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At least 55 records · Page 3

New Predictive Capabilities for Nuclear Weapons in Composite Fires

The prevalence of flammable carbon-based composite airframe materials and their use in high-temperature nuclear weapon re-entry systems requires analysts to address the abnormal thermal environment hazards associated with composite material fires. These fires tend to burn very differently than conventional fuel fires, usually burning less intensely, but much longer. This could lead to challenges in understanding margins in classic safety themes. The technical challenges in modeling the phenomena associated with these new types of fires are considerable, but new models have been developed. Their predictions have been compared with well-documented measurements of a vertical porous burner fire, known as a "wall fire" (a "wall-fire" validation simulation is reflected in the figures below). These measurements were conducted at FMGlobal, a mutual insurance company with a strong fire risk management program, as part of an ongoing collaboration between Sandia and FMGlobal. To date, the "wall-fire" scenario has been set up and initial model assessments with grid refinement studies have been conducted focusing on mesh resolutions suitable for full weapon system simulations. This work will continue with further verification and validation tasks assessing the predictions of the new model. Future work will address specific aspects of the wall models that are lacking in their predictive ability.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Intense formation of secondary ultrafine particles from Amazonian vegetation fires and their invigoration of deep clouds and precipitation

New particle formation (NPF) in fire smoke is thought to be unlikely due to large condensation and coagulation sinks that scavenge molecular clusters. We analyze aircraft measurements over the Amazon and find that fires significantly enhance NPF and ultrafine particle (UFP < 50 nm diameter) numbers compared to background conditions, contrary to previous understanding. We identify that the nucleation of dimethylamine with sulfuric acid, which is aided by the formation of extremely low volatility organics in biomass-burning smoke, can overcome the large condensation and coagulation sinks and explain aircraft observations. We show that freshly formed clusters rapidly grow to UFP sizes through biomass-burning secondary organic aerosol formation, leading to a 10-fold increase in UFP number concentrations. Here, we find a contrasting effect of UFPs on deep convective clouds compared to the larger particles from primary emissions for the case investigated here. UFPs intensify the deep convective clouds and precipitation due to increased condensational heating, while larger particles delay and reduce precipitation.

54 ENVIRONMENTAL SCIENCES↗

Airborne LiDAR to Improve Canopy Fuels Mapping for Wildfire Modeling

Increasing conflict between wildfire and the built environment has increased the need for more up-to-date and finer resolution canopy fuels data to improve wildfire modeling and associated risk forecasts. The US Forest Service and US Department of the Interior’s LANDFIRE product, which provides 30-m resolution canopy fuels data for the entire US, is one of the most widely used sources of fuels data. However, the last complete mapping effort for LANDFIRE is based on 2016 conditions, and subsequent updates reflect disturbances 1-2 years behind the release year. Airborne systems equipped with Light Detection and Ranging (LiDAR) sensors can be deployed to actively sense canopy structure and estimate canopy fuels data (cover, height, base height, bulk density) at finer resolutions. Canopy base height (CBH) and canopy bulk density (CBD) are difficult to measure both in the field and in LiDAR point clouds. Still, they are important for accurately modeling crown fires, which are often intense and difficult to contain. Additionally, point cloud datasets are large, and calculations require efficient utilization of computational resources. To address these challenges, we are working on an approach that uses openly available National Ecological Observatory Network (NEON) airborne LiDAR data, with calculations processed in the R programming language and parallelized through the lidR package. CBH and CBD are often derived from tree height, diameter at breast height, and species-specific allometries using the Fire and Fuels Extension of the Forest Vegetation Simulator (FFE-FVS). We aim to test if airborne LiDAR can estimate CBH and CBD without the use of empirical equations. Reliable estimates of canopy fuels data directly from airborne LiDAR could streamline quick, fine-resolution updates for use in wildfire behavior models.

