Effect of Plasma Temperature on Major Element Prediction Accuracy From Laser‐Induced Breakdown Spectroscopy
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K. H. Lepore↗
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Enhanced line emission from laser-produced plasmas
This communication reports the first systematic study on background gas-induced spectral-line-emission enhancement from laser-produced plasmas. Line emission from aluminum plasmas was enhanced by factors of up to 35 by the introduction of He, Ne, Xe, or N2. The enhancement has been attributed to three-body recombination.
Timmer, C.↗
Developement of the Potassium-Argon Laser Experiment (KArLE) for In Situ Geochronology
Absolute dating of planetary samples is an essential tool to establish the chronology of geological events, including crystallization history, magmatic evolution, and alteration. Thus far, radiometric geochronology of planetary samples has only been accomplishable in terrestrial laboratories on samples from dedicated sample return missions and meteorites. In situ instruments to measure rock ages have been proposed, but none have yet reached TRL 6, because isotopic measurements with sufficient resolution are challenging. We have begun work under the NASA Planetary Instrument Definition and Development Program (PIDDP) to develop the Potassium (K) - Argon Laser Experiment (KArLE), a novel combination of several flight-proven components that will enable accurate KAr isochron dating of planetary rocks. KArLE will ablate a rock sample, measure the K in the plasma state using laser-induced breakdown spectroscopy (LIBS), measure the liberated Ar using quadrupole mass spectrometry (QMS), and relate the two by measuring the volume of the abated pit using a optical methods such as a vertical scanning interferometer (VSI). Our preliminary work indicates that the KArLE instrument will be capable of determining the age of several kinds of planetary samples to 100 Myr, sufficient to address a wide range of geochronology problems in planetary science. Additional benefits derive from the fact that each KArLE component achieves analyses common to most planetary surface missions.
Cohen, Barbara A.↗
Development of the Potassium-Argon Laser Experiment (KArLE) Instrument for In Situ Geochronology
Absolute dating of planetary samples is an essential tool to establish the chronology of geological events, including crystallization history, magmatic evolution, and alteration. Traditionally, geochronology has only been accomplishable on samples from dedicated sample return missions or meteorites. The capability for in situ geochronology is highly desired, because it will allow one-way planetary missions to perform dating of large numbers of samples. The success of an in situ geochronology package will not only yield data on absolute ages, but can also complement sample return missions by identifying the most interesting rocks to cache and/or return to Earth. In situ dating instruments have been proposed, but none have yet reached TRL 6 because the required high-resolution isotopic measurements are very challenging. Our team is now addressing this challenge by developing the Potassium (K) - Argon Laser Experiment (KArLE) under the NASA Planetary Instrument Definition and Development Program (PIDDP), building on previous work to develop a K-Ar in situ instrument [1]. KArLE uses a combination of several flight-proven components that enable accurate K-Ar isochron dating of planetary rocks. KArLE will ablate a rock sample, determine the K in the plasma state using laser-induced breakdown spectroscopy (LIBS), measure the liberated Ar using quadrupole mass spectrometry (QMS), and relate the two by the volume of the ablated pit using an optical method such as a vertical scanning interferometer (VSI). Our preliminary work indicates that the KArLE instrument will be capable of determining the age of several kinds of planetary samples to +/-100 Myr, sufficient to address a wide range of geochronology problems in planetary science.
Cohen, Barbara A.↗
Update on Development of the Potassium-Argon Laser Experiment (KArLE) Instrument for In Situ Geochronology
Absolute dating of planetary samples is an essential tool to establish the chronology of geological events, including crystallization history, magmatic evolution, and alteration. We are addressing this challenge by developing the Potassium (K) -- Argon Laser Experiment (KArLE), building on previous work to develop a K-Ar in situ instrument. KArLE ablates a rock sample, determines the K in the plasma state using laser-induced breakdown spectroscopy (LIBS), measures the liberated Ar using quadrupole mass spectrometry (QMS), and relates the two by the volume of the ablated pit using laser confocal microscopy (LCM). Our goal is for the KArLE instrument to be capable of determining the age of several kinds of planetary samples to address a wide range of geochronolgy problems in planetary science.
