Search NASA⌕ Search

SEARCH · Search NASA

Results for “materials outgassing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Study of Poly(ether ketone ketone) (PEKK): Outgassing Characteristics and Likely Residual Synthesis Impurities

In May-June, 2020, a study was conducted to characterize the outgassing properties of a series PEKK (Poly(ether ketone ketone)) samples using cryo-GC/MS headspace analysis. Three sets of samples were interrogated: sample group 1 consisted of 2 additively manufactured PEKK samples (PEKK "ole and "New") prepared by KCNSC from powder material from Solvay Specialty Polymers USA, LLC. Sample groups 2 and 3 consist of 5 PEKK powder types (used as feedstock for additive manufacturing processes) and 4 additively-manufactured PEKK material lots, respectively. Contrary to expectations, all samples of PEKK material were observed to outgas sulfur-containing compounds. Other analyses (EDS/EMA, GC-TOF/MS of PEKK sample extractions) confirmed the presence of sulfur in the PEKK bulk material. Specifically, Diphenyl sulfone (used as a reagent or high-temperature solvent in the synthesis of Polyaryletherketone or PAEK polymers) was observed in three of the powders and in both the PEKK "Old" and "New" samples, suggesting that the source of the sulfur can be traced to impurities in the material left over from the synthesis process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Analysis of outgassing from natural fibers VIP core to improve their long-term performance

Buildings are the largest consumers of energy accounting for 40% of the total energy use in the US. The use of vacuum insulation panels (VIPs) with large R/in. values offers unique benefits in reducing building energy consumption such as providing excellent thermal insulation with significantly less thickness compared to convention insulation materials. Natural fibers are promising VIP core material because of their low cost and offer good thermal performance. However, the long-term thermal performance of the VIPs with natural fiber core can be compromised because of off-gassing from natural fibers. In this study, we utilize a mass spectrometer based analytical technique to investigate the composition of off-gassing from natural fibers. The result can be used to determine the optimal getters to help maintain the vacuum and improve the long-term thermal performance of the VIP for building insulation.

Tamraparni, Achutha [ORNL] (ORCID:0000000299658544↗
DOE OSTI2023

Refined Outgassing Model for the LiH/LiOH System

Previous models for H 2 and H 2 O outgassing from moisture exposed LiH specimens were based on temperature programmed desorption/decomposition (TPD) experiments and analyses that yielded kinetic descriptions which were specific to defined sets of initial conditions. Subsequently the inputs to the kinetic models were refined to correlate with infrared spectra of the adsorbed species. In this current enhancement, better agreement between prediction and experiment was obtained through: 1) refining the reaction mechanisms for some of the decomposition reactions; 2) developing the potential range of kinetic parameters by simultaneous fitting of all the TPD outgassing curves obtained at different heating rates; and, 3) limiting the scope of possible kinetic parameters to an optimized subset by matching the outgassing prediction curves at 3 different temperatures to the outcomes from the accurate but cumbersome, non-intuitive, and effort demanding isoconversional analysis.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Overview of advanced plasma-facing materials testing for Fusion Pilot Plants at DIII-D

Characterization and testing of advanced plasma-facing materials (PFMs) for Fusion Pilot Plants (FPP) is being conducted at the DIII-D National Fusion Facility through the ongoing two-year FPP Candidate Materials Thrust. Year one tested 17 novel materials utilizing the Divertor Materials Evaluation System (DiMES), with samples analyzed pre- and post-experiment via SEM, EDS, and confocal microscopy. Repeatable reference discharges were developed to ensure uniformity between experiments, including a new strike-point rastering scenario to provide more uniform heat/particle flux across DiMES during ELMing H-mode discharges. Various sample geometries and temperatures were used to achieve FPP-relevant conditions, including samples angled 10° towards the incident plasma flux and pre-heating up to 500 °C. The first exposure of liquid lithium (Li) capillary porous structures in a tokamak demonstrated uniform emission of Li vapor and suppression of Li droplets in H-mode when preheated to 350 °C. Dispersoid-strengthened W with 1 wt% TaC, TiC, and ZrC exposed to H-mode showed cracking and dispersoid ejection for all varieties except TiC, providing a clear down-selection. Ultra-high temperature ceramic materials TiB 2 and ZrB 2 showed minimal degradation under L-mode exposure. Silicon carbide (SiC) fiber composites showed arcing along edges, while CVD SiC remained pristine. Atmospheric plasma-sprayed W and SiC coatings endured H-mode exposure without macroscopic delamination; SiC exhibited granular ejection, while W showed increased outgassing. Additional W-based alloys were stress tested in H-mode, including Ni-based W heavy alloys, W f SiC f /W composites, W multi-principle element alloys, and functionally-graded W/SiC, to varying degrees of success.

