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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Experimental Fuel Consumption Results from a Heterogeneous Four-Truck Platoon

Platooning has the potential to reduce greenhouse gas missions of heavy-duty vehicles. Prior platooning studies have chiefly focused on the fuel economy characteristics and three-truck platoons, and most have investigated aerodynamically homogeneous platoons with trucks of the same trim. For real world application and accurate return on investment for potential adopters, non-uniform platoons and the impacts of grade and disturbances on a platoon’s fuel economy must also be characterized. This study investigates the fuel economy of a heterogeneous four-truck platoon on a closed test track. Tests were run for one hour at a speed of 45 mph. The trucks used for this study are two 2015 Peterbilt 579’s with a Cummins ISX15 and a Paccar MX-13, and two 2009 Freightliner M915A5’s, one armored and the other unarmored. Many analysis methodologies were leveraged to describe and compare the fuel data, including lap-wise and track-segment analysis. The methodology for dividing the data into laps is described in detail. The influence of other factors beyond the aerodynamics of platooning is discussed. CAN fuel rate analysis showed excellent agreement with previous experimental trends for two and three-truck platoons. In general, the indicated fuel economy benefits in this study were 5-11% for following vehicles and 0-4% for the lead vehicle in platoon relative to their baseline fuel consumption. On a cumulative basis, all platoons saved fuel, ranging from 6% to 8% versus the sum of the standalone trucks’ fuel consumption. The practical implications of the fuel economy results are discussed, as well as avenues for future research. Introduction and Motivation platooning is controlled coordination of two or more vehicles in a convoy, sometimes called CACC (Coordinated or Cooperative Adaptive Cruise Control). The distance between vehicles in a platoon can be controlled tightly at no additional fatigue to the driver. Platooning vehicles can also respond quickly to braking events of the leader, much more quickly than the typical human driver’s reaction time of 1-1.5 s. Therefore, vehicles in a platoon can follow each other much more closely than would usually be considered a safe following distance under human operation. It is implied that under very close following conditions, platooning technology must be extremely robust before it is safe for wide-scale implementation. Platooning is under investigation as a fuel-saving technology. Close-following significantly reduces aerodynamic drag for both leading and trailing vehicles. According to the NRC in 2010, aerodynamic drag represents roughly half of a Class-8 truck’s on-highway fuel usage, meaning a 20% reduction in drag roughly equals a 10% reduction in fuel usage, if all other sources of energy loss remain equal (i.e. accessory, rolling resistance, drivetrain, braking). It is by aerodynamics that platooning saves fuel. At risk of oversimplifying the aerodynamics, following (or trailing) vehicles experience reduced wind velocity due to shielding, and the leading vehicles experience an increased aft pressure, especially at distances closer than 75’ (23 m).

greenhouse gas emissions, truck platoon, heavy-dut↗
NASA NTRS2004

Plasma-Enhanced Pulsed Laser Deposition of Wide Bandgap Nitrides for Space Power Applications

The need for a reliable, inexpensive technology for small-scale space power applications where photovoltaic or chemical battery approaches are not feasible has prompted renewed interest in radioisotope-based energy conversion devices. Although a number of devices have been developed using a variety of semiconductors, the single most limiting factor remains the overall lifetime of the radioisotope battery. Recent advances in growth techniques for ultra-wide bandgap III-nitride semiconductors provide the means to explore a new group of materials with the promise of significant radiation resistance. Additional benefits resulting from the use of ultra-wide bandgap materials include a reduction in leakage current and higher operating voltage without a loss of energy transfer efficiency. This paper describes the development of a novel plasma-enhanced pulsed laser deposition system for the growth of cubic boron nitride semiconducting thin films, which will be used to construct pn junction devices for alphavoltaic applications.

