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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Fabrication of surrogate oxide spent fuel with various cracking patterns and design of an axial gas transport apparatus

In this article, understanding gas transport behavior in nuclear fuel rods is important for the design, performance, and safety of nuclear fuels. Surrogate materials help enable efficient research by reducing both the costs and the amount of time required. A parametric study using Darcy’s law is completed that demonstrates the feasibility of observing pressure decay over short 13-to-15-cm specimens to enable full characterization of the fabricated specimens using x-ray computed tomography. This paper demonstrates that thermally shocked and mechanically compressed alumina pellets produce surrogate samples whose various cracking patterns are representative of the severity of cracking observed as a function of burnup in irradiated nuclear fuels. Furthermore, image analyses of the cracking patterns—in conjunction with gas transport testing using surrogate samples—affords a valuable accelerated basis for developing gas transport simulations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Uncovering phase transformation, morphological evolution, and nanoscale color heterogeneity in tungsten oxide electrochromic materials

Controlling the electrochemical interfacial processes that govern the durability of electrochromic devices represents a key challenge in developing sustainable and cost-effective smart windows. Here, we revisit the classical tungsten trioxide (WO 3 ) materials as a platform to uncover the previously unknown interrelationship between phase transformation, morphological evolution, and nanoscale color heterogeneity in these materials. Through synchrotron/electron spectroscopic and imaging analyses, we report that the WO 3 –electrolyte interface is influenced by the tungsten dissolution and redeposition during the electrochemical cycling. The tungsten redeposition provokes the in situ crystal growth, which ultimately leads to the phase transformation from the semicrystalline WO 3 to a nanoflake-shaped, proton-trapped tungsten trioxide dihydrate (H x WO 3 · 2 H 2 O). The multidimensional quantification of the electronic structure reveals that the tungsten reduction caused by the proton trapping is heterogeneous at the nanometric scale and is responsible for the nanoscale color heterogeneity. The interplay between phase transformation, morphological evolution, and nanoscale color heterogeneity results in degraded optical modulation, switching kinetics, coulombic efficiency, and bleached-state transparency. Our results highlight that the high interfacial reactivity near the electrode surface may be the underlying mechanism for undesired bulk structural changes of electrochromic materials, and calls for fundamental studies in probing and controlling the electrode–electrolyte interfacial processes in electrochromic devices.

36 MATERIALS SCIENCE↗

Indirect searches for ultraheavy dark matter in the time domain

Dark matter may exist today in the form of ultraheavy composite bound states. Collisions between such dark matter states can release intense bursts of radiation that include γ -rays among the final products. Thus, indirect detection signals of dark matter may include unconventional γ -ray bursts. Such bursts may have been missed not necessarily because of their low arriving γ -ray fluxes, but rather their briefness and rareness. We point out that intense bursts whose nondetection thus far are due to the latter can be detected in the near future with existing and planned facilities. In particular, we propose that, with slight experimental adjustments and suitable data analyses, imaging atmospheric Cherenkov telescopes (IACTs) and Pulsed All-Sky Near-Infrared and Optical Search for Extra-Terrestrial Intelligence (PANOSETI) are promising tools for detecting such rare, brief, but intense bursts. We also show that, if we assume these bursts originate from collisions of dark matter states, IACTs and PANOSETI can probe a large dark matter parameter space beyond existing limits. Additionally, we present a concrete model of dark matter that produces bursts potentially detectable in these instruments. Published by the American Physical Society 2025

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Ectomycorrhizal fungi enhance pine growth by stimulating iron‐dependent mechanisms with trade‐offs in symbiotic performance