54 ENVIRONMENTAL SCIENCES↗

Exploring Wildfire & Energy data toward State Prioritization Index (WESPI)

Energy infrastructure can both induce and suffer risks from wildfires ranging from direct damage to energy assets such as substations and power lines to Public Safety Power Shutoffs. Recent wildfire events underscore the need for data-driven approaches that help states and utilities proactively plan for wildfire risk. Existing national tools such as Federal Emergency Management Agency (FEMA)’s National Risk Index (NRI) are valuable for community hazard planning. However, they are less suited for energy infrastructure, as they emphasize population and building exposure rather than system vulnerabilities. In this paper, we explore relationships between energy and wildfire data and present a Wildfire-Energy State Prioritization Index (WESPI). Our methodology combines data from the US Forest Service’s Fire Simulation (FSIM) dataset with energy resilience metrics, historical fire incidents, and geospatial data on transmission lines and fire stations. Correlation analyses suggest that FSIM burn probability is more strongly associated with power outage metrics (ρ = 0.32) than NRI wildfire frequency, and counties with a greater density of fire stations experience more frequent, but less intense wildfires. We further leverage data for burn probability, transmission line density, and fire station density to develop a Wildfire-Energy State Prioritization Index (WESPI) to highlight counties where wildfire hazard, infrastructure exposure, and limited suppression capacity converge. The index provides a consistent, scalable framework for state energy offices and utilities to screen counties for vegetation management, optimization of outage management system deployment, and to inform wildfire mitigation plans.

Critical infrastructure↗

Soil Temperature and Moisture within the Kougarok Fire Complex, Kougarok Road Mile Marker 86, Seward Peninsula, Alaska, 2019-2023

Daily averages of soil temperature and moisture measured once every hour at different heights located at Intensive Monitoring Stations within the Kougarok Fire Complex, Kougarok Road Mile Marker 86 site. Data were retrieved annually from 2019-2023. Package contains 21 *.CSV data files plus a file level metadata *.CSV, data dictionary *.CSV, data file inventory *.CSV, and sensor location site map *.JPG. Data files have header rows, NaN fields indicate invalid or missing data, and negative vertical offsets are above ground.The Kougarok tundra fire complex (KFC) is located north of Nome and the Kigluaik Mountains, near Quartz Creek and the Kougarok River. The site is accessed by foot from the end of the Nome-Taylor Highway (mile marker 86; also called the Kougarok or Beam Road). The KFC burned in six major fires in the decades since 1950 (Alaska Interagency Coordination Center, unpublished data). Lightning ignited five of these fires (1971, 1997, 2015, and 2019) and one was human caused (2002). The mosaic of overlapping fire scars allows for the study of repeat fires in the tundra which, until recently, was not a common phenomenon outside the boreal forest in Alaska. Our reference unburned tundra fire site is south of the KFC located at mile marker 80 of the Nome-Taylor Highway.The two most recent fires are the Mingvk Lake (2015; 21,698 acres burned from 7/27/2015 to 9/28/2015) and Garfield Creek (2019; 422 acres burned from 7/31/2019 to 8/20/19). The Mingvk Lake fire scar includes areas that burned 1-4x (1971, 1997, 2002), while the entirety of the Garfield Creek fire scar has burned 2x previously (1971, 2002).Previous research at the KFC focused on permafrost (Liljedahl et al. 2007; Narita et al. 2015; Iwahana et al. 2016; Tsuyuzaki, Iwahana, and Saito 2017) and vegetation (Narita et al. 2015; Hollingsworth et al. 2021) response to fire. The central Seward Peninsula is characterized by continuous permafrost with a thickness of 15 to 30 m and a mean active layer thickness of 56 cm (Hinzman et al. 2003). Sloping hills with mixed shrub–tussock tundra and tussock tundra vegetation in the uplands are characteristic of the region. Three micrometeorological towers near the Kougarok field site recorded a mean annual temperature of −2.4°C, mean January temperature of −23.1°C, mean July temperature of +11°C, and mean summer rainfall (June–August) of 94 mm from 2000 to 2006 (Liljedahl et al. 2007).The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