Triplett, G. E., Jr.↗
DOE OSTI2022

Probing Electronic and Structural Transformations during Thermal Reduction of the Promising Water Splitting Perovskite BaCe 0.25 Mn 0.75 O 3

Here, in this report, we investigate the thermal reduction of the octahedral perovskite BaCe 0.25 Mn 0.75 O 3 (BCM) using in situ electron energy loss spectroscopy (EELS) in an aberration-corrected transmission electron microscope (TEM). The 12R-polytype of BCM is known to demonstrate high solar thermochemical hydrogen production capacity. In situ EELS measurements show that Mn is the active redox cation in BCM, undergoing thermal reduction from Mn 4+ to Mn 3+ during heating to 700 °C inside the TEM under a high vacuum. The progressive reduction of Mn 4+ during oxygen vacancy (O v ) formation was monitored as a function of temperature. Additionally, atomic-resolution scanning transmission electron microscopy identified two different types of twin boundaries present in the oxidized and reduced form of 12R-BCM, respectively. These two types of twin boundaries were shown, via computational modeling, to modulate the site-specific O v formation energies in 12R-BCM. It is concluded that these types of atomic defects provide sites more energetically favorable for O v formation during thermal reduction.

36 MATERIALS SCIENCE↗
NASA NTRS1977

Anodization improves GaAs solar cell performance

Anodization technique produces GaAs pn-junction solar cells exhibiting improved response to high energy photons and higher open circuit voltages through reduction of reflection loss.

Hovel, H. J.↗
DOE OSTI2021

Results from a wake-steering experiment at a commercial wind plant: investigating the wind speed dependence of wake-steering performance

Wake steering is a wind farm control strategy in which upstream wind turbines are misaligned with the wind to redirect their wakes away from downstream turbines, thereby increasing the net wind plant power production and reducing fatigue loads generated by wake turbulence. In this paper, we present results from a wake-steering experiment at a commercial wind plant involving two wind turbines spaced 3.7 rotor diameters apart. During the 3-month experiment period, we estimate that wake steering reduced wake losses by 5.6% for the wind direction sector investigated. After applying a long-term correction based on the site wind rose, the reduction in wake losses increases to 9.3%. As a function of wind speed, we find large energy improvements near cut-in wind speed, where wake steering can prevent the downstream wind turbine from shutting down. Yet for wind speeds between 6–8 m/s, we observe little change in performance with wake steering. However, wake steering was found to improve energy production significantly for below-rated wind speeds from 8–12 m/s. By measuring the relationship between yaw misalignment and power production using a nacelle lidar, we attribute much of the improvement in wake-steering performance at higher wind speeds to a significant reduction in the power loss of the upstream turbine as wind speed increases. Additionally, we find higher wind direction variability at lower wind speeds, which contributes to poor performance in the 6–8 m/s wind speed bin because of slow yaw controller dynamics. Further, we compare the measured performance of wake steering to predictions using the FLORIS (FLOw Redirection and Induction in Steady State) wind farm control tool coupled with a wind direction variability model. Although the achieved yaw offsets at the upstream wind turbine fall short of the intended yaw offsets, we find that they are predicted well by the wind direction variability model. When incorporating the expected yaw offsets, estimates of the energy improvement from wake steering using FLORIS closely match the experimental results.

17 WIND ENERGY↗
DOE OSTI2025

Valued peaks: Sustainable water allocation for small hydropower plants in an era of explicit ecological needs

Optimizing hydropower operations to balance economic profitability and support functioning ecosystem services is integral to river management policy. In this article, we propose a dynamic, constrained optimization framework for small hydropower plants (SHPs) to evaluate trade-offs between economic profitability and socio-ecological requirements. Specifically, we examine the balance between short-term losses in hydropower generation and the potential for compensatory benefits in the form of revenue from recreational ecosystem services, irrespective of the direct beneficiary. Our framework integrates a fish habitat model, a hydropower optimization model, and a recreational ecosystem service estimate to evaluate different environmental flow scenarios. The optimization process gives three outflow release scenarios, informed by previous streamflow realisations (dam inflow), and designed environmental flow constraints. The framework is applied and tested for the river Kuusinkijoki in North-eastern Finland, which is a habitat for migratory brown trout and grayling populations. We show that the revenue loss due to the environmental flow constraints arises through a reduction in revenue per generated energy unit and through a reduction in turbine efficiency. Additionally, the simulation results reveal that all the designed environmental flow constraints cannot be met simultaneously. Under the environmental flow scenario with both minimum flow and flow ramping rate constraints, the annual hydropower revenue decreases by 16.5 %. An annual increase of 8 % in recreational fishing visits offsets the revenue loss. In conclusion, the developed framework provides knowledge of the costs and benefits of hydropower environmental flow constraints and guides the prioritizing process of environmental measures.