Iron (Fe) is crucial for metabolic functions of living organisms. Plants access occluded Fe through interactions with rhizosphere microorganisms and symbionts. Yet, the interplay between Fe addition and plant–mycorrhizal interactions, especially the molecular mechanisms underlying mycorrhiza-assisted Fe processing in plants, remains largely unexplored. Here, we conducted mesocosms in Pinus plants inoculated with different ectomycorrhizal fungi (EMF) Suillus species under conditions with and without Fe coatings. Meta-transcriptomic, biogeochemical, and X-ray fluorescence imaging analyses were applied to investigate early-stage mycorrhizal roots. While Fe addition promoted Pinus growth, it concurrently reduced mycorrhiza formation rate, symbiosis-related metabolites in plant roots, and aboveground plant carbon and macronutrient content. This suggested potential trade-offs between Fe-enhanced plant growth and symbiotic performance. However, the extent of this trade-off may depend on interactions between host plants and EMF species. Interestingly, dual EMF species were more effective at facilitating plant Fe uptake by inducing diverse Fe-related functions than single-EMF species. This subsequently triggered various Fe-dependent physiological and biochemical processes in Pinus roots, significantly contributing to Pinus growth. However, this resulted in a greater carbon allocation to roots, relatively reducing the aboveground plant carbon content. Our study offers critical insights into how EMF communities rebalance benefits of Fe-induced effects on symbiotic partners.

36 MATERIALS SCIENCE↗

pyMSDtorch v0.1.0

pyMSDtorch is a python implementation of the MSDNet developed by Sethian and Pelt [1] for image analyses, using the pytorch framework. The availability these networks in mainstream ML packages makes it easier to attach standard expansions and other approaches to make it more flexible and user friendly.

Zwart, PetrusH↗

PRESSURE-FILM OPEN SOURCE SCANNING AND MAPPING

SF-22-099 Pressure-film Open Source Scanning and Mapping (POSSM) is software that analyses images of pressure-film (scans or photographs). POSSM collects data from that analysis in order to produce a number of visual aides, including pressure maps, histograms, and 3d surface plots. POSSM is designed to be able to analyze an entire folder full of images, exporting numeric data as .csv files and visual graphics as .png files.

Grider, Patrick↗

Evolution of Pore Structure and Permeability of Rocks Under Hydrothermal Conditions (Final Report)

The physical and transport properties of porous rocks can be altered by a variety of diagenetic, metamorphic, and tectonic processes, and the changes that result are of critical importance to such industrial applications as resource recovery, carbon dioxide sequestration, and waste isolation in geologic formations. The associated interrelationships between rocks, pore fluids and deformation are also key to understanding many natural processes, including dynamic metamorphism, fault mechanics, fault stability and pressure solution creep. In this project, we investigated the changes of permeability and pore geometry owing to inelastic deformation by solution-transfer, brittle fracturing and dislocation creep. In particular, we studied the coupling between pore fluids and deformation in fluid-filled quartz, calcite, mudstones and ultramafic rocks and examine the effects of coupled mechanical and chemical processes on the evolution of porosity and permeability under hydrothermal conditions. The investigations used a combination of techniques, that included triaxial laboratory experiments; uniaxial compressive loading with in situ observations of microstructure; permeability under hydrostatic compression; observations of microstructure using optical and electron microscopes, and micro-CT imaging; and numerical calculations. Laboratory experiments were designed to provide mechanical and transport data under conditions that isolate the particular mechanisms responsible for the changes. The data obtained were used to quantify changes in surface roughness, porosity, pore dimensions and their spatial fluctuations. The results of the experiments and data from image analyses were compared to the results of network, finite-difference and other numerical models to verify the validity of experimentally established relations between permeability and other rock properties. A bibliography for the period from 2015-2019 is appended below. New results obtained in the final year and the unfunded extension period are detailed below.

58 GEOSCIENCES↗

Development of an Open-source Alloy Selection and Lifetime Assessment Tool for Structural Components in CSP

