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At least 55 records · Page 3

Organic carbon burial by river meandering partially offsets bank erosion carbon fluxes in a discontinuous permafrost floodplain

Abstract. Arctic river systems erode permafrost in their banks and mobilize particulate organic carbon (OC). Meandering rivers can entrain particulate OC from permafrost many meters below the depth of annual thaw, potentially enabling the production of greenhouse gases. However, the amount and fate of permafrost OC that is mobilized by river erosion is uncertain. To constrain OC fluxes due to riverbank erosion and deposition, we collected riverbank and floodplain sediment samples along the Koyukuk River, which meanders through discontinuous permafrost in the Yukon River watershed, Alaska, USA, with an average migration rate of 0.52 m yr−1. We measured sediment total OC (TOC) content, radiocarbon activity, water content, bulk density, grain size, and floodplain stratigraphy. Radiocarbon activity and TOC content were higher in samples dominated by silt as compared to sand, which we used to map OC content onto floodplain stratigraphy and estimate carbon fluxes due to river meandering. Results showed that the Koyukuk River erodes and re-deposits a substantial flux of OC each year due to its depth and high migration rate, generating a combined OC flux of a similar magnitude to the floodplain net ecological productivity. However, sediment being eroded from cutbanks and deposited as point bars had similar OC stocks (mean ± 1 SD of 125.3±13.1 kg OC m−2 in cutbanks versus 114.0±15.7 kg OC m−2 in point bars) whether or not the banks contained permafrost. We also observed radiocarbon-depleted biospheric OC in both cutbanks and permafrost-free point bars. These results indicate that a substantial fraction of aged biospheric OC that is liberated from floodplains by bank erosion is subsequently re-deposited in point bars rather than being oxidized. The process of aging, erosion, and re-deposition of floodplain organic material may be intrinsic to river–floodplain dynamics, regardless of permafrost content.

54 ENVIRONMENTAL SCIENCES↗

Multi-axial and multi-energy channeling study of disorder evolution in ion-irradiated nickel

In this study, to better understand defect structure and the evolution of irradiation-induced damage in single crystal Ni, in situ Rutherford backscattering spectroscopy in channeling geometry (RBS/C) is performed along the <100>, <110>, and <211> axes with different probing beam energies. The RBS/C data reveal that damage evolution occurs in three steps. The first step at low doses (up to 0.2 dpa), characterized by a linear increase with dose, is related to the formation of point defects and small clusters. The second step in the intermediate dose range (0.2–1.0 dpa) shows a sublinear increase in disorder to saturation. This sublinear increase is due to the growth of defect clusters resulting from the interaction of irradiation-induced defects with already existing damage from previous ion impacts. The third step at high doses (1.0–32.4 dpa) exhibits a surprising decrease in the disorder level, which may be attributed to defect evolution from black spot defects to large dislocation loops that leads to strain relaxation. In addition, the damage extends much deeper than the predicted depths and is attributed to long-range defect migration effects confirmed by transmission electron microscopy (TEM) observations. Although similar damage evolution trends have been observed along all channeling directions, the disorder accumulation is largest along the <100> and <211> axes than observed along <110> axis. This “preferential” disordering process along <100> and <211> suggests that more defects are shielded by the <110> atomic rows than the two other axes. Finally, the co-existence of both uncorrelated displaced lattice atoms and dislocation loops in Ni irradiated at 1 ion/nm 2 is revealed by the energy-dependent RBS/C studies along all three axes. In contrast, dislocation loops and stacking fault tetrahedral are simultaneously present in the crystal structure of Ni irradiated at 100 ions/nm 2 that is consistent with previous molecular dynamics simulations and TEM observations.

