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The chemistry of comets

Comets appear to represent a population of rather homogeneous objects. In particular, the original size distribution peaks at a mean diameter of the order of 10 km. Cometary dust grains appear to be made of clusters of extremely fine particles (0.1-1.0 micron) sintered by heat at a variable degree during their perihelion passages. The brightness laws of comets appear to be derived only by the sublimation of water ice or at least of gas hydrates of the clathrate type. Pristine nuclei are likely to be radially undifferentiated; only their crustal surface must be outgassed and sintered by the heat of perihelion passages. Comet Halley is confirmed to be in the same general class as the bright comets of the 1970s. With an organic fraction of 33 percent in the cometary dust, the carbon of Comet Halley is close to cosmic abundances.

Delsemme, A. H.↗

Physical mechanism of comet outbursts - An experimental result

Attention is given to an experimental investigation of the physical mechanism of comet outbursts which is consistent with the general picture of mantle presence on comets and clarifies the relation of mantles to eruptive activity. The experiment and closeup observation of Comet P/Halley suggest a result different from most mathematical models in that the release of gas pressure does not occur only from uniform gas flow out of the entire surface. In some active comets near perihelion within a few AU of the sun, gas production rates and disturbance of the surface may be so high that the outflow is nearly continuous, with the regolith being entirely stripped away, as in many of the models. The present model provides a cyclic eruption and recharge mechanism which is lacking in most other models.

Hartmann, William K.↗

Annealing of Silicate Dust by Nebular Shocks at 10 AU

Silicate dust grains in the interstellar medium are known to be mostly amorphous, yet crystalline silicate grains have been observed in many long-period comets and in protoplanetary disks. Annealing of amorphous silicate grains into crystalline grains requires temperatures greater than or approximately equal to 1000 K, but exposure of dust grains in comets to such high temperatures is apparently incompatible with the generally low temperatures experienced by comets. This has led to the proposal of models in which dust grains were thermally processed near the protoSun, then underwent considerable radial transport until they reached the gas giant planet region where the long-period comets originated. We hypothesize instead that silicate dust grains were annealed in situ, by shock waves triggered by gravitational instabilities. We assume a shock speed of 5 km/s, a plausible value for shocks driven by gravitational instabilities. We calculate the peak temperatures of pyroxene grains under conditions typical in protoplanetary disks at 5-10 AU. We show that in situ annealing of micron-sized dust grains can occur, obviating the need for large-scale radial transport.

Harker, David E.↗

Plasma-tail activity and the interplanetary medium at Halley's Comet during Armada Week: 6-14 March 1986

The encounters of five spacecraft with Halley's Comet during 6-14 March 1986 offered a unique opportunity to calibrate the solar-wind interaction with cometary plasmas as recorded by remote wide-field and narrow-field/narrowband imaging. Perhaps not generally recognized in the comet community is the additional opportunity offered by the Halley Armada to study the structure of the solar-wind and interplanetary magnetic field (IMF) in three dimensions using five sets of data obtained over similar time intervals and heliocentric distances, but at somewhat different heliolatitudes. In fact, the two problems, i.e., comet physics and the structure of the interplanetary medium, are coupled if one wants to understand what conditions pertained at the comet between the encounters. This relationship is discussed.

Niedner, Malcolm B., Jr.↗

Measurements of thermal ion energy spectra from the Giotto encounter with Comet Halley

Ram ion measurements made by the Giotto neutral mass spectrometer show the spatial evolution of the composition and energy spectrum of coma ions. Near the nucleus the plasma is cold and has many constituents, but at distances of the order of 200,000 km the main ions are the terminal products of water dissociation, H(+) and O(+). The ion velocity distribution at the time of the Giotto encounter is highly anisotropic. Ion flow is generally away from the comet with energies increasing with distance to the order of 100 eV in the comet frame of reference. Similarities in the proton and oxygen ion energy spectra in the comet frame suggest an acceleration mechanism other than v x B pickup.

