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At least 55 records · Page 3

Numerical modeling of physical vapor transport in a vertical cylindrical ampoule, with and without gravity

Numerical modeling has been performed of the fluid dynamics in a prototypical physical vapor transport crystal growing situation. Cases with and without gravity have been computed. Dependence of the flows upon the dimensionless parameters aspect ratio and Peclet, Rayleigh, and Schmidt numbers is demonstrated to a greater extent than in previous works. Most notably, it is shown that the effects of thermally-induced buoyant convection upon the mass flux on the growth interface crucially depend upon the temperature boundary conditions on the sidewall (e.g., whether adiabatic or of a fixed profile, and in the latter case the results depend upon the shape of the profile assumed).

Miller, T. L.↗

Oxygen stabilization induced enhancement in J(sub c) and T(sub c) of superconducting oxides

In an attempt to enhance the electrical and mechanical properties of the high temperature superconducting oxides, high T(sub c) composites were prepared composed of the 123 compounds and AgO. The presence of extra oxygen due to the decomposition of AgO at high temperature is found to stabilize the superconducting 123 phase. Ag is found to serve as clean flux for grain growth and precipitates as pinning center. Consequently, almost two orders of magnitude enhancement in critical current densities were also observed in these composites. In addition, these composites also show much improvement in workability and shape formation. On the other hand, proper oxygen treatment of Y5Ba6Cu11Oy was found to possibly stabilize superconducting phase with T(sub c) near 250 K. I-V, ac susceptibility, and electrical resistivity measurements indicate the existence of this ultra high T(sub c) phase in this compound. Detailed structure, microstructure, electrical, magnetic and thermal studies of the superconducting composites and the ultra high T(sub c) compound are presented and discussed.

Wu, M. K.↗

The interaction of impulsive solar wind discontinuities with the magnetosphere - A multi-satellite case study

Data collected on September 4-5, 1984 by the outbound AMPTE/IRM spacecraft which stayed just outside the expanding earth's bow shock for 7.5h are examined. The data are gathered during an unusual period for which the solar wind pressure and magnetic field are relatively constant except for two discontinuities with associated approximately equal to 1 min duration pressure pulses. The observations indicate that the bow shock reacts rapidly to solar wind dynamic pressure variations; that both discontinuity/pressure pulse events were followed more or less immediately by a decrease in the geosynchronous particle fluxes, indicating the growth phase of a substorm and possibly also the shadowing of energetic ions by the compressed magnetopause followed after 10-30 min by a sudden enhancement in the energetic particles which began on the nightside and drifted to the dayside; and sudden impulse ground signatures are observed which seem to depend critically on the IMF orientation as well as on the longitude and latitude of the particular ground stations.

Labelle, J.↗

Oxygen stabilization induced enhancement in superconducting characteristics of high-Tc oxides

In an attempt to enhance the electrical and mechanical properties of the high temperature superconducting oxides, high T(sub c) composites were prepared composed of the 123 compounds and AgO. The presence of extra oxygen due to the decomposition of AgO at high temperature is found to stabilize the superconducting 123 phase. Ag is found to serve as clean flux for grain growth and precipitates as pinning center. Consequently, almost two orders of magnitude enhancement in critical current densities were also observed in these composites. In addition, these composites also show much improvement in workability and shape formation. On the other hand, proper oxygen treatment of Y5Ba6Cu11Oy was found to possibly stabilize superconducting phase with T(sub c) near 250 K. I-V, ac susceptibility, and electrical resistivity measurements indicate the existence of this ultra high T(sub c) phase in this compound. Detailed structure, microstructure, electrical, magnetic and thermal studies of the superconducting composites and the ultra high T(sub c) compound are presented and discussed.