13 HYDRO ENERGY↗
DOE OSTI2020

Adapting In Situ Accelerators for Sparsity With Granular Matrix Reordering

Neural network (NN) inference is an essential part of modern systems and is found at the heart of numerous applications ranging from image recognition to natural language processing. In situ NN accelerators can efficiently perform NN inference using resistive crossbars, which makes them a promising solution to the data movement challenges faced by conventional architectures. Although such accelerators demonstrate significant potential for dense NNs, they often do not benefit from sparse NNs, which contain relatively few non-zero weights. Processing sparse NNs on in situ accelerators results in wasted energy to charge the entire crossbar where most elements are zeros. To address this limitation, this paper proposes Granular Matrix Reordering (GMR): a preprocessing technique that enables an energy-efficient computation of sparse NNs on in situ accelerators. GMR reorders the rows and columns of sparse weight matrices to maximize the crossbars' utilization and minimize the total number of crossbars needed to be charged. The reordering process does not rely on sparsity patterns and incurs no accuracy loss. Finally, GMR achieves an average of 28% and up to 34% reduction in energy consumption over seven pruned NNs across four different pruning methods and network architectures.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

Austin Sustainable and Holistic Integration of Energy Storage and Solar PV [Austin SHINES]. Final Report, Version 2

The Austin SHINES project and solution is a software management platform, for an electric grid with a high penetration of dispersed photovoltaic (PV) solar generation sites, which maintains the traditional power quality and reliability associated with grid service. This project developed and deployed the platform as a Distributed Energy Resource Management System (DERMS), engaging multiple advanced controls, to evaluate operation and optimization of a fleet of diverse DER assets, installed at several locations among Austin Energy’s customers and distribution system. The project also produced a methodology to create a replicable DERMS template, adaptable to other regions and market structures. Last, Austin SHINES aimed to demonstrate the solution’s methodology would enable the DER grid ecosystem to serve load at a technical cost (System Levelized Cost of Electricity, or System LCOE) of less than the U.S. Department of Energy SHINES program metric of $0.14/kWh, in a defined boundary, while enabling a high penetration of distributed PV. Research was categorized in 6 reports (Final Deliverables = FD) listed below, with titles and descriptions indicating which area of understanding was investigated: FD-1: System Levelized Cost of Electricity (System LCOE) Methodology The creation and use of the System LCOE to Serve Load metric that encompasses the holistic, system-level costs and benefits of all resources, and enables them to be evaluated based on their ability to support an efficient and low-cost integrated grid ecosystem. FD-2: Software Platform Product Description The creation of new DER control methodologies deployable within a utility-grade software platform that enable DER's to maximize their benefit within a grid, that is capable of serving load enabling a high penetration of distributed PV generation. FD-3: Optimal Design Methodology Optimal design methodologies for individual DER installations that enable utilities to determine the optimal combinations and sizing for individual DER sites. FD-4: Austin SHINES Ownership and Operation Models for DER System Performance A comparison of multiple DER aggregation and ownership methodologies including direct utility control, third-party aggregator, and autonomous. FD-5: Economic Modeling & Optimization A comparison of multiple DER technology mixes and configurations within the distribution system, providing insight into an optimal blend of technologies that best enable the distribution system to serve load at the lowest cost at high penetrations of solar. FD-6: Fielded Assets Deployed DER assets within the Austin Energy SHINES circuits. Austin SHINES provided an opening for state-of-the-art technology products to be deployed, providing a rich opportunity for improving how each of the products perform as stand-alone products, and in concert with other complementary products. The Austin SHINES project comprised of two key metrics for System LCOE: SystemLCOE_SHINES<$0.14/kWh Modeled ΔSystemLCOE_SHINES/ΔSystemLCOE_Base≥20% at same solar penetration The System LCOE calculation uses the costs of the utility-owned infrastructure as it exists today, the cost of the DERs that exist in the system today, and the cost of the purchase of energy from ERCOT wholesale markets over the course of the calendar year. All costs are on an annualized basis. The capital and operating costs are derived from the rate case, which produces a yearly cost. The net cost of energy and services imported to the