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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2003

Solar Array in Simulated LEO Plasma Environment

Six different types of solar arrays have been tested in large vacuum chambers. The low earth orbit plasma environment was simulated in plasma vacuum chambers, where the parameters could be controlled precisely. Diagnostic equipment included spherical Langmuir probes, mass spectrometer, low-noise CCD camera with optical spectrometer, video camera, very sensitive current probe to measure arc current, and a voltage probe to register variations in a conductor potential. All data (except video) were obtained in digital form that allowed us to study the correlation between external parameters (plasma density, additional capacitance, bias voltage, etc) and arc characteristics (arc rate, arc current pulse width and amplitude, gas species partial pressures, and intensities of spectral lines). Arc inception voltages, arc rates, and current selections are measured for samples with different coverglass materials and thickness, interconnect designs, and cell sizes. It is shown that the array with wrapthrough interconnects have the highest arc threshold and the lowest current collection. Coverglass design with overhang results in decrease of current collection and increase of arc threshold. Doubling coverglass thickness cases the increase in arc inception voltage. Both arc inception voltage and current collection increase significantly with increasing a sample temperature to 80 C. Sustained discharges are initiated between adjacent cells with potential differences of 40 V for the sample with 300 micron coverglass thickness and 60 V for the sample with 150 micron coverglass thickness. Installation of cryogenic pump in large vacuum chamber provided the possibility of considerable outgassing of array surfaces which resulted in significant decrease of arc rate. Arc sites were determined by employing a video-camera, and it is shown that the most probable sites for arc inception are triple-junctions, even though some arcs were initiated in gaps between cells. It is also shown that the arc rate increases with increasing of ion collection current. The analysis of optical spectra (240-800 nm) reveals intensive narrow atomic lines (Ag, H) and wide molecular bands (OH, CH, SiH, SiN) that confirms a complicated mechanism of arc plasma generation. The results obtained seem to be important for the understanding of the arc inception mechanism, which is absolutely essential for progress toward the design of high-voltage solar array for space application.

Vayner, Boris↗
NASA NTRS2004

Solar Array in Simulated LEO Plasma Environment

Six different types of solar arrays have been tested in large vacuum chambers. The low Earth orbit plasma environment was simulated in plasma vacuum chambers, where the parameters could be controlled precisely. Diagnostic equipment included spherical Langmuir probes, mass spectrometer, low-noise CCD camera with optical spectrometer, video camera, very sensitive current probe to measure arc current, and a voltage probe to register variations in a conductor potential. All data (except video) were obtained in digital form that allowed us to study the correlation between external parameters (plasma density, additional capacitance, bias voltage, etc) and arc characteristics (arc rate, arc current pulse width and amplitude, gas species partial pressures, and intensities of spectral lines). Arc inception voltages, arc rates, and current collections are measured for samples with different coverglass materials and thickness, interconnect designs, and cell sizes. It is shown that the array with wrapthrough interconnects have the highest arc threshold and the lowest current collection. Coverglass design with overhang results in decrease of current collection and increase of arc threshold. Doubling coverglass thickness causes the increase in arc inception voltage. Both arc inception voltage and current collection increase significantly with increasing a sample temperature to 80 C. Sustained discharges are initiated between adjacent cells with potential differences of 40 V for the sample with 300 m coverglass thickness and 60 V for the sample with 150 m coverglass thickness. Installation of cryogenic pump in large vacuum chamber provided the possibility of considerable outgassing of array surfaces which resulted in significant decrease of arc rate. Arc sites were determined by employing a video-camera, and it is shown that the most probable sites for arc inception are triple-junctions, even though some arcs were initiated in gaps between cells. It is also shown that the arc rate increases with increasing of ion collection current. The analysis of optical spectra (240-800 nm) reveals intensive narrow atomic lines (Ag, H) and wide molecular bands (OH, CH, SiH, SiN) that confirms a complicated mechanism of arc plasma generation. The results obtained seem to be important for the understanding of the arc inception mechanism, which is absolutely essential for progress toward the design of high-voltage solar array for space application.

