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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Chapter 3: Thermal Exchanges and Temperature Stress

Thermal comfort during space flight is discussed. Heat production of man during space flight and wear loss as a mean of dissipating heat are described. Water cooled garments are also considered, along with tolerance for extreme heat and body heat storage. Models of human temperature regulation are presented in the form of documented FORTRAN programs.

Paul Webb

EMU Ag-Zn battery wet-life extension test

The Extravehicular Mobility Unit (EMU) silver/zinc (Ag/Zn) battery is an 11 cell battery of approximately 30 AH. The Ag/Zn battery is comprised of two 4-cell monoblocks and one 3-cell monoblock. A discussion of a wet-life extension test performed on the battery is given in viewgraph form.

Bragg, Bobby J.

Exploration of an Adaptive Routine for Battery Modeling

The purpose of this document is to explore the use of adaptive routines in battery modeling. The adaptive routines consist of real-time state estimators combined with battery parameter model components that are adjusted in real-time as battery data becomes available. Several aspects are explored. It is shown that model parameter identification is possible for simple battery models using available input/output data measurements. The online system identification used is recursive least squares. Model identification may be combined with a state observer such as the extended Kalman filter or the unscented Kalman filter to form an adaptive model combined with state estimation. However, such a combination is found to be problematic due to uncertainty, observability and stability issues. This paper is organized as follows. Section 1 introduces adaptive routines and possible roles they play in battery modeling. In Section 2 real-time parameter identification is described with results based on battery data. Section 3 reviews various state estimators and results using a simple battery model. In Section 4 parameter identification and state estimation are combined to form an adaptive routine. Finally, in Section 5 conclusions are drawn and future work is suggested.

Adaptive

Hubble Space Telescope nickel hydrogen battery system briefing

The topics covered are presented in viewgraph form and include the following: the Hubble Space Telescope (HST) Mission; system constraints; battery specification; battery module; simplified block diagram; cell design summary; present status; voltage decay; system depth of discharge; pressure since launch; system capacity; eclipse time vs. trickle charge; capacity test objectives; and capacity during tests.

Nawrocki, David

Advanced Solid Rocket Motor Project Status

The objectives of the project are the following: (1) to improve system safety and reliability; (2) to improve Space Shuttle Payload performance - 12,000 lb; (3) to optimize program cost; and (4) to promote a competitive solid rocket motor industry. The topics are presented in viewgraph form and include the Advanced Solid Rocket Motor (ASRM) project team, ASRM design, design schedules, and technical issues.

Keith Coates

Research and development of high thermal stability fuels

Increases in aircraft performance are leading to increases in the thermal stress on the primary aircraft coolant--the fuel. Fuel thermal stability limitations may offset future aircraft performance gains. The Air Force's Wright Laboratory is sponsoring several research programs to address this problem. The development of an additive package for JP-8 to improve its thermal stability is the primary focus of this paper. This program involves extensive testing of fuels and additives in a variety of test devices, culminating in tests in a fuel system simulator and engine tests. These tests involve Air Force personnel, on-site contractors (University of Dayton Research Institute, Systems Research Laboratories), Pratt and Whitney Aircraft Co., additive manufacturers, and Sandia National Laboratory. The test devices include several flowing and static tests, where the behavior of a fuel is investigated in a wide variety of environments. The study of several baseline fuels in these devices has led to some new insights into the mechanisms of fuel thermal (in)stability. It is becoming clear that a fuel's tendency to oxidize (to form peroxides, for example) is often inversely proportional to its tendency to form insoluble deposits.

T Edwards

Hubble Space Telescope Battery Background

The following topics are presented in viewgraph form and include the following: the MSFC Hubble Space Telescope (HST) Nickel-Hydrogen Battery Contract; HST battery design requirements; HST nickel-hydrogen battery development; HST nickel-hydrogen battery module; HST NiH2 battery module hardware; pressure vessel design; HST NiH2 cell design; offset non-opposing vs. rabbit ear cell; HST NiH2 specified capacity; HST NiH2 battery design; and HST NiH2 module design.

Dan Standlee

Battery Review Board

The topics covered are presented in viewgraph form: NASA Battery Review Board Charter; membership, board chronology; background; statement of problem; summary of problems with 50 AH standard Ni-Cd; activities for near term programs utilizing conventional Ni-Cd; present projects scheduled to use NASA standard Ni-Cd; other near-term NASA programs requiring secondary batteries; recommended direction for future programs; future cell/battery procurement strategy; and the NASA Battery Program.