system is integrated over the test year, as is the load served and solar penetration. The first metric was easily achieved by every scenario considered. The goal was set when the Department of Energy’s SHINES Funding Opportunity Announcement was written in 2015 and was a more difficult target at the time. Due mostly to rapidly declining costs for DERs and the significant decrease in the Electric Reliability Council of Texas (ERCOT) energy market prices, which results in lower net cost of energy purchases, the System LCOE is well below this target for all scenarios considered. A fleet of DERs can assume different mixtures, each of which serves the load at a different LCOE. The optimal mixture of DERs serves load at the smallest System LCOE. The second metric (hereinafter %delta metric) asks that the holistic DERMS controls reduce the incremental cost above the baseline of going to a high solar penetration future by at least 20% as compared to the case of a DER deployment with no sophisticated controls (autonomous). Many comparison sets were created throughout this project. Physical technology was installed for informing utility engineering and testing several types of operational control schemes, through the DERMS. The types of operational control which were compared for valuation of the System LCOE Metric were: Holistic control = using the full suite of the DERMS platform to decide and optimize how/why the systems operate depending on weather, market, and reliability signal input. Autonomous control = a local mode at the asset site, wherein a schedule operates the asset, with visibility into performance only No control = the baseline for comparing value against the other two types of control The types of ownership control included: Direct Utility control = the utility dispatches a signal to each asset Third-Party Aggregator = a third party aggregates a fleet of assets and the utility dispatches one signal for all Autonomous = a local mode is set for operation at the asset site, wherein a schedule operates the asset, with visibility into performance only The types of control methodologies deployable within a utility-grade software platform included: Utility Peak Load Reduction = Lower transmission cost obligation Day-Ahead Energy Arbitrage = Realize economic value through price differential Real-Time Price Dispatch = Realize economic value from real-time price spikes Voltage support = Reduce losses and increase solar generation Distribution Congestion Management = Increase local grid reliability Demand Charge Reduction = Lower customer bills and realize system benefit The fielded assets deployed for the project were: Utility Scale Kingsbery Energy Storage System: 1.5 MW / 3 MWh Li-Ion battery storage Mueller Energy Storage System: 1.75 MW / 3.2 MWh Li-Ion battery storage, 7 Energy Storage Units (250 kW each) La Loma Community Solar: 2.6 MW Commercial Scale Aggregated storage installations at 3 sites, with existing solar (300+ kW): One 18 kW / 36 kWh Li-Ion battery storage Two 72 kW / 144 kWh Li-Ion battery storage Residential Scale Aggregated storage installations: -Six stationary battery storage systems (10 kWh each) at homes with existing solar -One Electric Vehicle installed as Vehicle-to-Grid (V2G) Utility-Controlled Solar via Smart Inverters at 12 homes Autonomously-Controlled Smart Inverters at 6 homes Over the course of the project, Austin SHINES undertook installing more than 3 MW of distributed battery energy storage, smart PV inverters, a DER control platform, and other enabling technologies utilizing customer and utility locations and aggregation models. All of these resources were to be integrated and optimized at the utility level. DER assets and control methodologies were designed to achieve a credible pathway to a System LCOE for energy delivered to load of $0.14//kWh or less by 2020, while maximizing distributed solar generation and maintaining acceptable standards of power quality. The project also established a template for other regions to follow, to maximize the adoption of distributed solar PV in support of an economic and efficient grid. In total, the Austin SHINES project added value to the DER subject area in each layer of integration. From utility, to commercial to residential scales, the sheer hierarchy of communication and coordination was a significant accomplishment in addition to learnings from what these communications revealed was unique to each. Economically, the most effective method demonstrated was the criticality of planning phases. Contingencies and multiple projection scenarios helped guide the project to deploy optimal design as close as feasible, in real world conditions. The project and reports will serve public benefit by outlining specific areas of DER strategy and installation where many stakeholders and needs can be addressed with improved efficiency. Overall, communities and utilities should use the results to guide the increasing options available for powering the grid with DER, renewables, and carbon considerate energy.

