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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
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NASA NTRS1982

Recent researches into solid bodies and magnetic fields in the solar system; Proceedings of the Topical Meeting and Symposium, Ottawa, Canada, May 16-June 2, 1982

Topics discussed include the magnetic history of the early solar system, impact processes in solid bodies (e.g., meteoroids and asteroids), and topics related to cometary missions. The section devoted to cometary missions lays particular stress on missions to Comet Halley; attention is given to such aspects of these missions as the investigation of hypervelocity impact on the Giotto Halley mission dust shield, the detection of energetic cometary and solar particles by the EPONA instrument on the Giotto mission, the dust hazard near Comet Halley in regard to the Vega project, and cometary ephemerides for spacecraft flyby missions.

Vette, J. I.↗
NASA NTRS1999

NASA's Near-Earth Object Office

Near-Earth Objects (NEOs) are scientifically interesting remnants of the early solar system formation process, accessible resources for the raw materials necessary for colonizing the inner solar system in the next century, and objects that can threaten life on Earth.

Near Earth Objects Comets Asteroids↗
NASA NTRS2014

Timing of Formation of a Wassonite-bearing Chondrule

Wassonite, ideally stoichiometric TiS, is a titanium monosulfide recently discovered in the Yamato 691 EH3 enstatite chondrite. Wassonite grains were located within the mesostasis of a single barred olivine chondrule. Such chondrules likely formed in the solar nebula by melting of fine grained precursor dust. The reduced nature of enstatite chondrites, and the wassonite-bearing chondrule in particular, may suggest precursor materials included Ti-bearing troilite, metallic Fe-Ni, and possibly graphite. Under the reducing conditions present in enstatite chondrites S can partition more readily into silicate melt, leading to raised Ti content of the residual Fe-FeS melt. By the time sulfide crystallized from the melt, the Ti concentration was high enough to form small grains of pure TiS - wassonite. As a mineral not previously observed in nature wassonite and its host chondrule may provide additional constraints on physical and chemical conditions in the solar nebula at a specific time and location relevant to planetary formation. Enstatite chondrites and Earth share similar isotopic compositions of Cr, Ni, Ti, O and N. Understanding the formation conditions of enstatite chondrite chondrules may therefore have wider relevance for terrestrial planet accretion and other early inner solar system processes. Here we present preliminary results of an investigation of the Al-Mg systematics of the only known wassonite-bearing chondrule. The goal of this study is to determine whether this chondrule's formation was contemporaneous with other enstatite chondrite chondrules and to establish its place in the broader timeline of solar system events.

Needham, A. W.↗
NASA NTRS2016

Organic Analysis in the Miller Range 090657 CR2 Chondrite: Part 2 Amino Acid Analyses

Primitive carbonaceous chondrites contain a wide variety of organic material, ranging from soluble discrete molecules to insoluble, unstructured kerogen-like components, as well as structured nano-globules of macromolecular carbon. The relationship between the soluble organic molecules, macromolecular organic material, and host minerals are poorly understood. Due to the differences in extractability of soluble and insoluble organic materials, the analysis methods for each differ and are often performed independently. The combination of soluble and insoluble analyses, when performed concurrently, can provide a wider understanding of spatial distribution, and elemental, structural and isotopic composition of organic material in primitive meteorites. Using macroscale extraction and analysis techniques in combination with in situ microscale observation, we have been studying both insoluble and soluble organic material in the primitive CR2 chondrite Miller Range (MIL) 090657. In accompanying abstracts (Cao et al. and Messenger et al.) we discuss insoluble organic material in the samples. By performing the consortium studies, we aim to improve our understanding of the relationship between the meteorite minerals and the soluble and insoluble organic phases and to delineate which species formed within the meteorite and those that formed in nebular or presolar environments. In this abstract, we present the results of amino acid analyses of MIL 090657 by ultra performance liquid chromatography with fluorescence detection and quadrupole-time of flight mass spectrometry. Amino acids are of interest because they are essential to life on Earth, and because they are present in sufficient structural, enantiomeric and isotopic diversity to allow insights into early solar system chemical processes. Furthermore, these are among the most isotopically anomalous species, yet at least some fraction are thought to have formed by aqueously-mediated processes during parent body alteration.