36 MATERIALS SCIENCE↗

Reduced ENSO Variability at the LGM Revealed by an Isotope-Enabled Earth System Model

Studying the El Nino Southern Oscillation (ENSO) in the past can help us better understand its dynamics and improve its future projections. However, both paleoclimate reconstructions and model simulations of ENSO strength at the Last Glacial Maximum (LGM; 21 ka B.P.) have led to contradicting results. Here we perform model simulations using the recently developed water isotope-enabled Community Earth System Model (iCESM). For the first time, model-simulated oxygen isotopes are directly compared with those from ENSO reconstructions using the individual foraminifera analysis (IFA). We find that the LGM ENSO is most likely weaker comparing with the preindustrial. The iCESM suggests that total variance of the IFA records may only reflect changes in the annual cycle instead of ENSO variability as previously assumed. Furthermore, the interpretation of subsurface IFA records can be substantially complicated by the habitat depth of thermocline-dwelling foraminifera and their vertical migration with a temporally varying thermocline.

El Niño–Southern Oscillation;isotope-enabled si↗

Mars: Long Term Changes in the State and Distribution of H2O

A model for H2O distribution and migration on Mars was formulated which takes into account: (1) thermal variations at all depths in the regolith due to variations in obliquity, eccentricity and the solar constant; (2) variations in atmospheric PH2O caused by corresponding changes in polar surface insolation; and (3) the finite kinetics of H2O migration in both the regolith and atmosphere. Results suggest that regolith H2O transport rates are more strongly influenced by polar-controlled atmospheric PH2O variations than variations in pore gas PH2O brought about by thermal variations at the buried ice interface. The configuration of the ice interface as a function of assumed soil parameter and time is derived. Withdrawal of ice proceeds to various depths at latitudes less than 50 deg and is accompanied by filling of regolith pores at latitudes greater than 50 deg and transfer of H2O to the polar cap. The transfer has a somewhat oscillatory character, but only less than 1g/sq cm is shifted into and out the regolith during each obliquity cycle. It is concluded that this process combined with periodic thermal cycles played a major role in development of the fretted terrain, deflationary features in general, patterned ground, the north polar cap and the layered terrain.

Fanale, F. P.↗

Feasibility Assessment of Long-Term Electrical Resistivity Monitoring of a Nitrate Plume

Long-term monitoring solutions at contaminated sites are necessary to track plume migration and evaluate the performance of remediation efforts. Electrical resistivity imaging (ERI) can potentially provide information about plume dynamics; however, the feasibility and likelihood of success is seldom evaluated before conducting a field study. Coupling flow and transport models with geoelectrical models provides a powerful way to assess the potential effectiveness of an actual ERI field campaign. in this paper, we present a coupled approach for evaluating the feasibility of monitoring nitrate migration and remediation using 4D time-lapse ERI at a legacy nuclear waste facility. This kilometer-scale study focuses on depths below the water table (~70 m). A flow and transport model is developed to perform simulations of nitrate migration and removal via a hypothetical pump-and-treat system. A tracer injection is also simulated at the leading edge of the nitrate plume to enhance the conductivity contrast between the native subsurface and the groundwater fluids. Images of bulk conductivity provide limited information concerning plume migration while time-lapse difference images, which remove the static effects of geology, provide more useful information concerning plume dynamics over time. A spatial moment analysis performed on flow and transport and ERI models matches well during the tracer injection; however, inversion regularization smoothing otherwise limits the value in terms of locating the center of mass. We find that the addition of a tracer enables ERI to characterize plume dynamics during pump-and-treat operations, and late-time ERI monitoring provides a conservative estimate of nitrate plume boundaries in this synthetic study.

54 ENVIRONMENTAL SCIENCES↗

Interfacial Characterization of Positive Bias Voltage Degradation in PV Modules

Degradation from high system voltage is a prevailing failure mode in fielded photovoltaic modules, and the degradation mechanism is inherently dependent on the bias polarity. Here we report the effects of positive bias. Modules under positive bias demonstrated a significant photocurrent loss caused by two routes. First, delamination and discoloration of the silicon nitride layer, leading to optical loss determined by reflectance measurements. Second, chemical discoloration of the cell gridlines and encapsulant (EVA), which is linked to an electrochemical reaction at the silver electrodes. Chemical compositional analysis using X-ray photoemission spectroscopy demonstrated that the discoloration is attributed to Ag 2 S and/or Ag 2 O. Evidence of Ag ion migration from the cell grid into the encapsulant is observed after shallow depth profiling on the EVA surface. However, Ag was not detected at the EVA/glass interface, inferring limited Ag ion transport through the EVA. The source of sulfur is believed to be ambient air, which diffused into the module through the breathable backsheet.

