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At least 55 records · Page 3

Bed form-induced hyporheic exchange and geochemical hotspots

Small-scale bed form topographies control hyporheic exchange and biogeochemical processes within aquatic sediments, which ultimately affect water quality and nutrient cycling at the watershed scale. The impact of three-dimensional and small-scale bed form topographies on hyporheic exchange and solute mixing is investigated in the present work. The effect of bed form morphologies on the development of zones of enhanced reaction rates (i.e., hotspots) is also studied. A computational fluid dynamics model to simulate river flow over bed forms is combined with a subsurface flow and multicomponent reactive solute transport model. A wide variety of bed form topographies are generated using geometric models by varying parameters controlling curvature as well as bed form wavelength and amplitude. The results in this research suggest that out-of-phase bed forms generate more complex hyporheic flow patterns which reduce the efficiency of solute transformations. Higher phase shifts in bed form shapes result in overall higher average velocity, larger zones of enhanced pressure and reaction rates, and higher amounts of solute exchange. Moreover, the bed form shapes control the reaction process for a wide range of sediment conductivities. Here this study advances the understanding of the effects of complex and small scale morphological features on hyporheic exchange processes including the rate and spatio-temporal distribution of reaction hotspots.

54 ENVIRONMENTAL SCIENCES↗

Programming entropy production hotspots via interaction patterning

Dissipation in soft matter and living systems is highly heterogeneous, giving rise to complex local entropy production patterns. Recent work has identified the connection between local entropy production and locally extractable amount of work. This suggests that locally produced entropy can be recovered to power nanorobots and biological machines, prompting the need for efficient strategies to modulate and fine-tune local entropy production. In this work, we propose to program entropy production hotspots by leveraging local interaction patterns and test this approach in simulations of a fluid driven through a nanopore or past an obstacle. Here, the results show that patterning the surface of the pore with a repulsive patch gives rise to an entropy production hotspot around the patch, while an attractive patch leads to an entropy production cold spot. Varying the strength of the interaction and width of the patch enables modulating the hotness and extent of the hot spot. In flows past interaction patterned-obstacles, we show that the combined effects of steric hindrance and attraction allows to program a specific entropy production map, thereby opening the door to the precise powering of nanomachines.

Desgranges, Caroline [University of Massachusetts,↗

Hotspot conditions achieved in inertial confinement fusion experiments on the National Ignition Facility

We describe the overall performance of the major indirect-drive inertial confinement fusion campaigns executed at the National Ignition Facility. With respect to the proximity to ignition, we can describe the performance of current experiments both in terms of no-burn ignition metrics (metrics based on the hydrodynamic performance of targets in the absence of alpha-particle heating) and in terms of the thermodynamic properties of the hotspot and dense fuel at stagnation—in particular, the hotspot pressure, temperature, and areal density. We describe a simple 1D isobaric model to derive these quantities from experimental observables and examine where current experiments lie with respect to the conditions required for ignition.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Hotspot formation due to shock-induced pore collapse in 1,3,5,7-tetranitro-1,3,5,7-tetrazoctane (HMX): Role of pore shape and shock strength in collapse mechanism and temperature

The shock to detonation transition in heterogeneous high energy density solids starts with the spatial localization of mechanical energy into so-called hotspots that form due to the interaction between the leading wave and microstructural features and defects. We used large-scale molecular dynamics to characterize the hotspots resulting from the shock-induced collapse of cylindrical voids and elongated cracks focusing on the effect of shock strength, defect shape, and size. The temperature fields resulting from the collapse of cracks elongated along the shock direction show significantly higher sensitivity to both shock strength and size than cylindrical voids. Cracks 80 nm in length result in temperatures almost three times higher than voids 80 nm in diameter, reaching values corresponding to the ideal case of isentropic recompression of a gas. The molecular dynamics trajectories reveal the atomic origin of this contrasting behavior. While circular voids undergo a transition from viscoelastic pore collapse to a hydrodynamic regime with increasing shock strength, shock focusing in elongated cracks results in jetting and vaporization which, upon recompression, leads to increased heating.