AmeriFlux FLUXNET-1F US-xJE NEON Jones Ecological Research Center (JERC)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-xJE NEON Jones Ecological Research Center (JERC). This is the FLUXNET version of the carbon flux data for the site US-xJE NEON Jones Ecological Research Center (JERC) produced by applying the standard ONEFlux (1F) software. Site Description - This terrestrial relocatable field site is located in the Joseph Jones Ecological Research Center is an 11,000-hectare reserve located within the Lower Coastal Plains and Flatwoods areas in southern Georgia. The Jones site has been managed with low intensity, dormant-season prescribed fires for the past 75 years at a frequency of every 3-4 years.

Network), NEON (National Ecological Observatory↗

AmeriFlux FLUXNET-1F US-Me2 Metolius mature ponderosa pine

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-Me2 Metolius mature ponderosa pine. This is the FLUXNET version of the carbon flux data for the site US-Me2 Metolius mature ponderosa pine produced by applying the standard ONEFlux (1F) software. Site Description - Site Description before Fire (January, 2002 - August, 2020): The mean stand age is 71 years old and the stand age of the oldest 10% of trees is about 108 years old. This site is one of the Metolius core cluster sites with different age and disturbance classes and part of the AmeriFlux network. The overstory is almost exclusively composed of ponderosa pine trees (Pinus ponderosa Doug. Ex P. Laws) with a few scattered incense cedars (Calocedrus decurrens (Torr.) Florin) and has a peak leaf area index (LAI) of 2.1 m2 m-2. Tree height is relatively homogeneous at about 18 m, and the mean tree density is approximately 339 trees ha-1 (Irvine et al., 2008). The understory is sparse with an LAI of 0.2 m2 m-2 and primarily composed of bitterbrush (Purshia tridentata (Push) DC.) and greenleaf manzanita (Arctostaphylos patula Greene). Soils at the site are sandy (69%/24%/7% sand/silt/clay at 0–0.2 m depth and 66%/27%/7% at 0.2–0.5 m depth, and 54%/ 35%/11% at 0.5–1.0 m depth), freely draining with a soil depth of approximately 1.5 m (Irvine et al., 2008; Law et al., 2001b; Schwarz et al., 2004). Green Ridge Fire: On August 20, 2020, the Green Ridge Fire burned through Us-Me2. The fire was ignited by lightning on August 16th, and grew rapidly to the east over the first few days driven by strong, downslope (westerly) afternoon winds. Fire behavior and observed fire effects were highly heterogeneous due to the localized wind pattern carrying the flaming head of the fire forward, and the efforts being made by suppression resources to contain the fire. The site experienced the full range of fire effects, from <1 m high surface fire that charred litter and duff and only consumed shrubs and herbaceous material to full tree (>15 m) crown fire that consumed 100% of needles, small limbs, and surface fuels at high intensity, leaving only ash and bare soil post-fire. Salvage Logging: From late March to late April 2021, salvage logging by the landowner occurred at the site. Almost all trees within the flux footprint were logged except a small area with lower burn severity, where sap flow and automatic soil respiration measurements are continued since the fire. In August 2022 the primary flux system was moved from the top of the damaged tall tower to a nearby shorter tower centering on the salvage/regenerating footprint.

Hanson, Chad↗

Geochemistry, volumetric water content, and active layer depths from rainfall simulations at the Kougarok Fire Site, Seward Peninsula, Alaska, 2022

Rainfall frequency and intensity is expected to increase in the Arctic, with potential implications for permafrost thaw and geochemical fluxes in soils. To conduct controlled rainfall experiments at remote field sites in the Arctic, the Next-Generation Ecosystem Experiments Arctic Rainfall Simulator (NARS) was developed at Los Alamos National Laboratory as part of the NGEE Arctic project. To better understand how rainfall may affect interflow biogeochemistry and permafrost thaw, rainfall simulations were performed on the Seward Peninsula of Alaska during late September and early October 2022 at the Kougarok Fire Site near mile marker 86 of the Nome-Taylor Highway. Water samples were collected before, during, and after rainfall simulations until interflow had ceased. Additional data collected included soil pore water samples from macrorhizons, active layer depths, and volumetric water content at each of the experimental plots. This dataset contains one *.csv file of water sample properties, one *.csv file of thaw depths, one *.csv file of soil moisture measurements, and one *.kml file of the locations where samples were collected.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy’s Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy’s Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

