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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Mass transport in a highly immiscible alloy on extended shear deformation

Forced mixing to a single phase or supersaturated solid solution (SSS) and its prerequisite microstructure evolution in immiscible systems has been a focus of research for both fundamental science and a variety of applications. Controlling the formation of SSS by shear deformation assisted processing could enable a material design beyond conventional equilibrium microstructure in immiscible systems. Here, a highly immiscible (mixing enthalpy of ~ 20 kJ·mol -1 ) Cu-50 at. % Cr binary alloy was employed to investigate the microstructure evolution and localized tendencies of SSS during severe shear deformation. The present results demonstrate distinctive microstructure refinement process in each phase and how they lead to localized SSS as a function of shear strain. Preferential dynamic recrystallization occurs in the softer Cu phase due to strain localization, leading to substantial grain refinement. The refinement of Cr phase in the top-most layer, however, is enabled by the progressive evolution of grain lamination, splitting, and fragmentation as a function of shear strain. The eventual SSS is found to be strongly dependent on the local environments that affect the dislocation activity, including the level of microstructure refinement, the interfacial orientation relationship, hardness difference, and supposed stability of oxidation. Ab initio simulations comfirm that it is more favorable to oxidize Cr than Cu at incoherent Cu/Cr interfaces which then limits the mass transport on an incoherent boundary. Our results shed light on the underpinning mechanism for non-equilibrium mass transport in immiscible systems upon severe deformation that can be applicable to a variety of processing techniques aimed at producing immiscible alloys with superior mechanical properties.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Mass transport in nanoarray monolithic catalysts: An experimental-theory study

Reducing the mass transfer resistance globally of a catalyst is a key to enhancing the catalytic reaction kinetics and fully utilizing the catalyst activity. Despite the success in tailoring the external mass transfer in the widely studied washcoat monoliths, the internal mass transfer resistance is difficult to be reduced due to the requirement of increasing macroporosity while maintaining high specific surface area and mechanical stability. Therefore, nanostructured array-based monolithic catalysts (nanoarray catalysts) have been developed in the past decade as a promising class of structured catalysts that may complement or substitute washcoat catalysts. This work fundamentally elucidates the enhanced mass transport properties of the nanoarray monolithic catalysts by a combination of experimental measurements and theoretical modeling. Using a low-dimensional model, the relative contributions of resistances were quantified in terms of chemical kinetics, internal and external mass transfers based on a probe model of C2H4 oxidation over the TiO2 supported Pt-based monolithic catalysts. The nanoarray catalysts displayed a lower internal mass transfer resistance than the washcoat counterparts as a result of the high macroporosity and small thickness of nanoarray layers. Finally, the nanoarray configuration provides a new pathway towards designing high-performance monolithic reactors and catalysts with low internal diffusion limitations for various gas phase reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Effects of Supercritical CO 2 Injection on the Shale Pore Structures and Mass Transport Rates

Characterizing the pore structures and transport properties of low-permeability shales is critical for evaluating these formations as potential seals or storage sites for geological CO 2 sequestration. Here, we use low-pressure gas adsorption in conjunction with nuclear magnetic resonance (NMR) to characterize the pore-size distribution of shales before and after injection of supercritical CO 2 . Nitrogen gas was used as the detecting phase for the adsorption experiments and pentane liquid was used for the NMR experiments. We also performed time-resolved NMR and gravimetric microbalance measurements to observe mass transport during desaturation. We use these data to estimate the self-diffusion coefficient of pentane and changes in the saturation state of the pore network. We analyzed samples with a range of compositions from the Wolfcamp shale before and after exposure to supercritical CO 2 for 3 days. Integrating the gas adsorption and NMR data shows how supercritical CO 2 injection alters the pore-size distribution for pore sizes <1 nm to 1 mm. Finally, our results provide insights on how the pore structure and mass transport properties of different shale lithologies may evolve during storage of supercritical CO 2 .

58 GEOSCIENCES↗
NASA NTRS1993

Advances in Studies of Electrode Kinetics and Mass Transport in AMTEC Cells

Previous work reported from JPL has included characterization of electrode kinetics and alkali atom transport from electrodes including Mo, W, WRh x (Mn), in sodium AMTEC cells and vapor exposure cells; and Mo in potassium vapor exposure cells. These studies were generally performed in cells with small area electrodes (about 1 to 5 cm 2 ), and device geometry had little effect on transport. Alkali metal diffusion coefficients through these electrodes have been characterized, and approximate surface diffusion coefficients were derived in cases of activated transport. A basic model of electrode kinetics and transport at the alkali metal vapor/pourous metal electrode/alkali beta"-alumina solid electrolyte (BASE) three phase boundary has been proposed which accounts for electrochemical reaction rates with a collision frequency near the three phase boundary and tunneling from the porous electrode partially covered with adsorbed alkali metal atoms. The small electrode effect in AMTEC cells has been discussed in several papers, but quantitative investigations have described only the overall effect and the important contribution of electrolyte resistance. The quantitative characterization of transport losses in cells with large area electrodes has been limited to simulations of large area electrode effects, or characterization of transport losses from large area electrodes with significant longitudinal temperature gradients. This paper describes new investigations of electrochemical kinetics and transport, with four 14.4 cm 2 WPt 3.5 electrodes, including the influence of electrode size on the mass transport loss in the AMTEC cell. These electrodes exhibit very slow sintering, as well as excellent sodium transport properties, making them attractive candidates for AMTEC power conversion use. However, the facile sodium transport in WPt 3.5 electrodes makes characterization of the transport process difficult.

