A lamellar grating for use with infrared spectrophotometers
Far IR spectrophotometry improvement with lamellar grating, describing construction, alignment and performance
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Far IR spectrophotometry improvement with lamellar grating, describing construction, alignment and performance
Van der Walls bound lamellar solids interlayer binding energy computational model, discussing talc and pyrophyllite equilibrium stacking arrangements and force constants
Mechanical property characterization tests of a directionally solidified Ni-20 percent Cb-2.5 percent Al-6 percent Cr cellular eutectic turbine blade alloy demonstrated excellent long time creep stability and indicated intermediate temperature transverse tensile ductility and shear strength to be somewhat low for turbine blade applications. Alloy and structural optimization significantly improves these off-axis properties with no loss of longitudinal creep strength or stability. The optimized alloy-structure combination is a carbon modified Ni-20.1 percent Cb-2.5 percent Al-6.0 percent Cr-0.06 percent C composition processed under conditions producing plane front solidification and a fully-lamellar microstructure. With current processing technology, this alloy exhibits a creep-rupture advantage of 39 C over the best available nickel base superalloy, directionally solidified MAR M200+ Hf. While improved by about 20 percent, shear strength of the optimized alloy remains well below typical superalloy values.
A lamellar grating has been developed to be used for very far infrared observations on the airborne observatory. The design characteristics and performance during laboratory testing and initial observations of Jupiter at wavelengths between 50 and 500 microns are presented.
A rigorous modal analysis of lamellar grating, i.e., gratings having rectangular grooves, in conical mountings is presented. It is an extension of the analysis of Botten et al. which considered non-conical mountings. A key step in the extension is a decomposition of the electromagnetic field in the grating region into two orthogonal components. A computer program implementing this extended modal analysis is capable of dealing with plane wave diffraction by dielectric and metallic gratings with deep grooves, at arbitrary angles of incidence, and having arbitrary incident polarizations. Some numerical examples are included.
The olivine-rich Divnoe achondrite contains numerous large olivine grains which have a lamellar or banded appearance in back-scattered electron images, caused by minor compositional differences. One such grain, viewed in transmitted light, displays a system of lamellae with the same orientation and scale as the compositional banding. The only process known to produce such structure and chemical variability in olivine grains is high-pressure transformations between alpha-, beta- and gamma-olivines, but in other meteorites and in experimental products the structure is approximately 100 times finer than the Divnoe lamella.
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Colloidal self-assembly is one strategy for engineering anisotropic properties into otherwise isotropic materials. In this work, we demonstrate anisotropic exciton transport in an A 2 B-type superlattice containing columns of 5.3 nm CsPbBr 3 nanocubes assembled into a hexagonal lattice around 6.5 nm LaF 3 nanodisks. Using transient photoluminescence microscopy, we determined that the exciton diffusivity along the fast axis of the superlattice is more than twice as large as that along the slow axis at T = 5 K, but that anisotropy is greatly suppressed at room temperature. Calculations of the diffusivity anisotropy ratio based on Förster theory overestimate the measured values, highlighting the limitations of this theory in completely describing exciton transport. Overall, our results demonstrate how self-assembly of colloidal nanocrystals can be used to engineer directional energy transport, and raise more questions about the microscopic nature of dipole coupling in CsPbBr 3 NC superlattices.
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Recently, significant interest has arisen on the impact of dynamical ion correlations on the conductivity and transport properties of polymeric electrolyte materials. It has been hypothesized that confining ion motion to narrow channels may reduce such ion correlations and enhance the resulting ionic conductivity. Motivated by such considerations, in this study we used a multiscale simulation framework to study the dynamical ion correlations in the microphase-separated lamella phase of block copolymeric ionic liquids and compare with the corresponding results for homopolymeric systems. We probed the influence of ion correlations through the partial ionicity, Δ, which quantifies the ratio of true conductivity to the ideal, Nernst–Einstein conductivity for the anion-related contributions. Consistent with our original hypothesis, our results demonstrate that the partial ionicity relating to the mobile anions is much larger in the lamella phases of block copolymers compared to that in homopolymers. Analysis of the distinct conductivity contributions demonstrates that such results arise as a result of an intricate compensation among the nonideal dynamical correlations relating to anions in lamella phases. Overall, our results suggest that self-assembled phases of block copolymers may provide an avenue to tune the dynamical ion correlations in polymer electrolyte systems.