Burton, A. S.↗
NASA NTRS1989

Non-equilibrium chemistry in the solar nebula and early solar system: Implications for the chemistry of comets

Theoretical models of solar nebula and early solar system chemistry which take into account the interplay between chemical, physical, and dynamical processes have great utility for deciphering the origin and evolution of the abundant chemically reactive volatiles (H, O, C, N, S) observed in comets. In particular, such models are essential for attempting to distinguish between presolar and solar nebula products and for quantifying the nature and duration of nebular and early solar system processing to which the volatile constituents of comets have been subjected. The diverse processes and energy sources responsible for chemical processing in the solar nebula and early solar system are discussed. The processes considered include homogeneous and heterogeneous thermochemical and photochemical reactions, and disequilibration resulting from fluid transport, condensation, and cooling whenever they occur on timescales shorter than those for chemical reactions.

Fegley, Bruce, Jr.↗
NASA NTRS2003

Dawn Mission: A Journey in Space and Time

By successively orbiting both 4 Vesta and 1 Ceres the Dawn mission directly addresses the longstanding goals of NASA and the planetary community to understand the origin and evolution of the solar system by obtaining geophysical and geochemical data on diverse main belt asteroids. Ceres and Vesta are two complementary terrestrial protoplanets (one apparently "wet" and one "dry"), whose accretion was terminated by the formation of Jupiter. Ceres is little changed since it formed in the early solar system, while Vesta has experienced significant heating and differentiation. Both have remained intact over the age of the solar system, thereby retaining a record of events and processes from the time of planet formation. Detailed study of the geophysics and geochemistry of these two bodies provides critical benchmarks for the early solar system conditions and processes that shaped its subsequent evolution. Dawn provides the missing context for both primitive and evolved meteoritic data, thus playing a central role in understanding terrestrial planet formation and the evolution of the asteroid belt. Dawn is to be launched in May 2006 arriving at Vesta in 2010 and Ceres in 2014, stopping at each to make 11 months of orbital measurements. The spacecraft uses solar electric propulsion both in cruise and in orbit to make most efficient use of its xenon propellant. The spacecraft carries a framing camera, visible and infrared mapping spectrometer, gamma ray/neutron spectrometer, a laser altimeter, magnetometer, and radio science.

Russell, C. T.↗
NASA NTRS1992

Volatiles in interplanetary dust particles - A review

The paper presents a review of the volatiles found within interplanetary dust particles. These particles have been shown to represent primitive material from early in the solar system's formation and also may contain records of stellar processes. The organogenic elements (i.e., H, C, N, O, and S) are among the most abundant elements in our solar system, and their abundances, distributions, and isotopic compositions in early solar system materials permit workers to better understand the processes operating early in the evolutionary history of solar system materials. Interplanetary dust particles have a range of elemental compositions, but generally they have been shown to be similar to carbonaceous chondrites, the solar photosphere, Comet Halley's chondritic cores, and matrix materials of chondritic chondrites. Recovery and analysis of interplanetary dust particles have opened new opportunities for analysis of primitive materials, although interplanetary dust particles represent major challenges to the analyst because of their small size.

Gibson, Everett K., Jr.↗
NASA NTRS2003

Mineralogy and Textural Characteristics of Fine-grained Rims in the Yamato 791198 CM2 Carbonaceous Chondrite: Constraints on the Location of Aqueous Alteration

