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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Gravitational Influences on Flame Propagation through Non-Uniform, Premixed Gas Systems

Flame propagation through non-uniformly premixed (or layered) gases has importance both in useful combustion systems and in unintentional fires. As summarized previously, non-uniform premixed gas combustion receives scant attention compared to the more usual limiting cases of diffusion or uniformly premixed flames, especially regarding the role gravity plays. This paper summarizes our progress on furthering the knowledge of layered combustion, in which a fuel concentration gradient exists normal to the direction of flame spread. We present experimental and numerical results for flame spread through propanol-air layers formed near the flash point temperature (25 C) or near the stoichiometric temperature (33 C). Both the model and experimental results show that the removal of gravity results in a faster spreading flame, by as much as 80% depending on conditions. This is exactly the opposite effect as that predicted by an earlier model reported. We also found that having a gallery lid results in faster flame spread, an effect more pronounced at normal gravity, demonstrating the importance of enclosure geometry. Also reported here is the beginning of our spectroscopic measurements of fuel vapor.

Miller, Fletcher J.↗
DOE OSTI2020

Conversion, Stability, and Selectivity Improvements Through Catalyst Development for the Reductive Etherification Reaction

Economical pathways from lignocellulosic non-food biomass feedstocks to biofuels with appropriate fuel properties are necessary for displacing fossil-fuel derived diesel use in medium-/heavy duty vehicles. Oxygenated compounds have recently shown promise due to low sooting tendencies and autoignition properties and molecules with sufficiently high carbon numbers can meet the requisite standards for water solubility and flash point. Coupling waste biomass derived small molecules into bioblendstock targets through the reductive etherification reaction shows potential for increasing molecular weight without losing the advantages of oxygenates. However, the transition to industrial viability for this process is limited by strong catalyst deactivation in typical flow reactor systems. Strong acid resins such as Amberlyst-15 (A-15) show excellent activity in batch reactions but are limited to low temperatures and are poisoned by the side-product, water. In this talk, I will describe our recent work in catalyst synthesis and testing to select superior options with improved aqueous and thermal stability in reductive etherification flow reactions. Water-tolerant solid acid catalysts have potential to improve the conversion and selectivity to the ether target at temperatures above the degradation point of A-15. Analysis techniques such as physisorption, chemisorption, x-ray diffraction and transmission electron microscopy are being used to characterize the active sites. These techniques are also being used to evaluate degradation of the catalyst after extensive flow reactions in addition to comparative efficiency testing with standardized cyclohexene hydrogenation reactions. Finally, I will discuss a demonstration of the full pathway from bio-derived butyric acid to the performance-advantaged ether product and the additional obstacles from side-products and purification limitations in the preliminary upgrading reactions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

Sustainable Aviation Fuel via Hydroprocessing of Catalytic Fast Pyrolysis Oil

Cycloalkanes have been identified as a promising alternative for sustainable aviation fuel (SAF) in a recent US Department of Energy Review of Technical Pathways to SAF. Cycloalkanes can provide desirable SAF properties, including energy density, and, in addition, they may be able to provide necessary seal swelling and leakage protection and replace undesirable aromatics in aviation fuel. Catalytic fast pyrolysis (CFP) followed by hydroprocessing constitutes a platform well suited for converting biomass to cycloalkanes. CFP oils are rich in phenolic compounds and, depending on CFP catalyst, in aromatic hydrocarbons, which can both be hydrogenated to form cycloalkanes. In this work, we report results from hydroprocessing of two types of CFP oil to produce fractions boiling in the sustainable aviation fuel range and meeting tested aviation fuel specifications. CFP oils prepared over a zeolite catalyst (ZSM-5) and a hydrodeoxygenation catalyst (Pt/TiO2) were hydroprocessed over a sulfided NiMo/Al2O3 catalyst in a two-stage process (1st stage ~250 degrees C and 2nd stage 385 degrees C) in a continuous trickle-bed hydrotreater. The hydrotreated product contained 39-40% material boiling in the SAF range by distillation with a carbon efficiency of 36-37% from CFP oil to SAF fraction. The SAF fractions consisted of 82-87% of cycloalkanes, had non-detectable oxygen contents and lower heating values (LHV) above the jet fuel minimum limit of 42.8 MJ/kg. The SAF-range product also had acceptable volatility and freeze and flash points per aviation fuel specifications. The results suggest a promising pathway for SAF production via the catalytic fast pyrolysis pathway. Methods to enhance the yield of SAF will be discussed.

