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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

A two-electron transfer mechanism of the Zn-doped δ-MnO 2 cathode toward aqueous Zn-ion batteries with ultrahigh capacity

Neutral aqueous zinc-ion batteries (ZIBs) have attracted considerable attention due to their safe and green features. As one typical cathode, birnessite MnO 2 (δ-MnO 2 ) suffers from low conductivity and structural instability, and its energy storage mechanism is still not well established yet. Herein, we developed a Zn-doped δ-MnO 2 material via a facile and effective microwave-assisted method for the cathode in aqueous ZIBs. By incorporating Zn to modify the microstructure and promote reaction kinetics, the Zn-doped δ-MnO 2 electrode demonstrates significantly enhanced electrochemical performance with an ultrahigh reversible capacity of 455 mA h g –1 and excellent specific energy of 628 W h kg –1 . In addition, the successive insertion of H + and Zn 2+ and deep two-electron transfer routes are revealed systematically by ex situ experiments. In this study, the two-electron transfer route (Mn 4+ /Mn 3+ and Mn 3+ /Mn 2+ ) mechanism of Zn-doped δ-MnO 2 electrodes explains the exceedingly high capacity and opens new opportunities to develop high-energy aqueous ZIBs.

25 ENERGY STORAGE↗
NASA NTRS1990

Current limiting mechanisms in electron and ion beam experiments

The emission and collection of current from satellites or rockets in the ionosphere is a process which, at equilibrium, requires a balance between inward and outward currents. In most active experiments in the ionosphere and magnetosphere, the emitted current exceeds the integrated thermal current by one or more orders of magnitude. The system response is typically for the emitted current to be limited by processes such as differential charging of insulating surfaces, interactions between an emitted beam and the local plasma, and interactions between the beam and local neutral gas. These current limiting mechanisms have been illustrated for 20 years in sounding rocket and satellite experiments, which are reviewed here. Detailed presentations of the Spacecraft Charging at High Altitude (SCATHA) electron and ion gun experiments are used to demonstrate the general range of observed phenomena.

Olsen, R. C.↗
NASA NTRS2008

Wear Mechanisms in Electron Sources for Ion Propulsion, 2: Discharge Hollow Cathode

The wear of the keeper electrode in discharge hollow cathodes is a major impediment to the implementation of ion propulsion onboard long-duration space science missions. The development of a predictive theoretical model for hollow cathode keeper life has long been sought, but its realization has been hindered by the complexities associated with the physics of the partially ionized gas and the associated erosion mechanisms in these devices. Thus, although several wear mechanisms have been hypothesized, a quantitative explanation of life test erosion profiles has remained incomplete. A two-dimensional model of the partially ionized gas in a discharge cathode has been developed and applied to understand the mechanisms that drove the erosion of the keeper in two long-duration life tests of a 30-cm ion thruster. An extensive set of comparisons between predictions by the numerical simulations and measurements of the plasma properties and of the erosion patterns is presented. It is found that the near-plume plasma oscillations, predicted by theory and observed by experiment, effectively enhance the resistivity of the plasma as well as the energy of ions striking the keeper.

hollow cathode↗
DOE OSTI2023

Electronic transport mechanisms in a thin crystal of the Kitaev candidate α -RuCl 3 probed through guarded high impedance measurements