Vayner, Boris↗
NASA NTRS2021

Quantifying Feedback from Narrow Line Region Outflows in Nearby Active Galaxies. III. Results for the Seyfert 2 Galaxies Markarian 3, Markarian 78, and NGC 1068

Outflows of ionized gas driven by active galactic nuclei (AGN) may significantly impact the evolution of their host galaxies. However, determining the energetics of these outflows is difficult with spatially unresolved observations that are subject to strong global selection effects. We present part of an ongoing study using Hubble Space Telescope and Apache Point Observatory spectroscopy and imaging to derive spatially resolved mass outflow rates and energetics for narrow-line region outflows in nearby AGN that are based on multi-component photoionization models to account for spatial variations in gas ionization, density, abundances, and dust content. This expanded analysis adds Mrk 3, Mrk 78, and NGC 1068, doubling our earlier sample. We find that the outflows contain total ionized gas masses of M ≈ 10(exp 5.5)-10(exp 7.5) M⨀ and reach peak velocities of v ≈ 800-2000 km s(exp -1). The outflows reach maximum mass outflow rates of M(sub OUT) ≈ 3-12 M⨀ yr(exp -1) and encompass total kinetic energies of E ≈ 10(exp 54)-10(exp 56) erg. The outflows extend to radial distances of r ≈ 0.1-3 kpc from the nucleus, with the gas masses, outflow energetics, and radial extents positively correlated with AGN luminosity. The outflow rates are consistent with in situ ionization and acceleration where gas is radiatively driven at multiple radii. These radial variations indicate that spatially resolved observations are essential for localizing AGN feedback and determining the most accurate outflow parameters.

Active galaxies↗
NASA NTRS1976

Comparative studies of grain size separates of 60009

Five samples from 60009, the lower half of a double drive tube, were analyzed via grain-size methods, with particle types classified and counted in the coarser grain sizes. Studies were undertaken of particle types and distributions by petrographic methods, of magnetic fractions, of the size splits and magnetic splits as analyzed by ferromagnetic resonance (FMR) techniques, of maturity (based on agglutinate content, FMR index Is/FeO, mean size of sub-cm material, magnetic fraction), of possible reworking or mixing in situ, and of depositional history. Maturity indices are in substantial agreement for all of the five samples. Strong positive correlation of percent agglutinates and percent bedrock-derived lithic fragments, combined with negative correlation of those components with percent single crystal plagioclase, argue against in situ reworking of the same soil.

Mckay, D. S.↗
NASA NTRS1983

Small Gas Turbine Combustor Primary Zone Study

A development process is described which consists of design, fabrication, and preliminary test evaluations of three approaches to internal aerodynamic primary zone flow patterns: (1) conventional double vortex swirl stabilization; (2) reverse flow swirl stabilization; and (3) large single vortex flow system. Each concept incorporates special design features aimed at extending the performance capability of the small engine combustor. Since inherent geometry of these combustors result in small combustion zone height and high surface area to volume ratio, design features focus on internal aerodynamics, fuel placement, and advanced cooling. The combustors are evaluated on a full scale annular combustor rig. A correlation of the primary zone performance with the overall performance is accomplished using three intrusion type gas sampling probes located at the exit of the primary zone section. Empirical and numerical methods are used for designing and predicting the performance of the three combustor concepts and their subsequent modifications. The calibration of analytical procedures with actual test results permits an updating of the analytical design techniques applicable to small reverse flow annular combustors.

Sullivan, R. E.↗
NASA NTRS1987

Interfacial strength development in thermoplastic resins and fiber-reinforced thermoplastic composites

An experimental program to develop test methods to be used to characterize interfacial (autohesive) strength development in polysulfone thermoplastic resin and graphite-polysulfone prepreg during processing is reported. Two test methods were used to examine interfacial strength development in neat resin samples. These included an interfacial tension test and a compact tension (CT) fracture toughness test. The interfacial tensile test proved to be very difficult to perform with a considerable amount of data scatter. Thus, the interfacial test was discarded in favor of the fracture toughness test. Interfacial strength development was observed by measuring the refracture toughness of precracked compact tension specimens that were rehealed at a given temperature and contact time. The measured refracture toughness was correlated with temperature and contact time. Interfacial strength development in graphite-polysulfone unidirectional composites was measured using a double cantilever beam (DCB) interlaminar fracture toughness test. The critical strain energy release rate of refractured composite specimens was measured as a function of healing temperature and contact time.