Lack of sufficient data on high temperature mechanical and corrosion behavior of structural materials is a huge barrier in the technological maturity of current and future Concentrating Solar Power (CSP) technologies. Rapid development and selection of materials cannot be achieved by expensive and time-consuming acquisition of experimental data. The goal of the proposed work is development of an open-source alloy selection and lifetime prediction tool that will integrate validated physics-based models to describe influence of temperature, alloy composition, environment and component geometry (thickness) on mechanical and corrosion behavior of Ni and Fe-based alloys employed in molten salts/sCO 2 heat exchangers. This one-year project leveraged the extensive dataset on the creep\corrosion behavior of candidate materials generated at ORNL through past projects and input from current collaborations with industrial partners. Based on previous experience and the feedback provided by industry (Brayton Energy and Echogen), three candidate materials of interest, Ni-based alloys 740H, 282 and 625 and application-specific operating conditions (max. temperature of 730 °C and stress of 150 MPa) were identified for the heat exchanger. An extensive corrosion and creep dataset was assimilated for the relevant operating conditions and was supported by detailed characterization of about 100 metallographic cross-sections. The corrosion dataset consisted of scanning electron microscopy images (secondary electron and backscatter electron), measured concentration profiles of alloying elements using energy dispersive X-ray spectroscopy (EDS), widths of denuded zones (dissolution of strengthening phases) and depths of attack in molten KCl-MgCl 2 mixtures using image analyses. The creep dataset comprised of creep rupture data and creep strain curves (for 740H and 282). Coupled thermodynamic-kinetic microstructure-based models were employed to predict the stress-corrosion induced compositional and phase evolutions in the alloy during operation under the identified operating conditions. Reduced order models were developed from advanced physics-based models and were integrated in a user-friendly alloy selection tool. The corrosion model was able to predict the time to a critical Cr concentration at the oxide/alloy interface (chemical lifetime) within ±10% (1 standard deviation) of typical statistical variation in corrosion tests and EDS measurement errors (±0.5 wt%). The initial scope of the project was limited to predict creep rupture times (Larson-Miller parameter). Based on the input provided by industry, the mechanical lifetime of the heat exchanger is governed by accumulated creep strains (2%) rather than creep rupture. To be able to predict the times to specific creep strains, a more extensive creep model development was undertaken largely beyond the initial scope of the project. The continuum damage mechanics creep model was able to predict times to 2% creep strain, t 2% with an accuracy of ±500h. Ultimately, a screening protocol for SiC was generated to demonstrate the pathway for integration of one of the currently immature materials from a commercial adoption standpoint in the current material evaluation tool. The modeling tool developed here is accessible to the science community and stakeholders and lays the foundation for methods that will enable a rapid evaluation of optimum materials for CSP applications and reliable prediction of material degradation thereby considerably reducing operational costs, improving reliability and increasing overhaul intervals. However, the complete potential of such a tool to include a wider range of materials and test conditions can only be realized with a more concentrated combined experimental-characterization-computation effort.

14 SOLAR ENERGY↗

CRISPR/Cas9-Induced fad2 and rod1 Mutations Stacked With f ae1 Confer High Oleic Acid Seed Oil in Pennycress (Thlaspi arvense L.)

Pennycress (Thlaspi arvense L.) is being domesticated as an oilseed cash cover crop to be grown in the off-season throughout temperate regions of the world. With its diploid genome and ease of directed mutagenesis using molecular approaches, pennycress seed oil composition can be rapidly tailored for a plethora of food, feed, oleochemical and fuel uses. Here, we utilized Clustered Regularly Interspaced Short Palindromic Repeats (CRISPR)/Cas9 technology to produce knockout mutations in the FATTY ACID DESATURASE2 (FAD2) and REDUCED OLEATE DESATURATION1 (ROD1) genes to increase oleic acid content. High oleic acid (18:1) oil is valued for its oxidative stability that is superior to the polyunsaturated fatty acids (PUFAs) linoleic (18:2) and linolenic (18:3), and better cold flow properties than the very long chain fatty acid (VLCFA) erucic (22:1). When combined with a FATTY ACID ELONGATION1 (fae1) knockout mutation, fad2 fae1 and rod1 fae1 double mutants produced ~90% and ~60% oleic acid in seed oil, respectively, with PUFAs in fad2 fae1 as well as fad2 single mutants reduced to less than 5%. MALDI-MS spatial imaging analyses of phosphatidylcholine (PC) and triacylglycerol (TAG) molecular species in wild-type pennycress embryo sections from mature seeds revealed that erucic acid is highly enriched in cotyledons which serve as storage organs, suggestive of a role in providing energy for the germinating seedling. In contrast, PUFA-containing TAGs are enriched in the embryonic axis, which may be utilized for cellular membrane expansion during seed germination and seedling emergence. Under standard growth chamber conditions, rod1 fae1 plants grew like wild type whereas fad2 single and fad2 fae1 double mutant plants exhibited delayed growth and overall reduced heights and seed yields, suggesting that reducing PUFAs below a threshold in pennycress had negative physiological effects. Taken together, our results suggest that combinatorial knockout of ROD1 and FAE1 may be a viable route to commercially increase oleic acid content in pennycress seed oil whereas mutations in FAD2 will likely require at least partial function to avoid fitness trade-offs.

