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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Analysis of liquid metal embrittlement from a bond energy viewpoint

Absorption induced embrittlement of solid metals by certain liquid metals is analyzed through an Engel-Brewer calculation of the solid-liquid interaction energy, and of the effect of the latter in reducing fracture surface energy. The reduction in fracture surface energy is estimated by comparison of the electronic contribution to the solid-liquid interaction energy with solid-solid bond energy for some 40 liquid-solid couples. Regular solution theory is used to estimate mutual solubility as the relative difference in parameter values. Embrittlement can be predicted by using reduction in fracture surface energy and solubility parameter difference as critical variables. The effect of solute additions to the liquid on the degree of embrittlement is interpreted via the same two variables; the principal effect of solutes is to modify solubility relationships at the solid-liquid interface.

Kelley, M. J.↗

Solute diffusion in liquid metals

A gas model of diffusion in liquid metals is presented. In this model, ions of liquid metals are assumed to behave like the molecules in a dense gas. Diffusion coefficient of solute is discussed with reference to its mass, ionic size, and pair potential. The model is applied to the case of solute diffusion in liquid silver. An attempt was made to predict diffusion coefficients of solutes with reasonable accuracy.

Bhat, B. N.↗

Liquid metal cooled reactors for space power applications

The technology basis for evaluation of liquid metal cooled space reactors is summarized. Requirements for space nuclear power which are relevant to selection of the reactor subsystem are then reviewed. The attributes of liquid metal cooled reactors are considered in relation to these requirements in the areas of liquid metal properties, neutron spectrum characteristics, and fuel form. Key features of typical reactor designs are illustrated. It is concluded that liquid metal cooled fast spectrum reactors provide a high confidence, flexible option for meeting requirements for SP-100 and beyond.

Bailey, S.↗

On the Shape of Liquid Metal Droplets in Electromagnetic Levitation Experiments

We present calculations and measurements on the shape of liquid metal droplets in electromagnetic levitation experiments. A normal stress balance model was developed to predict the shapes of liquid metal droplets that will be obtained in a microgravity experiment to measure the viscosity and surface tension of undercooled metals. This model was tested by calculating the droplet shapes in containerless experiments conducted to determine the surface tension of liquid metals. Inconsistencies associated with the results of a previous paper are elucidated. The computational results of the mathematical model are compared with the results of ground-based experiments for two different metals. The importance of the ratio of electromagnetic skin depth-to-droplet radius to the accuracy of the mathematical model is discussed. A planned alternate approach to modeling the shape by consideration of the entire droplet rather than only the surface is presented. As an example of an application. the influence of the shape on the splitting of the surface oscillation modes of levitated liquid metal droplets is discussed.

Schwartz, E.↗

Liquid-metal-fed Pulsed Plasma Thrusters for In-space Propulsion

Liquid metal propellants may provide a path toward more reliable and efficient pulsed plasma thrusters (PPTs). Conceptual thruster designs which eliminate the need for high current switches and propellant metering valves are described. Propellant loading techniques are suggested that show promise to increase thruster propellant utilization, dynamic, and electrical efficiency. Calibration results from a compact, electromagnetically-pumped propellant feed system are presented. Results for lithium and gallium propellants show capability to meter propellant at flow rates up to 10 +/- 0.1 mg/s. Experiments investigating the initiation of arc discharges using liquid metal droplets are presented. High speed photography and laser interferometry provide spatially and temporally resolved information on the decomposition of liquid metal droplets , and the evolution of the accelerating current channel.

Markusic, Thomas E.↗

A Full-Induction Magnetohydrodynamics Solver for Liquid Metal Fusion Blankets in Vertex-CFD

Multiphysics modeling of liquid metal fusion blankets, which produce tritium and convert energy of neutrons created via fusion reactions into heat, is crucial for predicting performance, ensuring structural integrity, and optimizing energy production. While traditional blanket modeling of liquid metal flows during normal steady operating conditions commonly employs the inductionless approximation of the magnetohydrodynamics (MHD) equations, transient scenarios, when the plasma-confining magnetic field varies on millisecond time scales, require a full-induction MHD approach that dynamically evolves the magnetic field via the time-dependent induction equation. This paper presents the formulation, implementation, and initial verification of a full-induction MHD solver integrated within the open-source Vertex-CFD framework, which aims to achieve tight multiphysics coupling, a flexible software design enabling easy extension and addition of physics models, and performance portability across computing platforms. The solver utilizes finite element spatial discretization, implicit Runge–Kutta time integration, and an inexact Newton method to solve the resulting discrete nonlinear system, leveraging Trilinos packages for efficient computation. Verification against selected benchmark problems demonstrates accuracy and robustness of the solver. Furthermore, when the solver is applied to an idealized blanket model in 2.5D and full 3D, results obtained with Vertex-CFD are in good agreement with recently published quasi-2D simulations. These findings establish a computational foundation for future simulations of transient MHD phenomena in liquid metal blankets with Vertex-CFD, and open avenues for future extensions and performance optimizations.