Howes, Jeremy C.↗
NASA NTRS2010

Transfer of Satellite Rainfall Uncertainty from Gauged to Ungauged Regions at Regional and Seasonal Timescales

Hydrologists and other users need to know the uncertainty of the satellite rainfall data sets across the range of time/space scales over the whole domain of the data set. Here, uncertainty' refers to the general concept of the deviation' of an estimate from the reference (or ground truth) where the deviation may be defined in multiple ways. This uncertainty information can provide insight to the user on the realistic limits of utility, such as hydrologic predictability, that can be achieved with these satellite rainfall data sets. However, satellite rainfall uncertainty estimation requires ground validation (GV) precipitation data. On the other hand, satellite data will be most useful over regions that lack GV data, for example developing countries. This paper addresses the open issues for developing an appropriate uncertainty transfer scheme that can routinely estimate various uncertainty metrics across the globe by leveraging a combination of spatially-dense GV data and temporally sparse surrogate (or proxy) GV data, such as the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar and the Global Precipitation Measurement (GPM) mission Dual-Frequency Precipitation Radar. The TRMM Multi-satellite Precipitation Analysis (TMPA) products over the US spanning a record of 6 years are used as a representative example of satellite rainfall. It is shown that there exists a quantifiable spatial structure in the uncertainty of satellite data for spatial interpolation. Probabilistic analysis of sampling offered by the existing constellation of passive microwave sensors indicate that transfer of uncertainty for hydrologic applications may be effective at daily time scales or higher during the GPM era. Finally, a commonly used spatial interpolation technique (kriging), that leverages the spatial correlation of estimation uncertainty, is assessed at climatologic, seasonal, monthly and weekly timescales. It is found that the effectiveness of kriging is sensitive to the type of uncertainty metric, time scale of transfer and the density of GV data within the transfer domain. Transfer accuracy is lowest at weekly timescales with the error doubling from monthly to weekly.However, at very low GV data density (<20% of the domain), the transfer accuracy is too low to show any distinction as a function of the timescale of transfer.

Tang, Ling↗
NASA NTRS1990

Viral coefficient and hidden mass in the galaxy groups

The purpose is the verification of the virial mass estimations for small galaxy groups. The dynamical evolution of triple and quintuple galaxies was studied by the numerical simulations. The dependence of the virial coefficient k(t) versus time was derived. Initial k(O) = O. The function k(t) has some strong oscillations from 0.02 to 0.99. Generally, these oscillations are quasiperiodical ones. Such a behavior of k(t) is caused by formation in a system of close isolated temporary double subsystems. A strong correlation between the virial coefficient and the least mutual distance in the system is observed. Such wide oscillations may add into the estimation of virial mass of the galaxy groups an uncertainty of more than one order. An additional uncertainty is introduced by the projection effect. This uncertainty for the individual estimations of the masses approach three orders. Thus any individual estimation of the virial mass is impossible for small galaxy groups. Some possibility of statistical estimation (median or average) of the total mass, including a hidden mass, is shown for the homogeneous samples. The authors propose a method for these estimations based on a comparison of the medians of dynamical parameters (a mean size in projection and a dispersion of relative radial velocities) for the simulated and observed ensembles of the galaxy groups. This method has been applied to a sample of 46 probably physical triplets of galaxies. The probable median of the hidden mass in a volume of the triplet is about 4 M, where M is the total mass of visible matter.

