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At least 55 records · Page 3

A comparison of acoustic and random vibration testing of spacecraft

Before selecting the most suitable testing technique in a particular case, it has to be considered which of the two methods duplicates better the distribution of vibration responses to be expected during the actual launch phase. An investigation is conducted of the case of a large, low density spacecraft launched by a vehicle which produces significant acoustic noise and transmits relatively little vibration through the mechanical path provided by the vehicle structure in the area of the spacecraft interface. Criteria for vibration-acoustic equivalence are discussed along with tests conducted with the Synchronous Meteorological Satellite, the Radio Astronomy Explorer, and the Orbiting Geophysical Spacecraft. The investigation indicates that the vibration test is generally a poor substitute for an acoustic study.-

Bangs, W. F.↗

Interfacial thermal conductance between multi-layer graphene sheets and solid/liquid octadecane: A molecular dynamics study

Mixtures of paraffin and carbon nanofillers have promising potential for thermal storage, as paraffin (the matrix) possesses high latent heat and the nanofillers compensate for the low thermal conductivity (TC) of paraffin. Understanding thermal transport in these materials is essential for practical applications, as weak thermal transport hinders fast charge/discharge of thermal energy. Here, we use non-equilibrium molecular dynamics (NEMD) simulations to study the interfacial thermal conductance (ITC) between graphene sheets and octadecane (C18H38) matrix under the limiting conditions of the sheets being parallel or perpendicular to the direction of the imposed heat flux. The findings show that the systems containing thin graphene layers exhibit higher values of ITC. This study captures the asymptotic saturation of thermal conductance for the liquid phase of the perpendicular structure. Besides, given the greater number of structured layers of paraffin upon phase change, the ITC for the solid paraffin-graphene system is higher than the conductance of the liquid paraffin-graphene interface. We use the Pearson correlation coefficients of the vibrational power spectrum (VPS) of interfacing materials to explain the orders of magnitude variations of the observed ITC.

25 ENERGY STORAGE↗

Vibration mitigation in interlocking metasurfaces

Interlocking metasurfaces (ILMs) are a new class of mechanical metamaterials with patterned surface features that enable joining of two adjacent bodies, serving as an alternative to welds, fasteners, or adhesives. While the strength of ILMs has been explored previously, it is also possible to envision ILMs that possess the ability to dampen vibration or tailor energy transmission across the interface. In this study, we explore the vibration transmission under frequency sweep and random excitation of three ILM designs. This is the first study to characterize the response of ILMs under vibration. We find that ILMs which are tightly coupled (e.g., small interference fit) behave as a linear system and depart only marginally from the behavior of a solid body. However, through strategic manipulation of the ILM topology, and in particular the fit clearances, we show that vibrations can be damped by over an order of magnitude. Design strategies to employ ILMs for vibration mitigation are developed using a first-order model.

Bolmin, O. [Carnegie Mellon Univ., Pittsburgh, PA ↗

Molecular beam mass spectrometry measurements of vibrationally excited N 2 in the effluent of an atmospheric plasma jet: a comparison with a state-to-state kinetic model

Vibrationally excited N 2 molecules are suggested to be one of the possible key species responsible for the observed synergistic effects in plasma catalysis for NH 3 synthesis. To assess the impact of vibrationally excited species in plasma-catalysis, quantitative measurements near interfaces are required, which remains challenging. In this letter, we report spatially resolved measurements of vibrationally excited N 2 in the effluent of an atmospheric pressure plasma jet by molecular beam mass spectrometry (MBMS). The mass spectrometry signals as a function of electron energy of the ionizer were fitted with the effective electron-impact ionization cross section of N 2 (v) considering the vibrational distribution function as determined by a detailed vibrational level resolved plasma kinetic calculation. Here, the reported method presented in this letter shows the capability of MBMS to measure vibrationally excited species of N 2 near interfaces when the vibrational distribution function is known or assumed and shows excellent agreement with state-to-state kinetic models of N 2 (v).