Cohen, Barbara A.↗
The Potassium-Argon Laser Experiment (KARLE): In Situ Geochronology for Planetary Robotic Missions
Isotopic dating is an essential tool to establish an absolute chronology for geological events, including crystallization history, magmatic evolution, and alteration events. The capability for in situ geochronology will open up the ability for geochronology to be accomplished as part of lander or rover complement, on multiple samples rather than just those returned. An in situ geochronology package can also complement sample return missions by identifying the most interesting rocks to cache or return to Earth. The K-Ar Laser Experiment (KArLE) brings together a novel combination of several flight-proven components to provide precise measurements of potassium (K) and argon (Ar) that will enable accurate isochron dating of planetary rocks. KArLE will ablate a rock sample, measure the K in the plasma state using laser-induced breakdown spectroscopy (LIBS), measure the liberated Ar using mass spectrometry (MS), and relate the two by measuring the volume of the ablated pit by optical imaging. Our work indicates that the KArLE instrument is capable of determining the age of planetary samples with sufficient accuracy to address a wide range of geochronology problems in planetary science. Additional benefits derive from the fact that each KArLE component achieves analyses useful for most planetary surface missions.
Cohen, B. A.↗
The Side Plume of Magnetically Shielded Hall Thrusters
A combination of near-thruster laser-induced fluorescence and far-field plasma probe measurements collected from two magnetically shielded Hall thrusters have shown that there exist an independent ion population of medium-energy (on average, 60-190 eV) exiting out the side (60° to 100° from firing axis) of the thrusters. Studying the trends with background pressure and known discrepancies between the laser-induced fluorescence and far-field plasma probe data suggest that at zero pressure the side plume is likely to exhibit higher energy and lower density than at facility background pressures. The possibility that these ions were produced by the modified two-stream instability is explored and while the agreement is good, there are areas of notable disagreement. Based on the idea that production of the side plume and channel exit striations are due to the same plasma wave actions, a theory was explored that explains why striations form under certain circumstances but not others. Another theory, based on the idea that side plume production only occurs over certain portion of the global discharge oscillation cycle, was also explored and areas of disagreement were identified. While the exact mechanism for side plume acceleration remains unclear, if the theory behind side plume production is correct, then side plume can be expected to be present in a wide range of magnetically-shielded as well as non-shielded Hall thrusters.
Hall thruster↗
The Side Plume of Magnetically Shielded Hall Thrusters
A combination of near-thruster laser-induced fluorescence and far-field plasma probe measurements collected from two magnetically shielded Hall thrusters have shown that there exist an independent ion population of medium-energy (on average, 60-190 eV) exiting out the side (60° to 100° from firing axis) of the thrusters. Studying the trends with background pressure and known discrepancies between the laser-induced fluorescence and far-field plasma probe data suggest that at zero pressure the side plume is likely to exhibit higher energy and lower density than at facility background pressures. The possibility that these ions were produced by the modified two-stream instability is explored and while the agreement is good, there are areas of notable disagreement. Based on the idea that production of the side plume and channel exit striations are due to the same plasma wave actions, a theory was explored that explains why striations form under certain circumstances but not others. Another theory, based on the idea that side plume production only occurs over certain portion of the global discharge oscillation cycle, was also explored and areas of disagreement were identified. While the exact mechanism for side plume acceleration remains unclear, if the theory behind side plume production is correct, then side plume can be expected to be present in a wide range of magnetically-shielded as well as non-shielded Hall thrusters.
Electric propulsion↗
Downhole Elemental Analysis with LIBS
In this paper we discuss a novel instrument, currently under development at Honeybee Robotics with SBIR funding from NASA. The device is designed to characterize elemental composition as a function of depth in non-terrestrial geological formations. The instrument consists of a miniaturized laser-induced breakdown spectrometer (LIBS) analyzer integrated in a 2" diameter drill string. While the drill provides subsurface access, the LIBS analyzer provides information on the elemental composition of the borehole wall. This instrument has a variety of space applications ranging from exploration of the Moon for which it was originally designed, to Mars, as well as a variety of terrestrial applications. Subsurface analysis is usually performed by sample acquisition through a drill or excavator, followed by sample preparation and subsequent sample presentation to an instrument or suite of instruments. An alternative approach consisting in bringing a miniaturized version of the instrument to the sample has many advantages over the traditional methodology, as it allows faster response, reduced probability of cross-contamination and a simplification in the sampling mechanisms. LIBS functions by focusing a high energy laser on a material inducing a plasma consisting of a small fraction of the material under analysis. Optical emission from the plasma, analyzed by a spectrometer, can be used to determine elemental composition. A triangulation sensor located in the sensor head determines the distance of the sensor from the borehole wall. An actuator modifies the position of the sensor accordingly, in order to compensate for changes due to the profile of the borehole walls. This is necessary because LIBS measurements are negatively affected by changes in the relative position of the focus of the laser with respect to the position of the sample (commonly referred to as the "lens to sample distance"). Profiling the borehole is done by adjusting the position of the sensor with a vertical stage; a second actuator at the top of the downhole probe allows radial scanning of the borehole. Analysis of iron and titanium in lunar simulant with LIBS was performed in air using the method of standard addition. The results for lunar simulant NU-LHT-2M show a value for the concentration of iron ranging between 2.29% and 3.05% depending on the atomic line selected. The accepted value for the sample analyzed is 2.83%, showing the capability for the system in development to provide qualitative and semi-quantitative analysis in real-time.
