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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Theoretical justification for heat flux limiter 0.15

In this section, we describe a semi-nonlocal kinetic model for the electron heat flux. The model has no free parameters. It takes the more physically motivated approach of placing a limiter on the perturbation to the electron distribution function, rather than the usual ad-hoc limiter on the heat flux. If the kinetic model is fitted by a heat flux limiter model, we find that the higher value of f e = 0.15 is a much closer fit than other models with f e ≃ 0.02.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Design of a High-Pressure Fuel System for Use with Dimethyl Ether

The paper documents the modeling and experimental work on a common rail fuel injection system for Dimethyl Ether, a potential diesel substitute with a low carbon intensity signature. The DME fuel system is deployed on a light duty 2.2L compression ignition engine. The paper describes the injector optimization to shift to higher flows to account for the lower heating value and density of the DME when compared to diesel. The type of the injection system used for the DME application is an advanced rendering of the Common rail noted for a one-piece piston-needle injector construction and a solenoid driven spill valve featuring a pressure balanced poppet. A dedicated high-pressure fuel pump designed to pressurize DME is used. The design results in a fast acting open and close injection event, reduced leakage, with reduced cavitation in the fuel injector volume. Design parameters for system optimization included fill and spill orifices, needle lift, bias spring, and injector hole size. The design model provides good correlation of the instantaneous rates of injection with experiments across a wide range of pressure and injection timings. Proposed performance milestones for the design included similar DME injection duration to the diesel counterpart for same fuel energy injected into the cylinder to retain high engine cycle efficiency. Here, the dedicated DME design provided reduced hydraulic delays of 50%. Tests demonstrated sustained operation at pressures of 1000 bar, with capability to reach 1500bar. Durability tests showed no cavitation-deterioration over a 200-hour test cycle by means of spray imaging and hardware inspection.

De Ojeda, William [WM International Engineering, L↗
DOE OSTI2023

Group additivity values for entropy and heat capacities of C 2 –C 8 alkanes, alkyl hydroperoxides, and their radicals

Group additivity values for the thermodynamic properties of oxygenated radicals are poorly determined due to the absence of high quality reference data. Here, a set of 58 group additive values (GAV) for the standard entropy and heat capacity of relevance to alkane oxidation is derived from fits to an extensive and accurate database of standard entropies (298.15 K) and heat capacities (300–3000 K) recently calculated with the “STAR-1D” formalism. The 192 species in this database represent the alkanes (RH), alkyl radicals ($\dot{R}$), alkyl hydroperoxides (RO 2 H), alkyl-peroxy (R$\dot{O}$ 2 ) and hydroperoxy-alkyl ($\dot{Q}$OOH) radicals for all of the isomers of C 2 –C 5 alkane fuels and a select number of isomers of C 6 –C 9 species. The STAR-1D thermochemical data for this set of species was previously obtained from a coupling of scaled B2PLYPD3/cc-pVTZ vibrational analyses with scaled ωB97X-D/cc-pVTZ one-dimensional hindered rotor corrections. The 2σ uncertainties in the GAV results relative to the STAR-1D data set are 2.4 cal K –1 mol –1 for the entropies and at most 2.0 cal K –1 mol –1 for the heat capacities in the temperature range 500–800 K. The 2σ fitting uncertainties in the heat capacity gradually reduce at higher temperatures reaching a value of 0.8 cal K –1 mol –1 at 2000 K decreasing to only 0.5 cal K –1 mol –1 at 3000 K. The high degree of accuracy for the GAV representations is obtained through the introduction of various new group terms, together with the re-optimization of existing group terms. Among the full set of 58 GAV terms, 25 include non-next-nearest neighbor interactions (NNI) and β-corrections. The updated GAVs can be applied in the prediction of entropies and heat capacities for a wide range of hydrocarbons and hydroperoxide species and their radicals, which is important to the accurate prediction of fuel reactivity at low-temperatures in the range 600–1000 K.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Unraveling the relationship between physicochemical properties of NiFeReOx catalysts and the correlated performance toward electrochemical oxygen evolution reaction