DIII-D↗
DOE OSTI2022

Requirements for Soldering Fluxes Research using the B-53 Test Board

IPC J-STD-004B standard prescribes general requirements for the classification and testing of soldering flux for high qualify interconnections. This standard defines the classification of soldering materials through specifications of test methods and inspection criteria. The materials include liquid flux, paste flux, solderpaste flux, solder preform flux, and flux-cored solder. This research will use the proposed IPC-53 Surface Insulation Resistance (SIR) test patterns by means of an open comb (2D) and closed comb (3D to simulate a component over the comb pattern). The 2D open comb has uniformity of conductor spacing, sheet resistance, and flux outgassing. The 3D-closed comb simulates the effect of leadless or bottom-terminated components, which have non-uniform sheet resistance and flux outgassing. The response variables will include SIR testing and visual imaging. The objective is to investigate IPC test method improvements for characterizing soldering fluxes when using leadless components with narrow pad-to-pad spacing.

Diamond, Louis↗
DOE OSTI2024

Thermomechanical Degradation of Sintered Copper Under High-Temperature Thermal Shock

The need for reliable bonded interface materials is critical to realize the performance benefits of wide-bandgap devices in power electronics modules, especially in operating temperatures greater than 150 degrees C. In this paper, we investigate the thermomechanical performance of sintered copper (Cu) as a large-area attachment, bonded between Cu baseplates and active-metal-bonded substrates, under accelerated thermal shock (-40 degrees C to 200 degrees C) conditions. In the fabrication phase of the samples, we used different stencil patterns and found that the grid and stripe patterns resulted in a better outgassing of the residual organics during the sintering process, thereby ensuring a substantially improved bond quality compared to a full-area print. The paste consisted of Cu microflakes, and we performed sintering using a Budatec SP300 sintering press at 275 degrees C with 15 MPa of bonding pressure for 5 minutes in a nitrogen atmosphere. Under accelerated experiments, we monitored the degradation of the sintered Cu bond in the samples through C-mode scanning acoustic microscope (C-SAM) images. To quantify the defect percentage in C-SAM images, we investigated image denoising techniques to exclude the pattern prints. Finally, we cross-sectioned a sample and obtained scanning electron microscope images, which revealed adhesive fracture as the dominant failure mechanism.

ADVANCED PROPULSION SYSTEMS,INORGANIC, ORGANIC, PH↗
DOE OSTI2020

Effect of a Cr-rich surface layer on D retention in various RAFM steels

In this work, deuterium (D) retention is compared between various reduced-activation ferritic/martensitic steels, including CLF-1, Eurofer, F82H, and Rusfer, exposed to pure D plasma (ion flux ~1.5–2 × 10 21 m -2 s -1 , fluence, ϕ D , ~1 × 10 25 m -2 , sample temperature ~373 K, and incident ion energy ~100 eV). It is found that there is a large difference (up to ~30x) in the D retention between CLF-1 and F82H even with the same plasma exposure condition and similar nominal composition. The ϕ D dependence of the D retention exhibits a peculiar, counterintuitive feature: the D retention decreases with an increase in ϕ D from 2 × 10 23 m -2 to 1 × 10 25 m -2 . Surface analyses reveal that a Cr-rich surface layer is formed during outgassing at 773 K for 1 h before plasma exposure, and that there exists a clear correlation between the D retention and the Cr content in the surface layer.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Modeling moisture outgassing from silica-filled silicones with the generalized outgassing kinetics

Even though a generalized moisture outgassing modeling has been established and published in a peer-reviewed venue for as-received silica-filled silicones, it is still not yet intuitive for use in engineering/scientific applications. A simplification of the mathematics down to a practical level and illustration of how to do it would be beneficial to the practitioners in the field. In this report, simplified and more intuitive demonstrations of how to use the generalized outgassing kinetics for the prediction of H 2 O release from as-received and previously vacuum-baked silicones will be illustrated.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Development of pebble-based extruded carbon rods for extreme plasma heat flux environments

This work presents first experiments toward the development of continuously renewable (extrudable) pebble-based carbon rods for use as plasma-facing components in extreme steady-state plasma flux environments. The primary envisioned application of this work is a first wall that can survive long-term in future magnetic fusion power reactors while also improving recovery of the reactor fuel (tritium and deuterium atoms). Bench tests applying extreme steady-state front-surface heat loads of up to 50 MW/m 2 are presented. Continuous pebble rod front-surface recession and intact pebble recovery are successfully demonstrated, at a rate of order 0.2 cm/s. Numerical simulations of the pebble rod front-surface recession are able to match observations reasonably well, indicating that the recession mechanism can be understood as occurring due to pebble thermal expansion and resulting shock and cracking of the inter-pebble binder. Tests of the pebble rod extrusion demonstrate that friction between the rods and the stainless-steel extrusion channel is tolerably low (<50 N for the expected channel length) over a wide range of temperatures. Front-surface outgassing rates below 1000 Torr L/s/m 2 are achieved, believed to be sufficiently low for use in magnetic fusion reactors. In conclusion, initial parametric scans over pebble rod size and binder fraction to vary front-surface recession rates are presented.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Kinetics of TATB and LX-17 Decomposition by Thermal Analysis