characterization↗

Aqueous Alteration on Mars

The occurrence of extensive valley networks and layered deposits of phyllosilicates and sulfates during the late Noachian/Hesperian periods (approx. 3-4 Gyrs) indicates a past martian climate that was capable of maintaining liquid water at the surface. The planet’s climate drastically changed after these early “episodes” of water to a drier and colder environment during the Amazonian period (past 3.0 Gyrs). The objective of this paper is to describe aqueous alteration/weathering scenarios on Mars based on observations returned by rover and lander missions. The chemistry of most outcrops, rocks, and “soils” that have interacted with water has not been extensively changed from average Mars crustal basaltic composition. Little chemical variation suggests closed hydrologic systems were prominent on early Mars and/or the water/rock ratios were low. Open hydrologic systems occur at local scales, e.g., high Si and Ti rocks and “soil” deposits around a volcanic feature in Gusev crater. Geochemical and mineralogical indicators for aqueous alteration include jarosite and other Fe-sulfates at several locations suggesting acid-sulfate alteration conditions. High Si and Ti rocks, sediments, and “soil” deposits are consistent with basaltic residues extenively leached by extremely acidic fluids. Variations in the Fe/Mn ratio of fracture veins infilled with sulfate-rich materials suggest changes in redox and/or pH conditions of the migrating fluids. The increase of nanophase iron oxides and salts with depth in several “soil” pits escavated by the Spirit rover’s wheel in Gusev crater suggests the translocation/mobolization of these phases by liquid water. This “pedogenic” process is the result of limited water movement through the surface sediments during the Amazonian period; however, it is likely that paleosols exist on Mars that formed during the early “wetter” history of the planet. Soil scientists have the opportunity to continue to (and should) be involved in the exploration of the Red planet.

Ming, Douglas W.↗

Migration of noble gas tracers at the site of an underground nuclear explosion at the Nevada National Security Site

As part of an underground gas migration study, two radioactive noble gases and two stable tracer gases were injected into a nuclear explosion test chimney and allowed to migrate naturally. Soil gas samples were collected from a series of boreholes and a range of depths from the shallow subsurface (3 meters) to deeper levels (~160 meters) over a period of eleven months. These samples have provided insights into the development and evolution of the subsurface plume and constrained the relative migration rates of the radioactive and stable gas species. Analysis of the samples concluded that the stable tracer SF6 was consistently enriched in the subsurface samples relative to the radiotracer 127Xe, but the ratios of SF6 and 37Ar remained similar throughout the samples.

Johnson, Christine M.↗

Three-dimensional migration behavior of juvenile salmonids in reservoirs and near dams

To acquire 3-D tracking data on juvenile salmonids, Juvenile Salmon Acoustic Telemetry System (JSATS) cabled hydrophone arrays were deployed in the forebays of two dams on the Snake River and at a mid-reach reservoir between the dams. The depth distributions of fish were estimated by statistical analyses performed on large 3-D tracking data sets from ~33,500 individual acoustic tagged yearling and subyearling Chinook salmon and juvenile steelhead at the two dams in 2012 and subyearling Chinook salmon at the two dams and the mid-reach reservoir in 2013. This research investigated the correlation between vertical migration behavior and passage routes. The depth distributions of fish within the forebays of the dams were significantly different from fish passing the mid-reach reservoir. Fish residing deeper in the forebay tended to pass the dam using deeper powerhouse routes. This difference in depth distributions indicated that the depth distribution of fish at the mid-reach reservoir was not related to behaviors of fish passing through certain routes of the adjacent dams. For fish that were detected deeper than 17.5 m in the forebays, the probability of powerhouse passage (i.e., turbine) increased significantly. Another important finding was the variation in depth distributions during dam passage associated with the diel period, especially the crepuscular periods.