Carbonaceous chondrites provide important clues into the nature of physical and chemical processes in the early solar system. A question of key importance concerns the role of water in solar nebular and asteroidal processes. The effects of water on primary mineral assemblages have been widely recognized in chondritic meteorites, especially the CI and CM carbonaceous chondrites. These meteorites have undergone extensive aqueous alteration that occurred prior to their arrival on Earth. In the case of the CM chondrites, this alteration has resulted in the partial to complete replacement of the primary nebular phases with secondary alteration phases. Considerable controversy exists as to the exact location where the alteration of the CM chondrites occurred. Several textural lines of evidence have been cited in support of aqueous alteration prior to the accretion of the final parent asteroid. An important line of evidence to support this hypothesis is the dis-equilibrium nature of fine-grained rims and matrix materials. [2] also noted the juxtaposition of micron-sized Fe-Ni metal grains and apparently unaltered chondrule glass against hydrated rim silicates. Conversely, there is a large body of evidence in favor of parent body alteration such as the occurrence of undisturbed Fe-rich aureoles and the systematic redistribution of elemental components over millimeters, e.g., Mg(+2) into the matrix and Fe(+2) into chondrules etc.

Chizmadia, Lysa J.↗
NASA NTRS2020

FOSSIL—Finding Our Cosmic Roots

FOSSIL (Fragments from the Origins of the Solar System and our Interstellar Locale) is a concept to explore the largest solar system object visible to the unaided eye—the zodiacal cloud. The cloud’s many dust particles are each a tiny time capsule from a comet or asteroid. The FOSSIL concept is for the in situ compositional analysis of interplanetary dust particles, and also of the particles passing through the solar system from interstellar space. By measuring the zodiacal and interstellar particles’ velocity vectors and compositions, the approach resolves fundamental questions about the solar system’s origins. The FOSSIL concept is to: (1) Discover whether today’s local interstellar dust matches the composition of the feedstock from which the solar system formed; (2) Determine whether comets’ fine-grained component preserves unprocessed pre-solar dust or shows signs of processing in the early solar system; and (3) Learn whether comets’ and asteroids’ organic material share a common source or formed from distinct reservoirs. The FOSSIL concept is based on the use of a Dust Telescope (DT) with the capability to measure the composition and the velocity vector of dust particles to unambiguously separate interstellar from interplanetary particles, and identify a subset of zodiacal particles that are exclusively cometary. In the DT, particles pass through the trajectory sensor unharmed and impact a target plate, where they are vaporized and partially ionized. The ions are electrostatically focused onto a detector where the time-of-flight mass spectrum is recorded, enabling measurement of the composition of the interstellar solids, detection of cometary minerals altered by high temperatures or exposure to liquid water in the early solar system, and the characterization of the organic materials from the comets and asteroids that are still being delivered to the Earth today. FOSSIL’s objectives crosscut several disciplines with planetary science. Astrophysics interests lie in understanding interstellar solar matter and the only debris disk accessible in situ. Heliophysics interest is in the verification of large-scale heliospheric magnetic field models by the measured effect on the motion of electrically charged interstellar dust. Reporting the makeup of interplanetary dust that ablates in our atmosphere is valuable to Earth sciences. FOSSIL’s DT is scalable and can be accommodated to a variety of mission opportunities, without restriction on launch dates, and for a large number of possible orbits.

