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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Relationship Between Solution Shear Viscosity and Density at the Saturation Point

Properties of supersaturated solutions such as the density, viscosity, and solute diffusivity are dependent on the solute concentration. The diffusion-boundary-layer equations are derived and solved for the natural convection case with the viscosity and density dependent on the solute concentration. The solution obtained demonstrates that, at the vicinity of the saturation concentration c(sub s), there is a non-trivial dependence of the solution viscosity eta on its density rho: eta(c(sub s)) = eta(rho(sub s)) varies as rho(sub s)(exp 1/2), where rho(sub s) = rho(c(sub s)). This result has been verified in experiments with aqueous solutions of inorganic and organic salts.

Izmailov, Alexander F.↗
NASA NTRS1999

Flow Effects on the Flammability Diagrams of Solid Fuels: Microgravity Influence on Ignition Delay

The possibility of an accidental fire in space-based facilities is a primary concern of space exploration programs. Spacecraft environments generally present low velocity air currents produced by ventilation and heating systems (of the order of 0.1 m/s), and fluctuating oxygen concentrations around that of air due to CO2 removal systems. Recent experiments of flame spread in microgravity show the spread rate to be faster and the limiting oxygen concentration lower than in normal-gravity. To date, there is not a material flammability-testing protocol that specifically addresses issues related to microgravity conditions. The present project (FIST) aims to establish a testing methodology that is suitable for the specific conditions of reduced gravity. The concepts underlying the operation of the LIFT apparatus, ASTM-E 1321-93, have been used to develop the Forced-flow Ignition and flame-Spread Test (FIST). As in the LIFT, the FIST is used to obtain the flammability diagrams of the material, i.e., graphs of ignition delay time and flame spread rate as a function of the externally applied radiant flux, but under forced flow rather than natural convection conditions, and for different oxygen concentrations. Although the flammability diagrams are similar, the flammability properties obtained with the FIST are found to depend on the flow characteristics. A research program is currently underway with the purpose of implementing the FIST as a protocol to characterize the flammability performance of solid materials to be used in microgravity facilities. To this point, tests have been performed with the FIST apparatus in both normal-gravity and microgravity conditions to determine the effects of oxidizer flow characteristics on the flammability diagrams of polymethylmethacrylate (PMMA) fuel samples. The experiments are conducted at reduced gravity in a KC- 135 aircraft following a parabolic flight trajectory that provides up to 25 seconds of low gravity. The objective of the experiments is to obtain data of ignition delay and flame spread rate at low flow velocities (0.1 to 0.2 m/s), which cannot be obtained under normal gravity because of the natural convection induced flows (approx. 0.5 m/s). Due to the limited reduced gravity time, the data can only be obtained for high radiant fluxes, and are consequently limited in scope. These tests do, however, provide insight into the flammability diagram characteristics at low velocity and reduced gravity, and also into the implications of the flow-dependence of the flammability properties under environments similar to those encountered in space facilities.

Cordova, J. L.↗
NASA NTRS2015

Some General Principles in Cryogenic Design, Implementation, and Testing

Brief Course Description: In 2 hours only the most basic principles of cryogenics can be presented. I will concentrate on the differences between a room temperature thermal analysis and cryogenic thermal analysis, namely temperature dependent properties. I will talk about practical materials for thermal contact and isolation. I will finish by describing the verification process and instrumentation used that is unique to cryogenic (in general less than 100K) systems.

heat transfer↗
NASA NTRS1986

Growth and characterization of Hg(1-x)Zn(x)Se

Hg sub 1-xZn sub xSe alloys of composition x=0.10 were grown in a Bridgman-Stockbarger growth furnace at translation rates of 0.3 and 0.1 micron sec. The axial and radial composition profiles were determined using precision density measurements and IR transmission-edge-mapping, respectively. A more radially homogeneous alloy was produced at the slower growth rate, while the faster growth rate produced more axially homogeneous alloys. A determination of the electrical properties of the Hg sub 1-xZn sub xSe samples in the temperature range 300K-20K was also made. Typical carrier concentrations were on the order of magnitude of 10 to the 18th power cu/cm, and remained fairly constant as a function of temperature. A study was also made of the temperature dependence of the resistivity and Hall mobility. The effect of annealing in a selenium vapor on both the IR transmission and the electrical properties was determined. Annealing was effective in reducing the number of native donor defects and at the resulting lower carrier concentrations, charge carrier concentration was shown to be a function of temperature. Annealing caused the mobility to increase, primarily at the lower temperature, and the room temperature resistivity to increase. Annealing was also observed to greatly enhance the % IR transmittance of the samples. This was due primarily to the effect of annealing on decreasing the charge carrier concentration.