59 BASIC BIOLOGICAL SCIENCES↗

Propagation of viral genomes by replicating ammonia-oxidising archaea during soil nitrification

Ammonia-oxidising archaea (AOA) are a ubiquitous component of microbial communities and dominate the first stage of nitrification in some soils. While we are beginning to understand soil virus dynamics, we have no knowledge of the composition or activity of those infecting nitrifiers or their potential to influence processes. This study aimed to characterise viruses having infected autotrophic AOA in two nitrifying soils of contrasting pH by following transfer of assimilated CO 2 -derived 13 C from host to virus via DNA stable-isotope probing and metagenomic analysis. Incorporation of 13 C into low GC mol% AOA and virus genomes increased DNA buoyant density in CsCl gradients but resulted in co-migration with dominant non-enriched high GC mol% genomes, reducing sequencing depth and contig assembly. We therefore developed a hybrid approach where AOA and virus genomes were assembled from low buoyant density DNA with subsequent mapping of 13 C isotopically enriched high buoyant density DNA reads to identify activity of AOA. Metagenome-assembled genomes were different between the two soils and represented a broad diversity of active populations. Sixty-four AOA-infecting viral operational taxonomic units (vOTUs) were identified with no clear relatedness to previously characterised prokaryote viruses. These vOTUs were also distinct between soils, with 42% enriched in 13 C derived from hosts. The majority were predicted as capable of lysogeny and auxiliary metabolic genes included an AOA-specific multicopper oxidase suggesting infection may augment copper uptake essential for central metabolic functioning. These findings indicate virus infection of AOA may be a frequent process during nitrification with potential to influence host physiology and activity.

59 BASIC BIOLOGICAL SCIENCES↗

The ARGOS system used for tracking gray whales

The development of satellite whale tags used to track gray whales in the eastern north Pacific Ocean is summarized. Two gray whales were radio-tagged in San Ignacio Lagoon (Mexico) and tracked on their northbound migration. One of the transmitters was modified to record and relay depth-of-dive information at 15 sec intervals throughout the course of the dive. Technical elements of data acquisition and analysis are outlined. The major biological findings are discussed.

Mate, B. R.↗

Analysis of position-dependent cavity parameters in irradiated metals to obtain insight on fundamental defect migration phenomena

Motion of point defects is a fundamental process that governs microstructure and properties of materials. Here, we examine the near-surface and grain boundary cavity swelling depth profiles in neutron- and ion-irradiated simple metals (Cu, Ni, and Fe-Cr) and investigate diffusional broadening of implanted Ni ions in Fe-Cr alloys. Vacancy migration energies and radiation-enhanced diffusion were experimentally estimated. Cavity denuded zone widths near planar sinks are shown to be dependent on temperature, damage rate, balance of point defects and sinks, and vacancy migration energies. An enhanced cavity swelling zone adjacent to the void-denuded zone was observed in specimens with low to moderate sink strength and interpreted as evidence of 1D gliding interstitial clusters. Radiation-enhanced diffusional broadening of implanted Ni ions (at 400–550 °C) in Fe and Fe-Cr was up to 250 nm toward the surface, which leads to a much broader near-peak-damage region where cavity swelling is suppressed. Diffusional broadening of implanted ions is calculated to be similarly pronounced for self-ion irradiations, particularly near the peak and higher swelling temperature regimes. Adequately high ion energies (~8–15 MeV) are recommended for ion-irradiation studies to provide a sufficiently broad midrange safe analysis region with minimized surface and injected ion effects.