14 SOLAR ENERGY↗
DOE OSTI2021

Demonstration of reduced neoclassical energy transport in Wendelstein 7-X

Research on magnetic confinement of high-temperature plasmas has the ultimate goal of harnessing nuclear fusion for the production of electricity. Although the tokamak is the leading toroidal magnetic-confinement concept, it is not without shortcomings and the fusion community has therefore also pursued alternative concepts such as the stellarator. Unlike axisymmetric tokamaks, stellarators possess a three-dimensional (3D) magnetic field geometry. The availability of this additional dimension opens up an extensive configuration space for computational optimization of both the field geometry itself and the current-carrying coils that produce it. Such an optimization was undertaken in designing Wendelstein 7-X (W7-X), a large helical-axis advanced stellarator (HELIAS), which began operation in 2015 at Greifswald, Germany. A major drawback of 3D magnetic field geometry, however, is that it introduces a strong temperature dependence into the stellarator’s non-turbulent ‘neoclassical’ energy transport. Indeed, such energy losses will become prohibitive in high-temperature reactor plasmas unless a strong reduction of the geometrical factor associated with this transport can be achieved; such a reduction was therefore a principal goal of the design of W7-X. In spite of the modest heating power currently available, W7-X has already been able to achieve high-temperature plasma conditions during its 2017 and 2018 experimental campaigns, producing record values of the fusion triple product for such stellarator plasmas. The triple product of plasma density, ion temperature and energy confinement time is used in fusion research as a figure of merit, as it must attain a certain threshold value before net-energy-producing operation of a reactor becomes possible. Here we demonstrate that such record values provide evidence for reduced neoclassical energy transport in W7-X, as the plasma profiles that produced these results could not have been obtained in stellarators lacking a comparably high level of neoclassical optimization.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Real-Time Highly Resolved Spatial-Temporal Vehicle Energy Consumption Estimation Using Machine Learning and Probe Data

Real-time highly resolved spatial-temporal vehicle energy consumption is a key missing dimension in transportation data. Most roadway link-level vehicle energy consumption data are estimated using average annual daily traffic measures derived from the Highway Performance Monitoring System; however, this method does not reflect day-to-day energy consumption fluctuations. As transportation planners and operators are becoming more environmentally attentive, they need accurate real-time link-level vehicle energy consumption data to assess energy and emissions; to incentivize energy-efficient routing; and to estimate energy impact caused by congestion, major events, and severe weather. This paper presents a computational workflow to automate the estimation of time-resolved vehicle energy consumption for each link in a road network of interest using vehicle probe speed and count data in conjunction with machine learning methods in real time. The real-time pipeline can deliver energy estimates within a couple seconds on query to its interface. The proposed method was evaluated on the transportation network of the metropolitan area of Chattanooga, Tennessee. The volume estimation results were validated with ground truth traffic volume data collected in the field. To demonstrate the effectiveness of the proposed method, the energy consumption pipeline was applied to real-world data to quantify road transportation-related energy reduction because of mitigation policies to slow the spread of COVID-19 and to measure energy loss resulting from congestion.

Severino, Joseph↗
DOE OSTI2025

On the optimal sizing of power take-off systems for wave energy converters

The power take-off (PTO) system in a wave energy converter (WEC) is the means by which the energy in an ocean wave is converted into useful energy. There has been a general lack of technology convergence in the wave energy industry and PTO design has been largely device-specific with the design process determined by the WEC developer. An optimized PTO design can significantly affect the efficiency, reliability, performance, and overall cost and viability of a device. There remains a need in the marine energy industry for best practices and efficient design processes to be identified as it could greatly benefit developers and researchers in designing an optimal WEC PTO. This research utilizes the open-source Matlab-Simulink based software, WEC-Sim, which was developed by the National Renewable Energy Laboratory, and the Eagle, a high-performance computing system, to model and optimize two WECs of different archetypes and then investigates if any trends exist that can be exploited for greater efficiency in optimal PTO design. The results from this research indicate that there may be an optimal sizing for WEC PTOs for both power and PTO force rating and that substantial reductions can be made in the cost of a device without significant loss in the energy produced. Furthermore this optimal sizing may be independent of WEC type and deployment location. With an optimal, or near optimal, approach to WEC PTO sizing demonstrated, a methodology is proposed to address the challenge of nameplate ratings in the wave energy industry.