Endeve, Eirik [ORNL] (ORCID:0000000312519507)↗

Low Melting Temperature Gallium–Indium Liquid Metal Anode for Solid-State Li-Ion Batteries

Solid-state Li-ion batteries are attracting attention for their enhanced safety features, higher energy density, and broader operational temperature range compared to systems based on liquid electrolytes. However, current solid-state Li-ion batteries face performance challenges, such as suboptimal cycling and poor rate capabilities, often due to inadequate interfacial contact between the solid electrolyte and electrodes. To address this issue, we incorporated a gallium–indium (Ga–In) liquid metal as the anode in a solid-state Li-ion battery setup, employing Li 6 PS 5 Cl as the solid electrolyte. Operating at room temperature, this configuration achieved an initial capacity of 389 mAh g –1 and maintained 88% of this capacity after 30 cycles at a 0.05 C rate. It also demonstrated a capacity retention of 66% after 500 cycles at a 0.5 C rate. In comparison to solid anode materials, such as tin, the Ga–In liquid metal exhibited superior cycling stability and rate capacity, which is due to the self-healing and fluid properties of the alloy that ensure stable interfacial contact with solid electrolytes. In situ X-ray diffraction (XRD) and ex situ scanning electron microscope (SEM) analyses revealed that indium does not directly participate in the lithiation/delithiation process. Instead, it helps maintain the alloy’s low melting point, facilitating its return to a liquid state after delithiation. In a comparative analysis of stack pressure during cycling in cells utilizing Ga–In liquid metal and tin, the Ga–In liquid metal cell demonstrated an ability to buffer pressure increases associated with deformation. In conclusion, these findings suggest a promising approach for enhancing solid-state batteries by integrating liquid metal anodes, which improve interfacial contact and stability.

Alloys↗

Benchmarking Surface Tension Measurement Method using two Oscillation Modes in Levitated Liquid Metals

The Faraday forcing method in levitated liquid droplets has recently been introduced as a method for measuring surface tension using resonance. By subjecting an electrostatically-levitated liquid metal droplet to a continuous, oscillatory, electric field, at a frequency nearing that of the droplet’s first principal mode of oscillation (known as mode 2), the method was previously shown to determine surface tension of materials that would be particularly difficult to process by other means, e.g. liquid metals and alloys. It also offers distinct advantages in future work involving high viscosity samples because of the continuous forcing approach. This work presents 1) a benchmarking experimental method to measure surface tension by excitation of the second principal mode of oscillation (known as mode 3) in a levitated liquid droplet and 2) a more rigorous quantification of droplet excitation using a projection method. Surface tension measurements compare favorably to literature values for Zirconium, Inconel 625, and Rhodium, using both modes 2 and 3. Thus, this new method serves as a credible, self-consistent benchmarking technique for the measurement of surface tension

Levitation↗

NSTX-U liquid metal core-edge facility (LMCE)

NSTX-U/LMCE will provide a unique and world-leading research facility to address the primary challenge to delivering economic and timely magnetic fusion energy, namely the need to develop a power and particle exhaust and first-wall system that can withstand very high edge heat fluxes, maximize energy confinement, and avoid the production of large masses of solid eroded first-wall material. The NSTX-U/LMCE facility will assess the ability of liquid metals (LMs) – especially liquid lithium – to provide a new boundary condition for magnetic fusion systems, to extend the lifetime of the plasma facing components (PFCs) and improve core plasma confinement. Such capability is needed to establish the basis for next-step fusion facilities including fusion pilot plants, and to maintain U.S. world leadership in core-edge integration research. NSTX-U/LMCE will leverage the ability to generate very high divertor perpendicular heat flux q⊥ ~ 100MW/m 2 , extensive diagnostics, and liquid-metal-applicable infrastructure of NSTX-U. NSTX-U/LMCE will provide access to a high-confinement plasma core with majority self-driven plasma current, the flexibility to test a range of liquid metal divertor concepts, access to a range of separatrix collisionalities (from high to very low), and the ability to controllably vary the first-wall temperature to vary the plasma- wall interaction physics on liquid lithium components. Further, NSTX-U/LMCE will utilize more reactor-relevant high-Z refractory-metal PFC substrates. With these capabilities the NSTX-U/LMCE facility will explore the full continuum of core-edge solutions ranging from high core radiated power, to conditions with radiative losses concentrated in the scrape-off layer (SOL), and ultimately low recycling conditions. The low collisionality SOL that may be accessible in the low recycling regime is relatively unexplored and will require a kinetic treatment of the edge, which can be addressed theoretically, and with experiments in LTX-β. Additional smaller-scale preparatory R&D facilities will be required to reduce the risk of premature technical/engineering failure of liquid metal systems implemented in NSTX-U. The NSTX-U/LMCE facility aligns very well with recommendations in the FESAC Long-Range Plan and NASEM Pilot Plant reports and the Bold Decadal Vision, will be unique in the world program throughout the next decade, and is garnering private company interest in utilizing NSTX-U/LMCE for development of LM PFCs.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Recent progress in the development of liquid metal plasma facing components for magnetic fusion devices

One of the most critical challenges for future fusion reactors is to develop longevity plasma-facing components (PFCs) exposed to extremely high heat and neutron loads. As opposed to those employing solid metals, PFCs with flowing liquid metals (LM) have shown self-healing, heat removal and good impurity control capabilities, all essential to fusion devices. Recently, significant progress in LM-PFC development has been reported globally, with data from several magnetic fusion devices. These studies reveal that LM-PFCs can endure extreme heat fluxes while maintaining plasma compatibility. New design concepts have been proposed and numerically analyzed, advancing models for liquid PFCs in future reactors. Despite existing technical challenges, these developments suggest that LM-PFCs hold promise for future fusion applications.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Studies of cycles for liquid-metal magnetohydrodynamic generation of power

Studies of liquid-metal magnetohydrodynamic power cycles indicate that the overall efficiency of a binary cycle, employing a liquid-metal topping cycle and a bottoming steam cycle, may reach 60 percent. Details of analyses and data on cycles are presented, and the commercial potential of the binary cycle is discussed.

Lee, K.↗