Anosova, Joanna P.↗
NASA NTRS1994

An IUE survey of interstellar H I Ly alpha absorption. 2: Interpretations

We present an analysis of interstellar neutral hydrogen column densities obtained from archival Ly alpha absorption line data toward the complete sample of B2 and hotter stars observed at high spectral resolution with the IUE satellite. The full sample includes 554 stars and more than doubles the number of lines of sight previously observed. Many of the B2 and B1.5 stars exhibit contamination from stellar Ly alpha absorption, and were excluded from the subsequent analysis. The final working sample includes 393 stars. We present statistical averages for a number of quantities derived for the sample. The stars range in distance from 0.12 to 11 kpc with an average distance of 2.1 kpc. Values for average sight-line density range from 0.017 to 8.62 atoms cm(exp -3), with an overall average of 0.23 atoms cm(exp -3). Neutral hydrogen and dust are well correlated, with N(H I)/E(B - V) = 4.93 x 10(exp 21) cm(exp -2) mag(exp -1), and N(H I)/E(Bump) = 2.17 x 10(exp 21) cm(exp -2) mag(exp -1). There is an increase in the H I to dust ratios for the densest sight lines. Evidently, the H I to dust ratios in dense clouds are higher than in the lower density medium between the clouds and in interarm directions. The effect is probably an indication of dust modification in the dense clouds. The H I to dust ratios are approx. 17% smaller for the sight lines to O stars compared to the ratios found toward B stars. We have identified sight lines with anomalously large and small values of N(H I)/E(B - V) and H(H I)/E(Bump). Some of these sight lines are well-known examples of peculiar extinction (i.e., HD 147933 and HD 37061 (NU Ori)). Others are less well known and may provide important new examples of regions with highly modified dust. The number of stars with anomalously low H I to dust ratios is disproportionately larger than the number of stars with anomalously high H I to dust ratios. The distribution of the gas away form the Galactic plane for the sample of objects is complex. For the subset of 375 stars whose lines of sight have a statistically low probablility of intersecting a large cloud, the distribution may be roughly approximated by an exponential density distribution, with a midplane density of 0.366 atoms cm(exp -3), a scale height of 195 pc, and a random logarithmic scattering parameter sigma (sub p) of 0.159 dex. For the same sample of stars, interstellar dust is found to be confined closer to the plane than the H I, with (E(B - V)/r)(sub 0) = 0.257 mag kpc(exp -1), scale height h = 152 pc, and sigma(sub p) = 0.263 dex. The dust distribution is more inhomogeneous than the gas distribution. The observed distribution of H I away from the Galactic plane can also be fitted with a two-component exponential model including the effects of patchiness. Unfortunately, the foreground contamination produced by the cloudy and more confined component of H I makes it difficult to estimate the scale height of the extended component without invoking an independent estimate of its midplane density. Assuming n(sub 2)(0) = 0.16 cm(exp -3) from the Copernicus satellite H I/H(sub 2) survey, we obtain n(sub 1)(0) = 0.247 cm(exp -3), h(sub 1) = 73 PC, and h(sub 2) + 357 pc.

Diplas, Athanassios↗
NASA NTRS2003

The relationship between lifestyle regularity and subjective sleep quality

In previous work we have developed a diary instrument-the Social Rhythm Metric (SRM), which allows the assessment of lifestyle regularity-and a questionnaire instrument--the Pittsburgh Sleep Quality Index (PSQI), which allows the assessment of subjective sleep quality. The aim of the present study was to explore the relationship between lifestyle regularity and subjective sleep quality. Lifestyle regularity was assessed by both standard (SRM-17) and shortened (SRM-5) metrics; subjective sleep quality was assessed by the PSQI. We hypothesized that high lifestyle regularity would be conducive to better sleep. Both instruments were given to a sample of 100 healthy subjects who were studied as part of a variety of different experiments spanning a 9-yr time frame. Ages ranged from 19 to 49 yr (mean age: 31.2 yr, s.d.: 7.8 yr); there were 48 women and 52 men. SRM scores were derived from a two-week diary. The hypothesis was confirmed. There was a significant (rho = -0.4, p < 0.001) correlation between SRM (both metrics) and PSQI, indicating that subjects with higher levels of lifestyle regularity reported fewer sleep problems. This relationship was also supported by a categorical analysis, where the proportion of "poor sleepers" was doubled in the "irregular types" group as compared with the "non-irregular types" group. Thus, there appears to be an association between lifestyle regularity and good sleep, though the direction of causality remains to be tested.

NASA Program Biomedical Research and Countermeasur↗
NASA NTRS2005

In Vitro Experimental Model to Investigate the Biological Effects across the Bragg Curve of High-LET Radiation