Hodges, R. R.↗

Structures far from the head of comet Kohoutek. II - A discussion of the Swan Cloud of January 11 and of the general morphology of cometary plasma tails

Photographs show that the 'Swan Cloud' observed in comet Kohoutek on January 11, 1974 was an advanced stage of a plasma tail disconnection event, of which the rejected tail appeared to decelerate as it receded from the head. The event commenced with the development of strong tail ray activity followed by the actual tail disconnection, the merging of the disconnected tail with the new tail to form the Swan and the formation of arcade loops in the space between closing tail rays. The observed morphological sequence is easily understood in the sector boundary model (Niedner et al., 1978), and the arcade loops are proposed to be reconnected flux tubes between oppositely polarized tail rays in the incipient new tail which followed the disconnection

Niedner, M. B., Jr.↗

Halley's comet and plans for its observation during its return in 1986

The general characteristics and properties of Halley's comet, as they can be derived from earlier apparitions, are briefly discussed. Consideration is given to historical data on the comet, orbital characteristics, and physical characteristics, including the estimated diameter and density of nucleus, rotation period, observed spectra, tails, and associated meteor streams. The coming 1985/86 apparition is then discussed together with planned space missions for in situ observations. Finally, the major goals of the International Halley Watch, a comprehensive program to prepare for the next apparition of Halley's comet, are reviewed.

Rahe, J.↗

Long-slit ultraviolet spectroscopy of Comet Austin (1990 V)

The spatial distributions of the brightest features in the far-UV spectrum of Comet Austin were measured, and it is found that they are generally similar to those found for Comet Halley during two rocket observations in 1986. As in Halley, the CO profile can be fit to a radial outflow profile for a source whose size is smaller than the instrumental spatial resolution. Neither the shape nor the magnitude of the extended atomic carbon profiles, however, can be satisfactorily explained by the photodissociation of CO. No evidence is found for an extended source of CO in the coma; thus, suggestions that the additional carbon can come directly from grains are difficult to accept since Austin is a low-dust comet. The presence of the O I 1356 A feature implies that there is a photoelectron excitation source in the coma. The measured O I 1304 A distribution is consistent with H2O being the dominant source of oxygen in the coma. The atomic sulfur profile matches that expected for a daughter product of relatively short-lived parents.

Sahnow, David J.↗

Possible influence of comets on the chemical evolution of the galaxy

It has been suggested by Cameron (1973) that a cloud of comets containing a mass of condensable elements, comparable to the mass of such elements in the sun, formed on the outskirts of the solar system. If the formation of such comet clouds is a general feature of star formation, they constitute a significant sink of elements heavier than helium. It is shown here that this process provides a possible explanation for the very slow rate at which the mean metal abundance of disk stars has increased during the lifetime of the Galaxy.

Tinsley, B. M.↗

The roots of coronal structure in the Sun's surface

We have compared the structures seen on X-ray images obtained by a flight of the NIXT sounding rocket payload on July 11, 1991 with near-simultaneous photospheric and chromospheric structures and magnetic fields observed at Big Bear. The X-ray images reflect emission of both Mg X and Fe XVI, formed at 1 x 10(exp 6) K and 3 x 10(exp 6) K, respectively. The brightest H(alpha) sources correspond to a dying sub-flare and other active region components, all of which reveal coronal enhancements situated spatially well above the H(alpha) emission. The arches appear to lie in a small range of angle in the meridian plane connecting their footpoints. Sunspots are dark on the surface and in the corona. For the first time we see an emerging flux region in X-rays and find the emission extends twice as high as the H(alpha) arches. Many features which we believe to correspond to `X-ray bright points' (XBPs) were observed. Whether by resolution or spectral band, the number detected greatly exceeds that from previous work. All of the brighter XBPs correspond to bipolar H(alpha) features, while unipolar H(alpha) bright points are the base of more diffuse comet-like coronal arches, generally vertical. These diverge from individual features by less than 30 deg, and give a good measure of what the `canopies' must do. The H(alpha) data shows that all the H(alpha) features were present present the entire day, so they are not clearly disappearing or reappearing. We find a new class of XBPs which we call `satellite points', elements of opposite polarity linked to nearby umbrae by invisible field lines. The satellite points change rapidly in X-ray brightness during the flight. An M1.9 flare occurred four hours after the flight; examination of the pre-flare structures reveals nothing unusual.

