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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Scalable Variable Charge Molecular Dynamics Simulations of Metal-Oxide Systems

Interfaces between metals and oxides are an important feature in many technologically relevant materials, e.g., oxidation of metal surfaces, oxide-dispersion strengthened (ODS) alloys, dielectric components, and thermal barrier coatings among others. Experimental studies of such interfaces are challenging since the majority are buried within the bulk, making computational modeling an attractive alternative. Molecular dynamics (MD) simulations operate at the length scales relevant to many interface-mediated mechanisms, but the requisite interatomic potentials for metal-oxide systems require computationally expensive variable charge schemes to account for the disparate bonding types, thus often limiting their effectiveness. Here we introduce several improvements to the charge transfer interatomic potential (CTIP) model which enable greater computational efficiency for large scale MD simulations. Then, using a new CTIP parametrization for the Ni-O system, we demonstrate its capabilities to capture critical atomic scale mechanisms associated with metal-oxide interfaces. Long time scale simulations (>10 ns) are used to investigate high temperature oxidation and oxide precipitation from the melt, and large length scale simulations (> 1 million atoms) are used to study the interaction of dislocations with oxide particles. We have implemented the new CTIP model in the widely used, open-source MD code LAMMPS.

Gabriel Plummer↗
NASA NTRS1991

Diurnal water relations of walnut trees - Implications for remote sensing

Leaflet water content (WC), relative water content (RWC), and water potential, Phi(lf) were measured as indicators of diurnal change in tree water status in an experimental walnut orchard receiving two irrigation treatments: 100 and 33 percent of potential evapotranspiration (PET). Diurnal change was greatest in Phi(lf) throughout the experimental period, with minima occurring each day in early to mid-afternoon and maxima between midnight and sunrise. Leaflet WC and RWC were lower in the afternoon than at night, but had greater variability so that the diurnal pattern was not as clear. Comparison between the pattern of Phi(lf) and dielectric constants (DCs) measured from probes inserted 2 cm into a tree hole showed that both declined nearly in parallel in the morning. Phi(lf) recovered more rapidly than DC in the afternoon. This temporal discrepancy could be caused by cavitation of xylem elements in the vicinity of the DC probe. Microwave backscatter for L- and X-bands also measured diurnal variation that had local minima in the afternoon, but the pattern among wavelength and polarization signatures was complex.

Weber, James A.↗
NASA NTRS2009

Electrically Variable or Programmable Nonvolatile Capacitors

Electrically variable or programmable capacitors based on the unique properties of thin perovskite films are undergoing development. These capacitors show promise of overcoming two important deficiencies of prior electrically programmable capacitors: Unlike in the case of varactors, it is not necessary to supply power continuously to make these capacitors retain their capacitance values. Hence, these capacitors may prove useful as components of nonvolatile analog and digital electronic memories. Unlike in the case of ferroelectric capacitors, it is possible to measure the capacitance values of these capacitors without changing the values. In other words, whereas readout of ferroelectric capacitors is destructive, readout of these capacitors can be nondestructive. A capacitor of this type is a simple two terminal device. It includes a thin film of a suitable perovskite as the dielectric layer, sandwiched between two metal or metal oxide electrodes (for example, see Figure 1). The utility of this device as a variable capacitor is based on a phenomenon, known as electrical-pulse-induced capacitance (EPIC), that is observed in thin perovskite films and especially in those thin perovskite films that exhibit the colossal magnetoresistive (CMR) effect. In EPIC, the application of one or more electrical pulses that exceed a threshold magnitude (typically somewhat less than 1 V) gives rise to a nonvolatile change in capacitance. The change in capacitance depends on the magnitude duration, polarity, and number of pulses. It is not necessary to apply a magnetic field or to cool the device below (or heat it above) room temperature to obtain EPIC. Examples of suitable CMR perovskites include Pr(1-x)Ca(x)MnO3, La(1-x)S-r(x)MnO3,and Nb(1-x)Ca(x)MnO3. Figure 2 is a block diagram showing an EPIC capacitor connected to a circuit that can vary the capacitance, measure the capacitance, and/or measure the resistance of the capacitor.