α-RuCl 3 is considered to be the top candidate material for the experimental realization of the celebrated Kitaev model, where ground states are quantum spin liquids with interesting fractionalized excitations. It is, however, known that additional interactions beyond the Kitaev model trigger in α-RuCl 3 a long-range zigzag antiferromagnetic ground state. In this work, we investigate a nanoflake of α-RuCl 3 through guarded high impedance measurements aimed at reaching the regime where the system turns into a zigzag antiferromagnet. We investigated a variety of temperatures (1.45–175 K) and out-of-plane magnetic fields (up to 11 T), finding a clear signature of a structural phase transition at ≈160 K as reported for thin crystals of α-RuCl 3 , as well as a thermally activated behavior at temperatures above ≈30 K, with a characteristic activation energy significantly smaller than the energy gap that we observe for α-RuCl 3 bulk crystals through our angle resolved photoemission spectroscopy (ARPES) experiments. Additionally, we found that below ≈30 K, transport is ruled by Efros–Shklovskii variable range hopping (VRH). Most importantly, our data show that below the magnetic ordering transition known for bulk α-RuCl 3 in the frame of the Kitaev–Heisenberg model (≈7 K), there is a clear deviation from VRH or thermal activation transport mechanisms. Finally, our work demonstrates the possibility of reaching, through specialized high impedance measurements, the thrilling ground states predicted for α-RuCl 3 at low temperatures in the frame of the Kitaev–Heisenberg model and informs about the transport mechanisms in this material in a wide temperature range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2008

Wear Mechanisms in Electron Sources for Ion Propulsion, 1: Neutralizer Hollow Cathode

Upon the completion of two long-duration life tests of a 30-cm ion engine, the orifice channel of the neutralizer hollow cathode was eroded away to as much as twice its original diameter. Whereas the neutralizer cathode orifice opened significantly, no noticeable erosion of the discharge cathode orifice was observed. Noquantitative explanation of these erosion trends has been established since the completion of the two life tests. A two-dimensional model of the partially ionized gas inside these devices has been developed and applied to the neutralizer hollow cathode. The numerical simulations show that the main mechanism responsible for the channel erosion is sputtering by Xe+. These ions are accelerated by the sheath along the channel and bombard the surface with kinetic energy/charge of about 17 V at the beginning of cathode life. The density of the ions inside the neutralizer orifice is computed to be as high as 2.1 x 10(sup 22) m(sup -3). Because of the 3.5-times larger diameter of the discharge cathode orifice, the ion density inside the orifice is more than 40 times lower and the sheath drop 7 V lower compared with the values in the neutralizer. At these conditions, Xe+ can cause no significant sputtering of the surface.

ionized gas↗
DOE OSTI2026

Theoretical assessment of the transition between electron emission mechanisms in a collisional crossed-field gap

Understanding the transition to the limiting current under vacuum and collisional conditions for thermal-field emission in a crossed-field gap is critical for characterizing the operating regime for numerous applications, such as high-power microwaves and Hall thrusters. By deriving the exact solution for the current density as a function of cathode temperature (and, by extension, initial velocity), cathode electric field, applied voltage, collision frequency, and magnetic field, we determine the transition from the canonical current source (thermal-field emission) to the vacuum and collisional limiting currents under different operating conditions. Here, we further show that the exact solution recovers the asymptotic solutions for the canonical and limiting currents for vacuum and collisional crossed-field gaps under appropriate limits. The exact solution demonstrates that the critical current decreases with both increasing magnetic field strength and increasing collisionality. Nexus phase space plots constructed by matching the individual asymptotic solutions provide the conditions for the transitions between mechanisms, elucidating when a single mechanistic equation would suffice and when theories combining multiple mechanisms are necessary.

Breen, Lorin I. [Purdue Univ., West Lafayette, IN ↗
NASA NTRS1977

Electronic and mechanical improvement of the receiving terminal of a free-space microwave power transmission system

Significant advancements were made in a number of areas: improved efficiency of basic receiving element at low power density levels, improved resolution and confidence in efficiency measurements mathematical modelling and computer simulation of the receiving element and the design, construction, and testing of an environmentally protected two-plane construction suitable for low cost, highly automated construction of large receiving arrays.