36 MATERIALS SCIENCE↗

A knock-on deuteron imager for measurements of fuel and hotspot asymmetry in direct-drive inertial confinement fusion implosions (invited)

A knock-on deuteron imager (KoDI) has been implemented to measure the fuel and hotspot asymmetry of cryogenic inertial confinement fusion implosions on OMEGA. Energetic neutrons produced by D–T fusion elastically scatter (“knock on”) deuterons from the fuel layer with a probability that depends on ρR. Deuterons above 10 MeV are produced by near-forward scattering, and imaging them is equivalent to time-integrated neutron imaging of the hotspot. Deuterons below 6 MeV are produced by a combination of side scattering and ranging in the fuel, and encode information about the spatial distribution of the dense fuel. Here, the KoDI instrument consists of a multi-penumbral aperture positioned 10–20 cm from the implosion using a ten-inch manipulator and a detector pack at 350 cm from the implosion to record penumbral images with magnification of up to 35×. Range filters and the intrinsic properties of CR-39 are used to distinguish different charged-particle images by energy along the same line of sight. Image plates fielded behind the CR-39 record a 10 keV x-ray image using the same aperture. A maximum-likelihood reconstruction algorithm has been implemented to infer the source from the projected penumbral images. The effects of scattering and aperture charging on the instrument point-spread function are assessed. Synthetic data are used to validate the reconstruction algorithm and assess an appropriate termination criterion. Significant aperture charging has been observed in the initial experimental dataset, and increases with aperture distance from the implosion, consistent with a simple model of charging by laser-driven EMP.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Quantifying nitrogen loss hotspots and mitigation potential for individual fields in the US Corn Belt with a metamodeling approach

The high productivity in the US Corn Belt is largely enabled by the consumption of millions of tons of manufactured fertilizer. Excessive application of nitrogen (N) fertilizer has been pervasive in this region, and the unrecovered N eventually escaped from croplands in forms of nitrous oxide (N 2 O) emission and N leaching. Mitigating these negative impacts is hindered by a lack of practical information on where to focus and how much mitigation potential to expect. At a large scale, process-based crop models are the primary tools for predicting variables required by decision making, but their applications are prohibited by expensive computational and data storage costs. To overcome these challenges, we built a series of metamodels to learn the key mechanisms regarding the carbon (C) and N cycle from a well-validated process-based biogeochemical model, ecosys. The trained metamodel captures over 98% of the variability of the ecosys simulated outputs for 99 randomly selected counties in Iowa, Illinois, and Indiana. To identify hotspots with high mitigation potential, we introduce net societal benefit (NSB) as an indicator for synthesizing the loss in yield and social benefits through emissions and pollutants avoided. Our results show that reducing N fertilizer by 10% leads to 9.8% less N 2 O emissions and 9.6% less N leaching at the cost of 4.9% more SOC depletion and 0.6% yield reduction over the study region. The estimated total annual NSB is $\$395$ M (uncertainty ranges from $\$114$ M to $\$1271$ M), including $\$334$ from social benefits (uncertainty ranges from $\$46$ M to $\$1076$ M), $\$100$ M from saving fertilizer (uncertainty ranges from $\$13$ M to $\$455$ M), and –$\$40$ M due to yield changes (uncertainty ranges from –$\$261$ M to $\$69$ M). For the median scenario, we noted that 20% of the study area accounts for nearly 50% of the NSB, and thus represent hotspot locations for targeted mitigation. Although the uncertainty range suggests that developing such a high-resolution framework is not yet settled and the scenario based estimations are not appropriate to inform the management practices for individual farmers, our efforts shed light on the new generation of analytical tools for life cycle assessment.

54 ENVIRONMENTAL SCIENCES↗

Surface-wave tomography of the Emeishan large igneous province (China): Magma storage system, hidden hotspot track, and its impact on the Capitanian mass extinction