NiFeO x catalysts with single site Re dopants exhibit much higher active and stability toward electrochemical oxygen evolution reaction (OER) compared to traditional NiFeO x catalysts. Nevertheless, the relationship between physicochemical properties of NiFeReO x catalysts and the correlated performance toward OER is unclear, which hampers to enhance the OER performance further. Herein, we prepared a series of NiFeReO x catalysts with different physicochemical properties by treating them at different temperatures (up to 350 °C) and then evaluated their performance toward OER. Here, the results show that heat treatment can convert all metal oxidation states to higher values as well as specific surface areas, which are believed to favor real active site generation and OER activity enhancement. A decrease in activity is observed with the temperature increase at the low current range, and the smallest overpotential of 248 mV at 10 mA cm −2 is achieved with the pristine NiFeReO x catalyst. In contrast, the heat-treated samples possess smaller Tafel slopes and lower charge transfer resistance likely due to enhanced intrinsic activity (from higher oxidation states) and conductivity, which facilitate the reaction kinetics and surpass the pristine sample at a large current density. Additionally, the sample treated at 350 °C exhibits a higher activity at 1000 mA cm −2 (1.68 V vs. RHE compared to pristine sample of 1.92 V vs. RHE); however, it manifests a poorer stability compared to the pristine one due to the imbalance of reconstruction/transformations that occurred on the catalyst surface during OER operation. Our work unravels the relationship between physicochemical properties of NiFeReO x catalysts and the correlated OER performance and provides valuable insights for designing NiFeReO x catalysts with high activity and durability.

Catalyst reconstruction↗
DOE OSTI2024

Retrofitting Buildings with Solar-Reflective Roofs and Walls and its Impact on Peak Power Demand

Buildings are a major consumer of electricity in the United States and a significant portion of the consumption comes from heating, ventilation, and air-conditioning (HVAC) applications. Passive cooling strategies in the building envelope help to reduce the energy consumption for HVAC as well as peak electricity demand. Although being one of the most cost-effective passive cooling strategies, modern reflective roofing and reflective exterior wall technology is not well documented for its impact on peak demand. This study utilized whole building energy simulations on residential and commercial building prototype models to quantify the impact of cool roofs and cool exterior walls. The analysis was performed in three climate zones with varying insulation levels and solar reflectances for roofs and exterior walls. For both the residential and commercial buildings, the baseline building had a roof solar reflectance value of 0.10 and an exterior wall solar reflectance value of 0.25. The results from the simulations show that roofs and exterior walls with higher reflectance values increase cooling energy savings but can also increase heating energy consumption. The impact of changes in solar reflectances was greater in buildings with low roof/wall insulation levels compared to roofs/walls with higher insulation levels. A baseline for the simulations was set with the roof and exterior wall solar reflectances set at 0.1 and 0.25, respectively and simulations having varying roof and exterior wall thermal resistances were compared to the baselines.

14 SOLAR ENERGY↗
DOE OSTI2022

Understanding radiation effects in friction stir welded MA956 using ion irradiation and a rate theory model

We report an outstanding challenge in the manufacturing and joining of oxide dispersion strengthened steels is retaining the nanofeatures in the alloy throughout the fabrication and welding process. MA956 was friction stir welded with two different sets of welding parameters, resulting in a medium and high heat input. After welding, 5 MeV Fe ++ ion irradiations were performed at doses ranging from 50 to 200 dpa in the temperature range of 400 to 500°C. Post-irradiation characterization was performed with scanning transmission electron microscopy and energy-dispersive x-ray spectroscopy to investigate the Y-Al-O dispersoids, voids, and dislocations. After welding, the dispersoid microstructure coarsened, resulting in fewer and larger dispersoids regardless of heat input. After irradiation, the dispersoid behavior in the welded material was sensitive to temperature, exhibiting growth behavior attributed to Ostwald coarsening at 500 °C but a mixture of nucleation and more muted growth at 400 and 450 °C, attributed to competing mechanisms of radiation-enhanced diffusion and Ostwald coarsening. Void swelling correlated to heat input; being more prevalent in the welded conditions occurring at lower doses and in higher values relative to the base material. The low values of swelling despite microstructure coarsening caused by welding demonstrate the excellent swelling resistance of MA956, even after welding with the highest swelling values of 0.5% noted in the stir zone high heat input condition at 450 °C, 200 dpa. The dislocation behavior was inconsistent: the strongest trend was that network density was higher for welded versus base material, and an increase in loop diameter with temperature was observed. A rate theory model based on the observed microstructure suggests at high temperature interstitial loss to sinks was more likely to be dominant compared to mutual annihilation via point defect recombination, because of an increase of the radiation diffusion coefficient with temperature regardless of initial welded microstructure.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Study of Mechanical Properties, Microstructure, and Residual Stresses of AISI 304/304L Stainless Steel Submerged Arc Weld for Spent Fuel Dry Storage Systems