The kinetics of TATB decomposition have been investigated by thermal analysis (thermogravimetric analysis, TGA, and differential scanning calorimetry, DSC) at both LLNL and the University of Alabama Birmingham. This report summarizes progress in understanding from those results within the context of identifying the global reaction mechanism, i.e., sequential, autocatalytic, competitive, or some mixture thereof. A particularly important issue is how pressure affects both the reaction rate and enthalpy. The effect of pressure helps identify dominant mechanisms and construct and constrain a global mechanism that will work over a wide range of conditions. This memorandum is simply a snapshot of current progress and not a definitive interpretation. I have written it to organize work of others and my interpretations in a systematic manner with the intention of stimulating further advances in understanding. SDT data comes from Jen Montgomery at LLNL, and high-pressure DSC comes from Victoria Stanford and Sergey Vyazovkin at University of Alabama at Birmingham. Major observations and conclusions, some new and some not, are (1) outgassing below 150 °C prior to decomposition releases adsorbed water vapor, (2) outgassing between 150 and 250 °C may come primarily from intercalated water (3) initial thermal decomposition above 250 °C or so involves dehydration of TATB to create furazans, (4) quickly heating to higher temperatures in open pans with flowing gas leads primarily to TATB evaporation between 270 and 390 °C, (5) using a pinhole crucible at atmospheric pressure largely eliminates TATB sublimation, (6) at typical thermal analysis heat rates, the main stage of decomposition is described by a single mass loss process, and decomposition of residual material is spread over a wide range of thermal severity, (7) at typical thermal analysis heat rates and constant temperatures above 300 °C, heat release occurs in two overlapping peaks, with the first one a little faster than mass loss and the second on a little slower than mass loss, (8) total heat release increases significantly with heating rate and substantially with increased pressure, and (9) isothermal experiments at 340 °C indicate that the first exotherm increases by more with LX-17 than TATB, which suggests a possible chemical role of Kel-F decomposition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Power Electronics Materials and Bonded Interfaces - Reliability and Lifetime

The need for reliable bonded interface materials is critical to realize the performance benefits of wide-bandgap devices in power electronic modules, especially in operating temperatures greater than 150 degrees Celsius. In this paper, we investigate the thermomechanical performance of sintered copper (Cu) as a large-area attachment, bonded between Cu baseplates and active-metal-bonded substrates, under accelerated thermal shock (-40 degrees Celsius to 200 degrees Celsius) conditions. In the fabrication phase of the samples, we used different stencil patterns and found out that the grid and stripe patterns resulted in a better outgassing of the residual organics during the sintering process, thereby ensuring a substantially improved bond quality than a full-area print. The paste consisted of Cu microflakes and we performed sintering using a Budatec SP300 sintering press at 275 degrees Celsius with 15 MPa of bonding pressure for 5 minutes in a nitrogen atmosphere. Under accelerated experiments, we monitored the degradation of the sintered Cu bond in the samples through C-mode scanning acoustic microscope (C-SAM) images. To quantify the defect percentage in C-SAM images, we investigated image denoising techniques to exclude the pattern prints. Finally, we cross-sectioned a sample and obtained digital microscope images, which revealed adhesive fracture as the dominant failure mechanism.

ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2020

Robust fluorescent calcium coordination polymers as Cu 2+ sensors with high sensitivity and fast response

A three-dimensional (3D) and highly fluorescent calcium-based coordination polymer (Ca-CP) has been synthesized and structurally characterized. Furthermore, built on a strongly fluorescent (FL) chromophore ligand, [Ca(H 2 tcbpe)(H 2 O) 2 ] (1) (H 4 tcbpe = 4',4''',4''''',4'''''''-(ethene-1,1,2,2-tetrayl)tetrakis(([1,1'-biphenyl]-4-carboxylic acid))) is highly luminescent. Photoluminescence (PL) studies indicate that 1 undergoes a bathochromic shift in emission energy from blue to green color upon outgassing or under mechanic force. Notably, 1 exhibits selective FL sensing for Cu 2+ ions with a detection limit (LOD) of 0.064 ppm, far below the U.S. WHO and EPA standard for drinking water. Detailed investigation of the sensing mechanism reveals that uncoordinated COO– groups in 1 play a major role in recognizing Cu 2+ ions.