Brown, W. C.↗
DOE OSTI2022

Nematicity and nematic fluctuations in iron-based superconductors

The reduction of rotational symmetry in a crystalline solid driven by an electronic mechanism is referred to as electronic nematicity. This phenomenon – initially thought to be rare – has by now been observed in an increasing number of systems. Here, the iron-based superconductors present an ideal material platform to study nematicity in crystalline solids. Their nematic transition is pronounced, it can be studied with a wide range of experimental techniques; it is easily tunable; and high-quality samples are widely available. As research on nematicity in iron-based materials is now in its second decade, it builds on tremendous progress in theoretical concepts and experimental techniques. Thus, a stage has been reached at which the nematic phase can be addressed with confidence in its full complexity, including momentum-, time- and material- dependence of the order parameter. Important open questions concern the mechanism by which nematicity affects superconducting pairing and normal-state properties, with a central role for the challenging issue of nematic quantum criticality.

Electronic properties and materials↗
NASA NTRS1982

Free-electron laser from wave-mechanical beats of 2 electron beams

It is possible, though technically difficult, to produce beams of free electrons that exhibit beats of a quantum mechanical nature. (1) the generation of electromagnetic radiation, e.g., light, based on the fact that the beats give rise to alternating charge and current densities; and a frequency shifter, based on the fact that a beam with beats constitutes a moving grating. When such a grating is exposed to external radiation of suitable frequency and direction, the reflected rediation will be shifted in frequency, since the grating is moving. A twofold increase of the frequency is readily attainable. It is shown that it is impossible to generate radiation, because the alternating electromagnetic fields that accompany the beats cannot reform themselves into freely propagating waves. The frequency shifter is useless as a practical device, because its reflectance is extremely low for realizable beams.

Lichtenstein, R. M.↗
DOE OSTI2022

Novel Class of Rhenium Borides Based on Hexagonal Boron Networks Interconnected by Short B 2 Dumbbells

Transition metal borides are known due to their attractive mechanical, electronic, refractive, and other properties. A new class of rhenium borides was identified by synchrotron single-crystal X-ray diffraction experiments in laser-heated diamond anvil cells between 26 and 75 GPa. Recoverable to ambient conditions, compounds rhenium triboride (ReB 3 ) and rhenium tetraboride (ReB 4 ) consist of close-packed single layers of rhenium atoms alternating with boron networks built from puckered hexagonal layers, which link short bonded (~ 1.7 angstrom) axially oriented B 2 dumbbells. The short and incompressible Re-B and B-B bonds oriented along the hexagonal c-axis contribute to low axial compressibility comparable with the linear compressibility of diamond. Sub-millimeter samples of ReB 3 and ReB 4 were synthesized in a large-volume press at pressures as low as 33 GPa and used for material characterization. Crystals of both compounds are metallic and hard (Vickers hardness, H V = 34(3) GPa). Geometrical, crystal-chemical, and theoretical analysis considerations suggest that potential ReB x compounds with x > 4 can be based on the same principle of structural organization as in ReB 3 and ReB 4 and possess similar mechanical and electronic properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

On the Prospect of Chemically Transferable Coarse-Grained Electronic Models for Soft Materials

Electronic coarse-graining (ECG) methods predict quantum-mechanical electronic properties directly from coarse-grained (CG) molecular configurations, enabling electronic predictions at mesoscale length scales. Here, we present a diagnostic assessment of the feasibility of chemically transferable ECG models across a broad polymer-relevant chemical space using all-atom, united-atom, and Martini-scale representations. While high-resolution ECG models achieve near-quantitative accuracy, we show that chemically transferable ECG at the Martini resolution fails because the CG force field does not sample the same configurational distribution of local molecular structure as that underlying the DFT-parameterized ECG model. We demonstrate that our proposed Element-Count-Label (ECL) representation, which augments Martini beads with explicit stoichiometric data, significantly improves chemical generalization across diverse polymer chemistries. However, we find that even with improved chemical resolution, the model cannot recover electronic property distributions that are absent from the configurational space sampled by the CG force field. These results demonstrate that chemically transferable ECG requires future Martini-like force fields to explicitly preserve quantum chemistry–compatible local molecular structure in addition to thermodynamic and structural fidelity.

Kidder, Katherine M [Department of Chemistry; Univ↗