electrode↗
NASA NTRS1979

Energy and mass transport in the thermosphere

Examples illustrating the effects of large scale energy and mass transport in the thermosphere discussed include: (1) The seasonal variations reveal temperature, composition, and ionospheric anomalies involving energy exchange between the thermosphere and mesosphere. (2) The midnight temperature maximum in the thermosphere is interpreted as a signature of tidal waves emanating from the mesosphere and momentum coupling associated with ion drag. (3) The ionospheric storm in the F region illustrates the intricate effects of large scale atmospheric winds driven by magnetospheric energization processes. (4) Atmospheric signatures of Joule heating and electric field momentum coupling are markedly different.

Mayr, H. G.↗
NASA NTRS2008

Energy and Mass Transport of Magnetospheric Plasmas during the November 2003 Magnetic Storm

Intensive energy and mass transport from the solar wind across the magnetosphere boundary is a trigger of magnetic storms. The storm on 20-21 November 2003 was elicited by a high-speed solar wind and strong southward component of interplanetary magnetic field. This storm attained a minimum Dst of -422 nT. During the storm, some of the solar wind particles enter the magnetosphere and eventually become part of the ring current. At the same time, the fierce solar wind powers strong outflow of H+ and O+ from the ionosphere, as well as from the plasmasphere. We examine the contribution of plasmas from the solar wind, ionosphere and plasmasphere to the storm-time ring current. Our simulation shows, for this particular storm, ionospheric O+ and solar wind ions are the major sources of the ring current particles. The polar wind and plasmaspheric H+ have only minor impacts. In the storm main phase, the strong penetration of solar wind electric field pushes ions from the geosynchronous orbit to L shells of 2 and below. Ring current is greatly intensified during the earthward transport and produces a large magnetic depression in the surface field. When the convection subsides, the deep penetrating ions experience strong charge exchange loss, causing rapid decay of the ring current and fast initial storm recovery. Our simulation reproduces very well the storm development indicated by the Dst index.

Fok, Mei-Chging↗
NASA NTRS1988

On the mass transport properties of the GeSe-GeI4 system under normal and reduced gravity conditions

Previous work on the mass transport rate of the GeSe-GeI4 system has been reevaluated using the mass spectrometric results of Buchan and Rosenberger (1987), and considering the presence of GeSe(s) and GeSe2(s) phases in the source material. The present transport rate study confirms the previously derived dominance of the sublimation of GeSe at lower pressures of GeI4, and of chemical vapor transport at higher pressures of GeI4. It is noted that experimentally observed flux anomalies are model-independent.

Palosz, Witold↗
NASA NTRS1985

Thermophoretically enhanced mass transport rates to solid and transpiration-cooled walls across turbulent (law-of-the-wall) boundary layers

Convective-diffusion mass transfer rate predictions are made for both solid wall and transpiration-cooled 'law-of-the-wall' nonisothermal turbulent boundary layers (TBLs), including the mechanism of thermophoresis, i.e., small particle mass transport 'down a temperature gradient'. The present calculations are confined to low mass-loading situations but span the entire particle size range from vapor molecules to particles near the onset of inertial ('eddy') impaction. It is shown that, when Sc is much greater than 1, thermophoresis greatly increases particle deposition rates to internally cooled solid walls, but only partially offsets the appreciable reduction in deposition rates associated with dust-free gas-transpiration-cooled surfaces. Thus, efficient particle sampling from hot dusty gases can be carried out using transpiration 'shielded' probe surfaces.

Gokoglu, Suleyman A.↗
DOE OSTI2025

Autocorrelation and Multifractal Detrended Fluctuation Analyses Reveal Superdiffusive Mass Transport in Solvent-Filled Nanoporous Media

Fluorescence fluctuation spectroscopy experiments were conducted to better understand the complex mass transport dynamics of organic molecules in liquid-filled nanoporous media. Anodic aluminum oxide (AAO) membranes incorporating 10 and 20 nm diameter cylindrical pores were employed as model materials. Nile red (NR) dye was used as a fluorescent tracer. The dye was dissolved separately in ethanol and toluene at a concentration of 20 nM and used to fill the membrane nanopores. Confocal fluorescence microscopy was employed to capture photon intensity time series data reflecting apparent diffusion of the dye within the pores. Autocorrelation of these data revealed that NR diffusion within the membranes occurred over a broad range of time scales. The autocorrelation decays were fit to a model for one-dimensional diffusion incorporating both fast and slow components having apparent diffusion coefficients, D f and D s , differing by a factor of ∼100. The fast mechanism was attributed to hindered bulk-like diffusion in the central pore cavity, while slow diffusion likely involved absorption of the dye to the pore surfaces. Unfortunately, important evidence of diffusion anomalies is lost in the broad autocorrelation decays obtained. The method of multifractal detrended fluctuation analysis (MF-DFA) was applied to the same data as a means to overcome this limitation. MF-DFA revealed that time series acquired from within the nanopores were multifractal and exhibited evidence of anomalous superdiffusion, likely resulting from the participation of a desorption-mediated diffusion mechanism. Monte Carlo simulations of time series modeling desorption-mediated diffusion in cylindrical nanopores provided support for this assignment. Here, the new knowledge gained affords an improved understanding of hydrocarbon dynamics within nanoporous oil and gas shales.