42 ENGINEERING↗

Linearized Aeroelastic Solver Applied to the Flutter Prediction of Real Configurations

A fast-running unsteady aerodynamics code, LINFLUX, was previously developed for predicting turbomachinery flutter. This linearized code, based on a frequency domain method, models the effects of steady blade loading through a nonlinear steady flow field. The LINFLUX code, which is 6 to 7 times faster than the corresponding nonlinear time domain code, is suitable for use in the initial design phase. Earlier, this code was verified through application to a research fan, and it was shown that the predictions of work per cycle and flutter compared well with those from a nonlinear time-marching aeroelastic code, TURBO-AE. Now, the LINFLUX code has been applied to real configurations: fans developed under the Energy Efficient Engine (E-cubed) Program and the Quiet Aircraft Technology (QAT) project. The LINFLUX code starts with a steady nonlinear aerodynamic flow field and solves the unsteady linearized Euler equations to calculate the unsteady aerodynamic forces on the turbomachinery blades. First, a steady aerodynamic solution is computed for given operating conditions using the nonlinear unsteady aerodynamic code TURBO-AE. A blade vibration analysis is done to determine the frequencies and mode shapes of the vibrating blades, and an interface code is used to convert the steady aerodynamic solution to a form required by LINFLUX. A preprocessor is used to interpolate the mode shapes from the structural dynamics mesh onto the computational fluid dynamics mesh. Then, LINFLUX is used to calculate the unsteady aerodynamic pressure distribution for a given vibration mode, frequency, and interblade phase angle. Finally, a post-processor uses the unsteady pressures to calculate the generalized aerodynamic forces, eigenvalues, an esponse amplitudes. The eigenvalues determine the flutter frequency and damping. Results of flutter calculations from the LINFLUX code are presented for (1) the E-cubed fan developed under the E-cubed program and (2) the Quiet High Speed Fan (QHSF) developed under the Quiet Aircraft Technology project. The results are compared with those obtained from the TURBO-AE code. A graph of the work done per vibration cycle for the first vibration mode of the E-cubed fan is shown. It can be seen that the LINFLUX results show a very good comparison with TURBO-AE results over the entire range of interblade phase angle. The work done per vibration cycle for the first vibration mode of the QHSF fan is shown. Once again, the LINFLUX results compare very well with the results from the TURBOAE code.

Reddy, Tondapu S.↗

Control of the induced microgravity environment of the Man Tended Free Flyer (MTFF)

Induced disturbance sources have been identified on board the Man Tended Free Flyer (MTFF). Vibration responses at sensitive payload/spacecraft interfaces have been predicted by the application of an empirically found spacecraft dynamic transfer function. Vibrations from fluid loops (Freon, water) and of reaction wheels are assessed to be the main contributors to the induced microgravity environment. The expected payload acceleration response amplitudes presented here are more than one hundred times higher than the admissible values given by the MTFF system requirement, not considering the structural striction-friction effects which could be avoided by appropriate design. Real responses will be significantly lower because the derivation of excitation and transmission functions are based on worst case assumptions. The results indicate that future activities must be concentrated on equipment design improvement and the implementation of vibration reduction along the disturbance transmission path. The activities must be accompanied by early equipment and assembly development tests and transmissibility measurements with the integrated spacecraft engineering and structural models in order to improve the accuracy of payload response predictions.

Schlund, Juergen↗

Capturing 3D atomic defects and phonon localization at the 2D heterostructure interface

The three-dimensional (3D) local atomic structures and crystal defects at the interfaces of heterostructures control their electronic, magnetic, optical, catalytic, and topological quantum properties but have thus far eluded any direct experimental determination. Here, we use atomic electron tomography to determine the 3D local atomic positions at the interface of a MoS 2 -WSe 2 heterojunction with picometer precision and correlate 3D atomic defects with localized vibrational properties at the epitaxial interface. We observe point defects, bond distortion, and atomic-scale ripples and measure the full 3D strain tensor at the heterointerface. By using the experimental 3D atomic coordinates as direct input to first-principles calculations, we reveal new phonon modes localized at the interface, which are corroborated by spatially resolved electron energy-loss spectroscopy. We expect that this work will pave the way for correlating structure-property relationships of a wide range of heterostructure interfaces at the single-atom level.