A combined biological and chemical flue gas utilization system towards carbon dioxide capture from coal-fired power plants (Final Report)

Photosynthetic algal cultivation has been intensively studied for CO 2 capture and utilization for several decades. The footprint for using algae to capture CO 2 emitted from carbon-intensive industrial processes (power plants, cement plants, and fermentation processes) is extremely large, which creates serious technical and economic hurdles that must be cleared if algal technologies are to be commercially implemented. Fortunately, algal biomass is rich in proteins, carbohydrates, and lipids, providing a good chemical source for organic absorbents and other value-added chemical feedstocks. In particular, amino acids from algal protein can be used to generate amino acid salt solutions that have been proven to be effective for capturing CO 2 . In order to take advantage of both algal cultivation and biomass utilization, the goal of the proposed project is to develop a combined biological and chemical system for coal-fired power plants for sequestering CO 2 in biological absorbents and generating value-added products. This approach significantly reduces the land and energy footprint of CO 2 capture, and minimizes capital and operational expenses. Three specific objectives are targeted: 1) optimizing the growth of the selected algal strain to maximize biomass accumulation from the coal-fired flue gas; 2) developing a cascade biomass utilization to produce amino acid absorbents, polyurethanes, biodiesel, and methane; and 3) conducting techno-economic analysis (TEA) and life cycle assessment (LCA) of the proposed process. Three key technical outcomes were achieved: (1) With the selected robust algal strain and unique photobioreactor design, long-term culture stability can be extended, and algal biomass productivity reached 0.5 g dry biomass/L/day year-round at a biomass concentration of 1.2 g/L in the pilot photobioreactor; (2) The biomass utilization process led to complete utilization of the algal biomass to produce amino acid salt absorbent, polyurethanes, and methane; and (3) The combined biological and chemical flue gas utilization process concluded a technically and economically feasible commercial-scale system that completely captures CO 2 in coal-fired flue gas with greatly reduced energy consumption.

01 COAL, LIGNITE, AND PEAT↗

Investigation of powertrain system decarbonization using electrically assisted turbocharging and hybridization in off-road vehicles