Diffusion↗
DOE OSTI2022

Decoupling mass transport and electron transfer by a double-cathode structure of a Li-O 2 battery with high cyclic stability

Aprotic lithium-oxygen (Li-O 2 ) batteries have attracted extensive attention due to their ultrahigh theoretical energy density. However, slow and undesired electron transfer during cathodic reactions causes low cyclic stability in these batteries. Here, in this paper, we demonstrate that O 2 mass transport and electron transfer for cathodic reactions in Li-O 2 batteries could be decoupled by a double-cathode structure that efficiently enables stable electron transfer between the cathode and Li 2 O 2 /O 2 . This resolves various side reactions and slow Li 2 O 2 reaction kinetics issues in conventional Li-O 2 batteries, leading to stable operation of the cell for nearly 2 months at a capacity of 0.2 and 5 mAh cm -2 , with more than 4- and 10-fold increases in cycle life when compared with single-cathode batteries. These remarkable improvements in the cyclic stability of Li-O 2 batteries with double cathodes provide an interesting concept for improving the operational stability of other metal-rechargeable batteries with conversion-type chemistry.

25 ENERGY STORAGE↗
DOE OSTI2022

Exponential time differencing scheme for mass transport and depletion in molten salt reactors

This work extends the capability previously shown for addressing the problem of computing depletion and mass transport calculations in molten salt reactors (MSRs) by calculating matrix exponentials. Additional algorithms are implemented to compute the matrix exponential and the action of the matrix exponential on a matrix. These algorithms include two methods based on the Pade approximation, a Taylor series method, and three methods based on Cauchy's integral formula. In addition to the added matrix exponential solvers, a variable-order total variation diminishing scheme is applied to the convective flux approximation to provide enhanced accuracy. Finally, a simplified MSR problem is shown for each of the exponential time differencing solvers along with classical backwards differencing integrators. The results show excellent convergence for exponential time differencing methods. Computation time is a key element for selecting the optimal solver in these problems, and this work shows that Pade and Cauchy-based solvers may provided the fastest and most accurate solutions. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2024

Radionuclide tracing based in situ corrosion and mass transport monitoring of 316L stainless steel in a molten salt closed loop

In the study, we report an in situ corrosion and mass transport monitoring method developed using a radionuclide tracing technique for the corrosion study of 316L stainless steel (316L SS) in a NaCl–MgCl 2 eutectic molten salt natural circulation loop. This method involves cyclotron irradiation of a small tube section with 16 MeV protons, later welds at the hot leg of the molten salt flow loop, generating radionuclides 51 Cr, 52 Mn, and 56 Co at the salt–alloy interface. By measuring the activity variations of these radionuclides at different sections along the loop, both the in situ monitoring of the corrosion attack depth of 316L SS and corrosion product transport and its precipitation in flowing NaCl–MgCl 2 molten salt are achieved. While 316L SS is the focus of this study, the technique reported herein can be extended to other structural materials being used in a wide range of industrial applications.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Gastight rotating cylinder electrode: Toward decoupling mass transport and intrinsic kinetics in electrocatalysis

Abstract Decoupling and understanding the various mass, charge, and heat transport phenomena involved in the electrocatalytic transformation of small molecules (i.e., CO 2 , CO, H 2 , N 2 , NH 3 , O 2 , and CH 4 ) is challenging but it can be readily achieved using dimensionless quantities (i.e., Reynolds, Sherwood, Schmidt, Damköhler, Nusselt, Prandtl, and Peclet Numbers) to simplify the characterization of systems with multiple interacting physical phenomena. Herein we report the development of a gastight rotating cylinder electrode cell with well‐defined mass transport characteristics that can be applied to experimentally decouple mass transfer effects from intrinsic kinetics in electrocatalytic systems. The gastight rotating cylinder electrode cell enables the dimensionless analysis of electrocatalytic systems and should enable the rigorous research and development of electrocatalytic technologies.

Jang, Joonbaek↗
NASA NTRS1990

Viscosity and mass transport in nonuniform Keplerian disks

A quantitative formalism for Keplerian particulate disk dynamics having its basis in a heuristic description of viscous transport is presently applied to the case of a ring with optical thickness radial gradient. A steady-state velocity distribution solution directly yields both the radial mass transport and the viscosity. The analytical method employed involves the solution of a novel form of the Krook equation through the separation of the phase-space collisional-products distribution into a symmetrical component and a delta function-approachable remainder. While this model is simplified for the case treated, its general approach may be extended to less artificially restricted cases.

Ojakangas, G. W.↗