Search NASA⌕ Search

SEARCH · Search NASA

Results for “ion diffusion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3

Friction and Wear Characteristics of Cu-4Al Foil Bearing Coating at 25 and 650 degree C

The friction and wear performance of a Cu-4Al top foil coating has been investigated in Generation I foil air bearings. The copper alloy was applied by a novel deposition technique (ion diffusion) and the journal was coated with PS304, a plasma spray deposited high temperature composite solid lubricant coating. The ion diffusion coating process deposits a desirable smooth layer compared to other methods like cathodic arc deposition. The tribological performance of bearings with and without Cu-4Al foil coatings were evaluated through start-stop tests on an air bearing test rig at 25 and 650 C. The results indicate that the Cu-4Al assists during the initial break-in period, gives more stable friction performance with respect to temperature, and appears to prevent top foil wear at high temperature. The measured load capacity coefficient was 0.5, which was comparable to earlier testing of more advanced design Generation III bearings coated with standard cathodic arc deposited Cu-4Al. However, further studies are needed to determine if deeper penetration of the copper alloy into the foil would help make the transition in friction behavior from contact with the Cu-4Al coated foil to contact with the base foil material more gradual. Also, future work is recommended to assess the performance of ion diffusion coatings with different Cu-based alloy compositions and to investigate the effect the coating has on the elastic modulus of the foil material.

Stanford, Malcolm K.↗

Coupled hydromagnetic wave excitation and ion acceleration upstream of the earth's bow shock

A self-consistent theory is set forth for the excitation of hydromagnetic waves and the acceleration of 'diffuse' ions upstream of the earth's bow shock in the quasi-equilibrium that results when the solar wind velocity and the interplanetary magnetic field are nearly parallel. For the waves, the quasi-equilibrium derives from a balance between excitation by the ions, which stream relative to the solar wind plasma, and convective loss to the magnetosheath. For the diffuse ions, the quasi-equilibrium derives from a balance between injection at the shock front, confinement to the foreshock by pitch angle scattering on the waves, and acceleration by compression at the shock front. It also results from loss to the magnetosheath, loss due to escape upstream of the foreshock, and loss via diffusion perpendicular to the average magnetic field onto field lines that do not connect to the shock front. Diffusion equations describing the ion transport and wave kinetic equations describing the hydromagnetic wave transport are solved self-consistently to give analytical expressions. These describe (1) the differential wave intensity spectrum as a function of frequency and distance from the bow shock and (2) the ion omnidirectional distribution functions and anisotropies as functions of energy and distance from the bow shock.

Lee, M. A.↗

Excitation of compressional waves and the formation of shocklets in the earth's foreshock

Large-amplitude waves in the earth's foreshock are sometimes observed in highly time-developed form, implying that nonlinearities are sufficiently strong to modify their waveforms before the solar wind carries them out of the foreshock. It is presently suggested that parallel propagating waves grow to finite amplitude in the reflected and intermediate ion zones of the earth's foreshock, and refract as they are carried by the solar wind into the 'diffuse' ion region, thereby becoming increasingly oblique and compressional. The time evolution of oblique, low-frequency compressive waves is simulated by means of a one-dimensional hybrid code in which main ions are treated as superparticles, while diffuse ions are seen as a double-adiabatic fluid and electrons as an isothermal fluid.

Hada, T.↗

Two-Scale Ion Meandering Caused by the Polarization Electric Field During Asymmetric Reconnection

Ion velocity distribution functions (VDFs) from a particle-in-cell simulation of asymmetric reconnection are investigated to reveal a two-scale structure of the ion diffusion region (IDR). Ions bouncing in the inner IDR are trapped mainly by the electric field normal to the current sheet (N direction), while those reaching the outer IDR are turned back mainly by the magnetic force. The resulting inner layer VDFs have counter-streaming populations along N with decreasing counter-streaming speeds away from the midplane while maintaining the out-of-plane speed, and the outer layer VDFs exhibit crescent shapes toward the out-of-plane direction. Observations of the above VDF features and the normal electric fields provide evidence for the two-scale meandering motion.