Andrews, R. N.↗
NASA NTRS2014

Synthesis and Properties of Cross-Linked Polyamide Aerogels

We report our ongoing research on polyamide aerogels made by step growth polymerization using a combination of terephthaloyl chloride, isophthaloyl chloride and m-phenylenediamine. Crosslinking of the amine capped polymer chains with 1,3,5-benzenetricarbonyl trichloride causes gelation in as little as two to five minutes. Removing the reaction solvent is accomplished through solvent exchange, followed by drying using supercritical CO2 extraction to give colorless aerogels with densities ranging from 0.07 to 0.33 grams per cubic centimeter and surface areas as high as 440 square meters per gram. Statistical experimental design methodology has been utilized to investigate dependence of properties of these aerogels, such as density, compressive modulus, and surface area, on changes in fabrication parameters including formulated number of amide oligomer repeat units (n-value), acid chloride (meta, para or combination), and solids concentration of solution used for gelation. For example, the density of these materials was found to be dependent on the acid chloride type and the solids concentration, but n was not a significant variable. However, surface area was significantly influenced by all three parameters. The polyamide aerogels represent a potential cost savings over previously reported polyimide aerogels, since monomers are all inexpensive and commercially available. Surface area and density were both highest when 100 terephthaloyl chloride was used but a combination of 5 solid concentration, 100 terephthaloyl chloride and n of 20 gave the best combination of properties.

cross-linked↗
NASA NTRS1983

Combustion response to compositional fluctuations

A mechanism involving compositional fluctuations at certain frequencies is examined by which the heterogeneity of a composite solid propellant may contribute directly to the combustion response function of combustion instability theory. A combustion model appropriate to ammonium perchlorate (AP) is used to derive the combustion response to compositional fluctuations, and the properties of the combustion response are discussed in terms of the theoretical results obtained. The concentration exponent, i.e., the dependence of the burn rate on AP concentration, is found to be a signficant combustion parameter and to have a tremendous range of variability. It is suggested that the combustion response to compositional fluctuations may be a dominating factor in driving combustion instability.

Cohen, N. S.↗
NASA NTRS1998

Modeling of Substitutional Site Preference in Ordered Intermetallic Alloys

We investigate the site substitution scheme of specific alloying elements in ordered compounds and the dependence of site occupancy on compound stoichiometry, alloy concentration. This basic knowledge, and the interactions with other alloying additions are necessary in order to predict and understand the effect of various alloying schemes on the physical properties of a material, its response to various temperature treatments, and the resulting mechanical properties. Many theoretical methods can provide useful but limited insight in this area, since most techniques suffer from constraints in the type of elements and the crystallographic structures that can be modeled. With this in mind, the Bozzolo-Ferrante-Smith (BFS) method for alloys was designed to overcome these limitations, with the intent of providing an useful tool for the theoretical prediction of fundamental properties and structure of complex systems. After a brief description of the BFS method, its use for the determination of site substitution schemes for individual as well as collective alloying additions to intermetallic systems is described, including results for the concentration dependence of the lattice parameter. Focusing on B2 NiAl, FeAl and CoAl alloys, the energetics of Si, Ti, V, Cr, Fe, Co, Ni, Cu, Zr, Nb, Mo, Ru, Hf, Ta and W alloying additions are surveyed. The effect of single additions as well as the result of two simultaneous additions, discussing the interaction between additions and their influence on site preference schemes is considered. Finally, the BFS analysis is extended to ternary L1(sub 2) (Heusler phase) alloys. A comparison between experimental and theoretical results for the limited number of cases for which experimental data is available is also included.

Bozzolo, Guillermo↗
NASA NTRS1980

Advances in membrane technology for the NASA redox energy storage system

Anion exchange membranes used in the system serve as a charge transferring medium as well as a reactant separator and are the key enabling component in this storage technology. Each membrane formulation undergoes a series of screening tests for area-resistivity, static (non-flow) diffusion rate determination, and performance in Redox systems. The CDIL series of membranes has, by virtue of its chemical stability and high ion exchange capacity, demonstrated superior properties in the redox environment. Additional resistivity results at several acid and iron solution concentrations, iron diffusion rates, and time dependent iron fouling of the various membrane formulations are presented in comparison to past standard formulations.

Ling, J. S.↗
NASA NTRS1987

Crystal growing from the melt

The mechanical and electrical properties of crystals produced by a unidirectional process depend strongly on the temperature and flow fields since these control the concentration of solute at the melt-crystal interface. The solute gradient there drives morphological instabilities that lead to cellular or dendritic interfaces. In the presentation several features of flow-solidification interactions will be discussed. These will include the effects of convection driven by density changes and buoyancy and the imposition of forced flow.