42 ENGINEERING↗

Molecular Recognition at Mineral Interfaces: Implications for the Beneficiation of Rare Earth Ores

Ce-bastnäsite is the single largest mineral source for light rare-earth elements. In view of the growing industrial importance of rare-earth minerals, it is critical to develop more efficient methods for separating the valuable rare-earth-containing minerals from the surrounding gangue. In this work, we employ a combination of periodic density functional theory (DFT) and molecular mechanics (MM) calculations together with the de novo molecular design program HostDesigner to identify bis-phosphinate ligands that preferentially bind to the (100) Ce-bastnäsite surface rather than the (104) calcite surface. DFT calculations for a simple phosphinate ligand were employed to qualitatively understand key behaviors involved in ligand–metal, ligand–solvent, and solvent–metal interactions. These insights were then used to guide the search for flexible, rigid, and semirigid hydrocarbon linkers to identify candidate bis-phosphinate ligands with the potential to bind preferentially to Ce-bastnäsite. Among the five most promising bis-phosphinate ligands suggested by theoretical studies, three ligands were synthesized and their adsorption characteristics to bastnäsite (100) interfaces were characterized using vibrational sum-frequency (vSFG) spectroscopy, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, and isothermal titration calorimetry (ITC). The efficacy of the selective interfacial molecular binding was demonstrated by identifying a bis-phosphinate ligand capable of providing an overall higher surface coverage of alkyl groups relative to a monophosphinate ligand. The results highlight the interplay between adsorption binding strength and maximum surface coverage in determining ligand efficiency to render the mineral surface hydrophobic. DFT calculations further indicate that all tested ligands have higher affinity for Ce-bastnäsite than for calcite. Finally, this is consistent with the ITC data showing stronger adsorption enthalpy to bastnäsite than to calcite, making these ligands promising candidates for selective flotation of Ce-bastnäsite.

58 GEOSCIENCES↗

Formation of a Ti–Cu(111) single atom alloy: Structure and CO binding

A single atom Ti–Cu(111) surface alloy can be generated by depositing small amounts of Ti onto Cu(111) at slightly elevated surface temperatures (~500 to 600 K). Here, scanning tunneling microscopy shows that small Ti-rich islands covered by a Cu single layer form preferentially on ascending step edges of Cu(111) during Ti deposition below about 400 K but that a Ti–Cu(111) alloy replaces these small islands during deposition between 500 and 600 K, producing an alloy in the brims of the steps. Larger partially Cu-covered Ti-containing islands also form on the Cu(111) terraces at temperatures between 300 and 700 K. After surface exposure to CO at low temperatures, reflection absorption infrared spectroscopy (RAIRS) reveals distinct C–O stretch bands at 2102 and 2050 cm –1 attributed to CO adsorbed on Cu-covered Ti-containing domains vs sites in the Ti–Cu(111) surface alloy. Calculations using density functional theory (DFT) suggest that the lower frequency C–O stretch band originates specifically from CO adsorbed on isolated Ti atoms in the Ti–Cu(111) surface alloy and predicts a higher C–O stretch frequency for CO adsorbed on Cu above subsurface Ti ensembles. DFT further predicts that CO preferentially adsorbs in flat-lying configurations on contiguous Ti surface structures with more than one Ti atom and thus that CO adsorbed on such structures should not be observed with RAIRS. The ability to generate a single atom Ti–Cu(111) alloy will provide future opportunities to investigate the surface chemistry promoted by a representative early transition metal dopant on a Cu(111) host surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fast-Running Aeroelastic Code Based on Unsteady Linearized Aerodynamic Solver Developed