BASIC BIOLOGICAL SCIENCES,BIOMASS FUELS↗
DOE OSTI2020

A Section 110 Evaluation of Three Sites Associated with the Grable Test, Area 5, Nevada National Security Site, Nye County, Nevada

This report presents the results of a Section 110 recordation of the 280mm Atomic Gun emplacement and command post (CP) (26NY16244), an associated Flash Observation Point that was used to refine the gun’s firing range (26NY16243), and troop trenches used for Exercise Desert Rock V (26NY16242). All three of these resources are directly associated with the Grable test, a specific test in the Upshot-Knothole series of aboveground nuclear detonations. The Grable test occurred at 8:30 a.m. on May 25, 1953, in Area 5 of the Nevada National Security Site (NNSS). Desert Research Institute (DRI) recommends 26NY16244 and 26NY16242 eligible for listing in the National Register of Historic Places (NRHP) under a combination of the Secretary of the Interior’s Significance Criteria A and D at the national level of significance and related to the era of Nuclear Testing and the Cold War. All three of these resources are recommended as contributing elements to the Frenchman Flat Historic District (SHPO Resource No. D204).

280mm Atomic Gun↗
NASA NTRS1992

Observations of optical counterparts of Gamma-Ray bursts

This is a final report for a contract begun in Dec. 1987 and ended in Mar. 1989 to use the existing Lincoln Laboratory Experimental Test Site in Socorro, NM to search for optical counterparts to gamma-ray bursts. The objective was to develop an autonomous staring system to search for stationary, transient optical flashes. The search was to use an existing 31-inch telescope equipped with a sensitive video detector. The approach for the search was to develop real-time processing software to monitor the video signal from the detector and to record any transient, point-like flashes that occurred in the field of view. The system would have been able to detect fainter flashes (B is approximately 15(sup m) in 1/30 s, delta(m(sub v)) = 0.25(sup m)) than other systems but lacked a large field of view (only 1.2 deg diameter) necessary to give a high probability of detecting a random flash on the sky. As such, the plan was to monitor known gamma-ray burst error boxes and wait for a repetition of an earlier event. The high payoff of good sensitivity with high angular resolution (1 pixel = 10sec) and good time resolution (30 s) to allow post-burst searches warranted funding if the cost was not prohibitive. The contract began in the middle of the three-year cycle for High Energy Astrophysics Gamma-Ray Astronomy Research and Analysis Program. This final report briefly describes the portion of the plan completed under the original contract.

Knight, Frederick K.↗
DOE OSTI2024

Effects of processing conditions on flash sintering of commercial ZrN

Flash sintering (FS) is a potentially rapid and low-cost manufacturing technique for advanced ceramics. There are still many unknowns about ceramic FS, especially for highly conductive high-temperature ceramics (HTC), which often display decreased bulk conductivity with increasing temperature. This study qualitatively characterizes the flash behavior of highly conductive HTC materials using zirconium nitride (ZrN) as an example. The effects of processing parameters (e.g., DC voltage/electrical field strength, voltage ramp rate, post-flash holding time, mechanical pressure, sample milling, and choice of electrode materials) on ZrN flash behavior are also qualitatively studied and linked to samples microstructure and hardness. It is observed that best densification was achieved using 5 min Spex-milled ZrN powder under 25 MPa of applied pressure and constant 8 V DC. The potential mechanism for ZrN FS and the similarity and difference from FS of conventional oxides like YSZ have been proposed based on experimental observations, and the directions for future research are also pointed out.

Flash Sintering↗
DOE OSTI2021

Design of Novel Flash Ironmaking Reactors for Greatly Reduced Energy Consumption and CO2 Emissions

The development of a novel ironmaking technology based on fine iron ore concentrate in a flash reactor is summarized. The design of potential industrial reactors for flash ironmaking based on the computational fluid dynamics technique is described. Overall, this simulation work has shown that the size of the reactor used in the novel flash ironmaking technology (FIT) can be quite reasonable vis-à-vis the blast furnaces. A flash reactor of 12 m diameter and 35 m height with a single burner operating at atmospheric pressure would produce 1.0 million tons of iron per year. The height can be further reduced by either using multiple burners, preheating the feed gas, or both. The computational fluid dynamics (CFD)-based design of potential industrial reactors for flash ironmaking pointed to a number of features that should be incorporated. The flow field should be designed in such a way that a larger portion of the reactor is used for the reduction reaction but at the same time excessive collision of particles with the wall must be avoided. Further, a large diameter-to-height ratio that still allows a high reduction degree should be used from the viewpoint of decreased heat loss. This may require the incorporation of multiple burners and solid feeding ports.

36 MATERIALS SCIENCE↗
NASA NTRS1982

Flare buildup in X-rays, UV, microwaves and white light

Coordinated observations using space and ground-based instruments were made of active region complex numbers 2522/2530, 24-30 June, 1980. The 10 largest flares from these regions were of importance M1-M6 in X-rays, and all were observed from satellites, except for one observed from a balloon. Several kinds of buildup signature have been found in the tens of minutes before these flares. Among these signatures are the following: (1) relative faintness in X-ray lines of the pre-flare pixels, (2) X-ray (5-15 keV) 'flashes' at points displaced by 1-2 arcmin from the flare site, (3) rising filaments seen in H-alpha and ultraviolet, (4) microwave intensification, polarization increase, and polarization flip, and (5) coronal disturbances above limb flares at or before the impulsive phase.

