passages. The brightness laws of comets appear to be derived only by the sublimation of water ice or at least of gas hydrates of the clathrate type. Pristine nuclei are likely to be radially undifferentiated; only their crustal surface must be outgassed and sintered by the heat of perihelion passages. Comet Halley is confirmed to be in the same general class as the bright comets of the 1970s. With an organic fraction of 33 percent in the cometary dust, the carbon of Comet Halley is close to cosmic abundances.

Delsemme, A. H.↗

Physical mechanism of comet outbursts - An experimental result

Attention is given to an experimental investigation of the physical mechanism of comet outbursts which is consistent with the general picture of mantle presence on comets and clarifies the relation of mantles to eruptive activity. The experiment and closeup observation of Comet P/Halley suggest a result different from most mathematical models in that the release of gas pressure does not occur only from uniform gas flow out of the entire surface. In some active comets near perihelion within a few AU of the sun, gas production rates and disturbance of the surface may be so high that the outflow is nearly continuous, with the regolith being entirely stripped away, as in many of the models. The present model provides a cyclic eruption and recharge mechanism which is lacking in most other models.

Hartmann, William K.↗

Annealing of Silicate Dust by Nebular Shocks at 10 AU

Silicate dust grains in the interstellar medium are known to be mostly amorphous, yet crystalline silicate grains have been observed in many long-period comets and in protoplanetary disks. Annealing of amorphous silicate grains into crystalline grains requires temperatures greater than or approximately equal to 1000 K, but exposure of dust grains in comets to such high temperatures is apparently incompatible with the generally low temperatures experienced by comets. This has led to the proposal of models in which dust grains were thermally processed near the protoSun, then underwent considerable radial transport until they reached the gas giant planet region where the long-period comets originated. We hypothesize instead that silicate dust grains were annealed in situ, by shock waves triggered by gravitational instabilities. We assume a shock speed of 5 km/s, a plausible value for shocks driven by gravitational instabilities. We calculate the peak temperatures of pyroxene grains under conditions typical in protoplanetary disks at 5-10 AU. We show that in situ annealing of micron-sized dust grains can occur, obviating the need for large-scale radial transport.

Harker, David E.↗

Plasma-tail activity and the interplanetary medium at Halley's Comet during Armada Week: 6-14 March 1986

The encounters of five spacecraft with Halley's Comet during 6-14 March 1986 offered a unique opportunity to calibrate the solar-wind interaction with cometary plasmas as recorded by remote wide-field and narrow-field/narrowband imaging. Perhaps not generally recognized in the comet community is the additional opportunity offered by the Halley Armada to study the structure of the solar-wind and interplanetary magnetic field (IMF) in three dimensions using five sets of data obtained over similar time intervals and heliocentric distances, but at somewhat different heliolatitudes. In fact, the two problems, i.e., comet physics and the structure of the interplanetary medium, are coupled if one wants to understand what conditions pertained at the comet between the encounters. This relationship is discussed.

Niedner, Malcolm B., Jr.↗

A New Era of Nuclear Criticality Experiments: The First 10 Years of Comet Operations at NCERC

Comet is a general-purpose, heavy-duty, vertical-lift assembly designed for flexibility in conducting a variety of critical experiments. It is currently located at the National Criticality Experiments Research Center (NCERC) in Nevada. In the past, Comet resided at Technical Area-18 in Los Alamos, New Mexico, as part of the Los Alamos Critical Experiments Facility (LACEF). The Comet assembly was relocated to NCERC in 2008 and became fully operational in June of 2011. The first critical experiment performed on Comet at NCERC was a verification of one of the previous configurations of the Zeus experiment series. Over the next 10 years, many additional experiments followed including other Zeus configurations as well as completely new designs. This paper discusses the Comet vertical-lift assembly, the transition from LACEF to NCERC, and a selection of experiments that have been performed on Comet during its first 10 years of operation at NCERC.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Measurements of thermal ion energy spectra from the Giotto encounter with Comet Halley

Ram ion measurements made by the Giotto neutral mass spectrometer show the spatial evolution of the composition and energy spectrum of coma ions. Near the nucleus the plasma is cold and has many constituents, but at distances of the order of 200,000 km the main ions are the terminal products of water dissociation, H(+) and O(+). The ion velocity distribution at the time of the Giotto encounter is highly anisotropic. Ion flow is generally away from the comet with energies increasing with distance to the order of 100 eV in the comet frame of reference. Similarities in the proton and oxygen ion energy spectra in the comet frame suggest an acceleration mechanism other than v x B pickup.