The space environment consists of a varying field of radiation particles including high energy ions, with a spacecrafts shielding material providing the only major protection to astronauts from harmful exposure. Unlike lowLET gamma or Xrays, the presence of shielding does not always reduce the radiation risks for energetic charged particle exposure since the dose delivered by the charged particle increases sharply as the particle approaches the end of its range, a position known as the Bragg peak and the correlating spatial dose distribution identified as the Bragg curve. The Bragg curve does not necessarily represent the biological damage along the particle traversal since biological effects are influenced by the track structure of both primary and secondary particles. Therefore, the biological Bragg curve is dependent of the energy and the type of the primary particle, and may vary for different biological endpoints. Here we describe a unique irradiation geometry and experimental system to measure the biological response across the Bragg curve in one consistent biological sample. Polyethylene shielding was used to achieve a Bragg curve distribution with the beam geometry parallel to a monolayer of fibroblast cells. We present data that highlights the differential formation of DNA double strand breaks (DSBs) and chromosomal deletions across the Bragg curve in human fibroblasts irradiated with 600 MeV/nucleon iron ion beams. Qualitative analyses of gammaH2AX fluorescence, a known marker of DSBs, indicated potentially increased clustering of DNA damage before the Bragg peak, enhanced homogenous distribution at the peak, and provided visual evidence of high linear energy transfer (LET) particle traversal of cells beyond the Bragg peak in agreement with one-dimensional transport approximations. A biological response curve generated for micronuclei induction across the Bragg curve for 600 MeV/n Fe ions did not reveal an increase in the yield of micronuclei at the Bragg peak location. Assessment of such biological parameters employing the described in vitro experimental system may provide improved platforms to measure a number of biological consequences of shielding materials across the Bragg curve for high charge and energy (HZE) ions.

Desai, N.↗
NASA NTRS1977

Depositional history of the Apollo 16 deep drill core

Ferromagnetic resonance and magnetic hysteresis loop measurements were performed on 212 samples from the Apollo 16 deep drill core. The total iron content is generally uniform with a mean value of 5.7 plus or minus 0.9 wt%. The soils range in maturity from immature to mature. Two major contacts were observed. The contact at 13 cm depth represents a fossil surface whereas the contact at 190 cm depth has no time-stratigraphic significance. The data suggest that the core section below 13 cm depth was deposited in a single impact event and subjected to meteoritic gardening for about 450 m.y. However, our data do not preclude deposition by a series of closely spaced events. About 50 m.y. ago, the top 13 cm were added. Comparison with the Apollo 16 double drive tube 60009/60010 does not yield any evidence for a stratigraphic correlation with the deep drill core.

Gose, W. A.↗
NASA NTRS1994

Effects of thermomechanical processing on tensile and long-time creep behavior of Nb-1 percent Zr-0.1 percent C sheet

Effects of thermomechanical processing on the mechanical properties of Nb-1 wt. percent Zr-0.1 wt. percent C, a candidate alloy for use in advanced space power systems, were investigated. Sheet bars were cold rolled into 1-mm thick sheets following single, double, or triple extrusion operations at 1900 K. All the creep and tensile specimens were given a two-step heat treatment 1 hr at 1755 K + 2 hr 1475 K prior to testing. Tensile properties were determined at 300 as well as at 1350 K. Microhardness measurements were made on cold rolled, heat treated, and crept samples. Creep tests were carried out at 1350 K and 34.5 MPa for times of about 10,000 to 19,000 hr. The results show that the number of extrusions had some effects on both the microhardness and tensile properties. However, the long-time creep behavior of the samples were comparable, and all were found to have adequate properties to meet the design requirements of advanced power systems regardless of thermomechanical history. The results are discussed in correlation with processing and microstructure, and further compared to the results obtained from the testing of Nb-1 wt. percent Zr and Nb-1 wt. percent Zr-0.06 wt. percent C alloys.

Titran, Robert H.↗
NASA NTRS2012

Radio-to-Gamma-Ray Monitoring of the Narrow-line Seyfert 1 Galaxy PMN J0948+0022 from 2008 to 2011