The NASA Glenn Research Center has been developing aeroelastic analyses for turbomachines for use by NASA and industry. An aeroelastic analysis consists of a structural dynamic model, an unsteady aerodynamic model, and a procedure to couple the two models. The structural models are well developed. Hence, most of the development for the aeroelastic analysis of turbomachines has involved adapting and using unsteady aerodynamic models. Two methods are used in developing unsteady aerodynamic analysis procedures for the flutter and forced response of turbomachines: (1) the time domain method and (2) the frequency domain method. Codes based on time domain methods require considerable computational time and, hence, cannot be used during the design process. Frequency domain methods eliminate the time dependence by assuming harmonic motion and, hence, require less computational time. Early frequency domain analyses methods neglected the important physics of steady loading on the analyses for simplicity. A fast-running unsteady aerodynamic code, LINFLUX, which includes steady loading and is based on the frequency domain method, has been modified for flutter and response calculations. LINFLUX, solves unsteady linearized Euler equations for calculating the unsteady aerodynamic forces on the blades, starting from a steady nonlinear aerodynamic solution. First, we obtained a steady aerodynamic solution for a given flow condition using the nonlinear unsteady aerodynamic code TURBO. A blade vibration analysis was done to determine the frequencies and mode shapes of the vibrating blades, and an interface code was used to convert the steady aerodynamic solution to a form required by LINFLUX. A preprocessor was used to interpolate the mode shapes from the structural dynamic mesh onto the computational dynamics mesh. Then, we used LINFLUX to calculate the unsteady aerodynamic forces for a given mode, frequency, and phase angle. A postprocessor read these unsteady pressures and calculated the generalized aerodynamic forces, eigenvalues, and response amplitudes. The eigenvalues determine the flutter frequency and damping. As a test case, the flutter of a helical fan was calculated with LINFLUX and compared with calculations from TURBO-AE, a nonlinear time domain code, and from ASTROP2, a code based on linear unsteady aerodynamics.

Reddy, T. S. R.↗

Effect of interfacial vibrational coupling on surface wettability and water transport

Here, we report that the atomic-scale vibrational coupling at the solid-fluid interface can substantially alter the interfacial properties such as wettability and fluid slip. The wettability of water droplets on substrates subjected to various vibrational frequencies is studied using molecular dynamics simulation. The contact angle increases (i.e., becomes more hydrophobic) when the oscillation frequency of the substrate matches the intermolecular bending frequency of liquid water. We investigate the underlying mechanism by examining the dynamics of water molecules at the interface and find that the temporal contact between the solid and fluid is shorter when the frequencies match, resulting in weak solid-fluid adsorption. We further report that the vibrational match at the interface reduces wall-fluid friction and enhances water transport through the nanopore. Our findings demonstrate the importance of the atomic-scale vibrational coupling at the solid-fluid interface on the physicochemical behavior of nanodevices and biological nanochannels.