Hodges, R. R.↗

Structures far from the head of comet Kohoutek. II - A discussion of the Swan Cloud of January 11 and of the general morphology of cometary plasma tails

Photographs show that the 'Swan Cloud' observed in comet Kohoutek on January 11, 1974 was an advanced stage of a plasma tail disconnection event, of which the rejected tail appeared to decelerate as it receded from the head. The event commenced with the development of strong tail ray activity followed by the actual tail disconnection, the merging of the disconnected tail with the new tail to form the Swan and the formation of arcade loops in the space between closing tail rays. The observed morphological sequence is easily understood in the sector boundary model (Niedner et al., 1978), and the arcade loops are proposed to be reconnected flux tubes between oppositely polarized tail rays in the incipient new tail which followed the disconnection

Niedner, M. B., Jr.↗

Halley's comet and plans for its observation during its return in 1986

The general characteristics and properties of Halley's comet, as they can be derived from earlier apparitions, are briefly discussed. Consideration is given to historical data on the comet, orbital characteristics, and physical characteristics, including the estimated diameter and density of nucleus, rotation period, observed spectra, tails, and associated meteor streams. The coming 1985/86 apparition is then discussed together with planned space missions for in situ observations. Finally, the major goals of the International Halley Watch, a comprehensive program to prepare for the next apparition of Halley's comet, are reviewed.

Rahe, J.↗

Long-slit ultraviolet spectroscopy of Comet Austin (1990 V)

The spatial distributions of the brightest features in the far-UV spectrum of Comet Austin were measured, and it is found that they are generally similar to those found for Comet Halley during two rocket observations in 1986. As in Halley, the CO profile can be fit to a radial outflow profile for a source whose size is smaller than the instrumental spatial resolution. Neither the shape nor the magnitude of the extended atomic carbon profiles, however, can be satisfactorily explained by the photodissociation of CO. No evidence is found for an extended source of CO in the coma; thus, suggestions that the additional carbon can come directly from grains are difficult to accept since Austin is a low-dust comet. The presence of the O I 1356 A feature implies that there is a photoelectron excitation source in the coma. The measured O I 1304 A distribution is consistent with H2O being the dominant source of oxygen in the coma. The atomic sulfur profile matches that expected for a daughter product of relatively short-lived parents.

Sahnow, David J.↗

Possible influence of comets on the chemical evolution of the galaxy

It has been suggested by Cameron (1973) that a cloud of comets containing a mass of condensable elements, comparable to the mass of such elements in the sun, formed on the outskirts of the solar system. If the formation of such comet clouds is a general feature of star formation, they constitute a significant sink of elements heavier than helium. It is shown here that this process provides a possible explanation for the very slow rate at which the mean metal abundance of disk stars has increased during the lifetime of the Galaxy.

Tinsley, B. M.↗

The roots of coronal structure in the Sun's surface

We have compared the structures seen on X-ray images obtained by a flight of the NIXT sounding rocket payload on July 11, 1991 with near-simultaneous photospheric and chromospheric structures and magnetic fields observed at Big Bear. The X-ray images reflect emission of both Mg X and Fe XVI, formed at 1 x 10(exp 6) K and 3 x 10(exp 6) K, respectively. The brightest H(alpha) sources correspond to a dying sub-flare and other active region components, all of which reveal coronal enhancements situated spatially well above the H(alpha) emission. The arches appear to lie in a small range of angle in the meridian plane connecting their footpoints. Sunspots are dark on the surface and in the corona. For the first time we see an emerging flux region in X-rays and find the emission extends twice as high as the H(alpha) arches. Many features which we believe to correspond to `X-ray bright points' (XBPs) were observed. Whether by resolution or spectral band, the number detected greatly exceeds that from previous work. All of the brighter XBPs correspond to bipolar H(alpha) features, while unipolar H(alpha) bright points are the base of more diffuse comet-like coronal arches, generally vertical. These diverge from individual features by less than 30 deg, and give a good measure of what the `canopies' must do. The H(alpha) data shows that all the H(alpha) features were present present the entire day, so they are not clearly disappearing or reappearing. We find a new class of XBPs which we call `satellite points', elements of opposite polarity linked to nearby umbrae by invisible field lines. The satellite points change rapidly in X-ray brightness during the flight. An M1.9 flare occurred four hours after the flight; examination of the pre-flare structures reveals nothing unusual.