Moreschini, Paolo↗
Study of Laser Frequency Stability and Spectral Purity Semiannual Status Report, 1 Mar. - 31 Aug. 1968
Quantum phase noise and plasma-induced phase noise in He-Ne lasers
Siegman, A. E.↗
Optimization of the Magnetic Field Topology in the Hall Effect Rocket with Magnetic Shielding
NASA's Hall Effect Rocket with Magnetic Shielding (HERMeS) 12.5 kilowatt Technology Demonstration Unit-1 (TDU-1) has been the subject of extensive technology maturation in preparation for flight system development. The TDU-1 thruster implements a magnetically shielded field topology and has demonstrated the elimination of the discharge channel erosion. Extensive wear testing of the TDU Hall thrusters has identified the thruster front pole covers as the next life limiting component. This effort aims to explore and investigate alternate magnetic field topologies to assess whether reductions in the front pole cover erosion can be attained while still maintaining very low erosion rates on the discharge channel walls. NASA GRC (Glenn Research Center) and JPL (Jet Propulsion Laboratory) have begun a magnetic field topology characterization and optimization study by designing four candidate magnetic field topologies that reduce the effectiveness of the shielding along the discharge channel walls with the intent to also reduce the erosion rates along the pole covers. Three of the four candidate magnetic field topologies have been manufactured subjected to an extensive test campaign that includes performance, plume, and stability characterization. In the Phase I test segment, the thruster's oscillation magnitude and laser-induced fluorescence (LIF) measurements of the plasma plume were performed for the three candidate topologies. In Phase I, the thruster's oscillation magnitude and LIF measurements were performed for the three candidate topologies. Phase I test results found that the B1 configuration attained lower oscillation levels than the baseline topology (B0). Additionally, laser induced fluorescence measurements along the discharge chamber centerline found that upstream retraction of the thruster’s peak magnetic field does result in an upstream shift of the acceleration zone but the magnitude of the shift does not correspond one-to-one to the shift in the location of the peak radial magnetic field magnitude. Phase II test segment will include performing performance, stability, plume, and erosion measurements for the various candidate magnetic field topologies..
Kamhawi, Hani↗
Numerical investigations of background pressure effects and channel erosion in the SPT-140 Hall thruster for the Psyche mission
Four SPT-140 Hall thrusters are the main components of the electric propulsion system for the Psyche mission. We employ the 2-D (r-z) code Hall2De to conduct numerical simulations of the SPT-140 with the goal of estimating erosion of the acceleration channel rings for the Psyche mission profile. The simulations are informed by direct measurements of the plasma conditions in the acceleration channel that were obtained using laser-induced fluorescence. We validate our simulation results with additional plasma measurements, wear test erosion rates, and performance data as a function of background pressure. We then make use of a series of numerical simulations to compute the progressive erosion of the channel walls, using as input parameters a profile for the Psyche mission that includes operation at 4.5, 2.5 and 1.0 kW with duration of all segments increased by a 50% margin. We find that the channel walls are not completely eroded at the end of the mission (plus 50% margin). We also observe a progressive decrease in thrust as the channel walls erode that is consistent with the wear test and flight data, with a rate of ~4.5 mN/kh for the first 2,500 h and constant thrust after that. The reasons for these thrust trends are explained.
Lenguito, Giovanni↗
High resolution X-ray optics for astronomical and laboratory sources
In recent years X-ray telescopes have been used successfully for high resolution observations of astronomical objects, in particular the solar corona. At the present time X-ray microscopes are being developed for diagnostics of laser and electron beam induced fusion plasmas. This paper describes both types of imaging systems using as examples the AS&E X-ray telescope on Skylab and a 10X microscope being built for Los Alamos Scientific Laboratories. The designs, manufacturing tolerances, fabrication, testing, and performance are discussed. Steps for further development in both imaging areas are identified.