Large igneous provinces (LIPs) are commonly associated with mass extinctions. However, the precise relations between LIPs and their impacts on biodiversity is enigmatic, given that they can be asynchronous. It has been proposed that the environmental impacts are primarily related to sill emplacement. Therefore, the structure of LIPs' magma storage system is critical because it dictates the occurrence and timing of mass extinction. We use surface-wave tomography to image the lithosphere under the Permian Emeishan large igneous province (ELIP) in southwestern China. We find a northeast-trending zone of high shear-wave velocity (Vs) and negative radial anisotropy (Vsv > Vsh; v and h are vertically and horizontally polarized S waves, respectively) in the crust and lithosphere. We rule out the possibilities of rifting or orogenesis to explain these seismic characteristics and interpret the seismic anomaly as a mafic-ultramafic, dike-dominated magma storage system of the ELIP. We further propose that the anomaly represents a hidden hotspot track that was emplaced before the ELIP eruption. A zone of higher velocity but less-negative radial anisotropy, on the hotspot track but to the northeast of the eruption center in the Panxi region, reflects an elevated proportion of sills emplaced at the incipient stage of the ELIP. Liberation of poisonous gases by the early sill intrusions explains why the mid-Capitanian global biota crisis preceded the peak ELIP eruption by 2–3 m.y.

58 GEOSCIENCES↗

Untargeted Exometabolomics Provides a Powerful Approach to Investigate Biogeochemical Hotspots with Vegetation and Polygon Type in Arctic Tundra Soils

Rising temperatures in the Arctic have led to the thawing of tundra soils, which is rapidly changing terrain, hydrology, and plant and microbial communities, causing hotspots of biogeochemical activity across the landscape. Despite this, little is known about how nutrient-rich low molecular weight dissolved organic matter (LMW DOM) varies within and across tundra ecosystems. Using a high-resolution nano-liquid chromatography-mass spectrometry (LC/MS) approach, we characterized the composition and availability of LMW DOM from high-centered polygons (HCP) and low-centered polygons (LCP) with Eriophorum angustifolium or Carex aquatilis as the dominant vegetation. Over 3000 unique features (i.e., discrete mass/charge ions) were detected; 521 were identified as differentially abundant between polygonal types and 217 were putatively annotated using high mass accuracy MS data. While polygon type was a strong predictor of LMW DOM composition and availability, vegetation and soil depth were also important drivers. Extensive evidence was found for enhanced microbial processing at the LCP sites, which were dominated by Carex plant species. We detected significant differences between polygon types with varying aboveground landscape features or properties, and hotspots of biogeochemical activity, indicating LMW DOM, as quantified by untargeted exometabolomics, provides a window into the dynamic complex interactions between landscape topography, vegetation, and organic matter cycling in Arctic polygonal tundra soils.

58 GEOSCIENCES↗

Identifying Urban Pluvial Frequency Flooding Hotspots Using the Topographic Control Index and Remote Sensing Radar Images for Early Warning Systems

Identifying areas that frequently experience post-rainfall ponding is essential for effective flood mitigation and planning. This study integrates Sentinel-1 radar imagery and the Topographic Control Index (TCI) to identify 378 flood-prone urban depressions in Beaumont, Texas. Out of 159 major rainfall events, only six had Sentinel-1 radar imagery acquired within six hours of peak rainfall, and these were used to generate the flood frequency map; the ground-based flood sensor data were used to verify that these selected events corresponded to actual peak rainfall and to validate radar-detected water pixels. Validation results showed 100% precision, 70.87% recall, an F1-score of 82.95%, and 71.32% overall accuracy. Approximately 84% of medium-to-high TCI depressions overlapped with Beaumont’s two-year inundation map, confirming a strong relationship between TCI and observed flooding. A total of 124 depressions retained significant water, and after excluding 25 engineered detention ponds, 99 natural depressions remained flood vulnerable. Among these, 74 depressions with medium or high TCI were identified as the highest-priority nuisance flooding hotspots. The results demonstrate that combining TCI with radar imagery provides a reliable and cost-effective approach for identifying areas prone to frequent urban ponding. This framework supports practical decision-making for drainage improvements, hotspot identification, and early-warning system development in urban flood-prone regions.

Sentinel-1 radar imagery↗

Hotspots, polar wander, Mesozoic convection and the geoid

The geoid bears little relation to present tectonic features of the earth other than trenches. The Mesozoic supercontinent of Pangea, however, apparently occupied a central position in the Atlantic-African geoid high. This and the equatorial Pacific geoid high contain most of the world's hotspots. The plateaus and rises in the western Pacific formed in the Pacific geoid high and this may have been the early Mesozoic position of Pacifica, the fragments of which are now the Pacific rim portions of the continents. Geoid highs which are unrelated to present subduction zones may be the former sites of continental aggregations and mantle insulation and, therefore, hotter than normal mantle. The pent-up heat causes rifts and hotspots and results in extensive uplift, magmatism, fragmentation and dispersal of the continents and the subsequent formation of plateaus, aseismic ridges and seamount chains. Convection in the uppermantle would then be due to lateral temperature gradients as well as heating from below and would be intrinsically episodic.