Shangqing, Liu↗
NASA NTRS2013

Development of a Real Time Internal Charging Tool for Geosynchronous Orbit

The high-energy electron fluxes encountered by satellites in geosynchronous orbit pose a serious threat to onboard instrumentation and other circuitry. A substantial build-up of charge within a satellite's insulators can lead to electric fields in excess of the breakdown strength, which can result in destructive electrostatic discharges. The software tool we've developed uses data on the plasma environment taken from NOAA's GOES-13 satellite to track the resulting electric field strength within a material of arbitrary depth and conductivity and allows us to monitor the risk of material failure in real time. The tool also utilizes a transport algorithm to simulate the effects of shielding on the dielectric. Data on the plasma environment and the resulting electric fields are logged to allow for playback at a variable frame rate.

Posey, Nathaniel A.↗
NASA NTRS1974

External insulation systems for cryogenic storage systems. Volume 1: Optical properties of Kapton and report of process variable study

Investigations are conducted into the optical properties of the glass and Kapton substrate materials, and three variables were chosen: deposition rate, sputter gas pressure, and film contamination time. Substrate tests have shown that fabrication of an dielectric broadband reflector would require an extremely complex and expensive filter design.

Frank, A. M.↗
NASA NTRS1991

Emerging polyheterocyclic films, coatings and resins - Thermoplastic polyquinolines

The processing and performance characteristics of a soluble, thermoplastic polyquinoline suggest its utility in a variety of high performance applications. The polymer is characterized by excellent thermal and oxidative stability, very low moisture absorption, good mechanical properties, very low dielectric constant, and an unusually low thermal expansion coefficient. This polymer, designated PQ-100 (TM), can be cast into strong, transparent, free standing films from common solvents. Coatings of variable thickness can be spin-coated on to silicon and other surfaces. After processing into films, PQ-100 (TM) can be rendered insoluble in a wide range of solvents using a proprietary process. The low CTE contributes to very low residual stress when the polymer is spin-coated onto silicon wafers. PQ-100 (TM) is currently under evaluation for use as an interlayer dielectric substrate in high-density interconnect applications, including multichip modules. Many of the characteristics of the polymer also suggest its utility as a high-performance film and as a matrix resin for specialty composite applications.

Hendricks, Neil H.↗
NASA NTRS1983

Electromagnetic backscattering from a layer of vegetation - A discrete approach

Electromagnetic backscattering from a layer of vegetation over a flat lossy ground is studied. The vegetated region is composed of leaves which are modeled by lossy circular dielectric discs with prescribed orientation statistics. The mean field in the layer is computed by using the Foldy approximation and a two-variable technique which is valid for small fractional volume. Simple expressions are given for the skin depth of the mean wave. Following this, the distorted Born approximation is used to calculate the co-polarized and cross polarized backscattering coefficients. These are then computed as a function of angle of incidence for different layer depths and leaf configurations.

Lang, R. H.↗
NASA NTRS1988

Maser Oscillator With Dielectric Resonators

Two-resonator design yields low phase noise. Oscillator exhibits phase noise intermediate between phase noises of unstablized microwave oscillators and stabilized ruby-maser oscillators with superconducting cavities. Contains two total-internal-reflection dielectric resonators in normally-conductive copper cavity. Two-resonator maser design provides phase stability, isolation between pump and output channels, and variable maser coupling.

Dick, G. John↗
NASA NTRS1976

Thermal analysis of PMR-polyimides by dielectrometry

A preliminary study was conducted to determine the dielectric properties of glass fabric reinforced composites as influenced by the reactions occurring during the preparation of crosslinked polyimides by the PMR process. The variables studied included: formulated molecular weight, staging temperature and time; rate of temperature increase to cure temperature; and cure temperature and time. The changes of capacitance and, particularly, of dissipation factor were found to be strongly dependent on each of the variables studied.