The confinement boundaries of spent nuclear fuel (SNF) canisters are typically fusion welded. Welded microstructures, strain hardening, and residual stresses combined with a chemically aggressive, chloride-rich environment led to concerns that the welded canister may be susceptible to chloride-induced stress corrosion cracking (CISCC). A comprehensive understanding of the modification of stainless steel (SS) metallurgical and mechanical properties by fusion welding could accelerate the predictive analysis of CISCC susceptibility. This paper describes a submerged arc welding (SAW) procedure that was developed and qualified on 12.7 mm (0.5 in.) thick AISI 304/304L SS to produce joints in a way similar to actual SNF canister manufacturing. This procedure has the potential to reduce the production cost and weld CISCC susceptibility by using fewer welding passes and lower heat input than current industrial applications. Global and local mechanical behaviors and properties, as well as residual stress distributions on the welded joint, were studied. The results indicate that hardness values in the fusion zone (FZ) and heat-affected zone (HAZ) are slightly higher than that of the base metal. Strain localization was presented in the HAZ before the tensile stress reached its maximum value, and then it shifted to the FZ. The specimen finally broke in the FZ. High tensile residual stresses exhibited in the FZ and the nearby HAZ suggest the highest CISCC-susceptible spots. The maximum tensile residual stresses were along the welding direction, indicating that if cracks occur, they would be perpendicular to the welding direction. This study involved developing and qualifying a SAW procedure for SNF canister production. The new procedure yielded cost savings (SAW working efficiency increased by about 80%), improved mechanical properties, and presented moderate residual stresses. Analysis revealed that the welded joint’s low-stress and high-stress damage assessments may be affected by shifts in the strain localization spot under loading.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Fuel Properties of Oxymethylene Ethers with Terminating Groups from Methyl to Butyl

Oxymethylene ethers (OMEs) have been studied as possible additives or replacements for diesel fuels. Typically, studies have considered only methyl-terminated OMEs. Recent structure-property relationship models suggest that extended-alkyl OMEs may provide improvements to many of the properties of methyl-terminated OMEs that make them less suitable as diesel fuel blendstocks. In this work, we describe the synthesis and characterization of 16 different OMEs with methyl, ethyl, propyl, butyl, isopropyl, and isobutyl terminating alkyl groups with varying oxymethylene chain length. Indicated Cetane Number, Lower Heating Value, Flash Point, Density, Viscosity, Vapor Pressure, and Oxidative Stability are tested via ASTM standard methods. Additionally, Water Solubility, Boiling Point, seal material compatibility, and sooting propensity (via the Yield Sooting Index) are measured for these fuels. For diesel compatibility, all tested OMEs except smaller methyl and ethyl OMEs, and the branched isopropyl OME, meet cetane number requirements. Further, extending the alkyl end group increases the heating value, but all OMEs, due to their oxygen content, have heating values less than diesel; despite this, all OMEs show significant reductions in soot production per unit heating value. Only the heaviest OMEs meet diesel viscosity requirements, and most are higher density than diesel. OMEs with larger alkyl groups show the highest stability under accelerated auto-oxidation conditions. Increases in alkyl group length cause order of magnitude reduction in water solubility, from hundreds of g/L for methyl terminated OMEs to hundreds of mg/L for butyl terminated OMEs. Limited seal material testing indicates that PEEK polymers are unaffected by OMEs; while extended alkyl groups may improve compatibility with FKM (Viton), other common elastomers (NBR, silicone) remain incompatible with all tested OMEs. Overall, it is found that methyl-terminated OMEs exhibit the most potential for soot reduction, but OMEs with larger propyl and butyl terminating alkyl groups show improved compatibility with existing diesel systems.