Turner, Neal↗
NASA NTRSDate not supplied

Application of High-Spatial Resolution LA-MC-ICP-MS in Planetary Materials

High-precision stable and radiogenic isotopic measurements of planetary materials can help elucidate processes taking place during early Solar System formation, as well as during subsequent planetary differentiation. Laser Ablation Multi Collector Inductively Coupled Plasma Mass Spectrometry (LA-MC-ICP-MS) adds the valuable ability of preserving the spatial context of these isotopic measurements, by sampling small sample volumes (~10 – 60 um diameter) using a pulsed laser system. In the Center for Isotope Cosmochemistry and Geochronology (CICG) at NASA Johnson Space Center, these in-situ isotopic measurements are primarily made using the Applied SpectraTM iX-fs-Tandem LA-LIBS Instrument coupled to the Nu InstrumentsTM SP1700 MC-ICP-MS. The instrumental set-up also provides simultaneous Laser Induced Breakdown Spectroscopy (LIBS) measurements and the potential use of a low energy path with a collision/reaction cell for additional interference removal, though we focus here on the typical high-energy LA-MC-ICP-MS operation. We will provide examples of stable (e.g., Mg) and radiogenic (e.g., Lu-Hf) isotopic systems measured in planetary materials and their terrestrial analogs. The measurement of mass dependent Mg isotopic variations is an important tool for reconstructing processes such as evaporation and condensation of solids in the solar nebula. For early Solar System samples, Mg isotope measurements are also important for the short-lived (t1/2 = 0.7 Ma) Al-Mg chronometer. During laser ablation analyses, the measurement of the Al-Mg isotopic system is made in medium mass resolution (RP ~9500 at ~20% transmission) to limit interferences from 48Ti2+ and 48Ca2+ on 24Mg+, in addition to 52Cr2+ and 12C14N+ on 26Mg+. Measured in the mineral zircon, the 176Lu-176Hf decay system is often used for understanding the growth of continents on Earth, and is also a vital aid in deciphering early large-scale planetary differentiation processes, such as the crystallization of the lunar magma ocean, which is thought to be responsible for much of the Moon’s crust. Lu-Hf measurements are made in low resolution mode (RP <2000), with 10 ion masses (from 171Yb to 180Hf) measured simultaneously to facilitate corrections for isobaric interferences from 176Yb and 176Lu on 176Hf.

Jacob B Setera↗
NASA NTRS1988

Moderately volatile elements

That the fractionation of moderately volatile and highly volatile elements was a major process in the early solar system is reflected in the variable concentrations of Rb and associated variations in initial Sr-isotopic ratios in chondritic meteorites. Greater knowledge of processes leading to volatile depletion would place stronger constraints on the formation conditions of solid material in the solar system. It will especially become possible to ascertain whether evaporation or incomplete condensation was the major process in establishing the elemental abundance patterns observed in primitive meteorites and planets.

Palme, H.↗
NASA NTRS1978

Invited papers presented to a workshop on thermodynamics and kinetics of dust formation in the space medium

Abstracts of 25 papers relating to condensation processes in the early solar system are presented. Special emphasis is given to the transition of an initial vapor phase in the space medium, the characterization of condensation environments, and condensation processes in the space medium. The question of whether some fraction of the solar system solids (particularly exemplified by meteoritic solids) may be interstellar grains that gathered in the region of the proto-sun, rather than being products of local condensation is addressed.

Robertson, P. C.↗
NASA NTRS2004

Chondrites and the Protoplanetary Disk, Part 3

Contents include the following: Ca-, Al-Rich Inclusions and Ameoboid Olivine Aggregates: What We Know and Don t Know About Their Origin. Aluminium-26 and Oxygen Isotopic Distributions of Ca-Al-rich Inclusions from Acfer 214 CH Chondrite. The Trapping Efficiency of Helium in Fullerene and Its Implicatiion to the Planetary Science. Constraints on the Origin of Chondritic Components from Oxygen Isotopic Compositions. Role of Planetary Impacts in Thermal Processing of Chondrite Materials. Formation of the Melilite Mantle of the Type B1 CAIs: Flash Heating or Transport? The Iodine-Xenon System in Outer and Inner Portions of Chondrules from the Unnamed Antarctic LL3 Chondrite. Nucleosynthesis of Short-lived Radioactivities in Massive Stars. The Two-Fluid Analysis of the Kelvin-Helmholtz Instability in the Dust Layer of a Protoplanetary Disk: A Possible Path to the Planetesimal Formation Through the Gravitational Instability. Shock-Wave Heating Model for Chonodrule Formation: Heating Rate and Cooling Rate Constraints. Glycine Amide Hydrolysis with Water and OH Radical: A Comparative DFT Study. Micron-sized Sample Preparation for AFM and SEM. AFM, FE-SEM and Optical Imaging of a Shocked L/LL Chondrite: Implications for Martensite Formation and Wave Propagation. Infrared Spectroscopy of Chondrites and Their Components: A Link Between Meteoritics and Astronomy? Mid-Infrared Spectroscopy of CAI and Their Mineral Components. The Origin of Iron Isotope Fractionation in Chondrules, CAIs and Matrix from Allende (CV3) and Chainpur (LL3) Chondrites. Protoplanetary Disk Evolution: Early Results from Spitzer. Kinetics of Evaporation-Condensation in a Melt-Solid System and Its Role on the Chemical Composition and Evolution of Chondrules. Oxygen Isotope Exchange Recorded Within Anorthite Single Crystal in Vigarano CAI: Evidence for Remelting by High Temperature Process in the Solar Nebula. Chondrule Forming Shock Waves in Solar Nebula by X-Ray Flares. Organic Globules with Anormalous Nitrogen Isotopic Compositions in the Tagish Lake Meteorite: Products of Primitive Organic Reactions. Yet Another Chondrule Formation Scenario. CAIs are Not Supernova Condensates. Microcrystals and Amorphous Material in Comets and Primitive Meteorites: Keys to Understanding Processes in the Early Solar System. A Nearby Supernova Injected Short-lived Radionuclides into Our Protoplanetary Disk. REE+Y Systematics in CC and UOC Chondrules. Meteoritic Constraints on Temperatures, Pressures, Cooling Rates, Chemical Compositions, and Modes of Condensation in the Solar Nebula. The I-Xe Record of Long Equilibration in Chondrules from the Unnamed Antarctic Meteorite L3/LL3. Early Stellar Evolution.