13 HYDRO ENERGY↗
DOE OSTI2026

Through‐Plane Conductive Hydrophobic Electrodes for CO 2 Electrolysis to Ethylene

Copper catalyst gas diffusion electrodes (GDEs) have demonstrated unique electrochemical selectivity converting CO 2 to C 2 -hydrocarbons such as ethylene and ethanol but have been challenged by their hydrophobic chemical stability and internal electrical resistance leading to low energy efficiency. Carbon-supported GDEs have low electrical resistance but lack sufficient stability at industrially relevant current densities. While polymer-supported GDEs have improved hydrophobicity, they also display high in-plane electrical resistance, particularly at industrial scales. Here, in this work, we demonstrate a composite gas diffusion layer that combines hydrophobic porous polymers with an electrically conductive backbone addressing these core gas diffusion electrode (GDE) scaling challenges. We investigate the material properties of standalone porous perfluoropolyether (PFPE) polymers, including porosity and surface morphology, under varying processing conditions and then incorporate these polymers into a porous copper foam. This composite enhances the mechanical rigidity necessary for cell assembly and provides a through-plane electrical conduction path to reduce electrical resistive losses. This enhanced PFPE composite GDE displays efficient CO 2 reduction, achieving 15% ethylene energy efficiency at 100 cm 2 . These findings contribute to the development of advanced catalyst materials and electrode architectures and promote scalable strategies for electrochemical conversion of CO 2 into high-value carbon products.

Chemistry↗
DOE OSTI2022

Probabilistic Modeling of Climate Change Impacts on Renewable Energy and Storage Requirements for NM's Energy Transition Act (SAND Report)

This report provides a study of the potential impacts of climate change on intermittent renewable energy resources, battery storage, and resource adequacy in Public Service Company of New Mexico’s Integrated Resource Plan for 2020 – 2040. Climate change models and available data were first evaluated to determine uncertainty and potential changes in solar irradiance, temperature, and wind speed in NM in the coming decades. These changes were then implemented in solar and wind energy models to determine impacts on renewable energy resources in NM. Results for the extreme climate-change scenario show that the projected wind power may decrease by ~13% due to projected decreases in wind speed. Projected solar power may decrease by ~4% due to decreases in irradiance and increases in temperature in NM. Uncertainty in these climate-induced changes in wind and solar resources was accommodated in probabilistic models assuming uniform distributions in the annual reductions in solar and wind resources. Uncertainty in battery storage performance was also evaluated based on increased temperature, capacity fade, and degradation in round-trip efficiency. The hourly energy balance was determined throughout the year given uncertainties in the renewable energy resources and energy storage. The loss of load expectation (LOLE) was evaluated for the 2040 No New Combustion portfolio and found to increase from 0 days/year to a median value of ~2 days/year due to potential reductions in renewable energy resources and battery storage performance and capacity. A rank-regression analyses revealed that battery round-trip efficiency was the most significant parameter that impacted LOLE, followed by solar resource, wind resource, and battery fade. An increase in battery storage capacity to ~25,000 – 30,000 MWh from a baseline value of ~14,000 MWh was required to reduce the median value of LOLE to ~0.2 days/year with consideration of potential climate impacts and battery degradation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Temperature Distribution Within an Ignition Kernel Initiated by a Laser-Induced Plasma

The sizes of, and temperature distributions within, ignition kernels initiated by a Q-switched neodymium-doped yttrium aluminum garnet laser-induced plasma in an unconfined lean premixed hydrogen-air upward jet flow are investigated. The experiments involved a range of jet velocities and a range of deposited laser energies at a fixed height above the exit along the axis of a burner. The growth of, and the temperature distributions within, the ignition kernels, as affected by the size and the energy distribution of the laser-induced plasma, are monitored with an infrared camera. The initial ignition kernels’ areas are larger with higher laser pulse energies and remain unchanged up to [Formula: see text] and then increase by factors of up to 3 at [Formula: see text]. The change in the kernel area caused by the jet velocities is less than 1.5%. An increase of the bulk velocity by 190% decreases the ignition kernel temperature by 6%. This reduction in the ignition kernel temperatures is because of an increase in energy losses by a factor of 2 and decreases in heat releases by 2% at [Formula: see text] and by 11% at [Formula: see text]. The present contributions are: measurements of and insights into temperature distributions and kernel development rates during the laser-induced plasma ignition process at different deposited energies and flow velocities.

