Deposition of ion thruster effluents on SERT 2 spacecraft surfaces
Deposition of ion thruster effluents on SERT 2 spacecraft surfaces
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Deposition of ion thruster effluents on SERT 2 spacecraft surfaces
SERT 2 spacecraft surface contamination by Hg ion thrustor effluents, using solar cell sensors
Water quality management, treating of effluents, and system design for clean water
An experiment was performed in conjunction with the Apollo 16 launch to define operational and instrumentational problems associated with launch-vehicle exhaust effluent monitoring. Ground and airborne sampling were performed for CO, CO2, hydrocarbons, and particulates. Sampling systems included filter pads and photometers for particulates and whole-air grab samples for gases. Launch debris was identified in the particulate samples at ground level(taken immediately after launch) and in the airborne measurements (taken 40 to 50 minutes after launch approximately 40 km downwind of the pad). Operational problems were identified and included the need for higher instrumentation mobility and the need for real-time sampling instrumentation as opposed to collection-type samples such as the whole-air grab sample.
System consists of negative-lift airfoil mounted at or near top of smokestack without obstructing flow of effluents from stack. Controls adjust negative lift and drag of airfoil, for changing orientation of airfoil to maintain proper airflow over foil and for adjusting its vertical location with respect to top of smokestack.
Results for the predictions with the NASA/MSFC Multilayer Diffusion Model for the dispersive transport of the Titan 3C rocket exhaust effluents for the 1857 EST launch on December 13, 1973, from the Eastern Test Range at Cape Canaveral Air Force Station are presented. An atmospheric assessment is made in support of the joint Marshall Space Flight Center, Langley Research Center, and Kennedy Space Center rocket exhaust prediction and measurement program. The predictions are primarily intended to define a monitoring grid and for a postflight assessment of the field measurements in order to improve diffusion prediction techniques.
The sensitivity and reliability of neutron activation analysis in detecting trace elements in solid rocket effluents are discussed. Special attention was given to Al and Si contaminants. The construction and performance of a thermal column irradiation unit was reported.
Downwind in situ ground-level measurements of the exhaust from a Titan 3 C launch vehicle were made during a normal launch. The measurement activity was conducted as part of an overall program to obtain field data for comparison with the multilayer dispersion model currently being used to predict the behavior of rocket vehicle exhaust clouds. All measurements were confined to land, ranging from the launch pad to approximately 2 kilometers downwind from the pad. Measurement systems included detectors for hydrogen chloride (HCl), carbon dioxide (CO2), and particulates (Al2O3). Airborne and ground-based optical systems were employed to monitor exhaust cloud rise, growth, and movement. These measurement systems, located along the ground track (45 deg azimuth from the launch pad) of the exhaust cloud, showed no effluents attributable to the launch. Some hydrogen chloride and aluminum oxide were detected in the surface wind direction (15 deg azimuth) from the pad. Comparisons with the model were made in three areas: (1) assumption of cloud geometry at stabilization; (2) prediction of cloud stabilization altitude; and (3) prediction of the path of cloud travel. In addition, the importance of elemental analyses of the particulate samples is illustrated.
Automated chemiluminescent and bioluminescent sensors were developed for continuous monitoring of microbial levels in wastewater effluent. Development of the chemiluminescent system included optimization of reagent concentrations as well as two new techniques which will allow for increased sensitivity and specificity. The optimal reagent concentrations are 0.0025 M luminol and 0.0125 M sodium perborate in 0.75N sodium hydroxide before addition of sample. The methods developed to increase specificity include (1) extraction of porphyrins from bacteria collected in a filter using 0.1N NaOH - 50 percent Ethanol, and (2) use of the specific reaction rate characteristics for the different luminol catalysts. Since reaction times are different for each catalyst, the reaction can be made specific for bacteria by measuring only the light emission from the particular reaction time zone specific for bacteria. Developments of the bioluminescent firefly luciferase system were in the area of flow system design.
Seven standard types of measuring devices used to obtain the chemical composition of rocket exhaust effluents were discussed. The electrets, a new measuring device, are investigated and compared with established measuring techniques. The preliminary results obtained show that electrets have multipollutant measuring capabilities, simplicity of deployment, speed of assessment or analysis, and may be an important and valuable tool in measuring pollutants from space vehicle rocket exhaust.
An aircraft was selected and instrumented to measure effluents emitted from large solid propellant rockets during launch activities. The considerations involved in aircraft selection, sampling probes, and instrumentation are discussed with respect to obtaining valid airborne measurements. Discussions of the data acquisition system used, the instrument power system, and operational sampling procedures are included. Representative measurements obtained from an actual rocket launch monitoring activity are also presented.