Golub, Leon↗

Estimates of Comet Fragment Masses from Impact Crater Chains on Callisto and Ganymede

Chains of impact craters, or catenae, have been identified in Voyager images of Callisto and Ganymede. Although these resemble in some respects secondary crater chains, the source craters and basins for the catenae cannot be identified. The best explanation is a phenomenon similar to that displayed by former comet Shoemaker-Levy 9; tidal (or other) breakup close to Jupiter followed by gradual orbital separation of the fragments and collision with a Galilean satellite on the outbound leg of the trajectory. Because the trajectories must pass close to Jupiter, this constrains the impact geometry (velocity and impact angle) of the individual fragments. For the dominant classes of impactors, short period Jupiter-family comets and asteroids, velocities at Callisto and Ganymede are dominated by Jovian gravity and a satellite's orbital motion, and are insensitive to the pre-fragmentation heliocentric velocity; velocities are insensitive to satellite gravity for all impactor classes. Complex crater shapes on Callisto and Ganymede are determined from Voyager images and Schmidt-Holsapple scaling is used to back out individual fragment masses. We find that comet fragment radii are generally less than about 500 m (for ice densities) but can be larger. These estimates can be compared with those for the Shoemaker-Levy 9 impactors.

McKinnon, William B.↗

Icy Satellites of Saturn: Impact Cratering and Age Determination

Saturn is the first giant planet to be visited by an orbiting spacecraft that can transmit large amounts of data to Earth. Crater counts on satellites from Phoebe inward to the regular satellites and ring moons are providing unprecedented insights into the origin and time histories of the impacting populations. Many Voyager-era scientists concluded that the satellites had been struck by at least two populations of impactors. In this view, the Population I impactors, which were generally judged to be comets orbiting the Sun, formed most of the larger and older craters, while Population II impactors, interpreted as Saturn-orbiting ejecta from impacts on satellites, produced most of the smaller and younger craters. Voyager data also implied that all of the ring moons, and probably some of the midsized classical moons, had been catastrophically disrupted and reaccreted since they formed. We examine models of the primary impactor populations in the Saturn system. At the present time, ecliptic comets, which likely originate in the Kuiper belt/scattered disk, are predicted to dominate impacts on the regular satellites and ring moons, but the models require extrapolations in size (from the observed Kuiper belt objects to the much smaller bodies that produce the craters) or in distance (from the known active Jupiter family comets to 9.5 AU). Phoebe, Iapetus, and perhaps even moons closer to Saturn have been struck by irregular satellites as well. We describe the Nice model, which provides a plausible mechanism by which the entire Solar System might have experienced an era of heavy bombardment long after the planets formed. We then discuss the three cratering chronologies, including one based upon the Nice model, that have been used to infer surface ages from crater densities on the saturnian satellites. After reviewing scaling relations between the properties of impactors and the craters they produce, we provide model estimates of the present-day rate at which comets impact, and catastrophically disrupt, the saturnian moons. Finally, we present crater counts on the satellites from two different groups. Many of the heavily cratered terrains appear to be nearly saturated, so it is difficult to infer the provenance of the impactors from crater counts alone. More large craters have been found on Iapetus than on any other satellite. Enceladus displays an enormous range of surface ages, ranging from the old mid-latitude plains to the extremely young South Polar Terrain. Cassini images provide some evidence for the reality of Population II. Most of the observed craters may have formed in one or more cataclysms, but more work is needed to determine the roles of heliocentric and planetocentric bodies in creating the craters.