In recent years, the causes, effects, and existential threat of a global anthropogenic climate shift have drawn significant attention and stimulated mitigation efforts from all genres of scientific, political, and industrial bodies. The greenhouse effect and the detrimental environmental impact of excess greenhouse gas (GHG) emissions, like carbon dioxide, is well studied and targeted as the primary culprit for aversive action. However, some fields exist where reducing GHG emissions is met by considerable challenges. One such field is the production and operations of off-road vehicles. Applications of these vehicles are highly diverse and are often characterized by rugged, especially transient, and power intensive duty cycles that make one-fits-all vehicle configuration solutions impractical. This research surveys existing literature to identify the modern technologies packages and challenges that face development and configuration of powertrain systems which currently navigate the regulated emissions and unique duty cycle requirements of this market space. A novel powertrain concept is proposed and evaluated with respect to the pinnacle objectives of load performance improvement, criteria pollutant reduction, and reducing the life cycle GHG intensity of its operation. A sure-fire path to vehicular GHG reduction is through improving the fuel efficiency of internal combustion engines (ICEs), an entrenched component of the off-road vehicle sector. Unfortunately, this is more easily said than done. An approach that has proven successful in this endeavor is engine downsizing and turbocharging, where a larger engine is replaced with a smaller one with added air system boosting via turbocharger to reduce frictional and pumping losses while also enabling access to additional fuel energy. However, practical realization of these potential benefits is often impeded by the transient response capability of the smaller engine across the operating space. For this reason, downsized ICE powertrains have turned to electrified forced induction systems (EFISs) for a decoupling of exhaust energy and engine speed from boost capability. Platformed on 48V hybrid technology, these systems introduce the need for more sophisticated controls around the engine gas-exchange process for the management of boost performance and exhaust gas emissions. On this account, simulation studies utilizing a GT-POWER model of a turbocharged 4.5 L engine outfit with an EFIS using an electrically driven compressor (eBooster®) are conducted to provide insight into the performance of this air handling architecture on an off-road engine. The results show that improvement in transient torque response time in sync with reduction in engine-out soot and NOx emissions are possible with an engine recalibration that leverages the transient air-fuel ratio authority of the eBooster®. Benefits are further demonstrated when duty cycle simulations of the 48V mild-hybrid engine concept are exercised, showing an acute decrease in cumulative fuel usage and soot production. Powertrain hybridization is another technological pathway achieving pronounced GHG reduction successes in modern on-road vehicle applications through integration of Li-ion battery technology. In the off-road vehicle segment, a review of available literature concludes that hybridized architectures are present but generally lack the depth of technologies that have both high specific energy and power capabilities, and thus are limited in their inclusion of Li-ion batteries for ICE assistance and enhanced energy storage capability. Therefore, building on the mild-hybrid engine results, the downsized and eBoosted engine concept was integrated into a larger high-voltage battery-hybrid series-electric powertrain system. Hybrid powertrain parameter sensitivity studies were carried out in a numerical charge-sustaining framework, providing novel insights into power flows between the battery and the engine and how their respective capabilities and operation contribute to GHG and criteria pollutant emissions of diverse duty cycles. Application of supervisory power management introduced robustness into the power sourcing and battery SOC control process and showed that optimum specification of battery properties can yield synergies between GHG emissions and battery energy capacity. Furthermore, examination of recent literature on Li-ion batteries has shown that pack manufacturing is a highly energy intensive process, thereby producing considerable quantities of GHGs that scale with energy storage capacity. Also scaling with a battery’s energy storage capacity is its investment cost. In consideration of these factors, an inclusive technoeconomic and GHG life cycle analysis is conducted. This analysis systematically compares the carbon footprint and total cost of ownership associated with the proposed hybrid powertrain concept to reference and alternative powertrain configurations, facilitating a thorough evaluation of the decarbonization effectiveness and economic viability.

99 GENERAL AND MISCELLANEOUS↗

Cooperative carbon capture and steam regeneration with tetraamine-appended metal–organic frameworks

Natural gas has become the dominant source of electricity in the United States, and technologies capable of efficiently removing carbon dioxide (CO 2 ) from the flue emissions of natural gas–fired power plants could reduce their carbon intensity. However, given the low partial pressure of CO 2 in the flue stream, separation of CO 2 is particularly challenging. Taking inspiration from the crystal structures of diamine-appended metal–organic frameworks exhibiting two-step cooperative CO 2 adsorption, we report a family of robust tetraamine-functionalized frameworks that retain cooperativity, leading to the potential for exceptional efficiency in capturing CO 2 under the extreme conditions relevant to natural gas flue emissions. The ordered, multimetal coordination of the tetraamines imparts the materials with extraordinary stability to adsorption-desorption cycling with simulated humid flue gas and enables regeneration using low-temperature steam in lieu of costly pressure or temperature swings.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Systematically tracking the hourly progression of large wildfires using GOES satellite observations