We present more than three years of observations at different frequencies, from radio to high-energy γ-rays, of the Narrow-Line Seyfert 1 (NLS1) Galaxy PMN J0948+0022 (z = 0.585). This source is the first NLS1 detected at energies above 100 MeV and therefore can be considered the prototype of this emerging new class of γ-ray emitting active galactic nuclei (AGN). The observations performed from 2008 August 1 to 2011 December 31 confirmed that PMN J0948+0022 generates a powerful relativistic jet, which is able to develop an isotropic luminosity at gamma-rays of the order of 1048 erg per second, at the level of powerful quasars. The evolution of the radiation emission of this source in 2009 and 2010 followed the canonical expectations of relativistic jets with correlated multiwavelength variability (gamma-rays followed by radio emission after a few months), but it was difficult to retrieve a similar pattern in the light curves of 2011. The comparison of gamma-ray spectra before and including 2011 data suggested that there was a softening of the highenergy spectral slope. We selected five specific epochs to be studied by modelling the broad-band spectrum, which are characterised by an outburst at gamma-rays or very low/high flux at other wavelengths. The observed variability can largely be explained by changes in the injected power, the bulk Lorentz factor of the jet, or the electron spectrum. The characteristic time scale of doubling/halving flux ranges from a few days to a few months, depending on the frequency and the sampling rate. The shortest doubling time scale at gamma-rays is 2.3 +/- 0.5 days. These small values underline the need of highly sampled multiwavelength campaigns to better understand the physics of these sources.

monitoring↗
NASA NTRS2023

Measurement Report :Emission Factors of NH3 and NHx for Wildfires and Agricultural Fires in the United States

During the 2019 Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) study, the NASA DC-8 carried out in situ chemical measurements in smoke plumes emitted from wildfires and agricultural fires in the contiguous United States. The DC-8 payload included a modified proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) for the fast measurement of gaseous ammonia (NH 3 ) and a high-resolution time-of-flight aerosol mass spectrometer (AMS) for the fast measurement of submicron particulate ammonium (NH 4 + ). We herein report data collected in smoke plumes emitted from 6 wildfires in the Western United States, 2 prescribed grassland fires in the Central United States, 1 prescribed forest fire in the Southern United States, and 66 small agricultural fires in the Southeastern United States. Smoke plumes contained double to triple digit ppb levels of NH 3 . In the wildfire plumes, a significant fraction of NH 3 had already been converted to NH 4 + at the time of sampling (≥2 h after emission). Substantial amounts of NH 4 + were also detected in freshly emitted smoke from corn and rice field fires. We herein present a comprehensive set of emission factors of NH 3 and NH x , with NH x = NH 3 + NH 4 + . Average NH 3 and NH x emission factors for wildfires in the Western United States were 1.86±0.75 g kg −1 and 2.47±0.80 g kg −1 of fuel burned, respectively. Average NH 3 and NH x emission factors for agricultural fires in the Southeastern United States were 0.89±0.58 and 1.74±0.92 g kg −1 , respectively. Our data show no clear inverse correlation between modified combustion efficiency (MCE) and NH 3 emissions. The observed NH 3 emissions were significantly higher than measured in previous laboratory experiments in the FIREX FireLab 2016 study.

Laura Tomsche↗
NASA NTRS2001

Abiotic Versus Biotic Weathering Of Olivine As Possible Biosignatures

We are investigating the weathering of silicate minerals by both purely inorganic, and biologically mediated processes using field-emission scanning electron microscopy (FESEM) and energy dispersive x-ray spectroscopy (EDS). By resolving surface textures and chemical compositions of weathered surfaces at the sub-micron scale we hope to be able to distinguish abiotic from biotic weathering processes and so establish a new biosignature applicable to the study of astromaterials including but not limited to the Martian meteorites. Sterilized olivine grains (San Carlos, Arizona) no more than 1-2 mm in their longest dimension were optically assayed to be uniform in color and free of inclusions were selected as weathering subjects. Prior to all experiments surface morphologies and Fe/Mg ratios were determined for each grain using FE-SEM and EDS. Experiments were divided into two categories abiotic and biotic and were compared with "naturally" weathered samples. For the preliminary experiments, two trials (open and closed to the ambient laboratory environment) were performed under abiotic conditions, and three trials under biotic conditions (control, day 1 and day 2). The open system abiotic trials used sterile grains heated at 98 C and 200 C for both 24 and 48 hours in 1L double distilled de-ionized water. The closed system abiotic trials were conducted under the same conditions but in a sealed two layer steel/Teflon "bomb" apparatus. The biotic trials used sterile grains mounted in a flow-through device attached to a wellhead on the Columbia River aquifer. Several discolored, altered, grains were selected to document "natural" weathering surface textures for comparison with the experimental samples. Preliminary results indicate there are qualitative differences in weathered surface textures among all the designed experiments. The olivine grains in abiotic trials displayed etching, pitting, denticulate margins, dissolution and clay formation. The scale of the features ranged from tens to a few microns with textures that remained relatively sharp and were crystallographically controlled. These results were comparable to that observed in the "naturally" weathered comparison/reference grains. Chemical analysis by EDS indicates these textures correlated with the relative loss of Mg and Fe cations by diffusional processes. In contrast the biotic results indicated changes in the etching patterns on the scale of hundreds of nm, which are neither sharp nor crystallographically controlled (nanoetching). Organisms, organic debris and/or extracellular polymeric substances (biofilm) were often in close proximity or direct contact with the nanoetching. While there are many poorly constrained variables in natural weathering experiments to contend with, such as the time scale, the chemistry of the fluids and degree of biologic participation, some preliminary observations can be made: (1) certain distinct surface textures appear correlated with the specific processes giving rise to these textures; (2) the process of diffusing cations can produce many similar styles of surface textural changes; and (3) the main difference between abiotic and biotically produced weathering is the scale (microns versus nanometers) and the style (crystallographically versus noncrystallographically controlled) of the textural features. Further investigation into nanosize scale surface textures should attempt to quantify both textures and chemical changes of the role of microorganisms in the weathering of silicates. Additional experiments addressing nanoscale textures of shock features for comparison with the current data set.