Schmahl, E. J.↗
NASA NTRS1991

New constraints on neutron star models of gamma-ray bursts. II - X-ray observations of three gamma-ray burst error boxes

Exosat observations are presented for 3 gamma-ray-burst error boxes, one of which may be associated with an optical flash. No point sources were detected at the 3-sigma level. A comparison with Einstein data (Pizzichini et al., 1986) is made for the March 5b, 1979 source. The data are interpreted in the framework of neutron star models and derive upper limits for the neutron star surface temperatures, accretion rates, and surface densities of an accretion disk. Apart from the March 5b, 1979 source, consistency is found with each model.

Boer, M.↗
NASA NTRS1991

Weak positive cloud-to-ground flashes in Northeastern Colorado

The frequency distributions of the peak magnetic field associated with the first detected return stroke of positive and negative cloud-to-ground (CG) flashes were studied using lightning data from northeastern Colorado. These data were obtained during 1985 with a medium-to-high gain network of three direction finders (DF's). The median signal strength of positive flashes was almost two times that of the negatives for flashes within 300 km of the DF's, which have an inherent detection-threshold bias that tends to discriminate against weak signals. This bias increases with range, and affects the detection of positive and negative flashes in different ways, because of the differing character of their distributions. Positive flashes appear to have a large percentage of signals clustered around very weak values that are lost to the medium-to-high gain Colorado Detection System very quickly with increasing range. The resulting median for positive signals could thus appear to be much larger than the median for negative signals, which are more clustered around intermediate values. When only flashes very close to the DF's are considered, however, the two distributions have almost identical medians. The large percentage of weak positive signals detected close to the DF's has not been explored previously. They have been suggested to come from intracloud discharges and thus are improperly classified as CG flashes. Evidence in hand, points to their being real positive, albeit weak CG flashes. Whether or not they are real positive ground flashes, it is important to be aware of their presence in data from magnetic DF networks.

Lopez, Raul E.↗
NASA NTRS1984

Lightning attachment patterns and flight conditions experienced by the NASA F-106B airplane from 1980 to 1983

The direct lightning strike data and associated flight conditions recorded from 1980 to 1983 during 742 thunderstorm penetrations with a NASA F-106B in Oklahoma and Virginia are studied with an emphasis on aircraft protection design. The individual lightning attachment spots were plotted on isometric projections of the aircraft to identify lightning entry and exit points and swept flash patterns. The altitudes, ambient temperatures, turbulence, and precipitation at which the strikes occurred are summarized and discussed. It was noted that peak strike rates (0.81 strikes/min and 3 strikes/penetration) occurred at altitudes between 11 km and 11.6 km corresponding to ambient temperatures between -40 C and -45 C. The data confirmed that initial entry and exit points most frequently occur at aircraft extremities, in this case the nose boom, the wing tips, the vertical fin cap, and the afterburner. The swept-flash attachment paths and burn marks found in this program indicate that the mid-span areas of swept aircraft may be more susceptible to lightning than previously thought. It was also found that lightning strikes may attach to spots within the engine tail pipe.

Fisher, B. D.↗
NASA NTRS1973

A survey of compatibility of materials with high pressure oxygen service.

The literature on high pressure oxygen compatibility has been surveyed in order to present the existing state of knowledge. Searches have been conducted of NASA and NBS data retrieval systems. In addition, many individuals, active in the field, were contacted in order to retrieve useful unpublished information. Compatibility data, such as mechanical impact, pneumatic impact, ignition temperature, and flash-and-fire point, were compiled for pressures above 200 bar. Lower pressure data were included if they were useful for extrapolation to pressures above 200 bar. These data, too numerous to be given here, are available from the authors. Brief descriptions of the trends of these data are given. Recommendations for additional high pressure studies are included.