Gluyas, R. E.↗
NASA NTRSDate not supplied

Printed Electrochemical Sensor for Quantifying Bone Density Loss in Microgravity

Printed electrochemical biosensors have been developed for astronaut point-of-care testing. Our fabrication approach is complimentary with in-space manufacturing for an on-demand and hands-free fabrication process. These sensors are developed using a combination of thin film materials printing and 3D printing and are comprised of carbon nanotube, gold nanoparticle, silver nanoparticle and dielectric inks to make traditional electrochemical sensor devices. Initial prototyped printed electrochemical sensors demonstrate good electrochemical performance while also displaying low batch to batch variability. Here we report the development of a printed sensor to monitor bone turnover. The absence of load bearing forces experienced in microgravity causes a reduction of overall bone mass and results in the development of space osteopenia/osteoporosis.(1,2) Our approach to identify space osteopenia/osteoporosis is to monitor the change in bone mass indirectly through an excreted biomarker of bone remodeling, amino-terminal collagen crosslinks (NTX). Antibodies specific to NTX are added to the sensor’s electrode ink and applied during the manufacturing process. NTX is measured from a urine sample by changes in voltammetry and electrochemical impedance as it binds to the antibody modified electrode surface. The measurement is rapid, quantitative and requires only small handheld electronics to perform the measurement. By this process, ground and flight physicians will receive frequent and real-time insight into the development of space osteopenia/osteoporosis to guide appropriate countermeasures. REFERENCES [1] Nabavi, N. et al (2011) Bone 49, 965-974. [2] Tamma, R. et al (2009) FASEB J 23, 2549-2554.

in-space manufacturing↗
NASA NTRS1987

Martian surface physical properties to be derived by radar altimeter on the Mars observer spacecraft

The potential is described of a candidate Mars Observer altimeter for determining dielectric properties of Mars regolith. It is pointed out that it is straightforward to use the time between altimeter pulse trains for passive radiometry (hence dielectric properties) and roughness can be derived. Given the mission plan the whole surface can be mapped at least three times, yielding data on seasonal variability.

Garvin, J. B.↗
NASA NTRS1979

Solar-induced variations of environment affecting manned space flight and spacecraft operations

Estimates of short and long term solar activity are required for calculating variations in the environment with regard to spacecraft charging, radiation effects, and orbital lifetime. Correlations appear to exist between the time of solar activity and the time of operational anomalies due to electrical discharges when the dielectric surfaces of geosynchronous spacecraft are charged by interaction with the ambient plasma to levels above breakdown voltage. An ability to predict the solar induced variation variability of the plasmas could permit refinement of design criteria. The influence of the radiation on spacecraft materials, systems, and manned operations is summarized. Solar radition effects on the orbital altitude atmospheric density environment and spacecraft lifetimes are also considered.

Johnson, W. G.↗
NASA NTRS1985

Discharge pulse phenomenology

A model was developed which places radiation induced discharge pulse results into a unified conceptual framework. Only two phenomena are required to interpret all space and laboratory results: (1) radiation produces large electrostatic fields inside insulators via the trapping of a net space charge density; and (2) the electrostatic fields initiate discharge streamer plasmas similar to those investigated in high voltage electrical insulation materials; these streamer plasmas generate the pulsing phenomena. The apparent variability and diversity of results seen is an inherent feature of the plasma streamer mechanism acting in the electric fields which is created by irradiation of the dielectrics. The implications of the model are extensive and lead to constraints over what can be done about spacecraft pulsing.

Frederickson, A. R.↗
NASA NTRS2004

CoSSIR: A New Instrument for Exploring the Utility of Submillimeter-wave Radiometry for Earth Observation