Vaughn, Chester

A Review of Direct Ink Writing of Polymer Derived Ceramics

With the growing demand for materials capable of withstanding extreme temperatures and pressures, ceramic components with exceptional corrosion resistance and reliable mechanical properties have experienced a significant surge in demand. However, traditional ceramic forming methods involve high-temperatures and energy-intensive processes that often struggle to produce complex parts or composites efficiently. Polymer-Derived Ceramics (PDCs) offer a transformative solution by using polymeric precursors that can be converted into a wide variety of silicon-based and non-silicon-based ceramics through heat treatment. The polymeric nature of PDC precursors enables the fabrication of geometrically intricate components using conventional polymer-forming techniques at significantly lower processing temperatures. Furthermore, PDCs are well-suited for additive manufacturing (AM), allowing the production of complex structural and functional components through cost-effective, low-temperature processes. By leveraging the diverse properties of PDC materials – each with unique advantages and limitations – manufacturers can optimise performance for specific applications. This review provides an overview of the types of PDCs developed to date and their broad range of applications. Specifically, it delves into the Direct Ink Writing (DIW) process, exploring its rheological requirements and the critical role of fillers in tailoring the rheological properties of polymeric precursors to meet the specific demands of DIW.

Victoria Bishop

Design, Testing and Evaluation of Latching End Effector

The Latching End Effector (LEE) forms part of the Space Station Remote Manipulator System (SSRMS) for which Spar Aerospace Ltd, Space Systems Division is the prime contractor. The design, testing and performance evaluation of the Latching End Effector mechanisms is the subject of this paper focusing on: (1) ambient, thermal and vibration testing; (2) snare/rigidize performance testing and interaction during payload acquisition; and (3) latch/umbilical test results and performance.

B Walker

Effect of Thermomechanical Processing on the Microstructure, Properties, and Work Behavior of a Ti50.5 Ni29.5 Pt20 High-Temperature Shape Memory Alloy

TiNiPt shape memory alloys are particularly promising for use as solid state actuators in environments up to 300 °C, due to a reasonable balance of proper ties, including acceptable work output. However, one of the challenges to commercializing a viable high-temperature shape memory alloy (HTSMA) is to establish the appropriate primary and secondary processing techniques for fabrication of the material in a required product form such as rod and wire. Consequently, a Ti 50.5 Ni 29.5 Pt 20 alloy was processed using several techniques including single- pass high-temperature extrusion, multiple-pass high-temperature extrusion, and cold drawing to produce bar stock, thin rod, and fine wire, respectively. The effects of heat treatment on the hardness, grain size, room temperature tensile properties, and transformation temperatures of hot- and cold-worked material were examined. Basic tensile properties as a function of temperature and the strain-temperature response of the alloy under constant load, for the determination of work output, were also investigated for various forms of the Ti 50.5 Ni 29.5 Pt 20 alloy, including fine wire.

Grain Size

Evaluation of Fatigue Damage Accumulation Functions for Delamination Initiation and Propagation

The present report follows on the cohesive fatigue damage model methodology proposed in NASA-TP-2018-219838. In that report, an empirical function describing the incremental damage due to cyclic loading was used to calculate fatigue damage within a cohesive formulation. The form of the function was developed such that, when integrated at a constant stress amplitude from no damage to failure, it produces a life versus load response that is consistent with an S-N diagram. Therefore, the parameters of the damage model could be obtained by fitting the model predictions to an S-N diagram. The finite element analyses performed demonstrate that the cohesive fatigue accumulation function provides a link between the S-N diagram that describes crack initiation, and the Paris law that characterizes the rate of crack propagation. However, when the model was proposed, it was not known whether the form of the damage accumulation function associated with a desired S-N diagram is unique and, if not, if the link between S-N and the Paris law is unique and independent of the fatigue function selected. In the effort described herein, several alternative forms of the damage function that reproduce the desired features of S-N diagrams were found and evaluated. The effects of each of these functions on the predicted parameters of the Paris law and the propagation threshold are discussed. The results indicate that the predicted exponent m of the Paris law is indeed independent of the damage accumulation function. However, different functions predict different values for the pre-factor C of the Paris law. Therefore, the proper damage accumulation function must be selected by comparison with experiments. One of the new damage accumulation functions proposed herein was found to be particularly useful for analysis because of the ease with which the model parameters can be determined with a minimal amount of experimental information. The effectiveness of the proposed methodology and damage function was demonstrated by conducting analyses of a double cantilever beam test, a mixed-mode bending test, and a three-point bending test of a skin/doubler specimen. The results indicate that the same set of model parameters can provide accurate predictions of the rate of fatigue crack propagation for a variety of material interfaces, mode mixities, load levels, and stress ratios.

DKIN/Stiffener Debonding

Nickel-hydrogen battery design for the Transporter Energy Storage Subsystem (TESS)

Information is given in viewgraph form on nickel hydrogen battery design for the transporter energy storage subsystem (TESS). Information is given on use in the Space Station Freedom, the launch configuration, use in the Mobile Servicing Center, battery design requirements, TESS subassembley design, proof of principle testing of a 6-cell battery, possible downsizing of TESS to support the Mobile Rocket Servicer Base System (MBS) redesign, TESS output capacity, and cell testing.