74 ATOMIC AND MOLECULAR PHYSICS↗

Influence of Combined Whole-Body Vibration Plus G-Loading on Visual Performance

Recent engineering analyses of the integrated Ares-Orion stack show that vibration levels for Orion crews have the potential to be much higher than those experienced in Gemini, Apollo, and Shuttle vehicles. Of particular concern to the Constellation Program (CxP) is the 12 Hz thrust oscillation (TO) that the Ares-I rocket develops during the final ~20 seconds preceding first-stage separation, at maximum G-loading. While the structural-dynamic mitigations being considered can assure that vibration due to TO is reduced to below the CxP crew health limit, it remains to be determined how far below this limit vibration must be reduced to enable effective crew performance during launch. Moreover, this "performance" vibration limit will inform the operations concepts (and crew-system interface designs) for this critical phase of flight. While Gemini and Apollo studies provide preliminary guidance, the data supporting the historical limits were obtained using less advanced interface technologies and very different operations concepts. In this study, supported by the Exploration Systems Mission Directorate (ESMD) Human Research Program, we investigated display readability-a fundamental prerequisite for any interaction with electronic crew-vehicle interfaces-while observers were subjected to 12 Hz vibration superimposed on the 3.8 G loading expected for the TO period of ascent. Two age-matched groups of participants (16 general population and 13 Crew Office) performed a numerical display reading task while undergoing sustained 3.8 G loading and whole-body vibration at 0, 0.15, 0.3, 0.5, and 0.7 g in the eyeballs in/out (x-axis) direction. The time-constrained reading task used an Orion-like display with 10- and 14-pt non-proportional sans-serif fonts, and was designed to emulate the visual acquisition and processing essential for crew system monitoring. Compared to the no-vibration baseline, we found no significant effect of vibration at 0.15 and 0.3 g on task error rates (ER) or response times (RT). Significant degradations in both ER and RT, however, were observed at 0.5 and 0.7 g for 10-pt, and at 0.7 g for 14-pt font displays. These objective performance measures were mirrored by participants' subjective ratings. Interestingly, we found that the impact of vibration on ER increased with distance from the center of the display, but only for vertical displacements. Furthermore, no significant ER or RT aftereffects were detected immediately following vibration, regardless of amplitude. Lastly, given that our reading task required no specialized spaceflight expertise, our finding that effects were not statistically distinct between our two groups is not surprising. The results from this empirical study provide initial guidance for evaluating the display readability trade-space between text-font size and vibration amplitude. However, the outcome of this work should be considered preliminary in nature for a number of reasons: 1. The single 12 Hz x-axis vibration employed was based on earlier load-cycle models of the induced TO environment at the end of Ares-I first stage flight. Recent analyses of TO mitigation designs suggest that significant concurrent off-axis vibration may also occur. 2. The shirtsleeve environment in which we tested fails to capture the full kinematic and dynamic complexity of the physical interface between crewmember and the still-to-bematured helmet-suit-seat designs, and the impact these will have for vibration transmission and consequent performance. 3. By examining performance in this reading and number processing task, we are only assessing readability, a first and necessary step that in itself does not directly address the performance of more sophisticated operational tasks such as vehicle-health monitoring or manual control of the vehicle.

readability↗

Sensitivity of Force Specifications to the Errors in Measuring the Interface Force

Force-Limited Random Vibration Testing has been applied in the last several years at NASA/GSFC for various programs at the instrument and system level. Different techniques have been developed over the last few decades to estimate the dynamic forces that the test article under consideration will encounter in the operational environment. Some of these techniques are described in the handbook, NASA-HDBK-7004, and the monograph, NASA-RP-1403. A key element in the ability to perform force-limited testing is multi-component force gauges. This paper will show how some measurement and calibration errors in force gauges are compensated for w en tie force specification is calculated. The resulting notches in the acceleration spectrum, when a random vibration test is performed, are the same as the notches produced during an uncompensated test that has no measurement errors. The paper will also present the results of tests that were used to validate this compensation. Knowing that the force specification can compensate for some measurement errors allows tests to continue after force gauge failures or allows dummy gauges to be used in places that are inaccessible.

Worth, Daniel↗

Sensitivity of Force Specifications to the Errors in Measuring the Interface Force

Force-Limited Random Vibration Testing has been applied in the last several years at the NASA Goddard Space Flight Center (GSFC) and other NASA centers for various programs at the instrument and spacecraft level. Different techniques have been developed over the last few decades to estimate the dynamic forces that the test article under consideration will encounter in the flight environment. Some of these techniques are described in the handbook, NASA-HDBK-7004, and the monograph, NASA-RP-1403. This paper will show the effects of some measurement and calibration errors in force gauges. In some cases, the notches in the acceleration spectrum when a random vibration test is performed with measurement errors are the same as the notches produced during a test that has no measurement errors. The paper will also present the results Of tests that were used to validate this effect. Knowing the effect of measurement errors can allow tests to continue after force gauge failures or allow dummy gauges to be used in places that are inaccessible to a force gage.