Longazo, Teresa G.↗
NASA NTRS1993

Effects of processing and prolonged high temperature exposure on the microstructure of Nb-1Zr-C sheet

High temperature stability of the microstructure of Nb-1Zr sheet containing 0.1 and 0.06 wt. percent C was studied as affected by processing and prolonged 1350 K exposure with and without applied stress. Sheets were fabricated by cold rolling bars that were single-, double-, or triple-extruded at 1900 K. Creep samples were double-annealed (1 h at 1755 K + 2 h at 1475 K) prior to testing at 1350 K and 10,000 - 34,500 h. The microstructures of the as-cast, extruded, rolled, DA, and crept samples were characterized using various metallographic and analytical methods. The precipitates were rather coarse Nb2C initially, but transformed to finer (less than or equal to 1 micron) carbides of (Zr, Nb)C with each subsequent high temperature process. The grain size, and the relative amount and morphology of (Zr, Nb)C were found to be affected by the number of extrusions and to some extent by C-content. However, the microstructures of all the crept samples were similar with (Zr, Nb)C distributed throughout the matrix indicating that prolonged exposure to 1350 K gave rise to complete transformation of Nb2C to (Zr, Nb)C regardless of the processing history. These and other observations are presented with the emphasis on the correlation between processing, microstructure, and creep properties.

Uz, Mehmet↗
NASA NTRS1992

Static and dynamic strain energy release rates in toughened thermosetting composite laminates

In this work, the static and dynamic fracture properties of several thermosetting resin based composite laminates are presented. Two classes of materials are explored. These are homogeneous, thermosetting resins and toughened, multi-phase, thermosetting resin systems. Multi-phase resin materials have shown enhancement over homogenous materials with respect to damage resistance. The development of new dynamic tests are presented for composite laminates based on Width Tapered Double Cantilevered Beam (WTDCB) for Mode 1 fracture and the End Notched Flexure (ENF) specimen. The WTDCB sample was loaded via a low inertia, pneumatic cylinder to produce rapid cross-head displacements. A high rate, piezo-electric load cell and an accelerometer were mounted on the specimen. A digital oscilloscope was used for data acquisition. Typical static and dynamic load versus displacement plots are presented. The ENF specimen was impacted in three point bending with an instrumented impact tower. Fracture initiation and propagation energies under static and dynamic conditions were determined analytically and experimentally. The test results for Mode 1 fracture are relatively insensitive to strain rate effects for the laminates tested in this study. The test results from Mode 2 fracture indicate that the toughened systems provide superior fracture initiation and higher resistance to propagation under dynamic conditions. While the static fracture properties of the homogeneous systems may be relatively high, the apparent Mode 2 dynamic critical strain energy release rate drops significantly. The results indicate that static Mode 2 fracture testing is inadequate for determining the fracture performance of composite structures subjected to conditions such as low velocity impact. A good correlation between the basic Mode 2 dynamic fracture properties and the performance is a combined material/structural Compression After Impact (CAI) test is found. These results underscore the importance of examining rate-dependent behavior for determining the longevity of structures manufactured from composite materials.

Cairns, Douglas S.↗