Engineering↗
NASA NTRS1972

Reflecting ablating heat shields for planetary entry.

Heat shielding for planetary entry probes of future Jovian and Venusian missions will encounter heating levels well beyond those previously experienced. These entries are typically dominated by radiative heating from the shock layer. This paper demonstrates the potential of reflecting this incident radiation diffusely from an ablating material. This technique contrasts with the absorption experienced by char-forming or graphitic ablators. Two dielectric materials, Teflon (polytetra-fluoroethylene) and boron nitride, are examined for their ablative performance, including reflection, in a combined convective- and radiative-heating environment. For Teflon, at the conditions obtained, superimposition of radiative heating upon a convective stream causes no additional increase in surface recession over the convective only results. For boron nitride, an excellent room-temperature reflector in the visible spectrum, a decrease in reflectivity from 90 to 55 percent is experienced when the surface undergoes sublimation at high temperatures. The process of reflection in each of these materials is described in terms of backscattering from crystals. The significance of a sizable reflection as a mode of energy accommodation is demonstrated for Venusian entries as a potential reduction in mass loss due to ablation.

Peterson, D. L.↗
NASA NTRS1980

CF6-6D engine performance deterioration

Cruise cockpit recordings and test cell performance data in conjunction with hardware inspection data from airline overhaul shops were analyzed to define the extent and magnitude of performance deterioration of the General Electric CF6-6D model engine. These studies successfully isolated short-term deterioration from the longer term, and defined areas where a significant reduction in aircraft energy requirements for the 1980's can be realized. Unrestored losses which remain after engine refurbishment represent over 70% of the loss at engine shop visit. Sixty-three percent of the unrestored losses are cost-effective to restore which could reduce fuel consumed by CF6-6D engines in 1980 by 10.9 million gallons.

Wulf, R. H.↗
DOE OSTI2024

Plastic Parallel Pathways Platform- 4P Model

The U.S. generates 42 million metric tons of plastic waste each year - the most of any country - of which less than 9% is recycled. This represents an estimated loss of $2.3 billion and 3.4 EJ embodied energy per year. Plastic use reduction, reuse and recycling are thus increasingly important, but making informed policy and research decisions within this space can be challenging given the diverse range of available solutions. Various recycling and waste management options are available for plastics, such as conversion into energy (incineration, pyrolysis, gasification), conversion to lower- or higher-grade plastics (mechanical recycling, chemical or enzymatic depolymerization processes, dissolution) or up-cycling to feedstock chemicals (photo/electro/catalytic methods, pyrolysis, gasification). While many previous publications have investigated a subset of these options, there is currently no modelling platform that can quantitatively assess and compare the economic and environmental impacts of all these different plastic management pathways and their respective products simultaneously. To directly compare the benefits and disadvantages of plastic-to-x technologies, we propose a novel analysis framework: the Plastic Parallel Pathways Platform (4P). 4P will model a systems analysis framework for capturing plastic material flows processed via different waste management scenarios. The total economic cost and greenhouse gas emissions (as well as additional economic, energetic, and environmental metrics indicators) of a given scenario will be calculated enabling comparison to other scenarios, thereby informing decisions on plastic recycling pathways.

circular economy↗
DOE OSTI2021

Electronic structure of reduced CeO 2 (111) surfaces interacting with hydrogen as revealed through electron energy loss spectroscopy in comparison with theoretical investigations

Based on both, ab-initio cluster calculations as well as periodic density functional based loss function calculations, we have assigned the origins of the valence electron excitation regime in electron energy loss spectra of well-ordered ceria films in (111) orientation at various states of reduction as well as after exposing the reduced films to hydrogen from the gas phase (Li et al, Angew. Chem. Int. Ed., 58 (2019) 14686–14693). The explicit calculation of intensity distributions using the dipole approximation allow us to draw conclusions about the nature of oxygen vacancies, which occur upon reduction and how those interact with hydrogen to form hydride species. Herein, we also reports a brief discussion of vibrational excitations of hydrogen loaded ceria and corroborates previous interpretations, based on inelastic neutron scattering.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