Silk, J. K.↗
Spectral line shapes. Volume 4 - Proceedings of the Eighth International Conference, College of William and Mary, Williamsburg, VA, June 9-13, 1986
The present conference discusses topics in line broadening and shift phenomena in low-to-moderately dense plasmas, resonances in the continuum, hot and dense laser-produced plasmas, collisional broadening and intermolecular potentials, molecular broadening and collision-induced spectroscopy, collisional redistribution and laser-assisted collision processes, coherent and nonlinear spectroscopy, astrophysical line-shapes, and short-wavelength lasers. Attention is given to the widths and shifts of Be ion lines, the Stark broadening of Xe II and Fe I lines, perturbed and unperturbed series in the line-shapes of autoionizing Rydberg series, the line-broadening of hydrogenic ions in dense plasmas, Doppler-free line-shapes, the Franck-Condon principle, the dynamics of laser-assisted reactive collisions, the gas-kinetic effects of light, collision-induced processes in nonlinear optics, and line-shaping phenomena in cool stars.
Exton, Reginald J.↗
Ultrafast Modulation and Switching of Quantum-Well Lasers using Terahertz Fields
Modulation and switching of semiconductor lasers are important for laser-based information technology. Typically the speed of modulation and switching is limited by interband processes such as stimulated and spontaneous recombinations which occur on a nanosecond time scale. This is why the diode laser modulation has been restricted to tens of GHz. Modulation at higher speed is highly desirable as the information technology enters into the so-called tera-era. In this paper, we study the possibility of utilizing THz-field-induced plasma heating to modulate quantum-well lasers. This is a timely study since, with the advancement of THz solid-state sources and free-electron lasers, THz physics and related technology is currently coming out of its infancy. The investigation of interplaying THz and optical fields is also of intruiging fundamental interest. First, we introduce theoretical plasma heating results for the quantum-well optical amplifier in the presense of an intense half-cycle THz pulse. The heated carrier distributions are then utilized to calculate the THz-pulse-induced change in refractive index and gain profile. Since the electron-hole-plasma is heated using intraband transitions, we circumvent the usual complications due to an overall change in density, and the nonlinear recovery is governed solely by the carrier-LO-phonon interactions, typically 5 ps for a complete recovery. This procedure implies THz and sub-THz switching and recovery rates, respectively; using either gain modulation or index modulation. Plasma heating via steady-state THz fields is also studied. Finally, numerical simulation of a coupled set of equations to investigate the THz modulation based on a simplified model for quantum-well lasers is presented. Our results show that a semiconductor laser can be modulated at up to 1 THz with little distortion with a THz field amplitude at the order of a few kV/cm. Laser responses to a change in THz frequency will be shown. Constraints, practicalities, and applications will be discussed.
Ning, Cun-Zheng↗
Stationary Plasma Thruster Ion Velocity Distribution
A nonintrusive velocity diagnostic based on laser induced fluorescence of the 5d4F(5/2)-6p4D(5/2) singly ionized xenon transition was used to interrogate the exhaust of a 1.5 kW Stationary Plasma Thruster (SPT). A detailed map of plume velocity vectors was obtained using a simplified, cost-effective, nonintrusive, semiconductor laser based scheme. Circumferential velocities on the order of 250 m/s were measured which implied induced momentum torques of approximately 5 x 10(exp -2) N-cm. Axial and radial velocities were evaluated one mm downstream of the cathode at several locations across the width of the annular acceleration channel. Radial velocities varied linearly with radial distance. A maximum radial velocity of 7500 m/s was measured 8 mm from the center of the channel. Axial velocities as large as 16,500 m/s were measured.
Manzella, David H.↗
Recommended Practices in Laser-Induced Fluorescence (LIF) Diagnostics for Electric Propulsion
Laser-induced fluorescence (LIF) spectroscopy uses Doppler-shifted laser photons to excite a bound electron transition in an atom or ion, with subsequent fluorescence emission detected in order to measure the local velocity distribution function (VDF) and/or particle density. Due to its non-invasive nature, high spatial resolution, and acceptable difficulty of implementation, LIF has become a favored diagnostic for electric propulsion (EP) plasmas, particularly in the study of Hall thrusters. This paper presents recommended best practices for LIF measurements in electric thrusters, drawn from over three decades of implementation heritage in the EP community. Focusing on both single-photon LIF (typically used to measure VDFs) and two-photon LIF (TALIF, typically used to determine densities), the paper covers selection of atomic transitions to target, experimental setups, and interpretation of data. A number of special topics and advanced applications are discussed, including uncertainty analysis, techniques for high-speed measurements, and applications to a variety of propellants.
plasma plume↗
Diamond films for laser hardening
Laser-damage experiments were performed on free-standing polycrystalline diamond films prepared by plasma-enhanced CVD. The high laser-induced stress resistance found for this material makes it useful for thin-film coatings for laser optics. Results for diamond-coated silicon substrates demonstrate the enhanced damage threshold imparted by diamond thin-film coatings to materials susceptible to laser damage.
Albin, S.↗