Anderson, D. L.↗

Volcanic hotspots on Io - Stability and longitudinal distribution

The first results of a program to determine the longitudinal distribution of volcanic activity on Jupiter's satellite Io are presented. Infrared measurements at 8.7, 10, and 20 micrometers have been taken at a variety of orbital longitudes: strong variation in the 8.7- and 10-micrometer flux with longitude demonstrates that infrared emission arising from volcanic hotspots on Io is strongly concentrated in a few locations. Analysis of these data suggests that the active volcanic regions observed by the Voyager experimenters are still active, particularly the region around the feature known as Loki. Another source of flux, although of somewhat smaller magnitude, is indicated on the opposite hemisphere. If these sources are the only major volcanic centers on Io, then current global heat flow estimates must be revised downward. However, heat flow from as yet unobserved longitudes, hotspots at high latitudes, and conducted heat flow must still be measured.

Johnson, T. V.↗

Background heatflow on hotspot planets - Io and Venus

It is suggested that there is no simple relationship between lithospheric thickness and heatflow on planets where volcanism dominates the heatflow. This applies locally and globally, even away from regions of volcanic activity. This indicates that there is no basis for the assumption that the Io heatflow is as low as (or lower than) the hotspot component alone would suggest. A model is presented to describe the heatflow on hotspot planets. The model is applied to Io and Venus.

Stevenson, David J.↗

Coldspots or hotspots? The origin of plateau-shaped highlands on Venus

A compelling question for the terrestrial planets is the origin of the highland regions on Venus. Data on the topography, gravity signature, and surface morphology returned by the Pioneer Venus, Venera 15/16, and Magellan spacecraft represent a basis for dividing these highlands into two distinct groups: volcanic rises and plateau-shaped highlands. Volcanic rises are generally thought to be due to mantle upwellings in the form of large mantle plumes and are thus similar in origin to terrestrial hotspots. There is less agreement as to the origin of plateau-shaped highlands (PSH). Coldspot mantle downwelling can lead to the formation of a highland region under Venus conditions, and previous to Magellan some PSH (particularly W. Ishtar Terra and Ovda and Thetis Regiones) were suggested to be compressionally deformed regions of thickened crust created by mantle downwelling. A hotspot model proposes that such regions are formed by magmatism and tectonism related to the near-surface ascent of either the diapir-shaped large mantle plume or a solitary disturbance propagating up a plume conduit. The characteristics of both volcanic rises and plateau-shaped highlands on Venus and the models for their formation are briefly reviewed, and tests that may help to make clear which model best explains the plateau-shaped highlands are considered.

Bindschadler, D. L.↗

Hotspot evolution and Venusian tectonic style

Because hotspots represent an important manifestation of heat loss on Venus, their geological evolution is of fundamental importance for any attempt to understand Venusian tectonics. Eistla Regio is an approximately 7500-km-long, moderately elevated region inferred to overlie one or more large mantle upwellings or hotspots. It also contains many shield volcanoes and coronae believed due to the rise of thermal plumes in the mantle. Central Eistla Regio includes two large volcanoes, Sappho and Anala, and several coronae in close proximity. Detailed mapping in this region results in two conclusions of tectonic significance: (1) Sappho and Anala occur near the intersection of two major extensional deformation zones, and (2) the coronae are older than the large volcanoes. Several of the coronae occur as a chain along Guor Linea, one of the major extensional deformation zones. Stratigraphic relationships indicate that the coronae began forming very soon after the emplacement of the widespread regional plains materials. Thus Central Eistla Regio was the site of a swarm of plumes that first formed coronae and then later formed shield volcanoes. The expected result of such a swarm would be thermal thinning of the elastic lithosphere with time. However, model results, geological observations, and gravity data suggest that the change from coronae to shield volcanoes was accompanied by a thickening of the lithosphere with time. This thickening is interpreted to be the result of global cooling of the lithosphere following the most recent episode of near-global resurfacing. The global cooling must have occurred faster than local heating of the lithosphere due to the impingement of thermal plumes.