Hust, J. G.↗
DOE OSTI2022

Combined Optical and Radio–Frequency Perspectives on the Time Evolution of Lightning Measured by the FORTE Satellite

We use a cluster feature data set for the Fast On-orbit Recording of Transient Events (FORTE) satellite that combines detections from its pixelated Lightning Locating System (LLS), photodiode detector (PDD) and Radio-Frequency (RF) instrumentation to generate statistics describing the frequency and timing of lightning events detected by each instrument during lightning flashes. Coincident observations from the same vantage point allow us to directly compare flash details that can be resolved by the wide Field of View (FOV) instruments relative to the pixelated LLS—whose design is based on NASA's Lightning Imaging Sensor. We find that both the PDD and RF system typically generate more detections than the lightning imager (mean: 1.5 PDD events per LLS group, 2 RF events per LLS group) from pulses that are either not sufficiently bright in the optical band (in the case of RF) or that lack the optical energy density (in the case of the PDD) required to trigger one of the pixels on the LLS imaging array. This includes additional activity before the first LLS group or after the final LLS group. These FORTE results demonstrate that certain lightning processes would be better resolved by wide-FOV optical and RF instruments than lightning imagers. Current/future space-based missions that use/plan to use similar instruments will improve our understanding of flash evolution by resolving details missed by lightning imagers.

47 OTHER INSTRUMENTATION↗
NASA NTRS1975

Conspicuity of target lights: The influence of flash rate and brightness

The stimulus characteristics of lights that might aid a pilot to see and avoid, by alerting him to a potential threat were studied. The relative conspicuity of foveally equated, point-source, steady and flashing lights of several brightnesses, seen against a star background was examined. From the subject's viewpoint, these target lights could appear anywhere within a large (40 deg horizontal by 35 deg vertical) field of view. The lights appeared at random time intervals while the subject was periodically distracted by a simulated cockpit task. The results indicate that correct target detection increases and reaction time decreases with increased target intensity. Steady lights are missed more frequently and acquired more slowly than flashing lights, but no significant differences are found among the wide range of flash rates employed. The intensity of the light has a greater effect on both detection and reaction time to steady lights than to flashing lights. These results are compared with results of other researchers who used targets which appeared at fixed locations. The longest reaction times were recorded to lights which appeared either at the extremes or at the very center of the visual field.

Connors, M. M.↗
NASA NTRS2008

A Comparison of Lightning Flashes as Observed by the Lightning Imaging Sensor and the North Alabama Lightning Mapping Array

The Lightning Imaging Sensor (LIS) aboard the TRMM satellite has been collecting optical lightning data since November 1997. A Lightning Mapping Array (LMA) that senses VHF impulses from lightning was installed in North Alabama in the Fall of 2001. A dataset has been compiled to compare data from both instruments for all times when the LIS was passing over the domain of our LMA. We have algorithms for both instruments to group pixels or point sources into lightning flashes. This study presents the comparison statistics of the flash data output (flash duration, size, and amplitude) from both algorithms. We will present the results of this comparison study and show "point-level" data to explain the differences. AS we head closer to realizing a Global Lightning Mapper (GLM) on GOES-R, better understanding and ground truth of each of these instruments and their respective flash algorithms is needed.

Bateman, M. G.↗
NASA NTRS1985

Locating rocket triggered lightning using the LLP lightning locating system at the NASA Kennedy Space Center

Five rocket-triggered cloud-to-ground lightning flashes were detected by the operational lightning-locating system at the NASA Kennedy Space Center on August 17, 1984. The locating system, which was designed to detect natural lightning, detected at least 2 and as many as 6 strokes in the triggered flashes, suggesting that some of the strokes in the triggered lightning had signal-amplitude and waveshape characteristics similar to natural lightning. However, not all triggered strokes were detected, indicating that some strokes were atypical in nature. Since the ground-strike points of the triggered flashes were known quite precisely, the accuracy of the lightning-locating system was also evaluated. The three direction finders were found to have a mean bearing accuracy of + or - 0.5-0.6 deg. The distance errors of the real-time position solutions of the locating system on the triggered flashes were in the range of 195-770 m, with a mean of 480 m.

Maier, M. W.↗
NASA NTRS2011

Tests of the Grobner Basis Solution for Lightning Ground Flash Fraction Retrieval

Satellite lightning imagers such as the NASA Tropical Rainfall Measuring Mission Lightning Imaging Sensor (TRMM/LIS) and the future GOES-R Geostationary Lightning Mapper (GLM) are designed to detect total lightning (ground flashes + cloud flashes). However, there is a desire to discriminate ground flashes from cloud flashes from the vantage point of space since this would enhance the overall information content of the satellite lightning data and likely improve its operational and scientific applications (e.g., in severe weather warning, lightning nitrogen oxides studies, and global electric circuit analyses). A Bayesian inversion method was previously introduced for retrieving the fraction of ground flashes in a set of flashes observed from a satellite lightning imager. The method employed a constrained mixed exponential distribution model to describe the lightning optical measurements. To obtain the optimum model parameters (one of which is the ground flash fraction), a scalar function was minimized by a numerical method. In order to improve this optimization, a Grobner basis solution was introduced to obtain analytic representations of the model parameters that serve as a refined initialization scheme to the numerical optimization. In this study, we test the efficacy of the Grobner basis initialization using actual lightning imager measurements and ground flash truth derived from the national lightning network.

Koshak, William↗