Lapinski, John R.

Battery Cell Thermal Runaway Calorimeter

We currently have several methods for determining total energy output of an 18650 lithium ion cell. We do not, however, have a good method for determining the fraction of energy that dissipates via conduction through the cell can vs. the energy that is released in the form of ejecta. Knowledge of this fraction informs the design of our models, battery packs, and storage devices; (a) No longer need to assume cell stays together in modeling (b) Increase efficiency of TR mitigation (c) Shave off excess protection.

Darcy, Eric

Deep Electromagnetic Sounding of the Moon With Lunokhod 2 Data

Results of electromagnetic sounding distinguished an outer high resistance shell about 200 km thick in the moon's structure. A preliminary petrological interpretation of the moon's layers indicated their origin as a consequence of differentiation of the initial peridotite material. Upon melting, 20% to 40% of the material melts and is removed to form a high resistance basaltic shell underlain by a layer of spinal peridotites enriched in divalent iron oxides and having a reduced resistance.

L L Van'yan

Hidden in Plain Sight: A New Main Belt Population of Aqueously Altered and Thermally Metamorphosed Asteroids

C-complex low albedo asteroids are understood to be related to aqueously altered carbonaceous chondrite meteorites. However, in recent years, a new subgroup of aqueously altered meteorites that have experienced significant heating after their initial interactions with water has been extensively studied. It remains unclear where the aqueously altered and heated parent bodies are located in the asteroid belt. To address this question, we reanalyzed the original dataset that defined the Bus-DeMeo spectral taxonomy of asteroids (DeMeo et al., 2009) using a machine learning approach trained with near-infrared archival meteorite spectra. Results show that ~50% of the C-complex asteroids first identified in the Bus-DeMeo asteroid spectral taxonomy are aqueously altered and heated. Though Ryugu has been shown to also have experienced both of these processes, this is the first evidence of a population of aqueously altered and thermally metamorphosed asteroids in the Main Asteroid Belt. Based on the expected velocity and frequency of impacts in the main belt population, we conclude that impacts are the most likely heat source driving thermal metamorphism we identify. Moreover, these aqueously altered and thermally metamorphosed asteroids may represent a primordial population of low-albedo material that formed in situ in the inner solar system. If these asteroids formed in place, rather than being brought in from the outer solar system during giant planet migration, they would have experienced more frequent and higher velocity impacts, resulting in their distinct mineralogy.

Main Belt asteroids

Microbiological Characterization and Concerns of the International Space Station Internal Active Thermal Control System

Since January 1999, the chemical the International Space Station Thermal Control System (IATCS) and microbial state of (ISS) Internal Active fluid has been monitored by analysis of samples returned to Earth. Key chemical parameters have changed over time, including a drop in pH from the specified 9.5 +/- 0.5 ta = 58.4, an increase in the level of total inorganic carbon (TIC), total organic carbon (TOC) and dissolved nickel (Ni) in the fluid, and a decrease in the phosphate (PO,) level. In addition, silver (AS) ion levels in the fluid decreased rapidly as Ag deposited on internal metallic surfaces of the system. The lack of available Ag ions coupled with changes in the fluid chemistry has resulted in a favorable environment for microbial growth. Counts of heterotrophic bacteria have increased from less than 10 colony-forming units (CFUs)/l00 mL to l0(exp 6) to l0(exp 7) CFUs/100 mL. The increase of the microbial population is of concern because uncontrolled microbiological growth in the IATCS can contribute to deterioration in the performance of critical components within the system and potentially impact human health if opportunistic pathogens become established and escape into the cabin atmosphere. Micro-organisms can potentially degrade the coolant chemistry; attach to surfaces and form biofilms; lead to biofouling of filters, tubing, and pumps; decrease flow rates; reduce heat transfer; initiate and accelerate corrosion; and enhance mineral scale formation. The micro- biological data from the ISS IATCS fluid, and approaches to addressing the concerns, are summarized in this paper.

Monsi C Roman

Lewis Research Center battery overview

The topics covered are presented in viewgraph form and include the following: the Advanced Communications Technology Satellite; the Space Station Freedom (SSF) photovoltaic power module division; Ni/H2 battery and cell design; individual pressure vessel (IPV) nickel-hydrogen cell testing SSF support; the LeRC Electrochemical Technology Branch; improved design IPV nickel-hydrogen cells; advanced technology for IPV nickel-hydrogen flight cells; a lightweight nickel-hydrogen cell; bipolar nickel-hydrogen battery development and technology; aerospace nickel-metal hydride cells; the NASA Sodium-Sulfur Cell Technology Flight Experiment; and the lithium-carbon dioxide battery thermodynamic model.

Odonnell, Patricia