Absorption spectroscopy utilizing a video sensing technique was investigated as a means of visualizing SO2 in power plant stack plumes and for measuring SO2 concentration and effluent velocity in these plumes. The absorption of SO2 is measured in the ultraviolet region by using the sky as a background source. An additional spectral channel is used to correct for particulate scattering encountered in coal fired power plant plumes. The video system also tracks fluctuations in the SO2 concentration which leads to the determination of an eddy convection velocity. Field measurements were performed to show that the eddy convection velocity is proportional to the average in-stack velocity and to empirically determine their relationship. It was concluded that the video absorption technique is an attractive method for remotely determining both SO2 concentration and plume velocity with the same instrument.
Electrets used to detect the chemical composition of rocket exhaust effluents were investigated. The effectiveness of electrets was assessed while comparisons were made with hydrogen chloride measuring devices from chamber and field tests, and computed results from a multilayer diffusion model. The experimental data used were obtained from 18 static test firings, chamber tests, and the Viking 1 launch to Mars. Results show that electrets have multipollutant measuring capabilities, simplicity of deployment, and speed of assessment. The electrets compared favorably with other hydrogen chloride measuring devices. The summary of the measured data from the electrets and the hydrogen chloride detectors was within the upper and lower bounds of the computed hydrogen chloride concentrations from the multilayer diffusion model.
To obtain useable corrosion and erosion results it was necessary to have data with several levels of particulate matter in the hot gases. One level of particulate loading was as low as possible so that ideally no erosion and only corrosion occurred. A conical fluidized bed was used to obtain some degree of filtration through the top of the bed which would not be highly fluidized. This would minimize the filtration required for the hot gases or conversely the amount of particulate matter in the hot gases after a given level of filtration by cyclones and/or filters. The data obtained during testing characterized the effluent from the bed at different test conditions. A range of bed heights, coal flows, air flows, limestone flows, and pressure are represented. These tests were made to determine the best operating conditions prior to using the bed to determine erosion and corrosion rates of typical turbine blade materials.
Four candidate turbine airfoil superalloys were exposed to the effluent of a pressurized fluidized bed with a solids loading of 2 to 4 g/scm for up to 100 hours at two gas velocities, 150 and 270 m/sec, and two temperatures, 730 deg and 795 C. Under these conditions, both erosion and corrosion occurred. The damaged specimens were examined by cross-section measurements, scanning electron and light microscopy, and X-ray analysis to evaluate the effects of temperature, velocity, particle loading, and alloy material. Results indicate that for a given solids loading the extent of erosion is primarily dependent on gas velocity. Corrosion occurred only at the higher temperature. There was little difference in the erosion/corrosion damage to the four alloys tested under these severe conditions.
To investigate the possibility of inadvertent weather modification from rocket effluent, aerosol samples were collected from an instrumented aircraft subsequent to the Voyager 1 and 2 launches. The aerosol's morphology, concentration, and size distribution were examined with an electron microscope. The elemental compositions of individual particles were analyzed with an X-ray energy spectrometer. Ice nucleus concentration was measured with a thermal diffusion chamber. The particles' physical and chemical properties were related to their ice nucleation activity. A laboratory experiment on rocket propellant exhaust was conducted under controlled conditions. Both laboratory and field experimental results indicated that rocket propellant exhaust can produce active ice nuclei and modify local weather in suitable meteorological conditions.
A one dimensional steady state stratospheric aerosol model is developed that considers the subsequent perturbations caused by including the expected space shuttle particulate effluents. Two approaches to the basic modeling effort were made: in one, enough simplifying assumptions were introduced so that a more or less exact solution to the descriptive equations could be obtained; in the other approach very few simplifications were made and a computer technique was used to solve the equations. The most complex form of the model contains the effects of sedimentation, diffusion, particle growth and coagulation. Results of the perturbation calculations show that there will probably be an immeasurably small increase in the stratospheric aerosol concentration for particles larger than about 0.15 micrometer radius.
Superalloy turbine rotors in a single stage turbine with 6 percent partial admittance were operated in the effluent of a pressurized fluidized bed coal combustor for up to 164 hours. Total mass flow was 300 kg/hr and average particulate loadings ranged from 600 to 2800 ppm for several coal/sorbent combinations. A 5.5 atm turbine inlet gas pressure and inlet gas temperatures from 700 to 800 C yielded absolute gas velocities at the stator exit of about 500 m/s. The angular rotation speed (40,000 rpm) of the six inch diameter rotors was equivalent to a tip speed of about 300 m/s, and average gas velocities relative to the rotating surface ranged from 260 to 330 m/s at mean radius. The rotor erosion pattern reflects heavy particle separation with severe (5 to 500 cm/yr) erosion at the leading edge, pressure side center, and suction side trailing edge at the tip. The erosion distribution pattern provides a spectrum of erosion/oxidation/deposition as a function of blade position. This spectrum includes enhanced oxidation (10 to 100 x air), mixed oxides in exposed depletion zones, sulfur rich oxides in deposition zones, and rugged areas of erosive oxide removal.