Wang, Shan↗

Dual Ion Spectrometers and Their Calibration for the Fast Plasma Investigation on NASA's Magnetospheric Multiscale Mission

The scientific target of NASA's Magnetospheric Multiscale (MMS) mission is to study the fundamentally important phenomenon of magnetic reconnection. Theoretical models of this process predict a small size, on the order of hundred kilometers, for the ion diffusion region where ions are demagnetized at the dayside magnetopause. This region may typically sweep over the spacecraft at relatively high speeds of 50 km/s, requiring the fast plasma investigation (FPI) instrument suite to have an extremely high time resolution for measurements of the 3D particle distribution functions. As part of the FPI on MMS, the 16 dual ion spectrometers (DIS) will provide fast (150 ms) 3D ion velocity distributions, from 10 to 30,000 eV/q, by combining the measurements from four dual spectrometers on each of four MMS spacecraft. For any multispacecraft mission, the response uniformity among the spectrometer set assumes an enhanced importance. Due to these demanding instrument requirements and the effort of calibrating more than 32 sensors (16 × 2) within a tight schedule, a highly systematic and precise calibration was required for measurement repeatability. To illustrate how this challenge was met, a brief overview of the FPI DIS was presented with a detailed discussion of the calibration method of approach and implementation. Finally, a discussion of DIS performance results, their unit-to-unit variation, and the lessons learned from this calibration effort are presented.

Coffey, V. N.↗

Observations of Electron Vorticity in the Inner Plasma Sheet

From a limited number of observations it appears that vorticity is a common feature in the inner plasma sheet. With the four Cluster spacecraft and the four PEACE instruments positioned in a tetrahedral configuration, for the first time it is possible to directly estimate the electron fluid vorticity in a space plasma. We show examples of electron fluid vorticity from multiple plasma sheet crossings. These include three time periods when Cluster passed through a reconnection ion diffusion region. Enhancements in vorticity are seen in association with each crossing of the ion diffusion region.

Gurgiolo, C.↗

Ion radial diffusion in an electrostatic impulse model for stormtime ring current formation

Guiding-center simulations of stormtime transport of ring-current and radiation-belt ions having first adiabatic invariants mu is approximately greater than 15 MeV/G (E is approximately greater than 165 keV at L is approximately 3) are surprisingly well described (typically within a factor of approximately less than 4) by the quasilinear theory of radial diffusion. This holds even for the case of an individual model storm characterized by substorm-associated impulses in the convection electric field, provided that the actual spectrum of the electric field is incorporated in the quasilinear theory. Correction of the quasilinear diffusion coefficient D(sub LL)(sup ql) for drift-resonance broadening (so as to define D(sub LL)(sup ql)) reduced the typical discrepancy with the diffusion coefficients D(sub LL)(sup sim) deduced from guiding-center simulations of representative-particle trajectories to a factor of approximately 3. The typical discrepancy was reduced to a factor of approximately 1.4 by averaging D(sub LL)(sup sim), D(sub LL)(sup ql), and D(sub LL)(sup rb) over an ensemble of model storms characterized by different (but statistically equivalent) sets of substorm-onset times.

Chen, Margaret W.↗

The Micro‐Macro Coupling of Mass‐Loading in Symmetric Magnetic Reconnection With Cold Ions

We investigate how magnetic reconnection is influenced by an inflow of a dense cold ion population. We compare two 2.5D Particle-In-Cell simulations, one containing the cold population and one without. We find that the cold population influences the reconnection process on both global and kinetic scales, and that the dominant contribution can be explained through mass-loading. We provide an analysis of how these multiscale changes are related through kinetic processes in the ion diffusion region, the so-called micro-macro coupling of mass-loading. The inertia of the cold ion population is found to be the significant link that connects the changes on different scales. The cold and warm populations exhibit counter streaming behavior when and after the ion diffusion region reorganizes itself in response to the arrival of the cold population. This signature of the cold population should be observable by spacecraft observatories such as MMS.

