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Results for “electronically nonadiabatic”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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43 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

On the acceleration of energetic ions in Jupiter's magnetosphere

Several aspects of the problem of high-energy ions in the Jovian magnetosphere are addressed. Voyager observations pertaining to the problem of high-energy ions in the magnetosphere are summarized, and the charge exchange emission of fast neutral sulfur and oxygen atoms and their subsequent recapture by electron impact, charge exchange, and photoionization is considered. Solutions are given to the diffusion equation assuming a source of ions injected with a gyroenergy corresponding to pickup in the middle and outer magnetosphere. It is concluded that no reasonable model parameters exist to produce the required steep spectra of the particle observations with only pickup and adiabatic radial diffusion included. A local acceleration mechanism based on nonadiabatic wave-particle interactions is needed. The assumptions and model predictions of stochastic acceleration by MHD turbulence for the Jovian magnetosphere are described. The model makes a specific correspondence between MHD wave spectrum properties and particle spectrum properties at energies above the Alfven energy.

Barbosa, D. D.↗
NASA NTRS1987

Electron attachment in F2 - Conclusive demonstration of nonresonant, s-wave coupling in the limit of zero electron energy

Dissociative electron attachment to F2 has been observed in the energy range 0-140 meV, at a resolution of 6 meV (full width at half maximum). Results show conclusively a sharp, resolution-limited threshold behavior consistent with an s-wave cross section varying as sq rt of epsilon. Two accurate theoretical calculations predict only p-wave behavior varying as the sq rt of epsilon. Several nonadiabatic coupling effects leading to s-wave behavior are outlined.

Chutjian, A.↗
NASA NTRS1972

Magnetospheric access of solar particles and the configuration of the distant geomagnetic field, volume 1

The access of 1.2 to 40 MeV protons and 0.4 to 1.0 MeV electrons from interplanetary space to the polar cap regions was investigated with an experiment on board a low altitude, polar-orbiting satellite (0G0 4). A total of 333 quiet time observations of the electron polar cap boundary give a mapping of the boundary between open and closed geomagnetic field lines. Observations of events associated with co-rotating regions of enhanced proton flux in interplanetary space were used to establish the characteristics of the 1.2 to 40 MeV proton access windows. The results were compared to particle access predictions of the distant geomagnetic tail configurations. The role played by interplanetary anisotropies in the observation of persistent polar cap features is discussed. Special emphasis is given to the problem of nonadiabatic particle entry through regions where the magnetic field is changing direction.

Evans, L. C.↗
NASA NTRSDate not supplied

Ab Initio Electronic Structure Calculations of CNN for CN Excitation Studies

The CN molecule is an important contributor to radiative heat flux in shock layers around vehicles entering Titan’s atmosphere. Current data for heavy particle (de)excitation rate coefficients of CN leads to uncertainties in the population of CN in its first and second excited states. This in turn leads to uncertainties in the radiative heat flux predicted by Computational Fluid Dynamics (CFD) simulations of Titan atmospheric entry. This work performs ab initio electronic structure calculations of the CNN complex to create Potential Energy Surfaces (PESs) that correlate to the ground and first and second excited states of CN. Specifically, the state combinations of CN(X,A,B) + N(4S𝑜) correlate to six states of CNN (three Quintet A” and three Triplet A”). Initial calculations of these states suggest that heavy particle (de)excitation of CN by N atoms is likely to proceed through collinear geometries on triplet surfaces. Complete PESs will show all of the reaction pathways in detail, and will be used in nonadiabatic dynamics calculations to evaluate improved rate coefficients and reduce uncertainty in the radiative heat flux during Titan entry.

Eric C Geistfeld↗
NASA NTRSDate not supplied

Ab Initio Electronic Structure Calculations of CNN for CN Excitation Studies

The CN molecule is an important contributor to radiative heat flux in shock layers around vehicles entering Titan’s atmosphere. Current data for heavy particle (de)excitation rate coefficients of CN leads to uncertainties in the population of CN in its first and second excited states. This in turn leads to uncertainties in the radiative heat flux predicted by Computational Fluid Dynamics (CFD) simulations of Titan atmospheric entry. This work performs ab initio electronic structure calculations of the CNN complex to create Potential Energy Surfaces (PESs) that correlate to the ground and first and second excited states of CN. Specifically, the state combinations of CN(X,A,B) + N(4S𝑜) correlate to six states of CNN (three Quintet A” and three Triplet A”). Initial calculations of these states suggest that heavy particle (de)excitation of CN by N atoms is likely to proceed through collinear geometries on triplet surfaces. Complete PESs will show all of the reaction pathways in detail, and will be used in nonadiabatic dynamics calculations to evaluate improved rate coefficients and reduce uncertainty in the radiative heat flux during Titan entry.

Eric Geistfeld↗
NASA NTRS1983

Voyager 2 observations of energetic particle variations in the Ganymede wake region - A possible acceleration mechanism

Voyager 2's passage through the downstream corotation region of Ganymede found disturbances in the field and particle environment. Large fluctuations in the intensities and energy spectra of ions in the 0.1-to 4.0-MeV interval were also observed with the low energy charged particle experiment. All ion species were evidently affected, up through medium (C, N, O) nuclei. Electrons intensities, while disturbed, did not behave similarly to the ions. These effects are probably associated with the wake produced by the absorption of Jovian magnetospheric corotating plasma by Ganymede. A two-dimensional theoretical model for perturbed field in the wake region is proposed and it is shown by direct numerical simulation of exact particle trajectories that such perturbations are capable of modulating the charged particle energies to about the observed amount for the observed magnetic and plasma parameters. Analysis shows that the energization process is dependent on the pitch angles of the energetic ions and the process itself is nonadiabatic (the Larmor radius is approximately the size of the disturbance region).

Tariq, G.F.↗
NASA NTRS1997

An Accurate Potential Energy Surface for H2O

We have carried out extensive high quality ab initio electronic structure calculations of the ground state potential energy surface (PES) and dipole moment function (DMF) for H2O. A small adjustment is made to the PES to improve the agreement of line positions from theory and experiment. The theoretical line positions are obtained from variational ro-vibrational calculations using the exact kinetic energy operator. For the lines being fitted, the root-mean-square error was reduced from 6.9 to 0.08 /cm. We were then able to match 30,092 of the 30,117 lines from the HITRAN 96 data base to theoretical lines, and 80% of the line positions differed less than 0.1 /cm. About 3% of the line positions in the experimental data base appear to be incorrect. Theory predicts the existence of many additional weak lines with intensities above the cutoff used in the data base. To obtain results of similar accuracy for HDO, a mass dependent correction to the PH is introduced and is parameterized by simultaneously fitting line positions for HDO and D2O. The mass dependent PH has good predictive value for T2O and HTO. Nonadiabatic effects are not explicitly included. Line strengths for vibrational bands summed over rotational levels usually agree well between theory and experiment, but individual line strengths can differ greatly. A high temperature line list containing about 380 million lines has been generated using the present PES and DMF

Schwenke, David W.↗