36 MATERIALS SCIENCE↗

Cosmic Ray Mantle Visibility on Kuiper Belt Objects

Optically red objects constitute the dynamically cold, old component of the Classical Kuiper Belt (40 - 47 AU) with heliocentric orbits of low eccentricity and inclination. The red colors likely arise from primordial mixed ices processed by irradiation to meters in surface depth over the past four billion years, since the time of giant planet migration and Kuiper Belt stirring, at relatively moderate dosages of 60 gigarads provided by galactic cosmic ray protons and heavier ions. The red cosmic ray mantle is uniformly visible on the cold classical objects beneath a minimally thin eroded layer of more neutrally colored material arising from cumulative effects of heliospheric particle irradiation. The radiation fluxes are lowest in the middle heliospheric region containing the Classical Kuiper Belt and increase from there both towards and away from the Sun. Despite increasing irradiation at various times of solar system history from increases in solar and interstellar ion fluxes, the red object region has apparently never reached sufficiently high dosage levels to neutralize in color the red mantle material. Erosion processes, including plasma sputtering and micrometeroid impacts, act continuously to reduce thickness of the upper neutral crust and expose the cosmic ray mantle. A deeper layer at tens of meters and more may consist of relatively unprocessed ices that can erupt to the surface by larger impacts or cryovolcanism and account for brighter surfaces of larger objects such as 2003 UB313. Surface colors among the Kuiper Belt and other icy objects of the outer solar system are then a function, assuming uniform primordial composition, of relative thickness for the three layers and of the resurfacing age dependent on the orbital and impact history of each object.

Cooper, John F.↗

New Formation Models for the Kepler-36 System

Formation of the planets in the Kepler-36 system is modeled here by detailed numerical simulations according to the core-nucleated accretion scenario. The standard model is updated to include the dissolution of accreting rocky planetesimals in the gaseous envelope of the planet, leading to substantial enrichment of the envelope mass in heavy elements and a non-uniform composition with depth. For Kepler-36 c, models involving in situ formation and models involving orbital migration are considered. The results are compared with standard formation models. The calculations include the formation (accretion) phase as well as the subsequent cooling phase, up to the age of Kepler-36 (7 Gyr). During the latter phase, mass loss induced by stellar XUV radiation is included. In all cases, the results fit the measured mass, 7.84 M ⊕ , and radius, 3.68 R ⊕ , of Kepler-36 c. Two parameters are varied to obtain these fits: the disk solid surface density at the formation location and the "efficiency" factor in the XUV mass-loss rate. The updated models are hotter and therefore less dense in the silicate portion of the planet and in the overlying layers of H/He, as compared with standard models. The lower densities mean that only about half as much H/He is needed to be accreted to fit the present-day mass and radius constraints. For Kepler-36 b, an updated in situ calculation shows that the entire H/He envelope is lost, early in the cooling phase, in agreement with observation.

79 ASTRONOMY AND ASTROPHYSICS↗

New Formation Models for the Kepler-36 System

Formation of the planets in the Kepler-36 system is modeled by detailed numerical simulations according to the core-nucleated accretion scenario. The standard model is updated to include the dissolution of accreting rocky planetesimals in the gaseous envelope of the planet, leading to substantial enrichment of the envelope mass in heavy elements and a non-uniform composition with depth. For Kepler-36 c, models involving in situ formation and models involving orbital migration are considered. The results are compared with standard formation models. The calculations include the formation (accretion) phase, as well as the subsequent cooling phase, up to the age of Kepler-36 (7 Gyr). During the latter phase, mass loss induced by stellar XUV radiation is included. In all cases, the results fit the measured mass, 7.84 M, and radius, 3.68 R, of Kepler-36 c. Two parameters are varied to obtain these fits: the disk solid surface density at the formation location, and the "efficiency" factor in the XUV mass loss rate. The updated models are hotter and therefore less dense in the silicate portion of the planet and in the overlying layers of H/He, as compared with standard models. The lower densities mean that only about half as much H/He is needed to be accreted to fit the present-day mass and radius constraints. For Kepler-36 b, an updated in situ calculation shows that the entire H/He envelope is lost, early in the cooling phase, in agreement with observation.

planets and satellites:formation↗

Interfacial structure and bonding mechanism of weld seams during porthole die extrusion of aluminum alloy profiles