Worth, Daniel↗

Competitive Adsorption of Lubricant Base Oil and Ionic Liquid Additives at Air/Liquid and Solid/Liquid Interfaces

Oil-soluble ionic liquids (ILs) have been proved as effective additives in lubricant oils through tribological experiments and post-test analytical analyses. Here, surface structures of lubricant base oil, oil-soluble ILs, and their mixtures at the air/liquid and solid/liquid interfaces have been studied using sum frequency generation (SFG) vibrational spectroscopy. At the air/base oil and air/IL interfaces, the alkyl chains of the studied compounds were shown to be conformationally disordered and their terminal methyl groups point outward at the liquid surface. The base oil dominates the air/(base oil + IL) interface due to its higher surface excess propensity and larger bulk concentration. At the solid (silica) surface, ILs adopt a structure with their charged headgroups in contact with the silica surface, while their alkyl chains are more conformationally ordered or packed compared to the air/IL interface. At the interface between silica and (base oil + IL) mixtures, ILs also preferentially adsorb to the silica surface with their layer structures somewhat different from those of ILs alone. These results showed that ILs can adsorb onto the solid surface even before tribological contacts are made. The insights obtained from this SFG study provide a better understanding of the role of ionic liquids in lubrication.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A New Approach in Force-Limited Vibration Testing of Flight Hardware

The force-limited vibration test approaches discussed in NASA-7004C were developed to reduce overtesting associated with base shake vibration tests of aerospace hardware where the interface responses are excited coherently. This handbook outlines several different methods of specifying the force limits. The rationale for force limiting is based on the disparity between the impedances of typical aerospace mounting structures and the large impedances of vibration test shakers when the interfaces in general are coherently excited. Among these approaches, the semi-empirical method is presently the most widely used method to derive the force limits. The inclusion of the incoherent excitation of the aerospace structures at mounting interfaces has not been accounted for in the past and provides the basis for more realistic force limits for qualifying the hardware using shaker testing. In this paper current methods for defining the force limiting specifications discussed in the NASA handbook are reviewed using data from a series of acoustic and vibration tests. A new approach based on considering the incoherent excitation of the structural mounting interfaces using acoustic test data is also discussed. It is believed that the new approach provides much more realistic force limits that may further remove conservatism inherent in shaker vibration testing not accounted for by methods discussed in the NASA handbook. A discussion on using FEM/BEM analysis to obtain realistic force limits for flight hardware is provided.

force limiting responses↗

Vibration and acoustic environments for payload/cargo integration

Shuttle orbiter launch vibration and acoustic environments for cargo bay/payload interfaces are predicted. Data acquired during Shuttle flight tests are compared with the preflight estimates. Vibration response data for payload attachment locations are presented, along with acoustic data in the form of noise-level spectra measured at various locations in the cargo bay and space averages of the noise levels. It is shown that the payload-bay vibration and acoustic environments are generally less severe than predicted.

Hill, R. E.↗

Determination of physical and chemical states of lubricants in concentrated contacts, part 1

A Fourier emission infrared microspectrometer, set up on a vibration-proof optical table and interfaced to a dedicated minicomputer, was used to record infrared emission spectra from elastohydrodynamic bearing contacts. Its range was extended to cover the entire mid-infrared from 2 to 15 micron. A series of experiments with 5P4E polyphenyl ether showed the existence of a temperature gradient through the lubricant in an ehd contact, which is perpendicular to the flow direction. The experiments also show marked polarization of some of the spectral bands, indicating a molecular alignment. Alignment is less evident at high pressure than at low pressure. To account for this behavior, a model is suggested along the lines developed for the conformational changes observed in long-chain polymers when subjected to increased pressure--to accommodate closer packing, molecules become kinked and curl up. Experiments with a traction fluid showed periodic changes of flow pattern associated with certain spectral changes. These observations will be studied further. A study by infrared attenuated total reflection spectrophotometry was undertaken to determine whether gamma irradiation would change polyethylene wear specimens. The results were negative.

Lauer, J. L.↗