Magnetic reconnection↗

Correlation between the He/H ratios in upstream particle events and in the solar wind

The ratio of helium to proton differential intensities at a fixed energy per charge in the diffuse ion population during long-lived upstream particle events is compared with the simultaneously measured solar wind He/H ratio. It is found that the He/H intensity ratio at about 30 keV in upstream events is highly correlated with and on the average directly proportional to the He/H ratio in the solar wind, and larger than the He/H ratio in the solar wind by an average factor of 1.6. It is concluded that the solar wind is the parent population for the diffuse ions. The He abundance in the diffuse component is on average observed to be larger than in the solar wind. The observations are consistent with the predictions of Fermi acceleration models for a seed particle population drawn from the solar wind with little compositional bias and moderately enhanced in He during the acceleration process.

Ipavich, F. M.↗

Tunable Pseudocapacitive Intercalation of Chloroaluminate Anions into Graphite Electrodes for Rechargeable Aluminum Batteries

Rechargeable aluminum-graphite batteries using chloroaluminate-containing electrolytes have been the focus of significant research, particularly due to their high-rate capabilities. Engineered graphite electrodes have been shown to exhibit supercapacitor-like rate performance, despite the fact they store charge via the electrochemical intercalation of polyatomic AlCl4− anions. However, the origins of such rate capabilities are not well understood. Here, using electrochemical techniques, we disentangle quantitatively the diffusion-limited Faradaic, pseudocapacitive, and capacitive contributions to charge storage, revealing that AlCl4− anions intercalate into graphite with significant pseudocapacitive characteristics due to low ion diffusion limitations. Pristine and mildly exfoliated graphites are compared, where exfoliation resulted in significantly higher pseudocapacitive AlCl4− intercalation at the highest potential redox pair as well as higher galvanostatic capacity retention at faster discharge rates. The relationships between graphite structure, ion mass transport, and the overall rate of electrochemical AlCl4− intercalation are discussed. Ion diffusion within the electrolyte phase of the porous electrode is shown to play a key role in controlling the rate of intercalation at higher potentials and faster rates, which can be enhanced by reducing electrode tortuosity. The results establish that chloroaluminate anion intercalation into graphite exhibits non-diffusion-limited pseudocapacitive contributions that are tunable by modifying the graphite structure.

Jeffrey H. Xu↗

Observations of two distinct populations of bow shock ions in the upstream solar wind

Observations upstream of the earth's bow shock with the LASL/MPI fast plasma experiments on ISEE 1 and 2 reveal the presence of two distinct and mutually exclusive populations of low energy (no more than 40 keV) ions apparently accelerated at the bow shock. The first of these, the 'reflected' population, is characterized by (1) sharply peaked spectra seldom extending much above about 10 keV/ion and (2) relatively collimated flow coming from the direction of the shock. On the other hand, the 'diffuse' ions are distinguished by relatively flat energy spectra above about 10 keV and broad angular distributions. They are by far the most commonly observed upstream ion event. A close causal association is suggested between the diffuse ion population in the upstream solar wind and energetic plasma ions observed within the magnetosheath.

Gosling, J. T.↗

On the cross-field diffusion of ions in one- and two-dimensional hybrid simulations of collisionless shocks

It can be demonstrated analytically that under certain geometries used in numerical simulations of collisionless shocks in which there is at least one ignorable spatial coordinate, the transport of particles across the magnetic field is essentially zero. This notion is tested using one- and two-dimensional hybrid simulations (kinetic ions/fluid electrons). We find, as the theorem predicts, the particles treated kinetically are tied to the same field line on which they start.

Giacalone, Joe↗

A one-dimensional model of the atmospheric electric field near the Venusian surface

A one-dimensional model is developed for the development of an electric field below the Venus cloud layer, assuming an absence of cloud-to-ground lightning. The ion-bearing medium is considered as a collision dominated, partially ionized gas. Ion production by cosmic rays is accompanied by a sink of recombining positive and negative ions. The net diffusion of ions to the surface was examined, and modeled as resulting from differences between the ion diffusivities and electrical activity within the clouds. Calculations were made of the conduction and diffusion currents profiles, positive and negative ion densities, and the net space charge. Higher positive ion diffusivity was found to enhance the surface positive charge, producing an electric field which depended on the boundary layer mixing. Charge separation in the clouds also produces an electric field. Assuming a fair weather conduction current similar to earth leads to an electric field of 5 kV/sq m at the surface, with continuity to a few kilometers altitude.