Highlights: • Interfacial structures and bonding mechanisms of extrusion welds were studied. • Interfacial grain boundaries, amorphous layers and voids were found. • Bonding mechanisms in the absence/presence of a gas-pocket were proposed. • Voids closure, oxide films breaking and grain boundaries migration were discussed. - Abstract: Fine nanostructures of bonding interfaces of weld seams formed by porthole die extrusion in the absence/presence of a gas-pocket behind the bridge of the extrusion die were systematically studied to understand the underlying interfacial bonding mechanisms. Interfacial grain boundaries, nanoscale amorphous layers, and three kinds of new interfacial structures were found. Specifically, it was found that, in the absence of a gas-pocket behind the bridge, there are two distinctly different interfacial structures. For the first kind of bonding interface, interfacial grain boundaries exist in contact areas and micro-voids exist in non-contact areas. For the second kind of bonding interface, there are no interfacial grain boundaries in contact areas and only nanoscale micro-voids exist in non-contact areas. In the presence of a gas-pocket behind the bridge, nanoscale voids and amorphous layers exist at the bonding interface. It was also found that the formation of gas-pockets can be avoided by increasing the depth of the welding chamber, and the increase of the welding chamber's depth and extrusion speed also contributes to the volume reduction of micro-voids and the migration of grain boundaries at the bonding interface, so as to improve the welding quality of weld seams. Based on the experimental findings, two interfacial bonding mechanisms corresponding to the absence/presence of a gas-pocket are proposed. The specific behavior of micro-asperities contact, micro-voids closure, oxide films breaking and interfacial grain boundaries migration are described, and the solid-state bonding process during porthole die extrusion is revealed from the micro-nano scales.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Internal Structure of the Central Garlock Fault Zone From Ridgecrest Aftershocks Recorded by Dense Linear Seismic Arrays

Abstract We provide high‐resolution seismic imaging of the central Garlock fault using data recorded by two dense seismic arrays that cross the Ridgecrest rupture zone (B4) and the Garlock fault (A5). Analyses of fault zone head waves and P ‐wave delay times at array A5 show that the Garlock fault is a sharp bimaterial interface with P waves traveling ∼5% faster in the northern crustal block. The across‐fault velocity contrast agrees with regional tomography models and generates clear P ‐wave reflections in waveforms recorded by array B4. Kirchhoff migration of the reflected waves indicates a near‐vertical fault between 2 and 6 km depth. The P ‐wave delay times imply a ∼300‐m‐wide transition zone near the Garlock fault surface trace beneath array A5, offset to the side with faster velocities. The results provide important constraints for derivations of earthquake properties, simulations of ruptures and ground motion, and future imaging studies associated with the Garlock fault.

58 GEOSCIENCES↗

AI in Space: The Era of Autonomous Space Systems

The development of autonomy capabilities is the key to three vastly important strategic technical challenges facing NASA: the reduction of mission costs, the continuing return of quality science products through limited communications bandwidth, and the launching of a new era of solar system exploration characterized by sustained presence and in-depth scientific studies, including the search for life. Autonomy will benefit future NASA missions by migrating routine, traditionally ground-based functions to the spacecraft, by directly supporting the decoupling of spacecraft from the ground through new operations concepts, by enabling direct links between scientists and the space platforms carrying their instruments of investigation, and by the closing, of planning and control loops onboard, enabling space platforms to directly address uncertainty in the real-time mission context. The talk will survey ongoing, autonomy technology development projects at NASA, many of which have been or will soon be the subject of flight technology experiments, or are already targeted for mission use. The talk will also survey the exciting suite of future NASA space exploration missions, and make the case for the central role of autonomy in achieving the goals of these bold, unprecedented missions: cooperating rovers on the surface of Mars, the search for Earth-like planets around nearby stars, asteroid and comet landers, aerobots in planetary atmospheres, and a series of missions to intriguing Europa, perhaps culminating in a submersible to investigate its putative ocean. Finally, the talk will conclude with some farther-reaching speculations on how to create properties such as long-term survivability and evolvability in future space systems, such that they will be well equipped to extend humanity exploratory presence into the interstellar realm.

Doyle, Richard J.↗