09 BIOMASS FUELS↗
DOE OSTI2025

High-temperature stability and thermal expansion behavior of equi-atomic refractory multi-principal element alloys based on MoNbTi system for Gen IV reactor applications

The present study investigates the thermal stability and thermal expansion behavior of seven equi-atomic refractory multi-principal element alloys (MPEAs) based on the MoNbTi ternary system composed of low neutron absorption cross section elements. Through an integrated approach utilizing in-situ high-temperature X-ray diffraction (HT-XRD) in conjunction with differential scanning calorimetry (DSC), dilatometry and ageing heat treatment, the thermal stability of the MPEAs was comprehensively analyzed. In-situ HT-XRD experiment confirmed the stability of the room temperature phases up to 1000 °C with no peaks observed corresponding to additional phases in the HT-XRD patterns at 500, 800 and 1100 °C. DSC thermograms showed the absence of peaks up to 1000 °C, while peaks and valleys corresponding to exothermic and endothermic events were observed above 1000 °C. Coefficient of thermal expansion (CTE) derived from second order polynomial fitting of linear thermal expansion data from the dilatometry experiment showed linear increment up to 1000 °C for all the alloys except those containing Zr. The Cr containing alloys exhibited notably higher CTE values, particularly the Al containing alloy exhibited the highest value. Ageing heat treatment at 800 and 1000 °C for 96 h and subsequent microstructural analysis revealed significant precipitation of secondary phases in MoNbTiZr, MoNbTiZrV and MoNbTiCrAl. In conclusion, a substantial increase in hardness was observed in MoNbTiZr and MoNbTiCrAl due to secondary phase precipitation, while the other alloys maintained hardness values comparable to their as-cast and homogenized states.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Techno-Economic Analysis of Recuperated Joule-Brayton Pumped Thermal Energy Storage

This article describes a techno-economic model for pumped thermal energy storage systems based on recuperated Joule-Brayton cycles and two-tank liquid storage. Models have been developed for each component, with particular emphasis on the heat exchangers. Economic metrics such as the power and energy capital costs (i.e., per-kW and per-kWh capacity) and levelized cost of storage are evaluated by gathering numerous cost correlations from the literature, thereby enabling estimates of uncertainty. It is found that the use of heat exchangers with effectivenesses up to 0.95 is economically worthwhile, but higher values lead to rapidly escalating component size and system cost. Several hot storage fluids are considered; those operating at the highest temperatures (chloride salts) improve the round-trip efficiency but the benefit is marginal and may not warrant the additional material costs and risk when compared to lower-temperature nitrate salts. Cost-efficiency trade-offs are explored using a multi-objective optimization algorithm, yielding optimal designs with round-trip efficiencies in the range 59-72% and corresponding levelized storage costs of 0.12 0.03 and 0.38 0.10 $/kWhe. Lifetime costs are competitive with lithium-ion batteries for discharging durations greater than 6 h under current scenarios.

Carnot battery↗
DOE OSTI2024

Numerical Simulation of Light to Heat Conversion by Plasmonic Nanoheaters

Plasmonic nanoparticles are widely recognized as photothermal conversion agents, i.e., nanotransducers or nanoheaters. Translation of these materials into practical applications requires quantitative analyses of their photothermal conversion efficiencies (η). However, the value of η obtained for different materials is dramatically influenced by the experimental setup and method of calculation. Here, we evaluate the most common methods for estimating η (Roper’s and Wang’s) and compare these with numerical estimates using the simulation software ANSYS. Experiments were performed with colloidal gold nanorod solutions suspended in a hanging droplet irradiated by an 808 nm diode laser and monitored by a thermal camera. The ANSYS simulations accounted for both heating and evaporation, providing η values consistent with the Wang method but higher than the Roper approach. This study details methods for estimating the photothermal efficiency and finds ANSYS to be a robust tool where experimental constraints complicate traditional methods.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2020