Abstract. In the western United States, prolonged drought, a warming climate, and historical fuel buildup have contributed to larger and more intense wildfires as well as to longer fire seasons. As these costly wildfires become more common, new tools and methods are essential for improving our understanding of the evolution of fires and how extreme weather conditions, including heat waves, windstorms, droughts, and varying levels of active-fire suppression, influence fire spread. Here, we develop the Geostationary Operational Environmental Satellites (GOES)-Observed Fire Event Representation (GOFER) algorithm to derive the hourly fire progression of large wildfires and create a product of hourly fire perimeters, active-fire lines, and fire spread rates. Using GOES-East and GOES-West geostationary satellite detections of active fires, we test the GOFER algorithm on 28 large wildfires in California from 2019 to 2021. The GOFER algorithm includes parameter optimizations for defining the burned-to-unburned boundary and correcting for the parallax effect from elevated terrain. We evaluate GOFER perimeters using 12 h data from the Visible Infrared Imaging Radiometer Suite (VIIRS)-derived Fire Event Data Suite (FEDS) and final fire perimeters from the California's Fire and Resource Assessment Program (FRAP). Although the GOES imagery used to derive GOFER has a coarser resolution (2 km at the Equator), the final fire perimeters from GOFER correspond reasonably well to those obtained from FRAP, with a mean Intersection-over-Union (IoU) of 0.77, in comparison to 0.83 between FEDS and FRAP; the IoU indicates the area of overlap over the area of the union relative to the reference perimeters, in which 0 is no agreement and 1 is perfect agreement. GOFER fills a key temporal gap present in other fire tracking products that rely on low-Earth-orbit imagery, where perimeters are available at intervals of 12 h or longer or at ad hoc intervals from aircraft overflights. This is particularly relevant when a fire spreads rapidly, such as at maximum hourly spread rates of over 5 km h−1. Our GOFER algorithm for deriving the hourly fire progression using GOES can be applied to large wildfires across North and South America and reveals considerable variability in the rates of fire spread on diurnal timescales. The resulting GOFER product has a broad set of potential applications, including the development of predictive models for fire spread and the improvement of atmospheric transport models for surface smoke estimates. The resulting GOFER product has a broad set of potential applications, including the development of predictive models for fire spread and the improvement of atmospheric transport models for surface smoke estimates (https://doi.org/10.5281/zenodo.8327264, Liu et al., 2023).

Geology↗

Arbuscular mycorrhizal fungal response to fire and urbanization in the Great Smoky Mountains National Park

Wildfires are increasing in frequency and intensity as drier and warmer climates increase plant detrital fuel loads. At the same time, increases in urbanization position 9% of fire-prone land within the United States at the wildland–urban interface. While rarely studied, the compounded effects of urbanization and wildfires may have unknown synergistically negative effects on ecosystems. Previous studies at the wildland–urban interface often focus on aboveground plant communities, but belowground ecosystems may also be affected by this double disturbance. In particular, it is unclear how much fire and urbanization independently or interactively affect nutritional symbioses such as those between arbuscular mycorrhizal (AM) fungi and the majority of terrestrial plants. In November 2016, extreme drought conditions and long-term fire suppression combined to create a wildfire within the Great Smoky Mountains National Park and the neighboring exurban city of Gatlinburg, TN. To understand how the double disturbance of urbanization and fire affected AM fungal communities, we collected fine roots from the 5 dominant understory species in September 2018 at each of 18 sites spanning 3 burn severities in both exurban and natural sites. Despite large variation in burn severity, plant species identity had the largest influence on AM fungi. AM fungal colonization, richness, and composition all varied most among plant species. Fire and urbanization did influence some AM fungal metrics; colonization was lower in burned sites and composition was more variable among exurban locations. There were no interactions among burn severity and urbanization on AM fungi. Our results point to the large influence of plant species identity structuring this obligate nutritional symbiosis regardless of disturbance regime. Therefore, the majority of AM fungal taxa may be buffered from fire-induced ecosystem changes if plant community composition largely remains intact, plant species life history traits allow for AM fungal persistence after fire disturbance, and/or nearby undisturbed habitat can act as an inoculum source for recolonization following fires. Thus, it is critical to maintain natural, undisturbed habitats interspersed within the wildland–urban interface.