Mcgill, George E.↗

Satellite NO 2 Trends and Hotspots Over Offshore Oil and Gas Operations in the Gulf of Mexico

The Outer Continental Shelf of the Gulf of Mexico (GOM) is populated with numerous oil and natural gas (ONG) platforms which produce NO x (NO x = NO + NO 2 ), a major component of air pollution. The Bureau of Ocean Energy Management (BOEM) is mandated to ensure that the air quality of coastal states is not degraded by these emissions. As part of a NASA-BOEM collaboration, we conducted a satellite data-based analysis of nitrogen dioxide (NO 2 ) patterns and trends in the GOM. Data from the OMI and TROPOMI sensors were used to obtain 18+ year records of tropospheric column (TrC) NO 2 in three GOM regions: (a) Houston urban area, (b) near shore area off the Louisiana coast, and a (c) deepwater area off the Louisiana coast. The 2004–2022 time series show a decreasing trend for the urban (−0.027 DU/decade) and near shore (−0.0022 DU/decade) areas, and an increasing trend (0.0019 DU/decade) for the deepwater area. MERRA-2 wind and TROPOMI NO 2 data were used to reveal several NO2 hotspots (up to 25% above background values) under calm wind conditions near individual platforms. The NO 2 signals from these deepwater platforms and the high density of shallow water platforms closer to shore were confirmed by TrC NO 2 anomalies of up to 10%, taking into account the monthly TrC NO 2 climatology over the GOM. The results presented in this study establish a baseline for future estimates of emissions from the ONG hotspots and provide a methodology for analyzing NO 2 measurements from the new geostationary TEMPO instrument.

NO2↗

Hotspot Coevolution Is a Key Identifier of Near-Native Protein Complexes

Protein–protein interactions play a key role in mediating numerous biological functions, with more than half the proteins in living organisms existing as either homo- or hetero-oligomeric assemblies. Protein subunits that form oligomers minimize the free energy of the complex, but exhaustive computational search-based docking methods have not comprehensively addressed the challenge of distinguishing a natively bound complex from non-native forms. Current protein docking approaches address this problem by sampling multiple binding modes in proteins and scoring each mode, with the lowest-energy (or highest scoring) binding mode being regarded as a near-native complex. However, high-scoring modes often match poorly with the true bound form, suggesting a need for improvement of the scoring function. Here in this study, we propose a scoring function, KFC-E, that accounts for both conservation and coevolution of putative binding hotspot residues at protein–protein interfaces. We tested KFC-E on four benchmark sets of unbound examples and two benchmark sets of bound examples, with the results demonstrating a clear improvement over scores that examine conservation and coevolution across the entire interface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Plasmonic Core–Shell–Satellites with Abundant Electromagnetic Hotspots for Highly Sensitive and Reproducible SERS Detection

In this work, we develop a Ag@Al2O3@Ag plasmonic core–shell–satellite (PCSS) to achieve highly sensitive and reproducible surface-enhanced Raman spectroscopy (SERS) detection of probe molecules. To fabricate PCSS nanostructures, we employ a simple hierarchical dewetting process of Ag films coupled with an atomic layer deposition (ALD) method for the Al2O3 shell. Compared to bare Ag nanoparticles, several advantages of fabricating PCSS nanostructures are discovered, including high surface roughness, high density of nanogaps between Ag core and Ag satellites, and nanogaps between adjacent Ag satellites. Finite-difference time-domain (FDTD) simulations of the PCSS nanostructure confirm an enhancement in the electromagnetic field intensity (hotspots) in the nanogap between the Ag core and the satellite generated by the Al2O3 shell, due to the strong core–satellite plasmonic coupling. The as-prepared PCSS-based SERS substrate demonstrates an enhancement factor (EF) of 1.7 × 107 and relative standard deviation (RSD) of ~7%, endowing our SERS platform with highly sensitive and reproducible detection of R6G molecules. We think that this method provides a simple approach for the fabrication of PCSS by a solid-state technique and a basis for developing a highly SERS-active substrate for practical applications.

47 OTHER INSTRUMENTATION↗