Tzur, I.↗

Monte Carlo simulation of charged particles upstream of the earth's bow shock

A simple model of the earth's bow shock is presented and compared with ISEE-1 observations of diffuse ions upstream of the shock. Ion behavior is modeled in a test particle simulation using Monte Carlo techniques for a plane parallel shock at which cold solar wind ions are heated sufficiently to allow diffusion back upstream. Fitting of the model to the observations indicates that the diffusion coefficient must increase faster than linearly with velocity, and provides an upper limit to the acceleration efficiency defined as the proportion of incoming solar wind ions accelerated and observed upstream. Results suggest that astrophysical shocks are capable of accelerating ions directly from the thermal plasma without the need for a distinct preenergizing injection stage.

Ellison, D. C.↗

Nonneutral and quasi-neutral diffusion of weakly ionized multiconstituent plasma

A theory is developed for quasi-neutral and nonneutral ambipolar diffusion in a weakly ionized multiconstituent plasma. Magnetic field effects are disregarded. The effects of negative ions and various positive and negative ion diffusion coefficients are identified. It is found that the presence of negative ions leads to enhanced electron diffusion and a retarded diffusion of positive ions. In some cases electrons may be forcibly propelled from the area of perturbations in ionic concentrations. The ambipolar electric field is observed to cause negative ions to flow in a countergradient fashion where the gradient is small. Electrons tend toward a more homogeneous spatial distribution in the nonneutral case than in the quasi-neutral case.

Hill, R. J.↗

Electrochemical cell for obtaining oxygen from carbon dioxide atmospheres

For manned missions to Mars to become a reality, an efficient and reliable means of obtaining oxygen from the carbon dioxide-rich atmosphere will be required. Otherwise, the high cost of transporting the oxygen needed to sustain the astronauts will severely restrict the expedition to the martian surface. Recently, the use of electrochemical devices has been explored as a means of obtaining oxygen from the carbon dioxide-rich atmosphere. In these devices, oxygen ions diffuse through solid oxide membranes, thus, separating oxygen from the other gases presented. This phenomenon has only recently been explored as a means of obtaining large quantities of oxygen from toxic atmospheres, although first observed by Walter nernst in 1899. Nernst observed that stabilized zirconia will conduct oxygen ions when an electrical potential is applied across metallic electrodes applied to the ceramic membrane. Diatomic oxygen molecules are dissociated at the positive electrode/electrolyte interface. The oxygen ions enter the ceramic body due to the ion density gradient which is produced by the electrical potential across the electrolytic membrane. Once the ions have diffused through the membrane, they reform diatomic oxygen molecules at the anode. The separation of oxygen from carbon dioxide is achieved by the combination of thermal and electrochemical processes. The thermal decomposition of carbon dioxide (at 1000 C) results in the production of carbon monoxide and oxygen by the reaction.

Hooker, M. W.↗

VLF waves in the foreshock

Plasma waves observed in the VLF range upstream of planetary bow shocks not only modify the particle distributions, but also provide important information about the acceleration processes that occur at the bow shock. Electron plasma oscillations observed near the tangent field line in the electron foreshock are generated by electrons reflected at the bow shock through a process that has been referred to as Fast Fermi acceleration. Fast Fermi acceleration is the same as shock-drift acceleration, which is one of the mechanisms by which ions are energized at the shock. We have generated maps of the VLF emissions upstream of the Venus bow shock, using these maps to infer properties of the shock energization processes. We find that the plasma oscillations extend along the field line up to a distance that appears to be controlled by the shock scale size, implying that shock curvature restricsts the flux and energy of reflected electrons. We also find that the ion acoustic waves are observed in the ion foreshock, but at Venus these emissions are not detected near the ULF forshock boundary. Through analogy with terrestrial ion observations, this implies that the ion acoustic waves are not generated by ion beams, but are instead generated by diffuse ion distributions found deep within the ion foreshock. However, since the shock is much smaller at Venus, and there is no magnetosphere, we might expect ion distributions within the ion foreshock to be different than at the Earth. Mapping studies of the terrestrial foreshock similar to those carried out at Venus appear to be necessary to determine if the inferences drawn from Venus data are applicable to other foreshocks.

Strangeway, R. J.↗