09 BIOMASS FUELS↗

Red Wine Fermentation Alters Grape Seed Morphology and Internal Porosity

During wine fermentation, grape berry components, including seeds, undergo extensive physical and chemical changes that result in the release of flavonoids, such as tannins, from seeds into wine. Understanding changes in seed morphology during fermentation is crucial for aiding the development of accurate prediction models for flavonoid extraction during winemaking, which enhances fermentation management and ensures consistency in wines from year to year. High-resolution x-ray microcomputed tomography (x-ray μCT) was used to investigate the effect of red wine fermentation on changes in grape seed morphology. Using a PyTorch-based implementation of a fully convolutional network with a Resnet-101 backbone for semantic segmentation of x-ray μCT images, we quantified extensive alteration to grape seed structure during fermentation. Image analyses revealed the development of a pore network breaking apart the seed endosperm by the end of fermentation, leading to an increase in surface area. Fermentation significantly altered grape seed morphology. Such alterations could enable transport of seed flavonoids from inside the endosperm and integument to outside the seed. Further research on the physical processes occurring in seeds during wine fermentation is necessary to build better physiochemical models.

59 BASIC BIOLOGICAL SCIENCES↗

Measuring Airflow With Digital Holographic Interferometry

Digital image-processing system assists in analysis of holographic interferometric images of flow about airfoil. Operating semiautomatically, identifies, counts, and labels interference fringes, then processes distances between fringes into distribution of pressure on surface of airfoil. Yields data on pressure faster than manual image-analyses techniques, and data compares favorably with those obtained by manual analysis and by probe measurements of pressure. Uses computer programs evaluating interferograms along straight or curved lines represented by polygon segments. User prompted for such inputs as reference points and fringe number. Digitizes holographic interferograms of flow and processes them into data of pressure or other properties of flow.

Torres, Francisco J.↗

AVHRR monitoring of U.S. crops during the 1988 drought

Effects of the 1988 drought on crops in the U.S. Corn Belt were assessed and monitored by the Foreign Crop Condition Assessment Division (FCCAD), U.S. Department of Agriculture. The primary data were vegetation index numbers (VINs), each of which was calculated as an average vegetation index of a geographically referenced cell of AVHRR pixels. Using VINs, the FCCAD was able to detect the existence of drought early in the season, monitor changing conditions, and provide objective assessments of the drought's extent and severity. Field observations confirmed the image analyses, and underlined the importance of the timing of extreme weather events with respect to crop stages for interpreting VINs. The analyses were conducted in an operational environment, providing a unique test of the AVHRR data for large area, near real-time crop monitoring. Because large area, operational remote sensing of crops is quite different from traditional, controlled, small plot research studies, more work is needed to link the two; this would improve crop assessment capabilities.

Teng, William L.↗

Chromospheric Doppler Imaging

We reanalyzed the IUE data from the 1991, 1993, and 1995 AR Lac campaigns. Doppler imaging analyses show evidence for asymmetric chromospheric flux distributions, but the plages are not as compact as they were in the 1980's. The expected 1997 data were not obtained due to the failure of the IUE. A discussion of the data, the problems, and the initial results, is in "Stellar Chromospheres", F.M. Walter, in "Stellar Surface Structure", ed. K.G. Strassmeier & J.L. Linsky (Dordrecht:Kluwer) (1996), p. 355. We are currently working on a paper based on this work.