Source record↗
NASA NTRS1980

Single isotope fractionation of (16)O(-) implications for early history of solar system

Chemical fractionation processes are investigated with emphasis on selective single isotope fractionation in polyisotopic systems, particularly in oxygen. The related temperature parameters of meteoritic condensates and of their source medium are investigated by a thermometric method that is independent of assumptions regarding temperatures and pressures in the solar nebula. The crucial nonlinear chemical fractionation of O-16 was demonstrated experimentally. The effect was achieved in condensed CO2 formed from CO with C-12 O-16 selectively excited by H Ly alpha. The effect was verified by mass spectrometric measurements. The meteorite paleotemperature estimates were advanced from defining only thermal exposure to evaluating time and temperature independently. Grain temperatures at condensation of refractory inclusion materials are indicated to be less than 900 K in agreement with radiation temperature considerations and observations in circumstellar dust shells.

Arrhenius, G.↗
NASA NTRS1981

Interplanetary dust in the transmission electron microscope - Diverse materials from the early solar system

An analytical electron microscope study of dispersed interplanetary dust aggregates collected in the earth's stratosphere shows that, in spite of their similarities, the aggregates exhibit significant differences in composition, internal morphology, and mineralogy. Of 11 chondritic particles examined, two consist mostly of a noncrystalline chondritic material with an atomic S/Fe ratio equal to or greater than 2 in places, one consists of submicron metal and reduced silicate 'microchondrules' and sulfide grains embedded in a carbonaceous matrix, and another consists of submicron magnetic-decorated unequilibrated silicate and sulfide grains with thick low-Z coatings. Although the particles are unmetamorphosed by criteria commonly applied for chondritic meteorites, the presence of reduced chemistries and the ubiquity of mafic, instead of hydrated, silicates confirm that they are not simply C1 or C2 chondrite matrix material. The observations indicate that portions of some particles have not been significantly altered by thermal or radiation processes since their assembly, and that the particles probably contain fine debris from diverse processes in the early solar system.