Wu, M. K.↗

Sol-gel synthesis and densification of aluminoborosilicate powders. Part 2: Densification

Aluminoborosilicate (ABS) powders, high in alumina content, were synthesized by the sol-gel process utilizing four different methods of synthesis. The effect of these methods on the densification behavior of ABS powder compacts was studied. Five regions of shrinkage in the temperature range 25-1184 C were identified. In these regions, the greatest shrinkage occurred between the gel-to-glass transition temperature (T sub g approximately equal to 835 C) and the crystallization transformation temperature (T sub t approximately equal 900 C). The dominant mechanism of densification in this range was found to be viscous sintering. ABS powders were amorphous to x-rays up to T sub t at which a multiphasic structure crystallized. No 2Al2O3.B2O3 was found in these powders as predicted in the phase diagram. Above T sub t, densification was the result of competing mechanisms including grain growth and boria fluxed viscous sintering. Apparent activation energies for densification in each region varied according to the method of synthesis.

Bull, Jeffrey↗

A New Sea Ice Model: Pancakes to Metrics

We are developing, testing, and validating a new sea ice dynamics model that treats the ice cover as an elastic/decohesive material in the permanent pack and includes the correct frazil/pancake behavior in the marginal zone. Two salient features of present ice dynamics models are that they do not: 1) reproduce the oriented fracture patterns of openings and closings in the pack ice, and 2) accurately model the effects of frazil/pancake ice formation in the ice margin. These poorly modeled areas account for a substantial portion of the ice growth, turbulent heat flux to the atmosphere, salt flux to the ocean, and energy dissipation due to slippage, ridging, and rafting, in the Arctic. Existing sea ice models have shown limited success in predicting the degree to which a lead will open for prescribed or observed forcing conditions. An important aspect of the new model we are developing is that the existence of cracks, along with their orientation, opening, and closing, is predicted. To put this effort in perspective a short history of ice dynamics modeling and data collection is presented. The RGPS data set is used to validate the model. As part of the testing and validation of the model, we are working on a new metric for comparing linear features (leads and ridges) in the data and model to be used in data assimilation for this model. The model framework is presented as well as some results showing the creation and development of leads in a simulation of ice dynamics in the Beaufort Sea. Other presentations by the authors will show other results from this effort.

Coon, M.↗

Estimation of Sea Ice Thickness Distributions through the Combination of Snow Depth and Satellite Laser Altimetry Data

Combinations of sea ice freeboard and snow depth measurements from satellite data have the potential to provide a means to derive global sea ice thickness values. However, large differences in spatial coverage and resolution between the measurements lead to uncertainties when combining the data. High resolution airborne laser altimeter retrievals of snow-ice freeboard and passive microwave retrievals of snow depth taken in March 2006 provide insight into the spatial variability of these quantities as well as optimal methods for combining high resolution satellite altimeter measurements with low resolution snow depth data. The aircraft measurements show a relationship between freeboard and snow depth for thin ice allowing the development of a method for estimating sea ice thickness from satellite laser altimetry data at their full spatial resolution. This method is used to estimate snow and ice thicknesses for the Arctic basin through the combination of freeboard data from ICESat, snow depth data over first-year ice from AMSR-E, and snow depth over multiyear ice from climatological data. Due to the non-linear dependence of heat flux on ice thickness, the impact on heat flux calculations when maintaining the full resolution of the ICESat data for ice thickness estimates is explored for typical winter conditions. Calculations of the basin-wide mean heat flux and ice growth rate using snow and ice thickness values at the 70 m spatial resolution of ICESat are found to be approximately one-third higher than those calculated from 25 km mean ice thickness values.

Kurtz, Nathan T.↗

Transition from Ignition to Flame Growth under External Radiation in Three Dimensions (TIGER-3D)

This study focuses on localized ignition by external radiant flux and subsequent flame growth over thin polymeric materials (plastic and paper) in microgravity. Two transition stages were observed. The first transition stage covers the period from the onset of ignition to the formation of stabilized flame near the ignited area. This is followed by the second transition of the flame growth stage from the initial stabilized flame to sustained fire growth away from the ignited area. For the first stage, ignition experiments of thin PMMA sheets were conducted using a CO2 laser as an external source in the 10 s drop tower. The results of front side surface ignition and of backside surface ignition were observed. The effects of imposed flow velocity, sample thickness, and ambient oxygen concentration on ignition are obtained. Numerical study was conducted to investigate to understand and predict ignition behavior observed in the experiments. For the second stage, numerical study is being conducted to describe the effects of gravity on heat release rate of a PMMA sheet. The gravity level was varied from zero to normal gravity. The preliminary results show that the maximum heat release occurs at around 0.02 g.