Davis, S. H.↗
NASA NTRS2013

TPSAS-NF1676L-16299-DND

As part of the American Recovery and Reinvestment Act (ARRA) of 2009, the DOE ARM program deployed a new ground-­‐based Arctic High Spectral Resolution Lidar (AHSRL) at the North Slope of Alaska (NSA) site. This lidar, which is based on the AHSRL that was part of the NOAA’s SEARCH (Study of Environmental Arctic Change) contribution to the Canadian Network for the Detection of Atmospheric Change (CANDAC) facility at Eureka, Nunavut Territory, is an autonomous lidar that provides calibrated profiles of particulate (i.e. aerosol and cloud) backscatter cross section, optical thickness and circular depolarization at 532 nm. The AHSRL provides measurements of both intensive and extensive particulate properties. The intensive parameters depend only on the nature of the particles (size, composition, shape), not on the quantity or concentration. Here we show examples of the AHSRL data during both clear and cloudy conditions to show how these measurements can be used to depict aerosols and clouds over the NSA.

Marian Clayton↗
NASA NTRS2024

Enhancing Consistency of Microphysical Properties of Precipitation Across the Melting Layer in the Dual-Frequency Precipitation Radar Data

Stratiform rain and the overlying ice play crucial roles in Earth's climate system. From a microphysics standpoint, water mass flux primarily depends on two variables: particles' concentration and their mass. The Dual-frequency Precipitation Radar (DPR) on the Global Precipitation Measurement mission core satellite is a spaceborne instrument capable of estimating these two quantities through dual-wavelength measurements. In this study, we evaluate bulk statistics on the ice particle properties derived from dual-wavelength radar data in relation to the properties of rain underneath. Specifically, we focus on DPR observations over stratiform precipitation, characterized by columns exhibiting a prominent bright band, where the melting layer can be easily detected. Our analysis reveals a large increase in the retrieved mass flux as we transition from the ice to the rain phase in the official DPR product. This observation is in disagreement with our expectation that mass flux should remain relatively stable across the bright band in cold-rain conditions. To address these discrepancies, we propose an alternative retrieval algorithm that ensures a gradual transition of Dm (mean mass-weighted particle melted-equivalent diameter) and the precipitation rate across the melting zone. This approach also helps in estimating bulk ice density above the melting level. These findings demonstrate that DPR observations can not only quantify ice particle content and their size above stratiform rain regions but also estimate bulk density, provided uniform conditions that minimize uncertainties related to partial beam filling.

radar measurements from space↗
NASA NTRS1993

Growth experiment of narrow band-gap semiconductor PbSnTe single crystals in space (M-1)

An experiment on crystal growth of Pb(1-x)Sn(x)Te in microgravity is planned. This material is an alloy of the compound semiconductors PbTe and SnTe. It is a promising material for infrared diode lasers and detectors in the wavelength region between 6 and 30 micron. Since the electrical properties of Pb(1-x)Sn(x)Te depend greatly on the Pb/Sn ratio and crystalline defects as well as impurity concentration, homogeneous, defect-free, high-quality crystals are anticipated. Although many growth methods, such as the pulling method, the Bridgman method, the vapor growth method, etc., have been applied to the growth of Pb(1-x)Sn(x)Te, large, homogeneous, low-defect-density crystals have not yet been grown on Earth. The unsuccessful results were caused by buoyancy-driven convection in the fluids induced by the specific gravity difference between heated and cooled fluids on Earth. A crystal is grown by cooling the melt from one end of the ampoule. In crystal growth from the melt, about 30 percent of the SnTe in the melt is rejected at the solid-liquid interface during solidification. On Earth, the rejected SnTe is completely mixed with the remaining melt by convection in the melt. Therefore, SnTe concentration in the melt, and accordingly in the crystal, increases as the crystal grows. In the microgravity environment, buoyancy-driven convection is suppressed because the specific gravity difference is negligible. In that case, the rejected SnTe remains at the solid-liquid interface and its concentration increases only at the interface. If the growth rate is higher than the PbTe-SnTe interdiffusion rate, the amount of SnTe which diffuses from the interface into the melt increases as SnTe piles up at the interface, and finally it balances the amount of rejected SnTe during solidification, resulting in steady-state SnTe transportation at the interface. By using this principle, compositionally homogeneous crystals can be grown. Furthermore, low-defect-density crystals will be grown in microgravity, because convection causes crystalline defects by mising hot and cold fluids and generating temperature fluctuations in them.

Yamada, Tomoaki↗
NASA NTRS1982

Integrating matrix formulations for vibrations of rotating beams including the effects of concentrated masses

By expressing partial differential equations of motion in matrix notation, utilizing the integrating matrix as a spatial operator, and applying the boundary conditions, the resulting ordinary differential equations can be cast into standard eigenvalue form upon assumption of the usual time dependence. As originally developed, the technique was limited to beams having continuous mass and stiffness properties along their lengths. Integrating matrix methods are extended to treat the differential equations governing the flap, lag, or axial vibrations of rotating beams having concentrated masses. Inclusion of concentrated masses is shown to lead to the same kind of standard eigenvalue problem as before, but with slightly modified matrices.