The Conical Scanning Submillimeter-wave Imaging Radiometer (CoSSIR) has been developed to study the application of submillimeter-wave radiometry for remote sensing of cirrus clouds and humidity sounding. Measurements of the global distribution of ice cloud mass and particle size are important for understanding the Earth s energy budget and for evaluating global climate models. The spatial variability and the wide variety of cloud particle shapes and sizes make ice clouds particularly difficult to measure. Ice clouds are essentially undetectable at microwave frequencies due to the low dielectric of ice and small size of the particles relative to wavelength. However, submillimeter wavelengths demonstrate significant response to the presence of ice clouds thus this frequency regime is applicable to measuring ice clouds. Another potentially viable application for submillimeter-wave radiometry is humidity and temperature sounding. The principle of sounding at submillimeter wavelengths is similar to that at microwavelengths. Submillimeter-wave radiometry has the advantage of achieving finer spatial resolution using a smaller antenna aperture which is an important consideration for spaceborne observatories. Submillimeter-wave radiometry also offers the potential of sounding over land and as a surrogate measurement for precipitation. CoSSIR is a new instrument to explore these applications. The CoSSIR is designed to fly aboard the ER-2 aircraft and its modest size (approximately 100 kg) permits it to be configured for other aircraft. A dual-axes gimbals mechanism provides conical, across-track, and along-track scanning capability. In its present configuration CoSSIR has fifteen channels between 183 GHz and 640 GHz. Three channels are centered about the 183 GHz water vapor absorption line, four channels are centered about the 380 GHz water vapor absorption line, and three dual-polarized channels are centered about the 487 GHz oxygen absorption line. Two channels are located in atmospheric windows at 220 GHz and 640 GHz. All channels are single-linear polarized with the exception of those near 487 GHz. Calibration is achieved by periodically observing two blackbody radiators; one blackbody is heated to approximately 325 K and the other is approximately 250 K during flight. Details of the instrument design as well as measurements from the Cirrus Regional Study of Tropical Anvils and Cirrus Layers - Florida Area Cirrus Experiment will be presented.

Racette, P. E.↗
NASA NTRS1980

Theoretical regime diagrams for thermally driven flows in a beta-plane channel in the presence of variable gravity

The effect of a power law gravity field on baroclinic instability is examined, with a focus on the case of inverse fifth power gravity, since this is the power law produced when terrestrial gravity is simulated in spherical geometry by a dielectric force. Growth rates are obtained of unstable normal modes as a function of parameters of the problem by solving a second order differential equation numerically. It is concluded that over the range of parameter space explored, there is no significant change in the character of theoretical regime diagrams if the vertically averaged gravity is used as parameter.

Geisler, J. E.↗
NASA NTRS1972

Some methods for determining the profile functions of inhomogeneous media

The problem of determining the electric permittivity of an inhomogeneous dielectric medium is considered. Two analytical methods and one numerical method for solving this problem are presented. All these methods utilize the reflection coefficient measured as a function of the angular spectrum variable. This allows measurements at a fixed frequency, and these methods, therefore, can be used when the medium being studied is dispensive. A few examples are provided and some comments are made regarding the stability of solutions obtained using the various methods.

Mittra, R.↗
NASA NTRS1975

Temperatures and thermophysical properties of the lunar outermost layer

Comparisons of calculated diurnal and eclipse temperatures of the lunar outermost layer are made with earth-based infrared and millimeter data. The thermophysical model upon which the calculations are based incorporates variable physical properties. The thermal conductivity is a function of both density (depth) and temperature; the specific heat is a function of temperature; the density is a function of depth; and the dielectric constant and loss tangent are functions of density (depth). Laboratory measurements and Apollo-sample results are incorporated in the property data. Calculational cases are based largely upon different density profiles. The model is consistent with the data, and the comparisons of theoretical and observational temperatures are very favorable. For such comparisons, further sophistication of the thermophysical model of the outermost layer is probably not justified.

Jones, W. P.↗
NASA NTRS1988

Design guide: Designing and building high voltage power supplies, volume 2

This report contains an accumulation of publications and analyses aimed at developing guidelines for improving both high voltage and low voltage power supplies for the U.S. Air Force systems command. It is the intent of the report to supply good design and manufacturing techniques for the packaging and the building of high quality, reliable, long-life power supplies. These data are based on the wealth of engineering practices established by design and manufacturing engineers. The contents are: Fundamentals of Insulation: Gases, Liquid Dielectrics, Solid Insulation; Environment: Pressure, Particulates, Environmental Interactions with Space Power Systems, Surface Charging, System Design Criteria; Configuration and Design Data: Designs, Transients, Grounding and Bonding, Thermal Control; Materials and Processes: Insulation, Processes, Process Variables; Manufacturing: Yield, Government and Industrial Survey, Analysis, Problem Areas and Suggested Solutions, Designs That Have Worked in High Voltage Equipment, Manufacturing Summary; and Tests: Performance, Insulation Tests, Materials Testing, Component and Equipment Tests, Performance Testing, Facility and Environment, Accelerated Life Test; Maintenance and Repair: Maintenance, Test Sets, Pilots and Crewmen, Air Logistic Centers, Design Problem Recommendations.

W G Dunbar↗