Kashiwagi, Takashi↗

The evolution of a coronal streamer and the photospheric magnetic field

A large equatorial coronal streamer observed in the outer corona grew in brightness and size during successive limb passages between October 6, 1973 and January 10, 1974 (solar rotations 1606-1611). Unlike previous studies of streamers and their photospheric associations, no definite surface feature could be identified in the present case. This suggests that the streamer is associated with the large scale photospheric magnetic field. Comparison of the streamer growth with observed underlying photospheric magnetic flux changes indicated that as the streamer increased in brightness, areal extent, and density, the photospheric magnetic flux decreased. Three possible explanations for the streamer's growth are presented, the conceptually simplest being that the decrease in photospheric field results in an opening of the flux tubes under the streamer, which permits an increase mass flux through the streamer.

Poland, A. I.↗

Accurate Assessment of Land-Atmosphere Coupling in Climate Models Requires High Frequency Data Output

Land-atmosphere (L-A) interactions are important for understanding convective processes, climate feedbacks, the development and perpetuation of droughts, heatwaves, pluvials, and other land-centred climate anomalies. Local L-A coupling (LoCo) metrics capture relevant L-A processes, highlighting the impact of soil and vegetation states on surface flux partitioning, and the impact of surface fluxes on boundary layer (BL) growth, development, and entrainment of air above the BL. A primary goal of the Climate Process Team on Coupling Land and Atmospheric Subgrid Parameterizations (CLASP) is parameterizing and characterizing the impact of subgrid heterogeneity in global and regional earth system models (ESMs) to improve the connection between land and atmospheric states and processes. A critical step in achieving that aim is the incorporation of L-A metrics, especially LoCo metrics, into climate model diagnostic process streams. However, because land-atmosphere interactions span time scales of minutes (e.g., turbulent fluxes), hours (e.g., BL growth and decay), days (e.g., soil moisture memory), and seasons (e.g., variability of behavioural regimes between soil moisture and latent heat flux), with multiple processes of interest happening in different geographic regions at different times of year, there is not a single metric that captures all the modes, means, and methods of interaction between the land and the atmosphere. And while monthly means of most of the LoCo-relevant variables are routinely saved from ESM simulations, data storage constraints typically preclude routine archival of the hourly data that would enable the calculation of all LoCo metrics. Here we outline a reasonable data request that would allow for adequate characterization of sub-daily coupling processes between the land and the atmosphere, preserving enough sub-daily output to describe, analyse, and better understand L-A coupling in modern climate models. A secondary request involves embedding calculations within the models to determine mean properties in and above the BL to further improve characterization of model behaviour. Higher-frequency model output will (i) allow for more direct comparison with observational field campaigns on process-relevant time scales, (ii) enable demonstration of inter-model spread in L-A coupling processes, and (iii) aid in targeted identification of sources of deficiencies and opportunities for improvement of the models.

Kirsten L. Findell↗

Bias-Correcting Carbon Fluxes Derived From Land-Surface Satellite Data for Retrospective and Near Real-Time Assimilation Systems

The ability to monitor and understand natural and anthropogenic variability in atmospheric carbon dioxide(CO2) is a growing need of many stakeholders across the world. Systems that assimilate satellite observations, given their short latency and dense spatial coverage, into high resolution global models are valuable, if not essential, tools for addressing this need. A notable drawback of modern assimilation systems is the long latency of many vital in-put datasets, e.g., inventories, in situ measurements, and re-processed remote-sensing data can trail the current date by months to years. This paper describes techniques for bias-correcting surface fluxes derived from satellite observations of the Earth’s surface to be consistent with constraints from inventories and in situ CO2 datasets. The techniques are applicable in both short-term forecasts and retrospective simulations, thus taking advantage of the coverage and short latency of satellite data while reproducing the major features of long-term inventory and in situ records. Our approach begins with a standard collection of diagnostic fluxes which incorporate a variety of remote-sensing driver data, viz. vegetation indices, fire radiative power, and nighttime lights. We then apply an empirical sink so that global budgets of the diagnostic fluxes match given atmospheric and oceanic growth rates for each year. This step removes coherent, systematic flux errors that produce biases inCO2which mask the signals an assimilation system hopes to capture. Depending on the simulation mode, the empirical sink uses different choices of atmospheric growth rates: estimates based on observations in retrospective mode and projections based on seasonal fore-casts of sea surface temperature in forecasting mode. The retrospective fluxes, when used in simulations with NASA’s Goddard Earth Observing System (GEOS), reproduce marine boundary layer measurements with comparable skill to those using fluxes from a modern inversion system. The forecasted fluxes show promising accuracy in their application to the analysis of changes in the carbon cycle as they occur.