Golub, Leon↗

Estimates of Comet Fragment Masses from Impact Crater Chains on Callisto and Ganymede

Chains of impact craters, or catenae, have been identified in Voyager images of Callisto and Ganymede. Although these resemble in some respects secondary crater chains, the source craters and basins for the catenae cannot be identified. The best explanation is a phenomenon similar to that displayed by former comet Shoemaker-Levy 9; tidal (or other) breakup close to Jupiter followed by gradual orbital separation of the fragments and collision with a Galilean satellite on the outbound leg of the trajectory. Because the trajectories must pass close to Jupiter, this constrains the impact geometry (velocity and impact angle) of the individual fragments. For the dominant classes of impactors, short period Jupiter-family comets and asteroids, velocities at Callisto and Ganymede are dominated by Jovian gravity and a satellite's orbital motion, and are insensitive to the pre-fragmentation heliocentric velocity; velocities are insensitive to satellite gravity for all impactor classes. Complex crater shapes on Callisto and Ganymede are determined from Voyager images and Schmidt-Holsapple scaling is used to back out individual fragment masses. We find that comet fragment radii are generally less than about 500 m (for ice densities) but can be larger. These estimates can be compared with those for the Shoemaker-Levy 9 impactors.

McKinnon, William B.↗

Icy Satellites of Saturn: Impact Cratering and Age Determination

Saturn is the first giant planet to be visited by an orbiting spacecraft that can transmit large amounts of data to Earth. Crater counts on satellites from Phoebe inward to the regular satellites and ring moons are providing unprecedented insights into the origin and time histories of the impacting populations. Many Voyager-era scientists concluded that the satellites had been struck by at least two populations of impactors. In this view, the Population I impactors, which were generally judged to be comets orbiting the Sun, formed most of the larger and older craters, while Population II impactors, interpreted as Saturn-orbiting ejecta from impacts on satellites, produced most of the smaller and younger craters. Voyager data also implied that all of the ring moons, and probably some of the midsized classical moons, had been catastrophically disrupted and reaccreted since they formed. We examine models of the primary impactor populations in the Saturn system. At the present time, ecliptic comets, which likely originate in the Kuiper belt/scattered disk, are predicted to dominate impacts on the regular satellites and ring moons, but the models require extrapolations in size (from the observed Kuiper belt objects to the much smaller bodies that produce the craters) or in distance (from the known active Jupiter family comets to 9.5 AU). Phoebe, Iapetus, and perhaps even moons closer to Saturn have been struck by irregular satellites as well. We describe the Nice model, which provides a plausible mechanism by which the entire Solar System might have experienced an era of heavy bombardment long after the planets formed. We then discuss the three cratering chronologies, including one based upon the Nice model, that have been used to infer surface ages from crater densities on the saturnian satellites. After reviewing scaling relations between the properties of impactors and the craters they produce, we provide model estimates of the present-day rate at which comets impact, and catastrophically disrupt, the saturnian moons. Finally, we present crater counts on the satellites from two different groups. Many of the heavily cratered terrains appear to be nearly saturated, so it is difficult to infer the provenance of the impactors from crater counts alone. More large craters have been found on Iapetus than on any other satellite. Enceladus displays an enormous range of surface ages, ranging from the old mid-latitude plains to the extremely young South Polar Terrain. Cassini images provide some evidence for the reality of Population II. Most of the observed craters may have formed in one or more cataclysms, but more work is needed to determine the roles of heliocentric and planetocentric bodies in creating the craters.

Dones, L.↗