Lakin, W. D.↗
NASA NTRS1979

Near-surface daytime thermal conductivity in the lunar regolith

If mass and heat transport properties in the top few cm of the lunar surface correspond, estimates of the daytime thermal conductivity based on the diffusivity calculated from in situ concentration gradients of low temperature volatile elements should be possible. Concentration gradients of Hg and Br in response to the diurnal heat pulse have been measured in samples from cores. The conductivity estimated is either approximately 10 to the -3rd or approximately 2 x 10 to the -4th W/cm-degrees K depending on the assumptions made. The latter value is in agreement with near-surface daytime thermal properties calculated by Keihm et al. (1973) to explain the mean surface temperature. An activation energy for diffusion of Hg in the top few cm of the lunar surface is estimated to be approximately 8 kcal/mole and suggests either vapor or surface migration. Fixation of the concentration gradient after the cores were extracted may be due to lack of a temperature gradient to act as a driving force or to disruption of grain contacts or their corrosion on exposure to air.

Reed, G. W., Jr.↗
NASA NTRS2006

Polyimides From a-BPDA and Aromatic Diamines

Polymers having low color and a favorable combination of other properties, including high glass-transition temperature (Tg) and high mechanical properties (strength, tensile modulus, and toughness) will find use in a variety of terrestrial and space applications. Some of the space applications will be in thin films used as membranes on antennas, solar concentrators, coatings on second-surface mirrors, solar sails, sunshades, thermal and optical coatings, and multi-layer thermal insulation blankets. Depending upon the application, the film will be required to exhibit a unique combination of such properties as resistance to degradation by ultraviolet light, visible light, and electrons; low color and/or low solar absorptivity; resistance to tearing and/or wrinkling during packaging and deployment; and high mechanical properties (e.g. high strength, stiffness, and toughness).

Hergenrother, Paul M.↗
NASA NTRS1973

Thermodynamic properties of gases dissolved in electrolyte solutions.

A method based on perturbation theory for mixtures is applied to the prediction of thermodynamic properties of gases dissolved in electrolyte solutions. The theory is compared with experimental data for the dependence of the solute activity coefficient on concentration, temperature, and pressure; calculations are included for partial molal enthalpy and volume of the dissolved gas. The theory is also compared with previous theories for salt effects and found to be superior. The calculations are best for salting-out systems. The qualitative feature of salting-in is predicted by the theory, but quantitative predictions are not satisfactory for such systems; this is attributed to approximations made in evaluating the perturbation terms.

Tiepel, E. W.↗
NASA NTRS1993

Modeling of outgassing and matrix decomposition in carbon-phenolic composites

A new release rate equation to model the phase change of water to steam in composite materials was derived from the theory of molecular diffusion and equilibrium moisture concentration. The new model is dependent on internal pressure, the microstructure of the voids and channels in the composite materials, and the diffusion properties of the matrix material. Hence, it is more fundamental and accurate than the empirical Arrhenius rate equation currently in use. The model was mathematically formalized and integrated into the thermostructural analysis code CHAR. Parametric studies on variation of several parameters have been done. Comparisons to Arrhenius and straight-line models show that the new model produces physically realistic results under all conditions.

Mcmanus, Hugh L.↗
NASA NTRSDate not supplied

Comparison of INP Parameterizations for Dust Minerals in Climatological Simulations With a Global Model

The effect of aerosol particles on ice nucleation and, in turn, the formation of ice and mixed phase clouds is recognized as one of the largest sources of uncertainty in weather and climate prediction. We utilize an improved sectional dust module in NASA GISS Earth System ModelE2.1, which distinguishes eight different mineral species and accretions between iron oxides and the other minerals. Simulations over a period of 20 years have been carried out with this model, and the mineral fields and other model variables (temperature, relative humidity) are used to calculate the ice nucleating particle (INP) number concentration, applying time-independent and time-dependent INP parameterizations, such as active site parameterization and water activity based immersion freezing model (ABIFM). We study how the dependence of the parameterizations on different model variables affects the mean INP number concentration. The sensitivity of the INP number concentration to fundamental dust properties such as emitted mineral size distributions and mixing state between minerals is also investigated. Results show that the sensitivity of the total INP number concentration to the emitted dust size distribution is rather small, but the sensitivity over the whole size range obscures offsetting differences in the magnitude and the sign of the sensitivity between smaller and larger particles.

INP Parameterizations↗