CO2↗

VLF wave growth from dispersive bursts of field-aligned electron fluxes

Large-amplitude electrostatic whistler waves near the lower hybrid frequency were observed by an auroral sounding rocket during substorm breakup. The measured wavelengths indicate that the emissions were electrostatic and resonant with electrons that had parallel energies of a few hundred electron volts. We propose that the intense emissions drew their energy from dispersive bursts of low-energy, field-aligned electron fluxes. The dispersive bursts are known to cause a brief, but intense instability that results in large-amplitude Langmuir emissions. The high-frequency emissions can rapidly form a plateau in the one-dimensional electron distribution. We show, however, that these distributions remain unstable to electrostatic whistler waves near the lower hybrid frequency. The amplitude and wavelength of the observed emissions were sufficient to accelerate the hydrogen ions with energies between about 50 eV and about 200 eV.

Ergun, R. E.↗

Temporal evolution of whistler growth in a cold plasma injection experiment

The evolution of whistler mode turbulence and particle participation in a cold plasma release are studied experimentally as part of the Active Magnetospheric Particle Tracers Explorer (AMPTE) program. The investigation used a simple time dependent cold plasma density model, and an atypical ambient radiation belt was assumed. It is shown that a cold lithium injection in the AMPTE parameter range can give rise to whistler mode turbulence with significant gain to the wave amplitude in a single pass through a flux tube. Whistler mode growth results in the pitch angle diffusion of energetic electrons, which are in turn precipitated. The rate of power input into the ionosphere from these precipitating electrons is roughly estimated at 2 ergs per sq cm/s. It is found that this value of the precipitated power is large enough to continue producing a visible aurora until the injected plasma in the flux tube is lost or destroyed by magnetospheric convection or other processes.

Ganguli, G.↗

Effect of irradiance, sucrose, and CO2 concentration on the growth of potato (Solanum tuberosum L.) in vitro

Growth measurements were taken of potato plantlets (Solanum tuberosum L.) cvs. Norland (NL), Denali (DN), and Kennebec (KN), grown in vitro. Studies were conducted in a growth chamber, with nodal explants grown for 21 days on Murashige and Skoog salts with either 0, 1, 2, or 3% sucrose and capped with loose-fitted Magenta 2-way caps that allowed approximately 2.25 air exchanges/hour. Plantlets were exposed to either 100 or 300 micro mol/sq m/s photosynthetic photon flux (PPF), and the growth chamber was maintained at either 400 or 4000 micro mol/mol CO2. Regardless of PPF, all cvs. that were grown at 4000 micro mol/mol CO2 showed significant increases in total plantlet dry weight (TDW) and shoot length (SL) when sucrose was omitted from the media, indicating an autotrophic response. At 400 micro mol/mol CO2, all cvs. showed an increase in TDW and SL with increasing sucrose under both PPF levels. Within any sucrose treatment, the highest TDW for all cvs. resulted from 300 micro mol/sq m/s PPF and 4000 micro mol/mol CO2 At 4000 micro mol/mol CO2, TDW showed no further increase with sucrose levels above 1% for cvs. NL and DN at both PPF levels, suggesting that sucrose levels greater than 1% may hinder growth when CO2 enrichment is used.