36 MATERIALS SCIENCE↗
DOE OSTI2024

High-Fidelity Arc-Discharge Model for Hydrogen-Plasma-Smelting-Reduction of Iron Ore

Electrification and use of renewable hydrogen is currently a necessity for decarbonizing the iron-and-steel industry. In this regard, hydrogen plasma smelting reduction (HPSR) is a novel pathway that is being explored for reduction of iron ore. HPSR provides several decarbonization merits compared to conventional blast furnaces. Firstly, the use of renewable hydrogen drastically reduces the CO2 emissions compared to the use of coke. Secondly, renewable electricity in the form of a thermal plasma for making reactive hydrogen species (radicals, ions) are more efficient at reducing iron ore compared to neutral H2. Thirdly, a molten product compatible with downstream processes is obtained from the intense heat transfer from the plasma. However, the scale-up of this technology requires fundamental exploration of hydrogen plasma dynamics and its interaction with complex solid material that include phase changing iron-ore and slag. In this work, we present a first principles continuum scale model for thermal plasmas in Ar/H2 gas mixtures typically used for HPSR. The thermal plasma governing equations for mass, momentum and energy with Lorentz force and Joule heating source terms are solved along with electromagnetic equations for electrostatic and magnetic vector potential. Our solver will be based on Pele, a suite of reacting flow solvers designed for advanced scientific computing architectures (Henry De Frahan et al., Proceedings of SIAM Parallel Processing, 13-25, 2024), and will utilize adaptive mesh generation for enhanced resolutions at locations of intense physicochemical interactions. This study will present the impact of Ar to H2 ratios on excited/dissociated hydrogen species concentrations, plasma temperature and conductivity along with the impact of outgassed species (water, metal vapor, O, OH radicals) from ore surface on gas phase chemistry. Furthermore, the heat and species flux to the surface will be quantified as a function of applied voltages in a transferred arc configuration.

hydrogen plasma↗
DOE OSTI2021

High Dose and Dose Rate 60 Co γ-Irradiation of High-Density Polyethylene

We have irradiated high-density polyethylene ribbons and cylinders to ~200 kGy at a dose rate of ~5 kGy day -1 , using a 60 Co source. The radiolytically-generated gas consists almost entirely of H 2 . Based on the time- and dose-dependence of the outgassing, we have determined the radiation- chemical yield for the evolved H 2 , as well as the diffusion coefficient of H 2 in HDPE. We find that the evolved gas yield G evolved depends on the interplay of sample geometry, experimental timescale, and the diffusion coefficient of H 2 in HDPE. When these factors facilitate completion of diffusion prior to gas quantification, such as for sub-mm-thickness ribbons, we measure a time- and dose-invariant value of G evolved = 0.0076 cm 3 std. H 2 J -1 that is in agreement with literature reports. When sample geometry and experiment timescale do not permit completion of diffusion, we measure a time- and dose-dependent value of G evolved . We have developed a model for the transient outgassing behavior of the cylinders, and fitted it to the experimental data. Based on these fits, we estimate a room-temperature diffusivity of D H 2 /HDPE ≈ 1.67 ± 0.12 x 10 -6 cm 2 s -1 for H 2 in HDPE, in good agreement with literature values. At present, the effects of dose rate and γ-photon energy on HDPE gas yield are not known and require further investigation.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Vacuum-baking provides many advantages for LiH

In vacuum applications, the thermal decomposition of LiOH corrosion on LiH causes undesirable hydrogen outgassing. The quantity of outgassing is dependent on the thermal stability of the corrosion layer, which depends on sample treatment. We have measured the decomposition of LiOH on as-polished LiH and on previously vacuum-baked LiH (i.e., Li 2 O-covered LiH) which both experienced moisture re-exposure.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Side-by-side evaluation of the outgassing rate and ultimate pressure achieved inside tubes made of low-carbon and stainless steel

The hydrogen outgassing rate of a vacuum chamber made of AISI 1020 low-carbon steel was found to be notably smaller than a similar chamber made of AISI 316L stainless steel following heat treatment at 150 °C. When the chambers were baked at 400 °C, the outgassing rate of the 1020 low-carbon steel chamber was approximately 2000 times smaller than that of the 316L stainless-steel chamber. After quantifying hydrogen outgassing rates, vacuum chambers made of 1020 low-carbon steel and 316L stainless steel were heated for a prescribed duration and then pumped with an ion pump and nonevaporable getter pump to reach “ultimate pressure.” The 1020 low-carbon steel chamber reached lower pressures than the 316L stainless-steel chamber. Monte Carlo simulation predictions using the measured hydrogen outgassing rates are in good agreement with the ultimate pressure measurements. Finally, our measurements indicate that low-carbon steel can provide pressures within the extreme high vacuum range (<7.5 × 10 -13 Torr) if care is taken to minimize the surface area contribution from stainless steel.

36 MATERIALS SCIENCE↗