Dones, L.↗

Photometric Modeling of a Cometary Nucleus: Taking Hapke Modeling to the Limit

In the past two decades, photometric models developed by Bruce Hapke have been fit to a wide range of bodies in the Solar System: The Moon, Mercury, several asteroids, and many icy and rocky satellites. These models have enabled comparative descriptions of the physical attributes of planetary surfaces, including macroscopic roughness, particle size and size-distribution, the single scattering albedo, and the compaction state of the optically active portion of the regolith. One challenging type of body to observe and model, a cometary nucleus, awaited the first space based mission to obtain images unobscured by coma. The NASA-JPL Deep Space 1 Mission (DS1) encountered the short-period Jupiter-family comet 19/P Borrelly on September 22, 2001, about 8 days after perihelion. Prior to its closest approach of 2171 km, the remote-sensing package on the spacecraft obtained 25 CCD images of the comet, representing the first closeup, unobscured view of a comet's nucleus. At closest approach, corresponding to a resolution of 47 meters per pixel, the intensity of the coma was less than 1% of that of the nucleus. An unprecedented range of high solar phase angles (52-89 degrees), viewing geometries that are in general attainable only when a comet is active, enabled the first quantitative and disk-resolved modeling of surface photometric physical parameters.

Buratti, B. J.↗

The Mineralogy of Comet Wild 2

The nature of cometary solids is of fundamental importance to our understanding of the early solar nebula and protoplanetary history. Samples of Comet Wild 2, provided by the Stardust Mission, have now been examined in terrestrial labs for two years, and are very surprising! Here we describe mainly the critical phases olivine, pyroxene and Fe-Ni sulfides in Wild 2 grains, as a guide to the general mineralogy of the returned comet samples.

Zolensky, Michael↗

The neutral coma of comets: A review

The hypothesis that water snow controls the vaporization of the nucleus of some comets seems verified from the general order of magnitude of the size of their nucleus and of their nuclear albedo; the largest observed production rates are H and OH which both seem to originate from the photodissociation of H2O, as also confirmed by the scale length of the invisible parent molecule producing OH. However, comet Encke is not uniformly covered by water snow, as it produces only one tenth of the expected vaporization. Early results on comet Kohoutek suggest that the conclusions could be slightly different for some of the new comets in Oort's sense. If the far ultraviolet observations confirm the early assessments of the production rates of C, O and H, then at least another major constituent competing with water has not yet been detected. Such a major constituent is suggested by the ratios C/O = 0.24 and H/O = 2.5.

Delsemme, A. H.↗

The IHW reference star catalogs for Comets Halley and Giocobini-Zinner

The general categories of catalogs are observed and compiled. Observed catalogs are tabulations of positions determined with a single instrument (transit circle or astrograph) at a single location with a single approximate mean epoch. Compiled catalogs are produced from a combination of observed catalogs and have the advantage of many more observations per star. In addition, catalogs may be classified according to their density and type of instrument used to produce them. The specific catalogs that should be used for Halley's Comet and Giaobini-Zinner Comet are described.

Harrington, R. S.↗

The effect of multiple encounters on short period comet orbits

The observed orbital elements of short period comets are found to be consistent with the hypothesis of derivation from long period comets as long as two assumptions are made. First, the distribution of short period comets has been randomized by multiple encounters with Jupiter and second, the short period comets have lower velocities of encounter with Jupiter than is generally expected. Some 16% of the observed short period comets have lower encounter velocities than is allowed mathematically using Laplace's method. This may be due to double encounter processes with Jupiter and Saturn, or as a result of prolonged encounters. The distribution of unobservable short period comets can be inferred in part from the observed comets. Many have orbits between Jupiter and Saturn with somewhat higher inclinations than those with perihelions near the earth. Debris from those comets may form the major component of the zodiacal dust.

Lowrey, B. E.↗

The infrared spectral properties of frozen volatiles

Since Whipple's dirty snowball model of comet nuclei, it has been generally accepted that volatile ices help to explain cometary phenomena. The infrared spectral properties of many substances that are potential candidates for frozen volatiles in the solar system are being pursued; indeed some of these frozen materials have been found in the solar system: H2O, CO2, and SO2. A review of laboratory spectra in the range 1 to 20 microns of H2O, CO2, SO2, CH4, NH3, H2S, CO, NH4HS and NH3.H2O is presented. Both reflection spectra of thick frosts and transmission spectra of thin films are shown, and their main characteristics are described. Hydrates, clathrates, and composite spectra are discussed. When it is possible to observe the nuclei of comets at close range, it may be possible to identify frozen volatiles by their infrared spectra.

Fink, U.↗