59 BASIC BIOLOGICAL SCIENCES↗

Automated Fire Detection for Industrial Settings with Pretrained Convolutional Networks

Early fire detection in industrial environments is critical to preventing equipment damage, personal injury, and operational disruptions. Traditional smoke detectors, while effective, often experience delays due to the time required for smoke to reach sensors, allowing fires to spread. Manual fire watch operations and human surveillance of camera feeds are resource-intensive and prone to human error. To address these challenges, this paper explores the application of convolutional neural networks for automated fire detection, specifically in industrial settings. By leveraging 11 different pre-trained machine vision models from TensorFlow and enhancing them with transfer learning on a custom-built industrial fire dataset, we optimized fire detection performance. Here, we analyzed each machine vision model architecture in terms of its depth, width, and input image resolution, considering both resource requirements and detection accuracy. We further explored the option of combining multiple models into an ensemble classifier to evaluate whether the performance improvements could justify the much greater computational complexity and other practical impacts. A cost-benefit analysis is presented to evaluate the trade-offs between performance and computational expense. Our findings identify that EfficientNetV2L, specifically tailored for industrial applications, provides the optimal balance between costs involved in training and using the model versus the overall fire detection performance. Additionally, we present a qualitative analysis of model performance using the technique of gradient-based class activation mapping to provide explainability by visualizing model decisions.

artificial intelligence↗

Removable coatings: Thermal stability and decontamination of steel surfaces from 241 Am

This study presents a comparative analysis of several strippable materials for decontamination of steel surfaces from 241 Am. The strippable coatings were chosen to have a history of application, to be commercially available, easily handled and have different composition and formulation. Carbon steel and stainless steel surfaces (coupons) were utilized as the most representative industrial materials, and the experimental series were expanded to include the rusting treatment of these surfaces as it is common for decommissioned old nuclear facilities. The experiments followed the path of pre-screening of the strippable materials (easiness of application, peeling etc.), their characterization with Fourier-transform infrared (FTIR) spectroscopy and thermogravimetric analysis (TGA), decontamination factors (DF) or removal efficiencies for different types of steel surfaces, and enhancement of the removal efficiencies of the select strippable coatings via amendment with EDTA. As a result, DF and removal efficiencies for stainless steel (both pristine and with rusting treatment) are higher than for pristine carbon steel, and decontamination factors and removal efficiencies are higher for pristine than for rusted carbon steel across all the coatings. It is also shown that EDTA amendment can improve DF and removal efficiency for a strippable coating (i.e., CC Strip), however other factors should also be considered. Thus, the coating CC Strip exhibited easiness in handling and high DF (up to 97% when EDTA-amended), but its drying period was the longest among the rest of the materials and its thermal decomposition indicates on a risk of intense release of heat in case of a fire event.

36 MATERIALS SCIENCE↗

Utilizing multimodal high-intensity interval training for a firefighter training academy during the COVID-19 pandemic

Firefighters typically undergo a 16–24-week training academy during which they perform a variety of traditional exercise programs such as cardiovascular, resistance, and concurrent training. Because of limited facility access, some fire departments seek alternative exercise programs, such as multimodal high-intensity interval training (MM-HIIT), which essentially combines resistance and interval training. Here, the primary purpose of this study was to assess the effect of MM-HIIT on body composition and physical fitness in firefighter recruits who completed a training academy during the coronavirus (COVID-19) pandemic. A secondary purpose was to compare the effects of MM-HIIT to previous training academies that implemented traditional exercise programs. Healthy and recreationally-trained recruits (n=12) participated in 2-3 days/week of MM-HIIT for 12 weeks and had several components of body composition and physical fitness measured before and after the program. Because of COVID-19-related gym closures, all MM-HIIT sessions were performed outdoors at a fire station with minimal equipment. These data were retroactively compared to a control group (CG) that previously completed training academies with traditional exercise programs. Subjects in the MM-HIIT group significantly improved several components of body composition and fitness, including fat mass, fat-free mass, body fat percentage, aerobic capacity, and muscular endurance (p < 0.005). Moreover, there were no significant differences for any dependent variable when MM-HIIT was compared to the CG (p≥0.005). These results suggest that MM-HIIT may serve as an effective substitute for traditional concurrent training paradigms that are typically used for firefighter academies.