Walter, Frederick M.↗

Rapid in situ hybridization technique using 16S rRNA segments for detecting and differentiating the closely related gram-positive organisms Bacillus polymyxa and Bacillus macerans

A rapid, sensitive, inexpensive in situ hybridization technique, using 30-mer 16S rRNA probes, can specifically differentiate two closely related Bacillus spp., B. polymyxa and B. macerans. The 16S rRNA probes were labeled with a rhodamine derivative (Texas Red), and quantitative fluorescence measurements were made on individual bacterial cells. The microscopic fields analyzed were selected by phase-contrast microscopy, and the fluorescence imaging analyses were performed on 16 to 67 individual cells. The labeled 16S rRNA probe, POL, whose sequence was a 100% match with B. polymyxa 16S rRNA but only a 60% match with B. macerans 16S rRNA, gave quantitative fluorescence ratio measurements that were 34.8-fold higher for B. polymyxa cells than for B. macerans cells. Conversely, the labeled probe, MAC, which matched B. polymyxa 16S rRNA in 86.6% of its positions and B. macerans 16S rRNA in 100% of its positions, gave quantitative fluorescence measurements that were 59.3-fold higher in B. macerans cells than in B. polymyxa cells. Control probes, whose 16S rRNA sequence segment (P-M) was present in both B. polymyxa and B. macerans as well as a panprokaryotic probe (16S), having a 100% match with all known bacteria, hybridized equally well with both organisms. These latter hybridizations generated very high fluorescence signals, but their comparative fluorescence ratios (the differences between two organisms) were low. The control paneukaryotic probe (28S), which had less than 30% identity for both B. macerans and B. polymyxa, did not hybridize with either organism.

Non-NASA Center↗

Modeling Carbon Exchange

Model results will be reviewed to assess different methods for bounding the terrestrial role in the global carbon cycle. It is proposed that a series of climate model runs could be scoped that would tighten the limits on the "missing sink" of terrestrial carbon and could also direct future satellite image analyses to search for its geographical location and understand its seasonal dynamics.

Sellers, Piers↗

Extratropical Weather Systems on Mars: Radiatively-Active Water Ice Effects

Extratropical, large-scale weather disturbances, namely transient, synoptic-period,baroclinic barotropic eddies - or - low- (high-) pressure cyclones (anticyclones), are components fundamental to global circulation patterns for rapidly rotating, differentially heated, shallow atmospheres such as Earth and Mars. Such "wave-like" disturbances that arise via (geophysical) fluid shear instability develop, mature and decay, and travel west-to-east in the middle and high latitudes within terrestrial-like planetary atmospheres. These disturbances serve as critical agents in the transport of heat and momentum between low and high latitudes of the planet. Moreover, they transport trace species within the atmosphere (e.g., water vapor/ice, other aerosols (dust), chemical species, etc). Between early autumn through early spring, middle and high latitudes on Mars exhibit strong equator-to-pole mean temperature contrasts (i.e., "baroclinicity"). Data collected during the Viking era and observations from both the Mars Global Surveyor (MGS) and Mars Reconnaissance Orbiter (MRO) indicate that such strong baroclinicity supports vigorous, large-scale eastward traveling weather systems [Banfield et al., 2004; Barnes et al., 1993]. A good example of traveling weather systems, frontal wave activity and sequestered dust activity from MGS/MOC image analyses is provided in Figure 1 (cf. Wang et al. [2005]). Utilizing an upgraded and evolving version of the NASA Ames Research Center (ARC) Mars global climate model, investigated here are key dynamical and physical aspects of simulated northern hemisphere (NH) large-scale extratropica lweather systems,with and without radiatively-active water ice clouds. Mars Climate Model:

cyclones↗

Geometric accuracy of LANDSAT-4 MSS image data

Analyses of the LANDSAT-4 MSS image data of North Georgia provided by the EDC in CCT-p formats reveal that errors of approximately + or - 30 m in the raw data can be reduced to about + or - 55 m based on rectification procedures involving the use of 20 to 30 well-distributed GCPs and 2nd or 3rd degree polynomial equations. Higher order polynomials do not appear to improve the rectification accuracy. A subscene area of 256 x 256 pixels was rectified with a 1st degree polynomial to yield an RMSE sub xy value of + or - 40 m, indicating that USGS 1:24,000 scale quadrangle-sized areas of LANDSAT-4 data can be fitted to a map base with relatively few control points and simple equations. The errors in the rectification process are caused by the spatial resolution of the MSS data, by errors in the maps and GCP digitizing process, and by displacements caused by terrain relief. Overall, due to the improved pointing and attitude control of the spacecraft, the geometric quality of the LANDSAT-4 MSS data appears much improved over that of LANDSATS -1, -2 and -3.

Welch, R.↗