Fraundorf, P.↗
NASA NTRS2014

Bulk Composition of Vesta as Constrained by the Dawn Mission and the HED Meteorites

Of the objects in the main asteroid belt, Vesta is of particular interest as it is large enough to have experienced internal differentiation (520 km diameter), and it is known to have a basaltic surface dominated by FeO-bearing pyroxenes. Furthermore, visible-IR spectra of Vesta and associated Vestoids are remarkably similar to laboratory spectra of Howardite-Eucrite-Diogenite (HED) meteorites, leading to the paradigm that the HEDs ultimately came from Vesta. Geochemical and petrological studies of the HEDs confirm the differentiated nature of the near-surface region of their parent body, and imply that crust extraction occurred well within the first 10 Ma of solar system history Vesta is therefore a prime target for studies that aim to constrain the earliest stages of planet building, and it is within this context that the NASA Dawn spacecraft orbited Vesta from July 2011 to September 2012. The results of the Dawn mission so far have significantly reinforced the HED-Vesta connection, confirming a significant degree of internal differentiation, a surface mineralogy compatible with that of the HEDs, and near-surface ratios of Fe/O and Fe/Si consistent with HED lithologies. The combination of data from the HED meteorites and the Dawn mission thus presents an unprecedented opportunity to use Vesta as a natural laboratory of early differentiation processes in the early solar system. However, the bulk composition of Vesta remains a significant unknown parameter, but one that plays a key role on the physical and chemical properties of the internal and surface reservoirs (core, mantle, crust). Several attempts have been made to constrain the bulk composition of the eucrite parent body, early endeavours relying on petrological or cosmochemical constraints. More recently, individual chondrite class compositions, or mixtures thereof, have been considered, constrained by considerations such as O-isotopes, trace-element ratios and siderophile element concentrations of the eucrites. The work presented here builds upon these latter studies, with the primary aims of: i) illustrating the potential diversity of the geochemical and geophysical properties of a fully differentiated Vesta-sized parent body, and ii) assessing which, if any, of the known chondritic bulk compositions are plausible analogues for proto-Vesta.

Toplis, M. J.↗
DOE OSTI2022

Coordinated neutron and X-ray computed tomography of meteorites: Detection and distribution of hydrogen-bearing materials

The presence and distribution of hydrogen-bearing materials in meteorites are important constraints on processes in the early solar system, and the delivery of volatile constituents to growing planets. Here, in this paper, we show that coordinated neutron and X-ray computed tomography, NXCT, can reveal the presence and distributions of hydrogen-bearing materials in meteorites, and thus help constrain the presence and actions of water in the early solar system. NXCT is nearly nondestructive of meteorite samples. Neutron fluence in NXCT is approximately seven orders of magnitude less than in typical instrumental neutron activation analysis, and so produces little residual radioactivity and currently undetectable changes in isotope ratios. Heating during NXCT is minimal, but NXCT will overprint the record of cosmic ray exposure held in natural thermoluminescence. Two meteorites were examined. EET 87503 is a howardite, a regolith breccia inferred to be from the asteroid 4 Vesta, and contains fragments of eucrite basalt, diogenite pyroxenite, and H-rich carbonaceous chondrites. With NXCT, the chondrite fragments within the meteorite piece can be clearly located and characterized, in preparation for possible extraction and detailed analyses. Graves Nunataks (GRA) 06100 is a CR2 chondrite meteorite that contains abundant iron metal and H-bearing silicates from aqueous alteration. In NXCT, H-bearing altered material is clearly distinguished from metal, and its distribution in three dimensions is revealed as a constraint on the processes of alteration.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Solar wind contributions to Earth’s oceans

The isotopic composition of water in Earth’s oceans is challenging to recreate using a plausible mixture of known extraterrestrial sources such as asteroids—an additional isotopically light reservoir is required. The Sun’s solar wind could provide an answer to balance Earth’s water budget. Here, we used atom probe tomography to directly observe an average ~1 mol% enrichment in water and hydroxyls in the solar-wind-irradiated rim of an olivine grain from the S-type asteroid Itokawa. We also experimentally confirm that H + irradiation of silicate mineral surfaces produces water molecules. These results suggest that the Itokawa regolith could contain ~20 l m -3 of solar-wind-derived water and that such water reservoirs are probably ubiquitous on airless worlds throughout our Galaxy. The production of this isotopically light water reservoir by solar wind implantation into fine-grained silicates may have been a particularly important process in the early Solar System, potentially providing a means to recreate Earth’s current water isotope ratios.

79 ASTRONOMY AND ASTROPHYSICS↗