Yorio, Neil C.↗

Bridging Current Indirect and Future Direct Estimates of Convective Mass Flux Toward Quantifying the Role of Convective Cores on Anvil Area Time Tendencies

Anvil cloud spatial extent is strongly driven by convective mass flux. However, the lack of convective mass flux observations precludes global analyses of the functional relationship between anvil cloud area growth tendencies and convective areal coverage and vertical mass flux. Partly informed by analyses of a hierarchy of WRF mesoscale convective system (MCS) simulations, in this presentation, we discuss new work on estimating convective mass flux by way of an approach that casts the problem of quantifying convective mass flux into terms related to diabatic heating vertical structure, convective area and tropospheric stability. We demonstrate the usefulness of this approach at the MCS spatial scale via development of a simple, robust model that analytically connects system-scale convective mass flux and anvil cloud area growth rates. We show that the model predicts anvil area size changes in agreement with those observed in a global convective system tracking database (TOOCAN). An additional advantage of this approach for estimating convective mass flux is that it bridges future satellite mission plans for directly observing convective mass flux (e.g., AOS) with longer-record observations made by TRMM, GPM and satellite sounder mission data (the latter used for estimating stability) that, when combined, can be used for inferring convective mass fluxes at the MCS spatial scale spanning slowly changing, diverse environments. An evaluation and bridging of both direct and indirect approaches supports convective process analyses varying over longer time periods in this “era of convection.”

convective mass flux↗

Bridging current indirect and future direct estimates of convective mass flux toward quantifying the role of convective cores on anvil area time tendencies

Anvil cloud spatial extent is strongly driven by convective mass flux. However, the lack of convective mass flux observations precludes global analyses of the functional relationship between anvil cloud area growth tendencies and convective areal coverage and vertical mass flux. Partly informed by analyses of a hierarchy of WRF mesoscale convective system (MCS) simulations, in this presentation, we discuss new work on estimating convective mass flux by way of an approach that casts the problem of quantifying convective mass flux into terms related to diabatic heating vertical structure, convective area and tropospheric stability. We demonstrate the usefulness of this approach at the MCS spatial scale via development of a simple, robust model that analytically connects system-scale convective mass flux and anvil cloud area growth rates. We show that the model predicts anvil area size changes in agreement with those observed in a global convective system tracking database (TOOCAN). An additional advantage of this approach for estimating convective mass flux is that it bridges future satellite mission plans for directly observing convective mass flux (e.g., AOS) with longer-record observations made by TRMM, GPM and satellite sounder mission data (the latter used for estimating stability) that, when combined, can be used for inferring convective mass fluxes at the MCS spatial scale spanning slowly changing, diverse environments. An evaluation and bridging of both direct and indirect approaches supports convective process analyses varying over longer time periods in this “era of convection.”

convective mass flux↗

Failure Mechanisms and Life Prediction of Thermal and Environmental Barrier Coatings under Thermal Gradients

Ceramic thermal and environmental barrier coatings (TEBCs) will play an increasingly important role in gas turbine engines because of their ability to further raise engine temperatures. However, the issue of coating durability is of major concern under high-heat-flux conditions. In particular, the accelerated coating delamination crack growth under the engine high heat-flux conditions is not well understood. In this paper, a laser heat flux technique is used to investigate the coating delamination crack propagation under realistic temperature-stress gradients and thermal cyclic conditions. The coating delamination mechanisms are investigated under various thermal loading conditions, and are correlated with coating dynamic fatigue, sintering and interfacial adhesion test results. A coating life prediction framework may be realized by examining the crack initiation and propagation driving forces for coating failure under high-heat-flux test conditions.

Zju, Dongming↗

Nucleation mechanisms for compound semiconductors grown on Si by MOCVD

The influence of growth parameters on the initial stage of heteroepitaxial growth of GaP, GaAs and AlAs on (100) Si substrates was examined. GaP and GaAs grow on Si in three-dimensional growth mode, forming well separated islands. However, such islands were observed to be contiguous in the case of AlAs growth on Si. The island density was seen to be proportional to the growth rate. GaAs and GaP exhibit very different growth behavior with increasing V/III flux ratio. Misorientation of the Si substrate does not appear to affect the island densities. Possible mechanisms for this growth behavior, based on cluster formation and migration, are discussed for the growth of these compound semiconductors on Si.

Soga, Tetsuo↗