60 APPLIED LIFE SCIENCES↗

The hazard components of representative key risks. The physical climate perspective

The framework of Representative Key Risks (RKRs) has been adopted by the Intergovernmental Panel on Climate Change Working Group II in order to categorize, assess and communicate a wide range of regional and sectoral key risks, expected to become severe as a consequence of the potentially detrimental convergence of changing climate conditions, exposure and vulnerability of human and natural systems, and responses through (mal)adaptation measures. Other papers in this special issue treat each of eight RKRs by holistically assessing their current status and future evolution as a result of this convergence. However, their treatment cannot always organize such assessment according to a systematic gradation of climatic changes, often times having to extrapolate the big-picture evolution of risk from either qualitative effects of “low” medium” and “high” warming, or limited/focused analysis of the consequences of particular mitigation choices (e.g., benefits of limiting warming to 1.5 or 2C). In this study we offer as systematic a representation as possible – given current literature and assessments – of the future evolution of the hazard components of RKRs. We draw on the assessment of changes in climatic impact-drivers relevant to RKRs described in the 6th Assessment Report by Working Group 1 (WGI) supplemented when needed by more recent literature. We identify the relevant hazards for each RKR, based upon the WGII authors’ assessment, and we report on their current state and expected future changes in magnitude, intensity and/or frequency, linking these changes to Global Warming Levels to the extent possible. For some of these quantities - like regional trends in oceanic and atmospheric temperature and precipitation, some heat and precipitation extremes, permafrost thaw and Northern Hemisphere snow cover - a strong and quantitative relationship with global average temperature change has been assessed. For others - like frequency and intensity of tropical cyclones and extra-tropical storms, and fire weather - the link to increasing global temperatures can only be described qualitatively. For some processes - like the behavior of ice-sheets, or changes in circulation dynamics - large uncertainties about the effects of different levels of warming remain, and for a few others - like ocean pH and air pollution - the composition of the scenario of anthropogenic emissions is most relevant, rather than the warming reached. In almost all cases, however, the basic message remains that every small increment in CO2 concentration in the atmosphere and associated warming will bring changes in climate phenomena that will contribute to increasing risk of impacts on human and natural systems when these changes happen in conjunction with these systems’ conditions of exposure and vulnerability, and in lack of effective adaptation. Our picture of the evolution of RKR-relevant climatic impact-drivers complements and enriches the treatment of RKRs in the other papers in at least two ways: by filling in an often only cursory or limited representation of the physical climate aspects driving impacts, and by providing a fuller representation of their future possible evolution which represents an important component – if never the only one – of the potential future evolution of risk severity.

54 ENVIRONMENTAL SCIENCES↗

Estimating the influence of field inventory sampling intensity on forest landscape model performance for determining high-severity wildfire risk

Abstract Historically, fire has been essential in Southwestern US forests. However, a century of fire-exclusion and changing climate created forests which are more susceptible to uncharacteristically severe wildfires. Forest managers use a combination of thinning and prescribed burning to reduce forest density to help mitigate the risk of high-severity fires. These treatments are laborious and expensive, therefore optimizing their impact is crucial. Landscape simulation models can be useful in identifying high risk areas and assessing treatment effects, but uncertainties in these models can limit their utility in decision making. In this study we examined underlying uncertainties in the initial vegetation layer by leveraging a previous study from the Santa Fe fireshed and using new inventory plots from 111 stands to interpolate the initial forest conditions. We found that more inventory plots resulted in a different geographic distribution and wider range of the modelled biomass. This changed the location of areas with high probability of high-severity fires, shifting the optimal location for management. The increased range of biomass variability from using a larger number of plots to interpolate the initial vegetation layer also influenced ecosystem carbon dynamics, resulting in simulated forest conditions that had higher rates of carbon uptake. We conclude that the initial forest layer significantly affects fire and carbon dynamics and is dependent on both number of plots, and sufficient representation of the range of forest types and biomass density.

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