Sedimentary Geothermal Resources in Nevada, Utah, Colorado, and Texas

The objectives of this project were to (1) perform a literature review of sedimentary geothermal resources, (2) identify data sources and develop data-collection methodologies that characterize selected resources, (3) screen sedimentary basins and formations for sedimentary geothermal potential, and (4) evaluate the technical feasibility of one or more selected locations. Numerous publications have characterized geothermal resources within sedimentary basins. A literature search reviewed publications describing resources located in Colorado, Louisiana, Nevada, Texas, Utah, and Wyoming. The most attractive resources have high temperature gradients, low drilling costs, and reservoir permeabilities greater than 10 millidarcies (mD). Prospects in Colorado, Nevada, Texas, and Utah exhibit attractive characteristics and were chosen for further analysis. Sedimentary resources in Nevada and Utah are most attractive, followed by tested resources in Texas and untested resources in Colorado. The identified resources in Wyoming and Louisiana had lower geothermal gradients and were not evaluated. Reservoir modeling and techno-economic analysis were performed at Marys River Basin–North in Nevada. Geothermal energy production at this location is expected to have a levelized cost of energy (LCOE) ranging between 10 and 20 cents/kWh. Additional work may result in lower LCOE estimates at this location and at other attractive prospects in these three regions. The Great Basin carbonate and alluvial aquifer system of eastern Nevada and western Utah includes a lower carbonate aquifer unit, which has the potential for hosting both conduction- and convection-dominated geothermal systems. Mapping has identified lateral thickness variability expressed as a roughly 120–150-km-wide central corridor, which hosts the thickest and most continuous formations and extends from near Las Vegas north to the Idaho border. Purchase and analysis of privately held legacy seismic data could potentially compensate for the lack of sufficient data documenting measured depth to the lower carbonate aquifer unit. Multiple orogenies, extension episodes, and intrusive events have deformed and displaced the target formations of the lower carbonate aquifer unit. This structural complexity and potential for dipping reservoirs emphasizes the need for detailed geological, geophysical, and reservoir modeling. Heat flow within three Colorado sedimentary basins reviewed as part of this study was calculated in targeted studies by the Colorado Geologic Survey and Colorado School of Mines. These calculations are based on bottom-hole temperature data sets with significant limitations and some variability but produce values consistently higher than the global continental average of 65 mW/m2 for all three basins. Heat flow in the Raton Basin is the highest; however, permeability measurements from specific sedimentary formations with high heat flow have not been obtained. Promising formations for sedimentary geothermal systems were found in all three regions studied—Nevada-Utah, Colorado, and Texas. The next steps for developing sedimentary geothermal resources vary due to differences in available data and resource uncertainties. Additional scopes of work are recommended for identified basins in these three regions.

15 GEOTHERMAL ENERGY↗
DOE OSTI2023

Mapping gas around massive galaxies: cross-correlation of DES Y3 galaxies and Compton- y maps from SPT and Planck

ABSTRACT We cross-correlate positions of galaxies measured in data from the first three years of the Dark Energy Survey with Compton-y maps generated using data from the South Pole Telescope (SPT) and the Planck mission. We model this cross-correlation measurement together with the galaxy autocorrelation to constrain the distribution of gas in the Universe. We measure the hydrostatic mass bias or, equivalently, the mean halo bias-weighted electron pressure 〈bhPe 〉, using large-scale information. We find 〈bhPe 〉 to be $[0.16^{+0.03}_{-0.04},0.28^{+0.04}_{-0.05},0.45^{+0.06}_{-0.10},0.54^{+0.08}_{-0.07},0.61^{+0.08}_{-0.06},0.63^{+0.07}_{-0.08}]$ meV cm−3 at redshifts z ∼ [0.30, 0.46, 0.62, 0.77, 0.89, 0.97]. These values are consistent with previous work where measurements exist in the redshift range. We also constrain the mean gas profile using small-scale information, enabled by the high-resolution of the SPT data. We compare our measurements to different parametrized profiles based on the cosmo-OWLS hydrodynamical simulations. We find that our data are consistent with the simulation that assumes an AGN heating temperature of 108.5 K but are incompatible with the model that assumes an AGN heating temperature of 108.0 K. These comparisons indicate that the data prefer a higher value of electron pressure than the simulations within r500c of the galaxies’ haloes.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Plasma heating by electron cyclotron wave and the temperature effects on lower hybrid current drive on EAST

This paper presents the progress in the long—pulse operation of the electron cyclotron (EC) system and the achievements in high—electron temperature plasmas by the combined EC and lower hybrid (LH) waves heating since the EC system was built in 2015. An electron temperature of up to 12 keV with a duration over 100 s was realized by the simultaneous heating of EC and LH waves at the line-averaged density ${\bar n_{\text{e}}}$ ~1.8 × 10 19 m –3 . The plasma heating effect strongly depends on the location of EC power deposition. H-mode plasmas with solely EC wave auxiliary heating have been obtained on EAST for the first time. These H-mode discharges show an enhanced confinement factor H 98(y,2) around 1.0, which is higher than the previous H-mode using LH power alone (Xu et al 2011 Nucl. Fusion 51 072001). The total heating power is very close to the threshold value for L–H transition according to the international tokamak scaling. In addition to the temperature effects inside the separatrix, higher electron temperature produced by EC wave is found to reduce the LH power loss in the scrape-off layer due to collisional absorption, which is beneficial to further increase the LH current drive efficiency. Ray-tracing/Fokker–Planck modeling results indicate that higher electron temperature can shorten the LH wave propagation on EAST in a multiple-pass regime, thus decreasing the collisional dissipation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Experimental study of a tri-functional propane hydronic heat pump

This study investigates the performance of a propane hydronic heat pump system for space cooling, heating, and water heating applications, focusing on various operational conditions, with a total refrigerant charge below 1200 g. Cooling performance was evaluated at different outdoor temperatures, compressor stages (capacity levels), and water flow rates. The results showed that the coefficient of performance (COP) for cooling was higher at lower outdoor temperatures, with peak values exceeding 5.0 under low-stage operation and lower water flow rate. The cooling capacity increased with higher flow rates and compressor stages, reaching 12 kW. Space heating performance, evaluated at ambient temperatures ranging from −8.3 °C to 16.7 °C, revealed a decrease in COP with lower temperatures. However, high-stage operation maintained higher heating capacities even at low temperatures. The system demonstrated high Heating Seasonal Performance Factors (HSPF), exceeding 10.0. For water heating, the COP decreased with lower ambient temperatures and higher supply water temperatures. The system efficiently heated an 189-L water tank, outperforming conventional water heaters, with process COPs exceeding 4.0 under cooling-season conditions. Despite some efficiency loss due to defrosting at low temperatures, the propane heat pump consistently delivered strong performance. Seasonal energy efficiency ratios (SEER) and seasonal heating COP values indicated significant overall efficiency. The study concludes that propane is a promising refrigerant for heat pump systems, with future research needed to future reduce total system charge and optimize system performance through advanced controls and heat exchanger designs.

Hu, Yifeng [ORNL] (ORCID:0000000242875185)↗
DOE OSTI2021

Interfacial thermal conductance between multi-layer graphene sheets and solid/liquid octadecane: A molecular dynamics study

Mixtures of paraffin and carbon nanofillers have promising potential for thermal storage, as paraffin (the matrix) possesses high latent heat and the nanofillers compensate for the low thermal conductivity (TC) of paraffin. Understanding thermal transport in these materials is essential for practical applications, as weak thermal transport hinders fast charge/discharge of thermal energy. Here, we use non-equilibrium molecular dynamics (NEMD) simulations to study the interfacial thermal conductance (ITC) between graphene sheets and octadecane (C18H38) matrix under the limiting conditions of the sheets being parallel or perpendicular to the direction of the imposed heat flux. The findings show that the systems containing thin graphene layers exhibit higher values of ITC. This study captures the asymptotic saturation of thermal conductance for the liquid phase of the perpendicular structure. Besides, given the greater number of structured layers of paraffin upon phase change, the ITC for the solid paraffin-graphene system is higher than the conductance of the liquid paraffin-graphene interface. We use the Pearson correlation coefficients of the vibrational power spectrum (VPS) of interfacing materials to explain the orders of magnitude variations of the observed ITC.

25 ENERGY STORAGE↗
DOE OSTI2025

Impact of low-chemical storage pretreatment of loblolly pine bark on biochar from microwave pyrolysis

Forest product residues such as bark represent a low-cost, abundant feedstock for bioenergy, but their high ash and alkali and alkaline earth metal (AAEM) content limit thermochemical conversion efficiency. This study evaluates the use of low-severity chemical pretreatments during anaerobic storage to improve the performance of microwave pyrolysis for loblolly pine bark. Bark was treated with dilute sulfuric acid (0.1% and 1%, w/w) or sodium hydroxide (4%, w/w) and incubated anaerobically for one or two weeks to simulate in-pile biorefinery storage. The most effective treatment—1% H2SO4 for two weeks—reduced AAEM content by 35.7% and increased bio-oil yield by 11% compared to untreated controls, while also reducing pyrolysis gas production. In contrast, alkali treatment did not reduce AAEM levels and led to decreased bio-oil yields with increased gas formation. Although biochar yields were relatively stable across treatments, their physicochemical characteristics varied significantly. Acid-treated bark yielded biochars with higher carbon content, lower O/C and H/C ratios, greater surface area, and enhanced heating values. These improvements suggest that chemical pretreatment during storage can tailor biochar quality for specific end uses. Biochars produced under optimized conditions exhibited properties suitable for soil amendment, carbon sequestration, and solid fuel applications. This integrated approach—combining storage, mild chemical conditioning, and microwave pyrolysis—provides a viable pathway to enhance the value and sustainability of bark-derived bioenergy products.

09 - BIOMASS FUELS↗